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Abstract
This work aims on the ecient use of animal fat in a diesel engine by making its stable emulsions with ethanol and water. A single
cylinder direct injection diesel engine is tested using neat diesel, neat animal fat and animal fat emulsion (optimal emulsion) as fuels under
variable load operating conditions. Results show increased peak pressure and ignition delay with ethanol animal fat emulsion as compared to neat fat. Heat release pattern shows improvement in the premixed combustion phase with animal fat emulsion as compared to
neat animal fat. Drastic reduction in smoke, nitric oxide, hydrocarbon and carbon monoxide emissions are observed with the emulsion as
compared to neat fat and neat diesel mainly at high power outputs. Only, hydrocarbon and carbon monoxide emissions are found as high
with the emulsion at light loads. In general, animal fat emulsion shows considerable reduction in all emissions and improvement in engine
performance as compared to neat fat.
2006 Elsevier Ltd. All rights reserved.
Keywords: Diesel engine; Ethanol; Animal fat emulsion
1. Introduction
Diesel engines are mainly used in industrial, transport
and agricultural applications due to their high eciency
and reliability. However, they suer from high smoke and
nitric oxide emissions [13]. The increase in prices of diesel
fuel, reduced availability, more stringent governmental regulations on exhaust emissions and the fast depletion of
world-wide petroleum reserves provide a strong encouragement to the search for alternative fuels. It is commonly
accepted that clean combustion in diesel engines can be
achieved only if engine development with fuel reformulation and the use alternative fuels are implemented [46].
In the name of energy security, regional air quality and
greenhouse gas emissions reduction, use of oxygenated
alternative fuels are advocated to reduce emissions in diesel
0016-2361/$ - see front matter 2006 Elsevier Ltd. All rights reserved.
doi:10.1016/j.fuel.2006.05.023
13
7
20
16
15
10
Diesel
Tank
3
10
5
Diesel
Tank
4
14
12
19
2647
11
17
2
18
1. Test Engine
2. Dynamometer
3. Animal Fat Tank
4. Diesel Tank
5. A/D Card for Pressure
6. A/D Card for Analyser
7. Air Tank
8. Burette for diesel
9. Burette for Animal Fat
10. Charge Amplifier
2648
90
An infrared (COSMA) exhaust analyzer is used for measuring hydrocarbon (HC) and carbon monoxide (CO)
emissions. NO in the exhaust is measured by using a Beckman chemiluminescence NOx analyzer. Smoke levels are
measured using a standard HARTRIDGE smoke meter
which works on light absorption technique (passing a light
beam through the exhaust sample and the fraction of light
is absorbed by the exhaust gas). Light extinction coecient
K is used as the measure of smoke density.
100
80
70
60
Neat Diesel
50
700
1100
1500
1900
2300
2700
3100
Power (watts)
Ethanol Emulsion
40
300
Neat Fat
Ethanol Emulsion
80
Neat Diesel
60
40
20
-20
15
25
35
45
55
65
75
60
Speed : 1500 rpm
Inj. Timing : 20 BTDC
16
14
Ignition delay (CA)
2649
12
10
8
6
Neat Diesel
Neat Fat
50
40
30
20
Neat Diesel
10
Ethanol Emulsion
Ethanol Emulsion
2
300
700
1100
1500
1900
2300
2700
300
3100
700
1100
Power (watts)
1900
2300
2700
3100
emulsion is shown in Fig. 6. The specic energy consumption decreases with the increase in engine load. After a certain percentage of maximum load, any further increase in
brake load causes only a small increase in brake horsepower. This results in increased specic energy consumption at very high power outputs. It is seen that neat
animal fat results in higher SEC as compared to neat diesel.
