Chapter 6

THERMAL CONDUCTIVITY OF GAS -INORGANIC COMPOUNDS

Carl L. Yaws
Lamar University, Beaumont, Texas
Tabulation Results

The results are given in Table 6. For the tabulation, thermal conductivity of gas as a function of
temperature is given by the equation shown below:

kgas =A + B T + C T + D r'
2

(6)

kgas thermal conductivity of gas, W/(m K)

A, B, C, and D =regression coefficients for chemical compound
T = temperature, K

where

The tabulation is arranged by alphabetical order (Ag, AI, Ar,

, Zr ) to provide ease of use in
quickly locating the data by using the chemical formula. The compound name and CAS No (Chemical
Abstracts Registry Number) are next provided. Values for regression coefficients are given in the adjacent
columns. The temperature range for use is given in the next columns (TMIN and TMAX). The equation
should not be used for temperatures outside this range. The next column provides the code for the
tabulation. The last three columns provide values for thermal conductivity of gas at representative
temperatures. The tabulation is applicable to gas at low pressure.
In preparing the tabulation, a literature search was conducted to identify data source publications
(1-44). Both experimental values for the property under consideration and parameter values for
estimation of the property are included in the source publications. The publications were screened and
copies of appropriate data were made. These data were then keyed into the computer to provide a
database of values for compounds for which experimental data are available. The database also served
as a basis to check the accuracy of the estimation methods. Upon completion of data collection,
estimation of values for the remaining compounds was performed.
The compilations of Beaton and Hewitt (2); CRC (3-4); Daubert and Danner (5); and Yaws (2642) were used extensively for the tabulation. In the absence of experimental data, estimates were primarily
based on the on Stief and Thodos correlation and modified Eucken models (14). Experimental data and
estimates were then regressed to provide the same equation for all compounds.
Very limited experimental data are available for highly polar and high molecular weight compounds.
Also, very few experimental data are available at high temperatures above 600 K. Thus, the values for these
compounds and high temperatures should be considered rough approximations.
A comparison of calculated and data values is shown in Figure 6 for a representative compound.
The graph shows favorable agreement of equation and data.
Example

In an engineering analysis, thermal conductivity of gas is needed for oxygen (02) at 500 K.
Determine the thermal conductivity of gas for oxygen at this temperature.
Substitution of the coefficients from the tabulation and temperature into the above equation
yields:
2

kgas = 1.5475E-04 + 9.4153E-05*500 - 2.7529E-08*500 + 5.2069E-12*500

kgas =0.0410 W/(m K)

References
1.
2.
3.
4.
5.

Assael, M. J., S. Mixafendi, and W. A. Wakeham, "The Viscosity and Thermal Conductivity of Normal Hydrogen
in the Limit Zero Density", J. Phys. Chem. Ref. Data, 15, 1315 (1986).
Beaton, C. F. and G. F. Hewitt, PHYSICAL PROPERTY DATA FOR THE DESIGN ENGINEER, Hemisphere
Publishing Corp., Ney York, NY (1989).
CRC HANDBOOK OF CHEMISTRY AND PHYSICS, 75th - 86th eds., CRC Press, Inc., Boca Raton, FL
(1994-2006).
CRC HANDBOOK OF THERMOPHYSICAI AND THERMOCHEMICAL DATA, CRC Press, Boca Raton, FL
(1994).
Daubert, T. E. and R. P. Danner, DATA CaMpI! ATION OF PROPERTIES OF PURE COMPO! JNDS, Parts 1,

292

6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
31.
32.
33.
34.
35.
36.
37.
38.

2,3, and 4, Supplements 1 and 2, DIPPR Project, AIChE, New York, NY (1985-1994).
Ho, C. Y., R. W. Powell, and P. E. Liley, ''Thermal Conductivity of the Elements", J. Phys. Chem. Ref. Data,
1, No.2, 279-421 (1972).
Ho, C. Y., editor, PROPERTIES OF INORGANIC AND ORGANIC FLlJIDS, Volume V-1, Hemisphere
Publishing Corporation, New York, NY (1988).
Kestin, J., et aI., "Equilibrium and Transport Properties of the Noble Gases and Their Mixtures at Low Density",
J. Phys. Chem. Ref. Data, 13, 299 (1984).
Landolt, H. and R. Bornstein, ZAHLENWERTE liND FUNKIONEN ANS PHYSIK, CHEMEI ASTRONOMIE
lIND TECHNIK, Springer-Verlag, Heidelberg, Germany (1971-2005).
lANGE'S HANOBOOK OF CHEMISTRY, 13th, 14th, and 15th eds., McGraW-Hili, New York, NY (1985,
1992,1999).
Matsunaga, N. and A. Nagashima, "Transport Properties of Liquid and Gaseous D20 over a Wide Range of
Temperature and Pressure", J. Phys. Chem. Ref. Data, 12, 933 (1983).
Ohse, R. W., ed., HANOBOOK OF THERMODYNAMIC ANO TRANSPORT PROPERTIES OF ALKALI
METAl S, Blackwell-Scientific Publications, London, England (1985).
PERRY'S CHEMICAL ENGINEERING HANOBOOK, 6th and 7th eds., McGraw-Hili, New York, NY (1984,
1997).
Poling, B. E., J. M. Prausnitz, and J. P. O'Connell, THE PROPERTIES OF GASES AND IIOIIIOS, 5th ed.,
McGraw-Hili, New York, NY (2000).
Reid, R. C., J. M. Prausnitz, and B. E. Poling, THE PROPERTIES OF GASES AND L1011lDS, 4th ed.,
McGraw-Hili, New York, NY (1987).
Reid, R. C. and T. K. Sherwood, THE PROPERTIES OF GASES ANO IIOIIIOS, 3rd ed., McGraw-Hili, New
York, NY (1977).
Sengers, J. V. and J. T. R. Watson, "Improved International Formulation for the Viscosity and Thermal
Conductivity of Water Substance", J. Phys. Chem. Ref. Data, 15,1291 (1986).
Stephan, K. and T. Heckenberger, THERMAl CONOllCTIVITY ANO VISCOSITY DATA OF FI 1110
MIXTURES, Chemistry Data Series, Volume X, Part 1, DECHEMA, FrankurtlMain, Germany (1988).
THERMOPHYSICAI PROPERTIES OF MATTER, 1st and 2nd eds., IFI/Plenum, New York, NY (1970-1976).
Trengove, R. D. and W. A. Wakeham, "The Viscosity of Carbon Dioxide, Methane, and Sulfur Hexafluoride in
the Limit of Zero Density", J. Phys. Chem. Ref. Data, 16, 175 (1987).
Tsederberg, N. V., THERMAL CONPlJCTIVITY OF GASES ANO L1011l0S, MIT Press, Cambridge, MA (1965).
Vargaftik, N. B., TABI ES ON THE THERMOPHYSICAL PROPERTIES OF I 10lUOS ANO GASES, 2nd ed.,
English translation, Hemisphere Publishing Corporation, New York, NY (1975, 1983).
Vargaftik, N. B. and others, HANDBOOK OF THERMAL CONOUCTIVITY OF L10lUOS AND GASES,
Standards Press, Moscow, USSR (1978).
Vargaftik, N. B. and others, HANDBOOK OF THERMAL CONPlJCTIVITY OF L10lJlDS AND GASES, CRC
Press, Inc., Boca Raton, FL (1993).
Vescovic, V., et aI., "The Transport Properties of Carbon Dioxide", J. Phys. Chem. Ref. Data, 19, (1990).
Yaws, C. L. and Others, "Carbon Oxides (Carbon Monoxide and Dioxide) - Phy. and Thermo. Prop. (4)", Chem.
Eng., 81 (20),115 (Sept. 30,1974).
Yaws, C. L. and Others, "Ammonia and Hydrazine - Phy. and Thermo. Prop. (6)", Chem. Eng., 81 (25), 178
(Nov. 25,1974).
Yaws, C. L. and Others, "Major Diatomic Gases (Hydrogen, Nitrogen and Oxygen) - Phy. and Thermo. Prop.
(8)", Chem. Eng., B2 (2),99 (Jan. 20,1975).
Yaws, C. L. and Others, "N-Type Gas Phase Dopants - Physical and Thermodynamic Properties of Arsine,
Phosphine and Stibine", Solid State Technology, 11 (1),47 (1974).
Yaws, C. L. and Others, 'Oxides of Nitrogen (Nitrous Oxide, Nitric Oxide and Nitrogen Dioxide) - Phy. and
Thermo. Prop. (3)", Chem. Eng., 81 (17), 99 (August 19,1974).
Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Silane", Solid State Techn., 21 (1), 43
(January, 1978).
Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Silicon Tetrachloride", Solid State Techn.,
22 (No.2), 65 (February, 1979).
Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Silicon Tetrafluoride", J.Ch.I.Ch.E., 12 (1),
33 (1981).
Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Trichlorosilane", J.Ch.I.Ch.E., .1.4, 205
(1983).
Yaws, C. L. and Others, "Physical and Thermodynamic Properties of Dichlorosilane", Ind. Eng. Chem. Process
Des. Dev., 23,48 (1984).
Yaws, C. L. and Others, "P-Type Gas Phase Dopants (Diborane and Pentaborane): Physical and
Thermodynamic Properties", Solid State Technology,l1 (11), 31 (1974).
Yaws, C. L., PHYSICAl PROPERTIES, McGraw-Hili, New York, NY (1977).
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TX (1995,1997).

