TARGET IIT-JEE

13th ACCELERATION
ADVANCED TEST - 2

ALL INDIA TEST SERIES

ANSWER KEY WITH SOLUTION

PAPER - 2
MATHEMATICS
SECTION A
1.

2.

3.

4.

5.

6.

7.

8.

9.

10.

11.

12.

13.

14.

15.

16.

17.

18.

19.

20.

PHYSICS
SECTION - A
1.

2.

3.

4.

5.

6.

7.

8.

9.

10.

11.

12.

13.

14.

15.

16.

17.

18.

19.

20.

CHEMISTRY
SECTION - A
1.

2.

3.

4.

5.

6.

7.

8.

9.

10.

11.

12.

13.

14.

15.

16.

17.

18.

19.

20.

394 - Rajeev Gandhi Nagar Kota, Ph. No. 93141-87482, 0744-2209671

www. motioniitjee.com , email-info@motioniitjee.com

SOLUTIONS
MATHEMATICS

SECTION A
Single Correct
1.

f(2) = 4a +

Clearly I3 < I2 < I1 in 0,

(D) is correct.

2.

T=

(3e3x 2e 2 x e x ) (e3x e 2 x e x 1)
dx
e3 x e 2 x e x 1
5.

= ln e

3x

2x

e 1 x

ln 2

(12a 8b 6c 6d)
+e
3

2
(6a + 4b + 3c + 3d) + e = 0 + e
3

D
We have y Lim f (cos 3 x cos 2 x ) = x

x 0

ln(8 4 2 1) ln 2 ln 2 0 = ln

11
2

11
ln
11
11
ln 2 = ln
eT = e 4 =
Ans.
4
4

3.

f (2) = e

By Rolles theorem, there exist atleast

one value of x (0, 2) such that f ' (x) = 0

The equation ax3 + bx2 + cx + d = 0

has atleast one real root in [0, 2]

D
We have
ln 2

8b
+ 2c + 2d + e
3

Lim f (sin 2 x sin 3 x ) (Source :Q.B. of Limit

x 0

continuity Q.66)
cos3x cos2x 0

y
(0, 5)

(0, 4)

x2

t f (t) dt x

We have F(x2) =

x 5 ....(1)

(0, 3)

On differentiating both the sides w.r.t. x,

we get
2x (x2) f (x2) = 4x3 + 5x4

12

12

r 1

r 1

Lim f (cos3x cos2x) = 4

x 0

sin2x sin3x 0

5
f (x2) = 2 + x
2

from L.H.S.

....(2)

f (r 2 ) = 2 2 r
5 (12)(13)

= 24 + (15)(13)
2
2

= 24 +

= 24 + 195 = 219

from R.H.S.

Lim f (sin2x sin3x) = 3

x 0

Equation of the line is

4y = 3x

....(1)

3
Equation of line perpendicular to y = x and
4
4
passing (0, 1), is y 1 =
x
....(2)
3

On solving (1) and (2), we get

12

Hence

f (r 2 ) = 219

Ans.

3
y = x
4

r 1

(0, 1)
4.

B
We have ax3 + bx2 + cx + d = 0

ax 4
bx 3
cx 2
Let f(x) =
+
+
+ dx + e
4
3
2
f(0) = e

12 9
,
25 25

x
24 7
,

25 25

394 - Rajeev Gandhi Nagar Kota, Ph. No. 93141-87482, 0744-2209671

www. motioniitjee.com , email-info@motioniitjee.com

x=

12
9
, y=
25
25

8.

A
Assume f (x) = x3 + x so that g (x) = x3; h

24 7
,

Hence image point is

25 25

(x) = x and F (x) = x3

F ' (x) = 3x2

6.

9.

g ( t) =
2 cot1(3t)
2
=

We have ck + bk = a k =

2bc cos b c a 2
2 =
x
2
b

(b c )

1 t
2 cot (3 )
2
2

a 2 sec A
2 = DE
Hence x =
2 ( b c)

=
+ 2 cot1(3t)
2

,
x R)
2

10.

