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Curriculum Outcomes
C11-4-04
C11-3-05
C11-3-06
Materials
3 Thermometers
Stirring rod
3- 50 ml beakers
Stop watch
100 ml graduated cylinders
3 Stands and clamps
String and scissors
Weighing machine and spatula
Safety
o Wear goggles at all times to protect your eyes from chemical spills or splashes.
o Handle substances with care. Do not ingest any of the substances.
Pre-lab Questions
1. Explain the difference between an endothermic and an exothermic reaction?
2. What are hot packs and cold packs used for? Give some practical examples from your
own experiences.
3. Explain which type of reaction (exothermic or endothermic) would be required to make a
cold pack and a hot pack.
Procedures
1. Set up 3 stands with clamps, and attach the thermometers to the clamps.
2. Fill 3 beakers with 50 ml of water and place each on one of the stands, with the
thermometer immersed in the water but not touching the bottom or the sides of the
beakers.
3. Record the initial temperature of the water in the data table.
4. Using the weighing machine, add 25 g of ammonium nitrate to one beaker, and 25 grams
of calcium chloride to the second, and leave the third without any chemical added.
5. Stir the beakers with a stirring rod continuously and immediately start the stop watches.
6. Record the temperature every 20 seconds until the temperature becomes stable.
7. Repeat steps 2-6 for the other substances: sodium chloride and ammonium chloride.
Results
Ammonium nitrate
Time
(min)
0
20s
40s
60s
80s
Temp (C)
Calcium chloride
Time
(min)
0
20s
40s
60s
80s
Temp (C)
Sodium chloride
Time
(min)
0
20s
40s
60s
80s
Temp
(C)
Ammonium chloride
Time
(min)
0
20s
40s
60s
80s
Temp (C)
Conclusion
1. For each substance, what was its highest temperature and lowest temperature.
Substances
Lowest temperature(C)
Ammonium nitrate
Calcium chloride
Sodium chloride
Ammonium chloride
2. a) How do you know that a reaction is exothermic?
b) How do you know that a reaction is endothermic?
3. a) When mixed with water, which of the substances produces an exothermic reaction?
Explain your answer using the table in question 1.
b) When mixed with water, which of the substances produces an endothermic reaction?
Explain your answer using the table in question 1.
4. a) How does a cold pack work? Does it use an endothermic or an exothermic reaction?
b) How does a hot pack work? Does it use an endothermic or an exothermic reaction?
5. For each substance, would it be a good candidate for a hot pack or cold pack. Explain
your answer.
Substances
Ammonium nitrate
Calcium chloride
Sodium chloride
Ammonium chloride
Temperature (C)
Initial temp:
Final temp:
Initial temp:
Final temp:
Initial temp:
Final temp:
Initial temp:
Final temp:
6. a) Draw a water molecule and identify the partial charges on the water molecules.
c) During the dissociation of calcium chloride in water, which of the ions in the CaCl2
becomes an anion?
d) During the dissociation of calcium chloride in water, which of the ions in the CaCl2
becomes a cation?
e) Draw the ion-dipole interactions between the calcium and water, AND the chloride
ions and water, as the CaCl2 dissociates in the water and forms a solution. Note: Refer to
figure 1.
Extension Questions:
7. a) Complete the reaction for calcium chloride dissolving in water as it undergoes an
exothermic reaction and balance it. Note: Make sure to include a negative or positive
value for heat change to represent whether the heat is absorbed or released in the reaction.
__CaCl2 + __ H20
8. a) Why does the chloride ion bind with the hydrogen, not the hydroxide group?
b) Why does the calcium atom bind with the hydroxide group, not the hydrogen?
c) Why does the calcium atom combine with TWO hydroxide groups, not ONE?
9. Suggest a reason why some ionic compounds dissolve in water to release heat whereas
some compounds dissolve requiring or absorbing heat?