293

39.
40.
41.
42.
43.
44.

Yaws, C. l., CHEMICAl PROPERTIES HANDBOOK, McGraw-Hili, New York, NY (1999).

h
Yaws, C. L., MATHESON GAS DATA BOOK, i ed., Matheson Tri-Gas (Parisppany, NJ), McGraw-Hili, New
York, NY (2001).
Yaws, C. l., YAWS HANDBOOK OF THERMODYNAMIC AND PHYSICAL PROpERTIES OF CHEMICAL
COMPOllNDS, electronicedition, www.knovel.com. knovel, Norwich,NY (2003-present).
Yaws, C. L., YAWS HANDBOOK OF PHYSICAl PROPERTIES FOR HYDROCARBONS AND
CHEMICAl S, Gulf PUblishingCompany, Houston, TX (2005).
Yaws, C. L., YAWS HANDBOOK OF THERMODYNAMIC PROPERTIES FOR HYDROCARBONS AND
CHEMICAl S, Gulf Publishing Company, Houston, TX (2006).
Younglove, B. A. and H. J. M. Hanley, "The Viscosity and Thermal ConductiVity Coefficients of Gaseous and
Liquid Argon", J. Phys. Chem. Ref. Data, 15, 1323 (1986).

[ - - equation

data]

0.14 ,..---------,-------,---0.12

T-----,------~l

+------+-----+------+--~--""7i__---_I

0.10 +----0.08 +------+- -------1I--~....'----~-+-------+---____j

0.06 +-----+-----..1---+-------1------+--------1
0.04 + - - - - . - - - - t - - -

-1-------+-------1

0.02 +----tII.=---+-0.00

500

1000

1500

2000

2500

Temperature, K

Figure 6 Thermal Conductivity of Gas for Oxygen

294

Table 6 Thermal Conductivity of Gas - Inorganic Compounds

(kg.. - W/(m K), T - K)

ka..=A+BT+cr+or
NO

10

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
SO
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
66
69
70
71
72
73
74
75
76
77
78
79
80

80
82
86
96
200
203
226
230
231
234
245
265
361
363
369
372
390
391
392
393
394
401
404
405
406
413
579
626
628
633
640
641
842
644
645
846
647
848
851
852
653
655
656
661
863
891
892
893
894
896
898
899

900
903
905
1002
1099
1124
1302
1303
1404
1406
1407
1408
1409
1412
1413
1434
1585
1639
1640
1660
1661
1663
1664
1665
1668
1669
1670
1671

FORMULA
A1B3HI2
A1Br3
A1C2H6CI
A1C6HI5

Ar
AsBr3
AsCI3
AsF3
AsF5
AsH3
As203
BBr3
BCI3
BF3
BH3CO
BI3
B2C14
B2D6
B2F4
B2H5Br
B2H6
B3N3H6
B4Hl0
BSH9
B5Hll
Bl0H14
B1F5
BrF3
BrF5
Br2
CBr20
CCI20
CF20
CH4N20
CH4N2S
CNBr
CNCl
CNF
CN408
CO
COS
CO2
CS2
C2N2
C302
CIF
CIF03
CIF3
ClF5
CIN02
CI02
Cl2
CI20
Cl205S2
Cl207
CoNC304
Cr02Cl2
Cs
02
020
FH03S
FNO
FN02
FN03
F2
F20
F202
FeC505
GaCI3
GeBr4
GeCH6
GeCI3F
GeCI4
GeF2CI2
GeF3C1
GeF4
GeHCI3
GeH2Br2
GeH2CI2
GeH3Br

NAME
aluminum borohydride
aluminum bromide
aluminum, dimethyl chloride
aluminum, triethyl
argon
arseniC (iii) bromide
arsenic trichloride
arsenic trifluoride
arsenic penta/luoride
arsine
arsenic trioxide
boron tribromide
boron trichloride
boron trifluoride
borane carbonYl
boron trilodide
diborane, tetrachloro
diborane, deutero
diborane, tetralluoro
diborane hydrobromide
diborane
borazine
tetraborane
pentaborane
pentaborane
decaborane
bismuth pentafluoride
bromine trifluoride
bromine pentafluoride
bromine
carbonyl bromide
carbonyl chloride
carbonyl fluoride
urea
thiourea
cyanogen bromide
cyanogen chloride
cyanogen fluoride
tetranltromethane
carbon monoxide
carbonyl sulfide
carbon dioxide
carbon disulfide
cyanogen
carbon suboxide
chlorine monofluoride
perchloryl fluoride
chlorine trifluoride
chlorine pentafluoride
nitryl chloride
chlorine dioxide
chlorine
chlorine monoxide
pyrosulfurvt chloride
chlorine heptoxlde
coball nltrosyitricartJonyi
chromium oxychloride
cesium
deuterium
deuterium oxide
fluorosulfonlc acid
nitrosyl fluoride
nitryl fluoride
fluorine nitrate
fluorine
fluorine oxide
dlfluorine dioxide
Iron pentacarbonyl
gallium trichloride
germanium bromide
gennane, methyl
germane, trichlorofluoro
Igermanium chloride
germane, dlchlorodlfluoro
germane, chlorotrifluoro
gennanium (iv) fluoride
germane, trichloro
germane, dlbromo
gennane, dichloro
1germane, bromo