= g (t)
Hence g ( t) = g (t)
g is an odd function.
t

Also

g' (t) =

g' (t) < 0, t R

g is strictly decreasing in ( , )

D
is the angle between the tangent and the
line
Circle with centre (2, 1) and r = 3
perpendicular from centre on 3x 4y = 5 is
p=

2.3 ln 3

7.

a
bc

Also x y = b c k2

1
, x > 0)
x

(As cot1x + tan1x =

F is increasing

2 tan1(3t) (As cot1x

2

= tan1

3x+ 1

D = 3 12 < 0
F ' (x) > 0 x R

(A)

We have g (t) =
2 cot1(3t)
2

3x 2
+x
2

6 45
=1
5

1 ( 3 t ) 2

C
We have y = x3 + x + 16

dy
= 3x2 + 1 = 3x12 1
dx P

sin(90 ) =

1
3

(2,1)

1
cos =
3

2 2
sin =
Ans.
3

p=1
3

line
3x4y=5

2 2

Paragraph for Question Nos. 11 to 12

3x12

y1
x13 x1 16
1 = x =
x1
1

3x13 + x1 = x13 + x1 + 16 2x13 = 16

x1 = 2
Hence slope of line l = 3 (2)2 + 1 = 13 Ans.

11.

12.
(i)

B
We have h''(x) = 6x 4
h'(x) = 3x2 4x + C
As
h'(1) = 0

C=1
So,
h' (x) = 3x2 4x + 1
h(x) = x3 2x2 + x + k
Also
h(1) = 5

k=5

h(x) = x3 2x2 + x + 5
Now h'(2) = 5

394 - Rajeev Gandhi Nagar Kota, Ph. No. 93141-87482, 0744-2209671

www. motioniitjee.com , email-info@motioniitjee.com

The equation of tangent at

M(2, 7) to y = h(x), is
(y 7) = 5(x 2) 5x y = 3

(iii) Also range of

From equation (1), we get a = 2

g(x) = x3 6x2 + 11x + 6
Given f(x) = xg(x) 12x + 1 = x4 6x3
+ 11x2 6x + 1 = (x2 + 1)2 2x2 + 11x2
6x3 6x
= (x2 + 1)2 6x (x2 + 1) + (3x)2
f(x) = (x2 3x + 1)2 = {h(x)}2 (Given)
h(0) = 1
h(x) = x2 3x + 1

f g( x ) = 1, 0, 1

f g( x ) {0, 1}

fog ( x )

Hence range of sin1

= 0,

(i)

Paragraph for Question Nos. 13 to 14

13.

14.

We have g(x) = x3 6x2 + 11x + 6

g'(x) = 3x2 12x + 11

x , 2

8
O

We have h(x) = 2 + 2sin 4x

Clearly h(x) is periodic function with period

and from above graph, the length of a

2
longest i nterval in which the functi on

3
2

y = h(x) is increasing =

=
= .
8
8
8
4
We have h (x) = 4
2 + 2 sin 4x = 4
4x = 2n +

1
1

, and
2
3
3

g'(x) < 0 x 2

Graph of y = sin 4x

(ii)

g'(x) > 0
Y

(i)

= 3(x 2)2 1 = 3 ( x 2)
3

sin 4x = 1]

= (4n + 1)
2
2

x = (4n + 1) , n I
8

Paragraph for Question Nos. 15 to 16

15.

16.

C
We have g(x) = x3 + g''(1) x2 + {3g'(1)
g''(1) 1}x + 3g'(1)
Let g'(1) = a and g''(1) = b then
g(x) = x3 + bx2 + (3a b 1) x + 3a
Differentiating both sides w.r.t. x
g'(x) = 3x2 + 2bx + (3a b 1)
Put x = 1 g'(1) = 3 + 2b + 3a b 1
a = b + 3a + 2 2a + b = 2 .... (1)
g''(x) = 6x + 2b
Put x = 1
g''(1) = 6 + 2b b = 6 + 2b
b=6
.... (2)

1
1
,2

3
3

g(x) monotonically increases for

, and
x , 2
2
3
3

monotonically decreases for

1
1

x 2
,2

3
3

For x [1, 3]
g(x) = (x 1) (x 2) (x 3) + 12
g(1) = 12 and g(3) = 12
By Rolle's theorem in [1, 3] we have, g'(c) = 0
c=2

1
(both (1, 3) )
3

There exists two distinct tangents to the

curve y = g(x) which are parallel to the chord
joining (1, g(1)) and (3, g(3))
For x [0, 4]
g(0) = 6 and g(4) = 18
By LMVT
g' (c) =

18 6
3c2 12c + 11 = 3
40

3c2 12c + 8 = 0 c = 2

2
3

(both (0, 4) )
T here exi st s exactl y two di sti nct
Lagrange's mean value in (0, 4) for y = g(x).

