Safety Data Sheet

according to Regulation (EC) No 1907/2006

Stella Accelerator OF
Print date: 11.11.2014

Product code: 92085499

Page 1 of 10

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Stella Accelerator OF
Further trade names
valid for all package sizes
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Catalyst.
Uses advised against
The product is intended for professional use.
1.3. Details of the supplier of the safety data sheet

Company name:

DSB Surebau GmbH

Knigswinter
Bachstrae 38
D-53639 Knigswinter
+49 2223 928 0

Street:
Place:
Telephone:
e-mail:
Contact person:
e-mail:
Internet:
Responsible Department:

Telefax: +49 2223 928 461

info@didiersb.de
Surebau Labor
msds@didiersb.de
www.didiersb.de
+49 2223 928 321

1.4. Emergency telephone number:

Telephone: +49 2223 928 321

(001) 352 3233500 Emtel-Customer-No. 99496

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Indications of danger: Xn - Harmful, N - Dangerous for the environment
R phrases:
Possible risk of impaired fertility.
Harmful by inhalation, in contact with skin and if swallowed.
Limited evidence of a carcinogenic effect.
May cause sensitisation by skin contact.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
GHS classification
Hazard categories:
Respiratory/skin sensitization: Skin Sens. 1
Carcinogenicity: Carc. 2
Reproductive toxicity: Repr. 2
Hazardous to the aquatic environment: Aquatic Chronic 2
Hazard Statements:
May cause an allergic skin reaction.
Suspected of causing cancer.
Suspected of damaging fertility.
Toxic to aquatic life with long lasting effects.
2.2. Label elements
Hazardous components which must be listed on the label

cobalt bis(2-ethylhexanoate)
N,N-dimethylaniline
Signal word:
Pictograms:

Hazard statements
H317
H351
H361f
H411
Revision No: 1,00

Warning
GHS07-GHS08-GHS09

May cause an allergic skin reaction.

Suspected of causing cancer.
Suspected of damaging fertility.
Toxic to aquatic life with long lasting effects.
GB - EN

Revision date: 11.11.2014

Safety Data Sheet

according to Regulation (EC) No 1907/2006

Stella Accelerator OF
Print date: 11.11.2014

Product code: 92085499

Page 2 of 10

Precautionary statements

P261
Avoid breathing vapour/spray.
P273
Avoid release to the environment.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352
IF ON SKIN: Wash with plenty of water.
P308+P313
IF exposed or concerned: Get medical advice/attention.
P501
Dispose of contents/container to Dispose of waste according to applicable legislation..
2.3. Other hazards
Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. Keep away from food, drink and
animal feeding stuffs.

SECTION 3: Composition/information on ingredients

3.2. Mixtures
Chemical characterization
Mixture related information:
Amines / Solvent/Thinner.
Hazardous components
EC No

Chemical name

CAS No

Classification

Index No

GHS classification

Quantity

REACH No
229-934-9

80 - < 85 %

1-isopropyl-2,2-dimethyltrimethylene diisobutyrate

6846-50-0
01-2119451093-47
5 - < 10 %

205-250-6

cobalt bis(2-ethylhexanoate)

136-52-7

Repr. Cat. 3, N - Dangerous for the environment R62-43-50-53

Repr. 2, Skin Sens. 1, Aquatic Acute 1 (M-Factor = 1), Aquatic Chronic 1 (M-Factor = 1); H361f
H317 H400 H410

01-2119524678-29
5 - < 10 %

204-493-5

N,N-dimethylaniline

121-69-7

Carc. Cat. 3, T - Toxic, N - Dangerous for the environment R40-23/24/25-51-53

612-016-00-0

Carc. 2, Acute Tox. 3, Acute Tox. 3, Acute Tox. 3, Aquatic Chronic 2; H351 H331 H311 H301
H411