CAS No

16962-07-5 -5.8628E-03
7727-15-3 -8.1783E-G2
1184583 2.8578E-03
97-93-8 -2.8452E-G3
7440-37-1 -3.0142E-04
7784-33-0 -1.5313E-02
7784-34'1 -1.6448E-02
778435-2 -1.0810E-02
7784-36-3 -1.2112E-02
7784-42-1 -2.9159E-03
1327-53-3 -8.3793E-04
10294-33-4 -1.1429E02
10294-34-5 -4.1806E03
7637-072 -3.8789E-04
t3205-44-2 -6.3705E-03
13517-10-7 -1.5319E-02
13701-67-2 -1.3407E-02
20396-66-1 -2.8656E-02
13965-73-6 -1.8715E-02
-8.4518E03
19287-45-7 -3.5568E-03
6589-51-3 2.6731E-03
18283-93-7 -1.1889E-02
19824-22-7 1.2789E-02
18433-84-8 -8.7515E-03
5.1661E-03
7787-62-4 -4.2919E-02
7787-71-5 -1.2957E-02
7789-30-2 -2.8551E-03
7726-95-6 -4.1129E-05
593-95-3 -1.3968E-03
75-44-5 -5.1302E-G3
353-50-4 -6.8849E-G3
57-13-6 -2.1856E-02
62-56-6 -1.7559E-03
506-68-3 -2.3665E-02
506-77-4 -2.2865E-02
1495-SO7 -1.1275E-02
509-148 4.7784E-03
630-08-0 9.9186E-04
463-58-1 -3.2182E-03
124'38-9 -6.0783E-03
75-15-0 -2.5681E-03
460-195 -2.5269E-02
504-64-3 -1.0169E-02
7790-89-8 -4.7144E-03
7616-94-6 -5.1892E-03
7790-91-2 -1.2945E-02
13637-63-3 7.9164E-03
13444-90-1 -5.6848E-03
10049-04-4 -1.1690E-02
778250-5 -4.6211E-03
7791-21-1 -5.2636E-03
7791-27-7 -1.4568E-02
10294-48-1 -9.7495E-03
14096-82-3 -9.2492E-03
14977-61-8 7.7457E-03
7440-48-2 2.8190E-02
7782-39-0 3.7319E-02
7789-20-0 -6.2280E03
7789-21-1 -4.6813E-03
778925-5 -2.4256E-02
10022-50-1 -3.3430E-03
7789-266 -3.2051E-03
7782-41-4 -4.4107E-03
7783-41-7 -1.6197E-G3
7783-44-0 -5.2346E-03
13483-40-6 -4.5242E-02
13450-90-3 1.4283E-03
13450-92-5 -2.7927E-Q2
1449-65-6 -4.8701E-03
24422-20-6 -1.9979E-02
10038-98-9 -2.1912E-02
24422-21-7 -1.9079E-Q2
14188-40-0 -1.4741E-Q2
7783-58-6 -2.6297E-02
1184-65-2 1.3192E-02
13769-38-3 -1.4585E02
15230-48-5 -1.2149E-02
13589-43-2 -1.2318E-02

---

_.-

295

4.9500E-05
3.7168E-04
2.9499E-05
4.6162E-05
6.8128E-05
1.0779E-04
1.3781E-04
7.3272E-05
1.3386E-04
5.1229E-G5
1.1692E-G5
l.oo30E04
6.7432E-05
6.0520E-05
1.8297E-04
l.oo73E-04
1.3162E-04
7.6495E-04
1.0495E-04
1.2741E-04
4.7778E-05
-1.7029E-04
2.5114E-04
-2.8106E-04
2. 1752E-04
-4.3842E-04
1.5112E-04
8.5502E05
3.5280E05
1.3233E-05
5.8183E-05
6.7857E-05
9.1946E-05
1.6059E-05
2.4153E-05
1.5063E04
1.7038E-04
1.1939E-04
3.3223E-05
9.4020E05
5.6192E-05
7.5351E-05
3.5506E-05
1.9602E-04
1.2448E04
1.0459E-04
5.9871E-05
1.0635E-04
3.7111E-05
1.2043E-04
1.1519E04
5.2370E-05
7.54SOE-05
1.6268E-04
1.3067E-04
2.oo57E-05
1.0738E04
-4.7985E-G5
3.5503E-04
9.4286E-05
3.7828E-05
1.8856E04
7.8402E05
7.9434E-05
1.2636E-04
1.2478E-04
8.4969E-05
3.0776E-04
2.0275E-05
2.0559E-G4
1.3524E-04
1.8755E-04
1.9667E-04
1.7736E-04
1.4835E-04
1.8137E-04
1.4587E-04
1.1792E-04
1.3125E-04
1.0789E-04

4.3454E-07
2.8287E-07
4.0947E08
9.5447E-08
-3.1822E-08
-5. 1546E-08
-5.1791E06
1.0328E-07
2.3624E-07
1.0056E-06
-1.3119E-l0
3.2101E-08
7.0335E06
6.7399E-09
-6.4655E-08
-4.0351E-08
3.7780E-07
-3.3334E-07
5.6982E-07
8.2961E-06
1.7087E-07
1.7661E-06
2.7548E-08
1.9647E-06
3.4053E-08
2.4726E-06
1.4917E-07
2.8771E-08
4.1402E-G7
7.0867E-09
2.7330E-06
2.1508E-07
1.8754E-G7
4.9122E-07
2.4794E-06
-7.7437E08
-5.9426E-09
6.3086E-06
3.7381E08
-4.0761E-08
6.6223E-09
9.4928E-09
9.8144E-09
6.5321E-08
2.5608E-07
-1.2255E-07
1.2S07E-08
3.2745E-07
7.3467E-07
-4.7521E-08
-2.1418E-08
-2.4171 E-08
6.0317E-08
1.9833E-G7
1.0627E-07
6.2536E-07
-3.6081E09
3.6325E-08
-1.0634E-G7
-6.9560E-06
2.5884E-07
-4.3003E-08
1.4160E-07
2.5775E-07
-7.9654E06
-5.9593E-08
2.5685E-07
3.5561E-07
2.3274E-09
-I. 7692E-07
-9.0492E-06
3.6465E-08
1.9546E-06
1.0459E-07
1.4229E-07
2.0264E-07
-1.8407E-08
-1.4804E-08
-1.8572E-08
1.1856E-08

-6.8523E-l0
-1.9973E-ll
-1.3975Ell
-1.6238E-ll
6.854OE-12
-8.1638E-ll
-1.5884E-l0
-2.6067E-l0
-6.3360E-l0
-7.3774E-12
-4.1049E-14
-2.4727E-l 0
6.5584E-ll
-2.0024E-12
-2.0672E-l0
-6.0835E-ll
-9.9605El0
-2. 1439E-09
1.1324E-09
-3.6026E-l0
-5.5618Ell
2.3373E-09
-2.6869E-l0
-2.3276E-09
-2.2927E-l0
-2.3520E-09
-2.7497E-l0
-1.7231E-l0
-1.0787E-09
-3.5344E-12
-1.3962E-l0
-6.2409E-l0
-5.3799E-l0
-5.4oo8E-l0
-3.9699E-12
-9.0863E-ll
-2.6648E-l0
-3.8551E-l0
-2.2239Ell
1.3751E-ll
-6.2634E-12
-1.1275E-l1
-5.3013E-12
-4.7630E-l 0
-7.9173E-l0
1.oo56E-l0
-8.7075E-12
-6.0678E-l0
-1.4709E-09
-2.6344E-l0
-2.0714E-l0
5.8757E-12
-3.3655E-l0
-6.1665E-l0
-4.2777E-l0
-8.8888E-l0
-2.4801E-l0
-8.2500E-12
3.4037E-ll
1.0380E-l0
-5.3307E-l0
-5.0657E-l0
-5.5267El0
-8.3020E-l0
3.0842E-l1
-5.0990E-l0
-6.4196E-l0
-1.0601E-09
-1.7806E-12
5.6478E-ll
-1.6001E-l0
-4.1871E-l0
-4.4731E-l0
-5.0105E-l0
-5.1879E-l0
6.0383E-l0
-2.8311E-l0
-1.7104E-l0
-2.4349E-l0
-1.6805El0

TMIN TMAX code .....TMIN .....25C kp,.TMAX

209
478
295
295
90
304
257
267
193
21t
730
226
273
173
150
316
181
ISO
217
169
181
216
152
227
ISO
373
453
282
ISO
295
ISO
ISO
159
406
536
325
267
191
295
70

309
578
1000
1000
2000
404
357
367
293
1000
1000
328
1000
1000
236
416
281

200
317
269
1000
316
252
327
2SO
473
553
382
200
1500
200
245
259
506
1000
425
367
291
1000
1500
223 1000
195 1500
273 1000
245 345
162 262
ISO 218
150 1500
197 297
170 270
ISO 228
214 314
200 1500
153 253
200
300
182 282
362
262
177 277
1000 1500
233 1500
277 773
184 284
ISO 241
ISO 207
ISO 198
1500
70
ISO 149
ISO 219
253
353
295 1000
299 399
ISO 215
223
323
222
322
221
321
207 307
258
358
202
302
258
358
205 305
241
341

