2014-15/Test-1/11th/JEEMAIN(1)/Code-Q

Mittal Sir

III-A/172 , Nehru Nagar Ghaziabad. Ph : 9811212090, 9868502091.

email : bmcchemistry@gmail.com, website : www.bmcchemistry.com

CODE

TEST-1/11th/JEE-MAIN(1)
Topic : Mole Concept, Atomic Structure

Date : 21 May 2014

Max Marks : 120

Time : 50 minutes

INSTRUCTIONS
General Instructions
Ensure matching of OMR sheet code with the Question paper Code
before you start marking your answers on OMR sheet
On the answer sheet, darken the appropriate bubble with Blue/Black
Pen only. Use of pencil and any other ink strictly prohibited.
Any kind of cutting, rubbing or use of whitener not allowed on
answer sheet.
Marking Scheme
Section I (Ques 1 25) contains 25 multiple choice question
which have one correct answer. Each question carries +4 marks
for correct response and -1 mark for wrong answer. [100 Marks]
Section II (Ques 26 30) contains 5 integer type question
which have correct answer in digits of 0-9. Each question carries
+4 marks for correct response and -1 mark for wrong answer.
[20 Marks]

Roll No.
Name of the student

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2014-15/Test-1/11th/JEEMAIN(1)/Code-Q

Mittal Sir

All the best

Section - I
Single Correct Answer Type(+4/-1)
This section contains 25 multiple choice questions. Each question has 4 choices (a), (b), (c) and (d) for its
answer, out of which ONLY ONE is correct.
1. Which of the following does not give CO2 on heating
(a) Li2CO3
(b) Na2CO3
(c) Ca(HCO3)2

(d) MgCO3

2. Number of photons of wavelength 500 nm required to produce 1 kJ of energy is

approximately
(a) 2.5 1022
(b) 2.5 1021
(c) 2.5 1020
(d) 2.5 1018
3. Given that the abundances of isotopes
the atomic mass of Fe is
(a) 55.85
(b) 55.95

Fe,

54

Fe and

56

(c) 55.75

Fe are 5%, 90% and 5%, respectively,

57

(d) 56.05

4. According to Rutherfords atomic theory the spectrum of atom should be

(a) continuous
(b) discontinuous
(c) Initially continuous but later on discontinuous
(d) Initially discontinuous but later on continuous
5. 100 ml of water was saturated with H2S gas by which volume became 110 ml, if density of
this solution is 0.95 gm/ml. The percentage of H2S by mass in this solution is
(a) 4.5 %
(b) 4.3 %
(c) 4.9 %
(d) 5.1 %
6. In a closed vessel 112 gm of N2 was reacted with 224 lit of H2 measured at S.T.P. Total
number of moles of product and reactant (if any) in vessel after the reaction are
22
20
(a) 10 mols
(b)
mols
(c)
mols
(d) None of these
3
3
7. An organic compound contains 40% carbon and 6.67% hydrogen by mass. The empirical
formula of compound is
(a) CH2
(b) C2H4O2
(c) C2H6O
(d) CH2O
8. Wavelength of photon emitted when an electron jump from n = 3 to n = 2 in H atom.
(a) 121 nm
(b) 91 nm
(c) 375 nm
(d) 760 nm
9. An organic compound on analysis was found to contain 10.06% carbon, 0.84% hydrogen and
89.10% chlorine. What will be the empirical formula of the substance ?
(a) CH2Cl2
(b) CHCl3
(c) CCl4
(d) CH3Cl
10. A solution of NaOH is prepared by mixing 90 gm NaOH in water to obtain 500 ml solution. If
m
density of solution is 1.2 gm/ml the ratio of
is
M
(m = molality of solution, M = molarity of solution)
50
51
(a)
(b)
(c) 1
(d) 1.2
51
50
Space for rough work

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Mittal Sir

11. A gaseous mixture contain CH4, CO and He in molar ratio of 2 : 1 : 3 weight of oxygen
required to combust 1.2 moles of this gaseous mixture is
(a) 28.8 gm
(b) 35.4 gm
(c) 20.5 gm
(d) 41.4 gm
12. Ionisation potential of hydrogen atom is 13.6 eV the ionisation potential in kJ/mol for He + is
(a) 1312 kJ/mol
(b) 328 kJ/mol
(c) 5248 kJ/mol
(d) 2624 kJ/mol
13. Weight of oxygen required to react completely with 11.2 lit NH3 measured at S.T.P to produce
nitric oxide according to reaction.
4NH3 + 5 O2 4 NO + 6 H2O
(a) 32 gm
(b) 16 gm
(c) 40 gm
(d) 20 gm
14. A solution of glucose has 50 % by mass glucose, mole fraction of water in solution is
1
9
10
12
(a)
(b)
(c)
(d)
2
10
11
13
15. A sample of caustic soda contain 80% NaOH by mass. Weight of caustic soda required to
prepare 400 ml of 0.2 M solution of NaOH is (Na = 23)
(a) 4.0 gm
(b) 3.2 gm
(c) 2.56 gm
(d) 8 gm
16. A solution of sulphuric acid is labelled 2M if density of this solution is 1.12 gm/ml, weight
of H2SO4 present in 100 gm of solution is
(a) 19.6 gm
(b) 21.95 gm
(c) 13.8 gm
(d) 17.5 gm
17. Which of the following has largest number of oxygen atoms
(a) 1 mol of O3
(b) 48 gm of O2
(c) 54 gm of H2O
(d) 44.8 lit of CO2 at S.T.P
e
m
(a) cathode rays particle using H2 in discharge tube
(b) cathode rays particle using He in discharge tube
(c) cathode rays particle using O2 in discharge tube
(d) same in all