(D)

394 - Rajeev Gandhi Nagar Kota, Ph. No. 93141-87482, 0744-2209671

www. motioniitjee.com , email-info@motioniitjee.com

(ii)

We have h(x) =

x2

3 5

3x + 1 = x
2 4

The curve y = h(x) is an upward parabola,

intersecting x axis at two distinct points.
h(x) has exactly one critical point (i.e. the
vertex) and no any point of inflection.
Also h(x) = 0 x=

cos =

(Q)

3
5

(both (0, 3) )
2
2

C E = 0i j k
1
cos =

D
Here 24 matrices are possible.
Values of determinants corresponding to these
matrices are as follows :

(R)

1 0
4 2 = 2 (4 matrices),
(S)

And 12 more matrices are there, values of

whose determinants are 2, 4, 8.
Possible non-negative values of det. (A) are
2, 4, 8.
Sum of these 24 determinants is 0.
Mod. (det(A)) is least
|A|=2
( n 1)3

OP

and

=2

zero

| c | 8 3

bc
3 | b |2
3| b |

Now, cos = = =
| b| | c|
|b||c|
|c|

CE

3 ( 4)
3
=
8 3
2

5
Hence b ^ c =
Ans.
6

C E = 0i j k

(0,1,1)F

c 2 (2a b ) 3b

| c |2 4 | a b |2 9b 2 6b (2a b)

= 48 + 144 = 192

O P = i j k

E (0,0,1)

= 16 4 = 12

1
16
Now, | 4 A1 | = 16
=
= 2
|A|
8
and

2
3

2 (C) (P)

Given c ( 2a b) 3b

b c b ( 2a b ) 3b

b c 3 | b |2 ....(1)
2

now
a b a 2 b 2 (a b ) 2

Least value of det.(A) is 8

A
Angle between

3 2

| adj (adj (adj (A)) | = A

18.
(P)

= cot1

2 0
1 4 = 8 (4 matrices)

(S)

= cot1
(B) (S)
3
3

O P and O B
i j k and i j 0k

cos =

1 0
2 4 = 4 (4 matrices),

(Q)
(R)

2 2
=

Matrix Match Type

(P)

= cot1(0) (A) (R)

2
= C A and C E ,
C A = i j 0k
=

h(x) = 0 has exactly two distinct real

zeroes in (0, 3).

(C)
Every quadratic function has exactly one
tangent on x-axis or parallel to x-axis.

17.

0 1 1
=0
3 2

D(1,0,1)
P(1,1,1)

19.

B
Given

a b b c c a cos

d a d b d c cos
Since a , b and c are equally inclined like
and

O(0,0,0)

C (0,1,0)

A(1,0,0)
B(1,1,0)

the 3 edges emanating from the vertex of a

tetrahedron hence they are non coplanar.

394 - Rajeev Gandhi Nagar Kota, Ph. No. 93141-87482, 0744-2209671

www. motioniitjee.com , email-info@motioniitjee.com

Let

d x a yb zc
(S)

dot with

5
8

If = cos1 cos =

d a x y cos z cos ....(1)

dot with b d b x cos y z cos ....(2)

as d a d b d c cos

=1+2

5
5
9
=1+
=
8
4
4

cos2 =

9
3
=
12
4

d a b c

20.
(P)
(Q)
(R)

....(4)

3 2 2 1 1 1
A=
7 5 0 4 2 1

1
3 cos

Take dot with

a in eq. (4)

cos = (1 + 2 cos )

(P)

3 cos2 = 1 + 2 cos

....(5)

Now if =

3 cos2 = 1

cos2 =

1
1
cos =
3
3

If =

(R)

then
3
=

cos

If = cos1

cos2 =

cos2 =

2 0 1
16 3
3 8 4 = 24 5

Tr(A) = 16 + (5) = 21 Ans

Clearly

a a

[ u v w ] = a b
a c

a b
b b

bc

12

0

Now [a b c] =
1

1
(2)
3

= cos1

(Q)

2 2 1 1 1
3 0 4 2 1

= 7

(S)