2
2
2
2
1,2
2
2
2
2
2
2
2
2
1,2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
1,2
2
2
2
2
2
2
2
2
2
1,2
2
1,2
2
2
2
2
2
2
2
2
2
1,2
2
2
2
2
2
1,2
1,2
1,2
2
2
2
2
1,2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2

0.01716
0.03366
0.00905
0.01866
0.00558
0.01041
0.01286
0.01117
0.01802
0.00825
0.00761
0.01019
0.01033
0.01030
0.01692
0.00994
0.01681
0.07135
0.02229
0.01370
0.01032
0.02467
0.02594
0.02289
0.02390
0.06348
0.03060
0.00957
0.00611
0.00439
0.00624
0.00778
0.01033
0.02947
0.01770
0.01400
0.01709
0.01116
0.00770
0.00738
0.00957
0.00867
0.00776
0.02092
0.01333
0.00788
0.00404
0.014SO
0.01242
0.01022
0.00992
0.00493
0.00646
0.02097
0.01500
0.02297
0.00974
0.00828
0.11474
0.01675
0.00773
0.00134
0.00974
0.01171
0.00405
0.01404
0.01045
0.03826
0.00471
0.01624
0.01304
0.01906
0.01777
0.01987
0.01746
0.02364
0.01320
0.01193
0.01189
0.01065

0.02936

--

0.00921
0.01897
0.01736

---

0.01583
0.01331

-----

0.01306
0.01478
0.01141
0.01820

--------0.03699
---

0.02440
0.04695

--0.04195

------

0.01053
0.00444

_.-

----.-_.-

--

0.02034

._-

0.00786
0.02576
0.01396
0.01693
0.00875
0.02814

_.-

--0.01354
------0.01526
0.00900

--

0.03522

-------

0.02876

0.13462
0.01845

_.-

------0.02700
---_.0.05003
0.00478

---

0.02806
0.02661
0.02982
0.02839
0.02979
0.02116
0.01472
0.01888
0.01434

0.03066
0.04138
0.05361
0.12253
0.06350
0.01445
0.01893
0.01712
0.03149
0.05099
0.01068
0.01620
0.058SO
0.06487
0.02851
0.01379
0.03126
0.09385
0.03977
0.02481
0.15947
0.05141
0.04856
0.04947
0.04420
0.10201
0.03977
0.01430
0.01213
0.02383
0.00803
0.01525
0.02017
0.04205
0.04322
0.01939
0.02567
0.01932
0.04359
0.09672
0.05333
0.09025
0.03745
0.03298
0.02577
0.01120
0.06337
0.02632
0.02673
0.01599
0.01594
0.03938
0.01222
0.03543
0.02609
0.03781
0.01643
0.01010
0.44547
0.07298
0.01474
0.01154
0.01406
0.01620
0.11000
0.01399
0.01686
0.06110
0.01939
0.02236
0.01864
0.03032
0.02848
0.03209
0.02920
0.03691
0.02139
0.01789
0.01925
0.01644

Table 6 Thermal Conductivity of Gas Inorganic Compounds

(k.. W/(m K), T K)

k... =A+BT+cr+or
NO

10

81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
95
97
98
99
100
101
102
103
104
105
106
107
108
109
110
111
112
113
114
115
116
117
118
119
120
121
122
123
124
125
126
127
128
129
130
131
132
133
134
135
136
137
138
139
140
141
142
143
144
145
146
147
148
149
150
151
152
153
154
155
156
157
158
159
160

1672
1675
1686
1687
1691
1694
1695
1696
1697
1698
1699
1702
1709
1712
1713
1714
1716
1718
1719
1721
1722
1723
1724
1738
1739
1771
1774
1868
1869
1873
1960
2162
2203
2567
2572
2573
2582
2607
2608
2610
2613
2616
2619
2674
2675
2676
2678
2682
2683
2684
2685
2686
2701
2747
2748
2749
2750
2781
3034
3037
3091
3105
3198
3199
3222
3234
3235
3238
3378
3379
3380
3381
3382
3384
3387
3389
3392
3395
3396
3398

FORMULA
GeH3Cf
GeH4
Ge2H6
Ge3H8
HBr
HCN
HCI
HCI03S
HCI04
HF
HI
HN03
H2
H2O
H202
H2S
H2SO4
H2S2
H2Se
H2Te
H3NO
H3P02
H3P03
He
He
Hg
HgCH3CI
IF5

1F7
12
K
Kr
U
MoGI5
MoF5
MoF6
MoOF4
NCIO
NCI3
ND3
NF3
NHF2
NH3
NO
NOF3
N02
N2
N2F2
N2F2
N2F4
N2H4
N2H4C
N2H60
N20
N203
N204
N205
Na
NbCI5
NbF5
Ne
NiC404
02
03
Os04
P
P
PBra
PCIF2
PCf2F
PCI2F3
PCf3
PCI5
PF3
PF5
PH3
PH41
POBr3
POCl3
PSCI3

NAME
gennane, chloro
gennane
digennane
trigennane
hydrogen bromide
hydrogen cyanide
hydrogen chloride
chlorosulfonic acid
perchloric acid
hydrogen fluoride
hydrogen Iodide
nitric acid
hydrogen
water
hydrogen peroxide
hydrogen sulfide
sulfuric acid
hydrogen disulfida
hydrogen selenide
hydrogen telluride
hydroxylamine
hypophosphorous acid
phosphorous acid
helium-3
helium-4
mercury
methylmercury chloride
iodine pentafluoride
iodine heptafluoride
iodine
potassium
krypton
lithium
molybdenum (v) chloride
molybdenum (v) fluoride
molybdenum fluoride
molybdenum (vi) oxytetrafluoride
nitrosyl chloride
nitrogen trichloride
heavy ammonia
nllrogen trifluoride
difluoramine
ammonia
nitric oxide
trifluoramine oxide
nitrogen dioxide
nitrogen
cis-difluorodlazine
transdifluorodiazine
tetrafluorohydrazine
hydrazine
ammonium cyanide
hydrazine hydrate
nitrous oxide
nitrogen trioxide
nitrogen tetraoxide
nitrogen pentoxide
sodium
niobium (v) chloride
niobium (v) fluoride
neon
nickel carbonyl
oxygen
ozone
osmium tetroxide
phosphorus (white)
phosphorus (red)
phosphorus tribromide
phosphorus (iii) chloride difluoride
phosphorus (iii) dichloride fluoride
phosphorus (v) dichloride trifluoride
phosphorus (iii) chloride
phosphorus pentachloride
phosphorus (iii) fluoride
phosphorus (v) fluoride
phosphine
phosphonium iodide
phosphorus (v) oxybromide
phosphorus oxychloride
IDhosphorus thiochloride