215-535-7

xylene

1330-20-7

Xn - Harmful, Xi - Irritant R10-20/21-38

601-022-00-9

Flam. Liq. 3, Acute Tox. 4, Acute Tox. 4, Skin Irrit. 2; H226 H332 H312 H315

1-<5%

Full text of R-, H- and EUH-phrases: see section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures
General information
Move victim out of danger zone. In case of accident or unwellness, seek medical advice immediately (show directions
for use or safety data sheet if possible). Remove contaminated, saturated clothing immediately.
After inhalation
Provide fresh air. When in doubt or if symptoms are observed, get medical advice.
After contact with skin
After contact with skin, wash immediately with polyethylene glycol, followed by plenty of water. Take off immediately all
contaminated clothing and wash it before reuse. Medical treatment necessary.
After contact with eyes
After eye contact: Rinse immediately carefully and thoroughly with eye-bath or water. Consult an ophthalmologist.
After ingestion
Observe risk of aspiration if vomiting occurs. Rinse mouth immediately and drink plenty of water. Induce vomiting when
the affected person is not unconscious. Medical treatment necessary.
4.2. Most important symptoms and effects, both acute and delayed
No known symptoms to date. In all cases of doubt, or when symptoms persist, seek medical advice.

Revision No: 1,00

GB - EN

Revision date: 11.11.2014

Safety Data Sheet

according to Regulation (EC) No 1907/2006

Stella Accelerator OF
Print date: 11.11.2014

Product code: 92085499

Page 3 of 10

4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media
Water spray. Carbon dioxide (CO2). Dry extinguishing powder. Foam.
Co-ordinate fire-fighting measures to the fire surroundings.
Unsuitable extinguishing media
High power water jet.
5.2. Special hazards arising from the substance or mixture
In case of fire may be liberated: Carbon monoxide. Carbon dioxide (CO2). Nitrogen oxides (NOx).
5.3. Advice for firefighters
Wear a self-contained breathing apparatus and chemical protective clothing. In case of fire and/or explosion do not
breathe fumes.
Additional information
Use water spray jet to protect personnel and to cool endangered containers. Suppress gases/vapours/mists with water
spray jet. Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Provide adequate ventilation. Do not breathe gas/fumes/vapour/spray. Avoid contact with skin, eyes and clothes. Use
personal protection equipment.
6.2. Environmental precautions
Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil.
6.3. Methods and material for containment and cleaning up
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the
recovered material as prescribed in the section on waste disposal.
6.4. Reference to other sections
Safe handling: see section 7
Personal protection equipment: see section 8
Disposal: see section 13

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Advice on safe handling
Keep container tightly closed in a cool, well-ventilated place. Provide adequate ventilation. Wear personal protection
equipment. Do no eat, drink or smoke when using this product.
Advice on protection against fire and explosion
Keep away from sources of ignition. - No smoking.
In case of fire: Wear self-contained breathing apparatus.
Further information on handling
No special handling instructions are necessary. Observe technical data sheet.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Floors should be impervious, resistant to liquids and easy to clean. Observe in addition any national regulations! Keep
container tightly closed in a cool, well-ventilated place.Ensure adequate ventilation of the storage area.
Advice on storage compatibility
Do not store together with: Oxidizing agents.
Further information on storage conditions
Store in a well-ventilated place. Keep container tightly closed. Keep away from heat. Protect from sunlight.
Storage class:
7.3. Specific end use(s)

Restricted to professional users. Observe technical data sheet.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

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Revision date: 11.11.2014

Safety Data Sheet

according to Regulation (EC) No 1907/2006

Stella Accelerator OF
Print date: 11.11.2014

Product code: 92085499

Page 4 of 10

Exposure limits (EH40)

CAS No

Substance

121-69-7 N,N-Dimethylaniline

1330-20-7 Xylene: mixed isomers

ppm

mg/m

Category

Origin

25

TWA (8 h)

WEL

10

50

STEL (15 min)

WEL

50

220

TWA (8 h)

WEL

100

441

STEL (15 min)

WEL

fibres/ml

Biological Monitoring Guidance Values (EH40)