18. Which of the following has highest value of

19. Which of the following violate Aufbau rule

(a)

(b)

(c)

(d) All of these

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2014-15/Test-1/11th/JEEMAIN(1)/Code-Q

Mittal Sir

20. 400 ml of a solution of H2SO4 was diluted, due to dilution its molarity remain

4
of initial
5

molarity. Volume of water added for dilution is

(a) 500 ml
(b) 400 ml
(c) 300 ml

(d) 100 ml

Space for rough work

21. Volume of O2 released at S.T.P by heating 24.5 gm of potassium chlorate

2 KClO3 2 KCl + 3 O2
K = 39, Cl = 35.5
(a) 2.24 lit
(b) 4.48 lit
(c) 6.72 lit
(d) 3.36 lit
22. Mols of CO2 evolved on heating 10 gm a mixture containing equal moles of CaCO 3, MgCO3
and Na2CO3.
(Ca = 40, Mg = 24, Na = 23)
10
20
30
40
(a)
(b)
(c)
(d)
290
290
290
290
23. Volume of Cl2 evolved at S.T.P when 500 ml of 0.4 M HCl solution is added on excess of
powdered MnO2
MnO2 + 4 HCl MnCl2 + Cl2 + 2 H2O
(a) 2.24 lit
(b) 1.12 lit
(c) 0.56 lit
(d) 4.48 lit
24. Which of the following electronic transition in H atom require photon of smallest wavelength
(a) n = 1 to 2
(b) n = 2 to 3
(c) n = 2 to 4
(d) n = 3 to 12
25. 30 gm of C2H6(g) was combusted in limited supply of oxygen
2 C2H6(g) + 7 O2 4 CO2(g) + 6 H2O(l)
2 C2H6 + 5 O2 4 CO(g) + 6 H2O(l)
Both reactions occurred simultaneously. If 20% of C2H6(g) combusted to form carbon mono
oxide, than volume of oxygen required at S.T.P is
(a) 44.8 lit
(b) 67.2 lit
(c) 73.92 lit
(d) 86.41 lit

Space for rough work

BMC CLASSES
III-A/172, Nehru Nagar Ghaziabad. Ph : 9811212090, 9868502091

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2014-15/Test-1/11th/JEEMAIN(1)/Code-Q

Mittal Sir

Section - II
Integer type (+4/-1)
This section contains 5 questions. The answer to each of the questions is a single digit integer, ranging
from 0 to 9. The appropriate bubbles below the respective question numbers in the ORS have to be
darkened. For example, if the correct answer to question numbers X, Y, Z and W (say) are 6, 0, 9 and
2, respectively, then the correct darkening of bubbles will look like the following :

X Y Z W
0
1
2
3
4
5
6
7
8
9

0
1
2
3
4
5
6
7
8
9

0
1
2
3
4
5
6
7
8
9

0
1
2
3
4
5
6
7
8
9

26. Volume in litres of a 2.0 M solution of H2SO4 required to react completely with 160 gm of
NaOH is Ans (4)
27. If Hunds rule is violated number of unpaired electrons in oxygen (

16
8

O) is/are Ans (0)

28. Total number of unpaired electrons in Cr+3 (Cr = 24) Ans (3)
29. The energy of electron in second orbit of a hydrogenic species Ax+ is 54.4 ev. The value of
x is Ans (3)
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2014-15/Test-1/11th/JEEMAIN(1)/Code-Q

Mittal Sir

30. The magnetic moment of Mnx+ is 3.92 B.M the value of x is Ans (4)

Space for rough work

III-A/172 , Nehru Nagar Ghaziabad. Ph : 9811212090, 9868502091.

email : bmcchemistry@gmail.com, website : www.bmcchemistry.com

CODE

OMR ANSWER
SHEET

Roll No.

Candidate Sign

Name :
Sign of Examiner

Test Topic :..

.
Test Date : /..../..

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2014-15/Test-1/11th/JEEMAIN(1)/Code-Q

Mittal Sir

Section I (Straight Objective Type)

A
B
C
D
A
B
C
D
1
6

A
11

12

13

14

10

15

16

21

17

22

18

23

19

24

20

25

Section II (Integer Type)

0
1
2
3
4
26

27
28
29
30

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2014-15/Test-1/11th/JEEMAIN(1)/Code-Q

BMC CLASSES
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Mittal Sir

Page No - 8

2014-15/Test-1/11th/JEEMAIN(1)/Code-Q

Code P
Code - Q
Code P
Code - Q

1
17
16
1

2
21
17
10

3
13
18
2

4
18
19
19

5
15
20
4

6
22
21
8

Mittal Sir

7
16
22
12

8
24
23
3

9
14
24
9

10
20
25
5

11
23
26
28

12
6
27
30

13
25
28
29

14
7
29
26

15
11
30
27

Note : To check Code Q solutions kindly compare your question No. with Code P questions. Eg. question no. 10 of
Code Q is same as question no. 17 of Code P.

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2014-15/Test-1/11th/JEEMAIN(1)/Code-Q

BMC CLASSES
III-A/172, Nehru Nagar Ghaziabad. Ph : 9811212090, 9868502091

Mittal Sir

Page No - 10