CAS No

13637-655 -1.3369E-02
778265-2 1.2400E02
13818-89-8 -9.1592E-03
14691-44-2 -8.1425E-03
10035-10-6 -8.3366E-04
74-90-8 -2.4455E-02
764701-0 2.7487E-03
7790-94-5 4.6741 E03
7601-90-3 9.4298E-G3
7664-39-3 1.7093E-03
10034-85-2 -2.0000E-04
769737-2 3.7606E-03
1333-74.0 1.0979E-02
7732-18-5 5.6199E-03
7722-84-1 -6.1976E-03
7783-06-4 3.1184E03
7664-93-9 3.5316E-03
13465-07-1 6.6190E03
7783-07-5 -1.3315E-03
7783-09-7 -8.4098E-03
7803-49-8 6.7108E-03
630321-5 -1.5224E-02
13598-36-2 -1.8835E-02
14762-55-1 1.313OE-02
7440-59-7 3.0000E-02
7439-97-6 1.8250E03
115-09-3 4.2819E-03
7783-66-6 2.1528E-G2
16921-98-3 -4.0046E-02
7553-56-2 -1.1796E03
7440-09-7 1.4143E-Ol
7439-90-9 1.2610E-04
7439-93-2 1.5767E+OO
10241.05-1 9.0564E-02
13819-84-6 2.5178E-G2
7783-77-9 -3.9354E-02
14459-59-7 -2.0543E-02
2696-92-6 3.2585E-03
10025-85-1 -5.1900E-03
2.5994E-02
7783-542 -3.9082E-03
10405-27-3 -1.9770E-03
7664-41-7 9.1414E-03
10102-43-9 2.9995E03
13847-65-9 -4.4000E-03
10102-44-0 2.8701E-03
7727379 -2.2678E-04
13812-43-6 2.6579E-03
13776-62-0 4.6696E-03
10036-47-2 6.0721 E-03
302-01-2 -6.0522E-03
12211-52-8 -1.0962E-02
7803-57-8 -8.6618E-03
10024972 -8.3454E-03
10544-73-7 8.6155E03
10544-72-6 -1.4792E-02
1010203-1 -2.9117E-02
7440-23-5 1.5488E+OO
10026-12-7 -8.6134E-02
7783688 -4.6136E-02
7440-01-9 7.8034E-03
13463-39-3 -5.9075E-02
7782-447 1.5475E-04
10028-15-6 -3.2358E-03
20816-12-0 -1.5268E-02
772314-0 2.7678E04
772314.0 1.9797E03
7789-60-8 1.2275E-G2
14335-40-1 -1.4657E02
15597-63-4 -1.3347E-G2
13454-99-4 8.8704E03
7719-12-2 1.5364E-03
10026-13-8 -7.6631E-02
7783-55-3 -6.2490E-03
764719-0 1.0077E02
7803512 2. 1589E04
12125-09-6 -1.3540E02
778959-5 -2.7804E-02
10025-87-3 1.5210E-03
3982-91-0 -1.9215E02

_.

296

1.3009E-04
9.1289E05
1.3684E-04
1.2711E-04
2.8693E-05
1.8827E-04
6.1287E-05
5.7225E-05
1.4377E-04
6.3912E-05
2.3010E-05
4.7737E05
6.6411E-04
1.5699E-G5
7.5527E-05
3.5162E05
3.0385E05
8.4463E05
4.2854E-05
8.4825E-05
8.4479E-05
8.1OO4E05
6.8964E-05
7.3068E-04
4.2897E-04
6.5254E-06
3.3691E05
1.3274E04
2.2149E-04
1.7719E-05
2.4121E-04
3.3619E-05
1.4000E-03
4.0355E04
1.3030E-04
2.3809E-G4
7.2517E05
5.4642E-05
4.8811E-05
2.8906E04
6.9781E-05
7.4322E-05
7.2945E-06
8.3047E-05
1.2573E-04
5.4591E05
1.0275E-04
7.2079E-05
1.0201E-04
6.4653E05
6.5546E-05
1.9761E-05
7.7357E-05
9.3978E-05
9.6383E-05
8.4210E-05
1.2458E-04
-3.2414E-03
3.9313E-04
1.5381E04
1.4979E-04
4.4038E-04
9.4153E-05
7.7033E-05
8.7216E-G5
2.24745E-05
2.7751E-05
1.1330E04
1.5573E-04
1.4411E-04
1.5801E-04
3.0981E-05
3.7537E-G4
9.8371E05
5.6298E-05
5.6917E05
8.5633E-05
1.7503E-04
2.5134E-05
1.5359E-04

1.7108E-08
1.5424E-08
2.7316E-G8
-3.4770E09
9.5348E09
6.0312E-08
-7.9739E-09
1.2119E-07
3.8598E-08
2.8049E-08
3.4897E-09
2.1888E-G8
3.4378E-07
1.0106E-07
9.7463E-G9
4.4168E-08
9.0703E-09
-6.1993E-G9
5.1062E-09
-5.6937E-08
3.9258E08
1.9082E-07
2.6232E-07
6.3117E-07
-1.2065E-G7
1.5652E08
5.0288E-08
9.7639E08
3.6975E07
1.0367E08
1.5250E-07
8.2505E09
3.3333E-07
2.9799E-07
7.1037E-08
1.7024E07
2.1394E-G7
-2.6315E-09
-1.0609E-08
-1.2694E-07
1.9067E-08
4.4646E-08
2.1686E-07
1.5184E-08
6.0614E-08
2.5961E-08
-6.0151E-08
1.5630E-07
2.2127E-07
2.3992E-08
7.0138E-08
4.4512E-07
2.1711E-07
-l.6490E-08
1.9104E07
2.5931E-07
4.1364E-07
2.323OE-06
-2.8730E-07
1.6515E07
-4.8802E-08
5.7309E-08
2.7529E-G8
4.2930E-09
8.0122E08
2.08266E-09
5.0454E09
4.6206E08
1.2415E-07
4.7249E-08
4.3426E-09
-1.1549E-09
-2.5201E-07
3.8260E-07
8.9195E-07
5.9919E-08
7.4957E-08
-9.4781 E-08
5.6564E-l0
8.0854E-08

2.1896El0
O.OOOOE+OO
-2.6514E-l0
-2.6821E-l0
-3.9500E-12
-3.8547E-l0
1.2821E-12
-3.0550E-l0
-3.6486El0
1.2417Ell
9.5771E13
9.9748E12
9.7283E-l1
-2.4282E-l1
-6.9303E-12
1.4768E-ll
-3.3673E-12
-1.7666E-l0
-1.6227E-12
-6.9966E-ll
-1.7731E-ll
-3.5177E-l0
-3.8653E-l0
2.7567E-l0
2.6846E-l1
-6.7644E-12
-1.2490E-l0
-3.4164E-l0
-8.6953El0
3.1131E-12
-2.9167El1
2.1564E-13
1.3245E-23
-2.1741E12
2.4554El0
-5.8493E-l0
3.2564E-l0
1.8322E-12
O.OOOOE+OO
-4.5781E-l0
-2.1173E-ll
-1.4066E-l0
-6.4465E-ll
1.8810E-12
-2.1098E-l0
-1.4272E-ll
2.2332E-ll
-5.5807E-l0
-8.5063El0
-2.1983Ell
-2.5329Ell
-5.7975El0
-4.3120E-l0
1.1756E-12
-5.9027El0
-4.9955E-l0
-6.9338E-l0
-5.5333E-l0
1.1714E-ll
-2.9501El0
6.1061E-12
8.6007E-l0
5.2069E-12
-8.1952E12
-2.1313E-l0
4.5303E-13
7.4069E13
-1.5113El0
5.2511E-l0
-3.8733El0
-3.8010El0
-1.7142E-12
-5.7355E-ll
-l.l109E-09
-1.6812E-09
-2.5569E-ll
-2.1299E-l0
9.9260El1
1.2929E-12
-4.2245E-l0