CAS No

Substance

Parameter

1330-20-7 Xylene, o-, m-, p- or mixed isomers

Value

methyl hippuric acid

Test material

650 mmol/mol urine

Sampling time
Post shift

8.2. Exposure controls

Appropriate engineering controls

If handled uncovered, arrangements with local exhaust ventilation have to be used. Do not breathe
gas/fumes/vapour/spray.
Protective and hygiene measures
Remove contaminated, saturated clothing immediately. Draw up and observe skin protection programme. Wash hands
and face before breaks and after work and take a shower if necessary. When using do not eat or drink.
Eye/face protection
Wear eye/face protection. goggles.
Hand protection
When handling with chemical substances, protective gloves must be worn with the CE-label including the four control
digits. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working
place concentration and quantity of hazardous substances. For special purposes, it is recommended to check the
resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.
Tested protective gloves are to be worn:
Breakthrough times and swelling properties of the material must be taken into consideration.
Suitable material:
NBR (Nitrile rubber). Butyl rubber. FKM (fluororubber). PVC (Polyvinyl chloride).
Unsuitable material:
Chromate-free leather. CR (polychloroprenes, Chloroprene rubber).
Skin protection
Suitable protective clothing: Single-use suit.
Respiratory protection
In case of inadequate ventilation wear respiratory protection. With correct and proper use, and under normal conditions,
breathing protection is not required.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state:

liquid

Colour:
Odour:

dark violet
like: Amines
Test method

pH-Value (at 20 C):

6-8

Changes in the physical state

Melting point:
Initial boiling point and boiling range:
Flash point:

- 70 C (TXIB)
> 200 C
87 C ISO 3679

Flammability
Solid:
Gas:

not applicable
not applicable

Lower explosion limits:

Upper explosion limits:
Revision No: 1,00

not determined
not determined
GB - EN

Revision date: 11.11.2014

Safety Data Sheet

according to Regulation (EC) No 1907/2006

Stella Accelerator OF
Print date: 11.11.2014

Product code: 92085499

Ignition temperature:
Auto-ignition temperature
Solid:
Gas:
Decomposition temperature:

Page 5 of 10
370 C N,N-dimethylaniline
not applicable
not applicable
not determined

Oxidizing properties

Not oxidizing.
Vapour pressure:
(at 20 C)
Density (at 20 C):
Water solubility:
(at 20 C)
Solubility in other solvents
miscible with most organic solvents
Partition coefficient:
Viscosity / dynamic:
(at 20 C)
Vapour density:
Evaporation rate:
Solvent content:

0,015 hPa (TXIB)

0,95 g/cm ISO 2811
slightly soluble

not determined
5 - 10 mPas DIN 53018
not determined
not determined
87,96 %

9.2. Other information

Solid content:

0,10 %

(TXIB) = 1-isopropyl-2,2-dimethyltrimethylene diisobutyrate

SECTION 10: Stability and reactivity

10.1. Reactivity
No hazardous reaction when handled and stored according to provisions.
10.2. Chemical stability
The product is stable under storage at normal ambient temperatures.
10.3. Possibility of hazardous reactions
Reacts violently with peroxides.
10.4. Conditions to avoid
Keep away from heat. Protect from sunlight.
10.5. Incompatible materials
Oxidizing agents. Acid, concentrated. Alkalis (alkalis), concentrated.
10.6. Hazardous decomposition products
Carbon monoxide. Carbon dioxide. Nitrogen oxides (NOx).
In case of fire may be liberated: Gas/vapours, toxic.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Revision No: 1,00

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Safety Data Sheet

according to Regulation (EC) No 1907/2006

Stella Accelerator OF
Print date: 11.11.2014

Product code: 92085499

Page 6 of 10

Acute toxicity
CAS No

Chemical name
Exposure routes

6846-50-0

136-52-7

1330-20-7

Dose

Species

Source

oral

LD50

>3200 mg/kg

Rat

dermal

LD50

18900 mg/kg

Guinea-pig.

LD50

> 2000 mg/kg

Rat

oral

LD50

951 mg/kg

Rat

GESTIS

dermal

LD50

1690 mg/kg

Rabbit

Gestis

inhalative (4 h) vapour

LC50

5,1 mg/l

Rat

IUCLID

inhalative aerosol

ATE

0,5 mg/l

cobalt bis(2-ethylhexanoate)
oral

121-69-7

Method

1-isopropyl-2,2-dimethyltrimethylene diisobutyrate

N,N-dimethylaniline

xylene
oral

LD50

4300 mg/kg

Rat

GESTIS

dermal

LD50

3200 mg/kg

Rabbit

GESTIS

inhalative (4 h) vapour

LC50

21,7 mg/l

Rat

GESTIS

inhalative aerosol

ATE

1,5 mg/l

Sensitising effects
May cause an allergic skin reaction.
Carcinogenic/mutagenic/toxic effects for reproduction
Suspected of causing cancer.
Suspected of damaging fertility.
Specific effects in experiment on an animal
The product has not been tested. Toxicological data are not available.
Additional information on tests
This mixture is classified as hazardous according to regulation (EC) No. 1272/2008 [CLP]. Special hazards arising from
the substance or mixture!