2
3

1
1
0
=
4 1

(3)

cos =

1
4

1 1
= cos
= (1)
2
2 4

= 7

1
[substituting the value of =
]
3 cos

3
=
6
2

C
= 0, 3, 3
no. of positive solution
is 1 which is x = 3
Coefficient of x in D(x) = D (0)
Given PAQ = R
AQ = P1R
A = P1RQ1
1

Take dot with d in eq. (4) 1 = (3 cos )

c d c x cos y cos z ....(3)

(1) (2)
x(1 cos ) = y(1 cos )

x=y
(2) (3)
y(1 cos ) = z(1 cos )

y=z
Hence x = y = z = (say)

= cos

(4)

dot with

5
then 3 cos2
8

a c

b c [a b c ] = [a b c ]3 ;

c c

3 2 0
3 2 12
2
3

3 0
1
3 1 =
3 32
4
2 3

4 32
=
4

1
2

394 - Rajeev Gandhi Nagar Kota, Ph. No. 93141-87482, 0744-2209671

www. motioniitjee.com , email-info@motioniitjee.com

PHYSICS
6.

SECTION - A
1.

D
2Q
Q
E = 2A 2A
0
0

D
7V
= 1 A.
7
Current flows in anticolockwise direction in
the loop.

i=

Therefore
2.

(ii)

2Q Q
F = 2A 1
0

Q2
=
A 0

C
50
20 R
Potential drop across
R = Potential drop
across AB
50
R 30

20 R
R 30
i

B
IG = 10 mA
G = 10
S (I IG) = IGG
where S is shunt is parallel
S = 0.1

4.

A
Case I
Rg

3 Q
2 Cd
3Q
Ed =
= V
2C
F = EQ/2

E =

0 1 2 1 2 5 V1
V1 = 9V

3.

F =
(iii) Energy=

I
I
I 4
5
5

3Q

E = 2A
0

Q2
A 0

1
1
0 E 2 Ad = 0
2
2

7.

B
Equivalent circuit is

8.

3Q
9 Q2
2cd Ad =
8 C

R g 16

Rearrange the circuit

Case II
42
16I1
I I1
6

I1 I /13
so decrease in current to previous current
I /5 I /13
8

I/5
13
5.

B
In figure all resistance are connected in
parallel.

Ceq =
9.

8
F
3

D
Q1 Q2
V = C C = 0
1
2

C
2R R / 2
and curre nt i n al l
2R R / 2
resistance flow from positive terminal of
battery (means A end) to negative terminal
of battery (means B end).
So R e q

Final potential difference = zero

Final charge = Zero
Charge flow 30 c from A to D

394 - Rajeev Gandhi Nagar10.

Kota, APh. No. 93141-87482, 0744-2209671
www. motioniitjee.com , email-info@motioniitjee.com

18.

D
AQ;BR;CR;DR
When switch S is opened then right side
resistance R which was short circuited earlier
contributes to equivalent resistance. Hence,
equivalent resistance across the battery
increases, power dissipated by left resistance
R decreases, voltmeter reading decreases and
ammeter reading decreases.

19.

T he

e qui val e nt

cap aci t anc e

C eq

2C 6C 6C 4C

= 3.9 C
2C 6C 6C 4C
11.

C
A P ; B R ; C Q ; D P
The initial charge on capacitor=CVi=12 C=2C
The final charge on capacitor=CVf=14C=4C
Net charge crossing the cell of emf 4V is
qf qi = 4 2 = 2 C
The magnitude of work done by cell of emf 4 V
is
W = (qf qi) 4 = 8 J
The gain in potential energy of capacitor is
1
1
2
2
2
2
U= C (Vf Vi ) = 1 [4 2 ] J = 6 J
2
2
Net heat produced in circuit is
H = W U = 8 6 = 2 J
20.

B
A P,S ; B Q,R ; C Q ; D P

A
RA

R .R V
R
R RV

12.

A
RB = R + RG > R

13.

14.

15.

16.
17.

A
C
AQ;BS;CS;DQ
Since current in both rods is same.