TMIN TMAX code ""OTMIN ",,025C ""'OTMAX

0.01939
0.01220
0.01809
221
321
2
0.06347
0.00946
0.01345
250 1000
2
0.01139
0.02020
164 264
2
0.02048
0.01180
168 268
2
0.05033
0.00846
223 1500 1,2 0.00600
0.03314
0.02178
0.02682
260
360
2
0.07557
159 1500 1,2 0.00680 0.01485
0.01482
193 293
2
0.00870
0.02518
0.01458
172 272
2
0.01951
0.03160
295 450
2
0.01927
0.02970
0.00638
230 1500 1,2 0.00492
0.01215
0.05569
2
0.01197
295 1000
0.56195
14 1500 1,2 0.02021
0.18100
0.17461
0.01864
150 1500 1,2 0.01017
0.10563
0.01700
295 1500 1,2 0.01675
0.01714
0.10540
213 1500 1,2 0.01246
0.03256
2
0.01761
610 1000
0.00758
0.01280
183 283
2
0.01186
0.04501
231 1000
0.00883
2
0.01072
324
0.00996
0.00997
298
2
0.02117
0.02150
0.09929
2
295 1000
0.02517
0,01672
300 400
2
0.02992
2
0.02059
348 448
0.38831
0.18218
10 1000 1,2 0.02037
0.14788
0.62010
100 2000 1,2 0.07172
0.00498
0.02400
295 1500 1,2 0.00494
0.00832
0.00533
0.00692
250
350
2
0.02442
0.01607
0.01767
283
383
2
0.04976
0.03179
0.03581
280
380
2
0.00326
0.01258
295 1500 1,2 0.00323
0.02430
1100 1500 1,2 0.02180
0.03609
100 2000 1,2 0.00341
0.00942
0.11000
1700 2000 1,2 0.16000
0.04341
0.03550
491 591
2
0.02500
2
0.01770
340 440
0.04476
0.03126
291 391
2
0.02987
0.01919
0.02706
371 471
2
0.01115
0.01275
0.04692
268 1000
2
0.03301
0.00635
0.00842
250 1000
2
0.03668
197 297
2
0.02255
0.01803
0.06377
144 1000
2
0.00648
0.00998
150 200
2
0.00769
0.26811
0.02452
240 1500 1,2 0.01895
0.09975
121 1500 1,2 0.01286
0.02646
0.01753
150 212
2
0.01238
0.02108
0.09500
295 1500 1,2 0.02087
0.09392
0.02565
63 1500 1,2 0.00603
0.01355
0.00979
150 200
2
0.01788
150 201
2
0.01274
0.01475
0.06059
2
0.00757
199 1000
0.10430
0.01874
0.01905
295 1000
2
0.03193
0.02056
309 409
2
0.02432
0.02227
221
321
0.01443
2
0.09949
0.01824
173 1500 1,2 0.00744
0.01972
0.01039
170 270
2
0.02597
0.01607
0.02013
262 362
2
0.04417
314 414
2
0.02935
0.04600
1200 1450 1,2 0.04810
0.04281
477 577
2
0.03477
0.03948
452 552
0.02990
2
0.16102
0.04829
30 2000 1,2 0.01225
0.06582
2
0.04234
0.05452
254
354
0.12000
0.02592
80 2000 1,2 0.00751
0.01990
0.06990
162 1000
0.00931
2
0.01946
314 414
0.01343
2
0.03276
200 1600 1,2 0.00469
0.02147
700 1000 1,2 0.01523
0.01475
0.00971
0.01339
233
333
2
0.02889
0.02906
200 300
2
0.01725
0.02355
0.02368
0.01427
200
300
2
0.02480
0.01365
150 248
2
0.00755
0.02658
200 1000 1,2 0.00460
0.04317
433 533
0.03402
2
0.02225
0.01337
150 222
2
0.03861
179 279
0.01901
2
0.02140
0.09105
185 1000
0.01223
2
0.01253
0.01301
0.01870
292
392
2
0.02201
429
0.01600
329
2
0.02175
0.00581
0.00589
295 1000
2
0.02257
0.02556
237
337
2
0.01610

----

._...

.---

.---

.-

...-.

_.

.-.

...

---

--

.-.

--

_..-.

-_.

--

.-.

...
...

.....
.-

---

--

Table 6 Thermal Conductivity of Gas - Inorganic Compounds

(~. W/(m K), T K)

~=A+BT+cr+Dr
NO
161
182
163
164
165
166
167
168
169
170
171
172
173
174
175
176
177
178
179
160
181
182
183
184
185
186
187
188
189
190
191
192
193
194
195
196
197
198
199
200
201
202
203
204
205
206
207
208
209
210
211
212
213
214
215
218
217
218
219
220
221
222
223
224
225
226
227
228
229
230
231
232
233
234
235
236
237
238
239
240

ID

FORMULA

3399 PSClF2

3400 PSF3
3443 P2C14
34 P2F4
3448
3451
3461
3504
3781
3940
3974
3991

3994
3996
3998

3999
4000
4001

4002
4004
4005
4008
4007
4008
4009
4010
4013
4014
4015
4020
4042
4044
4047
4089
4109
4110
4115
4116
4118
4123
4143
4144
4145
4146
4149
4150
4152
4153
4157
4187
4198
4238
4240
4241
4242
4243
4244
4245
4246
4247
4248
4250
4251
4252
4253
4257
4258
4259
4280
4261
4274
4275
4288
4288
4289
4290
4291
4295
4298
4297

P203
P2S5
P406
PbC8H20
Rb
Rn
RuF5
S
SCl2
SCl20
SF4
SF5Br
SF5CI
SF6
SF80
SOBr2
SOCl2
SOF2
S02
S02CI2
S02F2
S03
S2CI2
S2F2
S2F2
S3C12
SbCI3
SbCI5
SbH3

sees
SeF4
SaF6
SaOCI2
SeOF2
Se02F2
Se2C
SIBrCI2F
SlBr2CIF
SiBr3C1
SIBr4
SlCH3C13
SiCH4CI2
SlC2HSCl3
SiC2H8CI2
SIC3Hl0
SlC7H8CI2
SICSH20
SiCIC3H9
SlCIF3
SlCI2F2
SlCl3Br
SiCI3F
SiCl4
SlF4
SiHBr3
SIHCl3
SiHF3
SiH2Br2
SlH2CI2
SIH2F2
SIH212
SiH3Br
SlH3CI
SIH3F
SIH31
SIH4
Sl2C6H180
Si2C6H19N
Si2CI6
Si2F6
Si2H8
Si2H60
Si20C13F3
Si3CI8
Si3H8
Sl3H9N

NAME
phosphoNS (v) sulfide chloride difluoride
phOSphoNs (v) sulfide trifluoride
phosphorous chloride
phosphorous difluoride
phOSphONS trioxide
phOSphoNS (v) sulfide
phosphorous (iii) oxide
tetraethyl leed
Nbldium
radon
Nthenlum (v) fluoride
sulfur
sulfur dichloride
thlonyl chloride
sulfur tetrafluoride
sulfur bromide pentefluoride
sulfur chloride pentafluoride
sulfur hexafluoride
sulfur fluoride hypofluorite
thlonyl bromide
thlonyl chloride
thlonyl fluoride
sulfur dioxide
sulfuryl chloride
sulfuryl fluoride
sulfur trioxide
sulfur monochloride
1,1 dlfluorodlsulfane
difluorodisulfane
trisulfur dichloride
antimony trichloride
antimony pentachloride
stiblne
selenosulflde, carbon
selenium tetrafluoride
salenlum hexafluoride
selanlum oxychlorida
selenium oxylluoride
selenium dioxvdlfluoride
dlselanlde, carbon
silane, bromodichlorofluoro
silane, dlbromochlorofluoro
silane, tribromochloro
tetrebromosilane
silane, methyltrichloro
silane, methytdichloro
silane, ethyttrichloro
silane, dlmelhyldlchloro
silane, lrimethyl
silane, methylphenyldlchloro
silane, letraethyl
chlorotrimelhylsllane
silane, chlorotrifluoro
silane, dlchlorodilluoro
silane, bromotrichloro
silane, lrichlorofluoro
silicon tetrachloride
silicon tetrafluoride
silane, tribromo
silane, trichloro
silane, lrifluoro
silene, dibromo
silane, dichloro
silane, difluoro
silane, dllodo
silane, monobromo
silane, monochloro
silane, monofluoro
sllane,lodo
silane
disiloxane, hexamethyl
disilazane, hexamethyl
disilane, hexachloro
disilane, hexafluoro
dlsilane
dlslloxane
disiloxane, trichlorotrifluoro
octachlorolrisilane
lrisilane
trisilazane