This can be explained by the poor combustion of the
injected fat as a result of high viscosity and density. However, there is an improvement in SEC with the emulsions of
animal fat. Minimum value of SEC is found at 60% of the
maximum load with the emulsion. The improvement in
specic energy consumption with the emulsion is attributed
to the changes occurring in the combustion process. The
physical and chemical dierences in fuel structure of ethanol and fat lead to a combination of changes in the combustion process. The physical properties of animal fat are
changed when ethanol is added. The addition of ethanol
causes the viscosity of animal fat to decrease. Presence of
70000
Neat Diesel
60000
Neat fat
Ethanol Emulsion
50000
SEC (kJ/kW.hr)
1500
Power (watts)
40000
30000
20000
10000
0
300
1100
1500
1900
2300
2700
3100
Power (watts)
2650
700
700
Speed : 1500 rpm
Inj. Timing : 20 BTDC
Neat Diesel
600
500
Hydrocarbon (ppm)
600
400
300
200
Neat Diesel
Neat Fat
Ethanol Emulsion
500
400
300
200
Neat fat
100
100
Ethanol Emulsion
0
0
700
1100
1500
1900
Power (watts)
2300
2700
3100
300
700
1100
1500
1900
2300
2700
3100
Power (watts)
3000
Neat Diesel
2500
Carbonmonoxide (ppm)
300
Neat fat
Ethanol Emulsion
2000
Speed : 1500 rpm
Inj. Timing : 20 BTDC
1500
1000
500
0
300
600
900
1200 1500
1800
3000
Power (watts)
delay and thus, enhances the mixing of fuel with air which
in turn makes better air utilization. The high oxygen content of the emulsion combined with low C/H ratio and aromatic fractions contributes to the reduction of smoke. High
level of oxygen atoms present in the fuel also results in
overall leaner mixture. All these factors result in overall
reduction in smoke emission.
The NO emission of the engine operating on diesel,
neat animal fat and ethanolanimal fat emulsions is given
in Fig. 11. It shows that the NO emission is reduced with
neat fat as compared to neat diesel. The maximum NO
emission is found as 1480 ppm with neat diesel and
965 ppm with neat animal fat. The reduction in NO emission with neat fat is due to the reduced premixed combustion as a result of slow burning. The NO emission is
further reduced with the emulsions of animal fat as compared to neat diesel and neat fat. The minimum value of
246 ppm at maximum power output is found with the animal fat emulsion. The main reason for the drastic reduction in NO emissions is again due to the high latent heat
of vaporization of water. In the absence of nitrogen in the
tested fuels, the formation of NO mainly depends on thermal NO and prompt NO. The kinetics formation of thermal NO are governed by the extended Zeltovitch
mechanisms. Since the latent heat of vaporization of
water is high, the charge temperature becomes low when
the fuel is injected into the combustion chamber. As a
result the peak combustion temperature becomes low
and leads NO to diminish. Presence of ethanol in the
emulsions also helps to suppress the formation of thermal
NO. The formation of prompt NO is initiated by the reaction between hydrocarbon radicals and molecular nitrogen. This kind of NO is principally formed in fuel rich
conditions. As the appearance of micro-explosion results
in a better air/fuel mixture, it prevents rich pockets.
Indeed, with animal fat emulsions the formation of
prompt NO is reduced to.
1800
Neat Diesel
Neat Diesel
Neat fat
1500
Neat fat
Ethanol Emulsion
Ethanol Emulsion
6
2651
5
4
3
2
1
1200
900
600
300
0
-1
300
700
1100
1500
1900
2300
2700
3100
Power (watts)
300
700
1100
1500
1900
2300
2700
3100
Power (watts)
2652
4. Conclusions
Inuence of ethanol on engine performance, emissions
and combustion characteristics of a diesel engine fuelled
with the optimum animal fat emulsion (explained in Part
1) is studied experimentally. Ethanol animal fat emulsion
shows increased cylinder peak pressure and ignition delay.
Higher premixed combustion and lower combustion duration are found with the emulsions as compared to neat fat.
Further, improvement in performance and signicant
reduction in smoke, nitric oxide emissions, hydrocarbon
and carbon monoxide emissions are achieved mainly at
high power outputs.
Emulsication of animal fat with ethanol and water can
be a promising technique for using animal fat eciently in
diesel engines without any modications in the engine.
Simultaneous reduction in nitric oxide and smoke can be
achieved with the use of animal fat emulsions. However,
poor part load performance needs attention. Techniques
like exhaust gas recirculation, cetane improvers etc. can
further improve the emulsion performance at part loads.
References
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