When switch S1 is closed

When switch S2 is closed

n1ev1A1 n2ev2 A2

v1 n2 A2 1 2

1
v2 n1 A1 2 1

(B) E J

(C)

I
A

When switch S3 is closed

E1 1 A2 2 2

4
E2 2 A1 1 1

p.d. across rod I E1 AB

4
p.d. across rod II E2 BC

Average time taken

by free electron to
move from A to B
AB v2

1
v1 BC
(D) Average time taken
by free electron to
move from B to C

When switch S4 is closed

394 - Rajeev Gandhi Nagar Kota, Ph. No. 93141-87482, 0744-2209671

www. motioniitjee.com , email-info@motioniitjee.com

CHEMISTRY

SECTION - A

1.

2/5

V = constant

P3/5 V = constant
or
or
14

5/3

PV

= constant

PV = constant

for He
3

CH 3CH=CHCHO +CH3CHO
O

Thus, process is adiabatic Q = 0.

CH3 CH CH 2 CH = CH CHO
6.

OH

C
AB isothermal expansin (T = const.)

CH3 CH CH 2 CH = CH CHO

V P

/H2O

Option (A) reted out

14

CH3 CH = CH CH = CH CHO

BC isochoric (V = const.)

Major product

T P
Option (B) ruted out because be does
neat pass thorugh origin
2.

DA isothermal Process (P = const.)

V T
3.

Only (C) follow

C
WAB = 1 R 300
7.

WAB = 1 R(600)

A
H2O(l)

4.

H2O(s)

1atm

1atm

(A) 34 : q = 0 w < 0 U < 0

273k

273k

(B) 23 : w = 0

it is the equilibrium condition for

(C) 41 : w = 0, U = q (pressure is de-

H2O(s) & H2O(l)

creasing temperature is decreasing

then in the given eq.

(D) 12 : V < 0 , volume is decreasing work

H2O (l)

is done on the gas.

2atm,273 K

H2O(s),
2atm,273K

The pressure has been increase so accord5.

ing to le chetelier system will try to move

towards as a state with less pressure or, we
T

P2 / 5

can say it will try to move towards denser

= constant

medium to reduce pressure.

2/5

or

T = constant P

PV = RT

H2O(l) is more denser than H2O(s), so, the

wil l be spontaneous in the backwards
2/5

PV = R constant P

direction.

394 - Rajeev Gandhi Nagar Kota, Ph. No. 93141-87482, 0744-2209671

www. motioniitjee.com , email-info@motioniitjee.com

16.

17.

Hence for the given reaction G > +ve.

AR, BP, CS

OH

OH
C

Cl

OH

OH2

Cl

OCH3
H2O
OCH 3

14

CH3 O

CH3

CH3O

OCH3
OCH 3

14

18.
CH3

C
APQ, BP, CPR, DPRS

19.

C
AQRST, BQRS, CP, DST

OH
+

Cl

C
14

CH3

Cl

14

OCH3

CH3

OCH3

A B (isobaric compresssion) V T
a U = nCT
T = Ve

8.

9.

U < 0
r H = H + PV = H + PV
V is Ve

10.

11.

& U is Ve
H < 0

O
CH3 C + CH2 CHO
H

t as there is confermation

O
CH3 CH CH2 CHO

work is done on gas

Protonation & heat

B C isochoric process =
CH3 CH = CH CHO

PT
q U = nCT
12.

13.

T is Ve
U < 0

14.

15.

Ph CH = CH CH3

r H = U + PV = U + VP
U is Ve
D. Br
peroxide

*
*
Ph CH CH CH3
D

Br

& P is Ve
H < 0

NBS

*
*
Ph CH CH CH3
Br
Br
Vicinal dibromide

C D isochoric process =
VT

394 - Rajeev Gandhi Nagar Kota, Ph. No. 93141-87482, 0744-2209671

www. motioniitjee.com , email-info@motioniitjee.com

10

20.

p U = nCT

D
APR, BPR, CR, DQ

T is + Ve

(A)

G = H TS
>0

U > 0

>0

+ve, +ve +ve

s U is + Ve

or
q = +Ve

+ve, +ve ve

D A isochoric compression

(B)

H = + ve
S >0

PV

G = H TS

T work done = PV
V is Ve
Work done is +Ve

(C)

>0

>0

<0

>0

G = H TS
G = 0 at 373 K

Work done on gas

but at 400 K
G < 0
(D)

H2O(l) H2O (s)

H < 0
S < 0
G = H TS
at below melting point
G < 0

394 - Rajeev Gandhi Nagar Kota, Ph. No. 93141-87482, 0744-2209671

www. motioniitjee.com , email-info@motioniitjee.com

11