CAS No

2524-02-9 -5.2472E-03
2404-52-6 -5.7155E-03
13497-91-1 -1.9907E-02
13824-74-3 -1.2274E-Q2
1314-24-5 -1.8788E-Q2
1314-80-3 -5.1602E-03
12440-00-5 -2.4785E-02
78-00-2 -2.0265E-03
7440-17-7 3.4200E-02
10043-92-2 -4.6415E-03
1452t-I8-7 -3.0828E-Q2
7704-34-9 1.8213E-03
10545-99-0 -2.0640E-03
7719-09-7 -2.3325E-03
7783-60-0 -6.5497E-03
15607-89-3 1.0435E02
13780-57-9 1.3289E-02
2551-624 1.2608E02
15179-32-5 1.2263E02
507-16-4 -8.3251E-03
7719-09-7 -7.2367E-03
7783-42-8 5.4377E03
7446-09-5 8.5308E-04
7791-25-5 -2.5536E-03
2699-79-8 -4.9145E-03
744611-9 -5.2423E-03
10025-67-9 -9.6121E-Q3
1019<17-3G-2 3.3686E03
13709-35-6 5. 1977E-03
31703-09-0 -2.0807E-02
10025-91-9 -4.0347E-Q4
7647-18-9 -2.4650E-02
7803-523 6.671 OE-03
595119-9 -6.223OE-Q3
13485-86-2 -8.9981E-Q3
7783-79-1 1.3689E-02
7791-23-3 1.5264E-Q2
7783-43-9 -1.1141E-02
14984-81-7 -9.0274E-Q3
506-80-9 7.7052E-03
_8.9533E-03
-8.6911E-03
f3485-78-4 1.5729E-02
7789-66-4 -2.3264E-02
75796 2.6130E-03
75-54-7 3.2504E-03
115-21-9 -9.3268E-Q4
7578-5 1.1159E03
933-07-7 8.3073E-04
149-74-6 -1.5783E-03
63136-7 -3.oo71E03
6.7184E-03
75-774
1404938..fl -9.1906E-03
18356-71-3 2.0493E-02
13485-74-2 -1.503OE-02
14985-52-7 -1.0837E-02
10028-04-7 7.3845E-04
7783-61-1 -1.9431E-03
7789-57-3 9.0268E-03
fOO25-78-2 -7.7555E-04
f3485-719 7.2282E03
13786-94-0 7.2109E-03
4109-96-0 -7.0566E-04
13824-36-7 -6.23OOE-Q3
13760-02-6 1.oo72E-02
13465-73-1 -5.2162E-03
13485-78-6 -5.84ooE-03
13537-33-2 -2.8028E-03
13598-42-0 -5.5943E-03
7803-62-5 -1.6229E-03
107-46-0 -3.8403E-03
999-97-3 -2.5185E-Q3
13465-77-5 3.0809E-02
1.5427E-02
1590-87-0 -4.9313E-Q3
13597-73-4 8.4608E-Q3
-1.7899E-02
1.6907E-02
7783-26-8 1.0736E-Q2
1.3050E-Q2

--

...

----.
---

297

1.3782E-04
7.0529E-05
1.6811E-04
1.4438E-04
1.1083E-04
5.8960E-05
7.5717E-05
2.0229E-05
-4.79OOE-05
5.5608E-05
1.0333E-04
1.7486E-05
3.6292E-05
3.8066E-05
8.1934E-05
1.1418E04
3.6381E05
1.0098E-Q4
1.4448E-04
8.2023E05
1.0154E-04
6.9419E-05
8.8212E06
3.75OOE05
5.2211E-05
5.9854E-05
1.0069E04
6.2802E-05
7.2546E05
1.8946E04
1.4994E-05
1.8227E-04
8.1264E05
7.0892E-05
5.6693E-Q5
9.1688E-Q5
1.1463E-04
7.1241E-05
1.2017E04
7.4120E05
1.3726E04
1.1971E-04
1.2738E04
1.7652E-Q4
3.4047E05
4.0189E-05
2.3483E-05
2.2935E05
2.3087E-Q5
3.0123E-05
2.7227E05
-1.8875E-05
1.1123E-04
1.7538E-04

-3.5839E-08
5.7tt8E-07
8.6485E-08
2.3725E-Q7
1.5094E-07
1.5038E-Q9
6.0969E-Q7
3.4781E-08
3.05OOE-08
-7.3986E-08
1.1429E-07
-7.5756E-l0
-3.3047E-09
-1.6990E09
5.3888E-07
2.4704E-07
9.5864E-07
-4.0571E-08
3.7161E07
8.223OE09
-7.2721E-09

-3.3429E-l0
-1.4112E-09
-4.2364E-l0
-6.7283E-l 0
-3.5540E-l0
-7.2873E-13
-9.2716E-l0
-1.1389E-l1
-5.0000E-12
O.OOOOE+OO
-2.0244E-l0
-4.6016E-13
-9.8212E-13
8.1021E13
1.2346E09
-6.0171El0
-1.6556E-09
8.6317E12
8.3367E-l0
1.7006El0
-2.3489E-l0
-7.4156El0
-5.0333Ell
-3.9111E-12
-1.1550E-09
-9.2357E-12
-3.3939El0
-7.5580El0
-6.6454E-l0
-4.7046E-l0
5.4166E-13
-2.9383E-l0
-1.2410E-l0
-1.7160E-l0
-3. 1883E-l0
-9.7582El0
1.3052El0
-1.9351E-l0
-3.3514E-l0
1.1667E-l0
-3.4533E-l0
-3.2052E-l0
-2.7071E-l0
-1.4022E-l0
6.2541E-12
8.7801E-12
-1.1584E-ll
-1.3574E-ll
-5.0834E-ll
-7.6638E-12
-2.1156Ell
-4.2549E-ll
-1.5879E-09
-7.0289E-l0
-3.6750E-l0
1.2273E09
1.1995E-l0
5.8693E-13
3.8205E-l0
-6.4615E-12
-1.2327E-09
-4.1483E-l0
4.2415E-l1
-7.9597E-l0
-2.0282E-l0
-4.8226E-l0
-6.4752E-l0
-4.8913E-l0
-3.3847E-l0
2.2874Ell
-1.8925E-ll
-4.4672Ell
6.6413El0
-1.4320E-09
-2.0866E-ll
-2.1824E-l0
-8.9756E-l0
-7.0565E-l0
-3.1162E-l0
-5.2087El0

"54'5E-04
1.2395E04
5.2908E-05
5.9859E-05
8.8529E05
2.4950E-05
8.8952E-05
6.1426E05
3.6337E-05
8.1823E-05
6.53OOE-Q5
5.1159E-05
7.6210E-05
1.0292E-04
4.0629E05
6.2666E05
3.9305E05
1.4591E-05
2.1121E-Q4
5.0062E05
6.0165E-05
2.0444E04
1.8849E04
2.0531E04
2.0004E-Q4
2.1250E-04

2.7794E07
8.3662E-08
5.0173E-09
5.1745E07
3.9263E-Q9
5.6946E08
2.4057E-07
2.153OE07
7.7029E-08
-2.1919E-Q9
9.5944E-Q9
-3.8140E-08
1.0837E-08
1.6313E07
5.5568E-07
3.0764E08
6.7116E-08
4.1866E-08
-1.7532E-08
5.5239E-Q9
2.5346E-Q8
3.8396E-08
-9.7420E08
1.2907E-08
1.9973E-Q8
4.0105E-08
4.9929E-08
1.1845E-07
3.8835E-08
7.0645E-08
1.3801E-07
6.0698E-07
2.5669E-07
3.5746E-08
4.1979E-07
-1.0829E-07
-3.9229E-09
9.5805E-08
2.1286E-08
5.2255E-07
1.7387E-07
-1.4033E-08
3.4994E-07
7.2794E-08
2.2254E-07
2.7326E-07
1.1638E-07
1.6963E-07
7.1298E-08
5.5859E08
1.0514E-07
2.4689E-07
9.6593E-Q7
5.2746E08
1.1254E-07
3.4963E07
1.8864E-07
-6.8285E-09
1.2267E07

TMIN TMAX code .....TMlN .....25C ......TMAX

150
150
245
187
297
787
297
295
1000
202
450
717
295
295
150
194
209
273
187
223
172
150
250
295
150
295
196
150
150
227
295
276
185
198
263
238
282
288
174
229
161
174
252
279
295
295
295
295
280
295
295
295
150
229
211
152
295
295
200
295
150
203
281
151
272
179
155
150
216
161
295
295
272
255
259
150
200
200
156
167