SECTION 12: Ecological information

12.1. Toxicity
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
CAS No

Chemical name
Aquatic toxicity

6846-50-0

136-52-7

Method

Dose

[h] | [d] Species

Source

1-isopropyl-2,2-dimethyltrimethylene diisobutyrate
Acute fish toxicity

LC50

1,55 mg/l

96 h Pimephales promelas

Acute algae toxicity

ErC50

>7,94 mg/l

72 h Pseudokirchneriella
subcapitata

Acute crustacea toxicity

EC50

1,46 mg/l

48 h Daphnia magna

ErC50

0,528 mg/l

72 h

cobalt bis(2-ethylhexanoate)
Acute algae toxicity

121-69-7

N,N-dimethylaniline

1330-20-7

Acute fish toxicity

LC50

65,6 mg/l

96 h Pimephales promelas

Acute algae toxicity

ErC50

340 mg/l

96 h Desmodesmus subspicatus.

Acute crustacea toxicity

EC50

5 mg/l

48 h Daphnia magna

Acute fish toxicity

LC50

26,7 mg/l

96 h Pimephales promelas

Acute crustacea toxicity

EC50

8,5 mg/l

48 h Daphnia magna

xylene

GESTIS

12.2. Persistence and degradability

The product has not been tested. No information available.

Revision No: 1,00

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Safety Data Sheet

according to Regulation (EC) No 1907/2006

Stella Accelerator OF
Print date: 11.11.2014
CAS No

Product code: 92085499

Page 7 of 10

Chemical name
Method

Value

70,73 %

28

Source

Evaluation
6846-50-0

1-isopropyl-2,2-dimethyltrimethylene diisobutyrate
CO2 Evolution Test
Readily biodegradable (according to OECD criteria).

12.3. Bioaccumulative potential

The product has not been tested. No information available. The product has not been tested.
Partition coefficient n-octanol/water
CAS No

Chemical name

Log Pow

6846-50-0

1-isopropyl-2,2-dimethyltrimethylene diisobutyrate

4,04-4,91

121-69-7

N,N-dimethylaniline

1330-20-7

xylene

2,31
3,12-3,20

12.4. Mobility in soil

The product has not been tested. No information available.
12.5. Results of PBT and vPvB assessment
The components in this formulation do not meet the criteria for classification as PBT or vPvB.
12.6. Other adverse effects
No information available.
Further information
Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Advice on disposal
Dispose of waste according to applicable legislation. Evidence for disposal must be provided.
Waste disposal number of waste from residues/unused products
WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of plastics, synthetic rubber and
070208
man-made fibres; other still bottoms and reaction residues
Classified as hazardous waste.
Waste disposal number of contaminated packaging
WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE CLOTHING
150110
NOT OTHERWISE SPECIFIED; packaging (including separately collected municipal packaging waste);
packaging containing residues of or contaminated by dangerous substances
Classified as hazardous waste.
Contaminated packaging
This material and its container must be disposed of as hazardous waste. Handle contaminated packages in the same
way as the substance itself. Completely emptied packages can be recycled.

SECTION 14: Transport information

Land transport (ADR/RID)
14.1. UN number:

UN 3082

14.2. UN proper shipping name:

14.3. Transport hazard class(es):

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (cobalt

bis(2-ethylhexanoate) / N,N-dimethylaniline)
9

14.4. Packing group:

III

Hazard label:

Classification code:
Special Provisions:
Limited quantity:
Transport category:
Hazard No:
Tunnel restriction code:

M6
274 335 601
5L
3
90
E

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Safety Data Sheet

according to Regulation (EC) No 1907/2006

Stella Accelerator OF
Print date: 11.11.2014

Product code: 92085499

Page 8 of 10

Other applicable information (land transport)

E1
Inland waterways transport (ADN)
14.1. UN number:

UN 3082

14.2. UN proper shipping name:

14.3. Transport hazard class(es):

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (cobalt

bis(2-ethylhexanoate) / N,N-dimethylaniline)
9

14.4. Packing group:

III

Hazard label:

Classification code:
Special Provisions:
Limited quantity:

M6
274 335 601
5L

Other applicable information (inland waterways transport)

E1
Marine transport (IMDG)
14.1. UN number:

UN 3082

14.2. UN proper shipping name:

14.3. Transport hazard class(es):

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

(cobalt bis(2-ethylhexanoate) / N,N-dimethylaniline)
9

14.4. Packing group:

III

Hazard label:

Marine pollutant:
Special Provisions:
Limited quantity:
EmS:
Segregation group:

yes
274, 335
5L
F-A, S-F
not applicable

Other applicable information (marine transport)

E1
Air transport (ICAO)
14.1. UN number:

UN 3082

14.2. UN proper shipping name:

14.3. Transport hazard class(es):

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

(cobalt bis(2-ethylhexanoate) / N,N-dimethylaniline)
9

14.4. Packing group:

III

Hazard label:

Special Provisions:
Limited quantity Passenger:

A97 A158
30 kg G

IATA-packing instructions - Passenger:

IATA-max. quantity - Passenger:
IATA-packing instructions - Cargo:
IATA-max. quantity - Cargo:

964
450 L
964
450 L

Other applicable information (air transport)

E1
Passenger-LQ: Y964
14.5. Environmental hazards
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Safety Data Sheet

according to Regulation (EC) No 1907/2006

Stella Accelerator OF
Print date: 11.11.2014

Product code: 92085499

ENVIRONMENTALLY HAZARDOUS:

yes

Danger releasing substance:

cobalt bis(2-ethylhexanoate); N,N-dimethylaniline

Page 9 of 10

14.6. Special precautions for user

Keep away from food, drink and animal feeding stuffs.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not classified for this carrier.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information

1999/13/EC (VOC):

8,891 % (84,463 g/l)

Additional information
To follow: 850/2004/EC , 79/117/EEC , 689/2008/EC
National regulatory information
Employment restrictions:

Water contaminating class (D):

Skin resorption/Sensitization:

Observe employment restrictions for young people. Observe employment

restrictions for child bearing mothers and nursing.
3 - highly water contaminating
Causes allergic hypersensitivity reactions.

15.2. Chemical safety assessment

Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information

Abbreviations and acronyms
ADR: Accord europen sur le transport des marchandises dangereuses par Route
(European Agreement concerning the International Carriage of Dangerous Goods by Road)
RID: Rglement international concernant le transport des marchandises dangereuses par chemin de fer
(Regulations Concerning the International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
GefStoffV: Gefahrstoffverordnung (Ordinance on Hazardous Substances, Germany)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
VOC: Volatile Organic Compounds (USA, EU, CH)
Relevant R-phrases (Number and full text)
10
Flammable.
20/21
Harmful by inhalation and in contact with skin.
23/24/25
Toxic by inhalation, in contact with skin and if swallowed.
38
Irritating to skin.
40
Limited evidence of a carcinogenic effect.
43
May cause sensitisation by skin contact.
50
Very toxic to aquatic organisms.
51
Toxic to aquatic organisms.
53
May cause long-term adverse effects in the aquatic environment.
62
Possible risk of impaired fertility.
Relevant H- and EUH-phrases (Number and full text)
H226
Flammable liquid and vapour.
H301
Toxic if swallowed.
H311
Toxic in contact with skin.
H312
Harmful in contact with skin.
H315
Causes skin irritation.
H317
May cause an allergic skin reaction.
H331
Toxic if inhaled.
H332
Harmful if inhaled.
Revision No: 1,00

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Revision date: 11.11.2014

Safety Data Sheet

according to Regulation (EC) No 1907/2006

Stella Accelerator OF
Print date: 11.11.2014

Product code: 92085499

Page 10 of 10

H351
Suspected of causing cancer.
H361f
Suspected of damaging fertility.
H400
Very toxic to aquatic life.
H410
Very toxic to aquatic life with long lasting effects.
H411
Toxic to aquatic life with long lasting effects.
Further Information
The above information describes exclusively the safety requirements of the product and is based on our present-day
knowledge. The information is intended to give you advice about the safe handling of the product named in this safety
data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In
the case of mixing the product with other products or in the case of processing, the information on this safety data sheet
is not necessarily valid for the new made-up material.
(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data
sheet.)

Revision No: 1,00

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Revision date: 11.11.2014