218
224
345
287
397
1000
397
1000
1500
302
550
1000
1000
1000
248
294

309
1500
287
323
272
244

900
1000
237
1000
296
209
240
327
1000
376
285
298
363

338
382
388
274
329
261
274
352
379
1000
1000
573
650
1000
1000
1000
650
235
329
311
252
650
702
300
650
242
303
650
251
372
279
255
200
316
750
1000
1000
372

355
1000
229

300
300
256
267

2
2
2
2
2
2
2
2
1,2
2
2
1,2
2
2
2
2
2
1,2
2
2
2
2
1,2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
1,2
1,2
2
2
2
1,2
2
2
2
2
1,2
1,2
2
1,2
2
2
1,2
2
2
2
2
2
2
1,2
2
2
2
2
2
2
2
2
2
2

0.01349
0.01295
0.02026
0.01857
0.01813
0.04184
0.02718
0.00668
0.01160
0.00362
0.02038
0.01380
0.00833
0.00873
0.01070
0.01664
0.02111
0.01212
0.02233
0.00850
0.00883
0.00873
0.00745
0.00885
0.01066
0.01252
0.00977
0.00891
0.00829
0.02069
0.00384
0.02020
0.00828
0.00690
0.01141
0.02654
0.01166
0.01033
0.01135
0.00697
0.01183
0.01120
0.01451
0.01532
0.00839
0.01012
0.00919
0.00965
0.01379
0.01049
0.01063
0.01207
0.01579
0.02482
0.01565
0.01345
0.00852
0.01539
0.00963
0.00827
0.01371
0.00896
0.00938
0.01135
0.00900
0.00833
0.01013
0.01360
0.00769
0.01022
0.01213
0.00979
0.03153
0.03629
0.01383
0.01894
0.02680
0.02606
0.01908
0.02353

---0.02667

--

0.01825

---

0.02741
0.00679

--

0.00542
_..

--

0.00844
0.00884

.---

0.03890
0.01412

--

0.01235

.---

0.00953
0.00897

..-

0.01271

--...
._.

0.03008
0.00389
0.02276

..-

0.01396
0.03718
0.01272
0.01094

.._.

0.00974

--

0.01849
0.01699
0.00852
0.01027
0.00933
0.00980
0.01523
0.01065
0.01083
0.01223

...

0.03616
0.02437

._.

0.00859
0.01557
0.01629
0.00838

._.

0.01556
0.01000

._.

0.01049

-..
-.--.

0.01263
0.02279
0.01234
0.00999
0.03651
0.04741
0.01714
_..
0.04579
0.04237
_..

-.-

0.01964
0.02292
0.03099
0.03276
0.02676
0.05460
0.04335
0.04159
0.01410
0.00547
0.02690
0.01809
0.02994
0.03322
0.02314
0.02921
0.04066
0.07670
0.04013
0.01330
0.01512
0.01725
0.03969
0.03605
0.02118
0.04930
0.01639
0.01334
0.01544
0.03295
0.01294
0.02962
0.01052
0.01130
0.01783
0.04316
0.01675
0.01531
0.02013
0.01064
0.02110
0.01941
0.02208
0.02199
0.03809
0.04813
0.02352
0.03116
0.08986
0.05972
0.07371
0.04108
0.02988
0.04019
0.02532
0.02745
0.02084
0.03837
0.01639
0.02286
0.02740
0.01583
0.02863
0.02373
0.01386
0.01592
0.02063
0.01852
0.01351
0.07583
0.07240
0.07254
0.04773
0.05992
0.08711
0.02985
0.04608
0.04261
0.03478
0.04259

Table 6 Thermal Conductivity of Gas -Inorganic Compounds

~=A+BT+cr+Dr
NO

ID

FORMULA

NAME

241 4300 Si4Hl0

tetrasHane
242 4335 SnBr4
stannic bromide
243 4337 SnCH6
methylstannane
244 4424 SnC/4
stannic chloride
245 4431 SnH4
stannane
246 4590 TeF6
tellurium hexafluoride
247 4643 TIBr4
titanium (Iv) bromide
248 4678 TICI4
titanium tetrachloride
249 4787 UF6
uranium fluoride
250 4860 VCI4
vanadium tetrachloride
251 4880 VOCl3
vanadium oxytrichloride
252 4917 WF6
tungsten fluoride
253 4926 WOCl4
tungsten (vi) oxytetrachloride
254 4927 WOF4
tungsten (vi) oxytetrafluoride
255 4945 Xe
xenon
256 4947 XeF2
xenon difluoride
257 4949 XeF4
xenon tetrafluoride
258 4950 XeF6
xenon hexafluoride
zinc
259 5021 Zn
code: 1 - data, 2 estimate
k.., - thermal conductivity of gas, W/(m K)

CAS No

7783-29-1 -1.2588E-02
7789-67-5 -2.7116E-02
1631-78-3 -6.5765E-03
7646-78-8 -2.4663E-02
2406-52-2 -5.1206E-03
7783-80-4 -2.0636E-02
7789-68-6 -5.0966E-02
7550-45-0 -2.3964E-02
7783-815 -3.8916E-02
7632-51-1 -1.4338E-03
7727-18-6 -1.3541E-Q3
7783-82-6 -3.1551E-02
1352().78-o 5.7826E-02
1352().79-1 -2.6155E02
744()'63-3 1.4358E-04
13709-36-9 -2.1064E-02
13709-61-0 -2.4509E-02
13693-09-9 1.71 Q9E02
744()'66-6 1.4926E03

A, B, C, and 0 - regression coellicients for chemical compound

T temperature, K
TMIN minimum temperature. K
TMAX - maximum temoerature. K

298

(kgo W/(m K), T - K)

1.6692E-04
2.0092E-04
1.1794E-04
2. 1538E04
1.0069E-04
1.6986E-04
2.4850E-04
1.9895E-04
2.2005E04
2.9516E-05
2.4639E-05
1.9198E04
2.6353E-04
1.2233E-04
1.8766E-05
1.0324E-04
9.4028E-05
5.1363E05
2.6956E-05

3.5453E-07
1.8596E-07
3.8142E-08
-8.2927E-08
-5.7443E-08
3.8787E-07
1.9722E07
-5.3692E-08
6.6806E-08
-3.8382E-Q9
-2.7181EQ9
2.2078E-07
1.3838E-07
3.4948E-08
1.9673EQ9
-2.4536E-08
1.5041E-07
4.2030E-07
-7.1293E-Q9

-7.7895E-l0
-3.5048E-l1
-1.6328E-l0
-2.8480El0
-1.9607El0
-8.7462E-l0
5.6464E-13
-2.7946E-l0
3.5284E-10
5.5586E13
1.3869E-13
-6.1827E-l0
-7.1789E-ll
-1.6713E-l0
5.5315E13
-7.2597E-ll
-2.6408E-l0
-5.9504E-l0
1.5839E12

TMIN TMAX code "".TMlN

0.02633
189 289
2
0.01566
302 402
2
2
0.00971
150 250
2
0.01820
239
339
150 227
2
0.00803
0.02946
236
336
2
0.02120
453 553
2
249
2
0.01794
349
0.02935
337 437
2
2
0.00695
295 1000
2
0.00568
295 1000
0.02516
275
375
2
451 551
2
0.02626
0.01614
379
479
2
100 1500 1,2 0.00200
0.01176
402 502
2
0.01940
2
390 490
2
0.02323
323 423
0.00781
250 1500
2

"".25C .....rMAX
0.04643
0.02134
0.01797
0.02773
0.02463
0.01249
0.04130
0.04699
0.02624
0.02705
0.02317
0.04057
0.00704
0.02480
0.02071
0.00575
0.03893
0.02893
0.03334
0.02210
0.00555
0.02200
0.01540
0.02662
0.03475
0.03123
0.00894

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