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Quantum Mechanics combines both wave and particle aspects of matter into a unified theory
Properties of Waves
Electromagnetic Spectrum a continuous range of radiant energy
- Gamma Rays, X-Rays, Ultraviolet, Visible Light, Infrared, Microwaves, Radio Waves
Know: visible range is 400750 nm (violet to red) and the
ORDER
of
Wavelength () the distance from crest to
crest or trough to trough on a wave
Frequency () the number of crests of a
wave that pass a stationary point of
reference per second
Hertz (Hz) the SI unit of frequency, 1 Hz = 1
s-1 = 1 cycle per second (cps)
Amplitude the height of the crest or the
Each element emits characteristic electromagnetic radiation when its atoms are heated to a sufficiently high
temp
Each element absorbs characteristic electromagnetic radiation when illuminated by an external source of
radiation
These emissions and absorptions occur at the SAME
Threshold Frequency (0) the minimum frequency of light required to produce this effect
Intensity depends on the number of e- possible, i.e. number of photos (1 photo = 1e-)
Each photon is absorbs by an individual e-, either giving it enough to break free, or
=h 0
not
If < 0, no photoelectrons (the name for e-s emitted by this effect), no matter how
minimum
needed to
intense
If 0, number of e-s depends on intensity (more photons higher intensity)
0, the frequency of the minimum quantum of absorbed energy needed to remove a
single e-from a metal surface minimum quantity of energy is called the metals work
KE=h h 0=h function ()
The value of is related to the strength of the attraction between the nuclei of
E photon=+ KE electron ;
the metal atoms & the e-s surrounding those nuclei (thus, different for different
E photon ,
metals)
If photons with > 0, any extra energy (in excess of ) is KE of each emitted
e
-
Hydrogen Spectrum
- Balmer lines corresponding to the visible spectrum of hydrogen fit in a simple equation
- Rydberg more general form1
1
1
2
1
=R
2 (lab)?
H
;
R H =1.097 10 nm
Only works for hydrogen
type
atoms
2
n 1 n2
- Bohr Model: hydrogen atom consists of an electron in a concentric orbit around the nucleus
Electrons can only exist in these discrete orbits
1
18
Each orbit corresponds to certain energy level
E=2.178
10
J 2
Lines in absorption and emission spectra correspond to e s moving
n between different
levels
n = 1 has the lowers energy; as n, E0; zero energy means that the e- is a free
e Shows that energy is quantized because only certain values determined by n
values
The parameter n is called a quantum number
Electrons can only move between discrete orbitals (while
absorb/emitting )
Quantum Number one of four related numbers that specify the
shape and energy of orbitals in an atom; the ''address'' of an
electron in an atom or ion
Ground State the most stable, lowest energy state available to
atom or ion
Excited State any energy state in an atom or ion above the
ground state
Electron Transition movement of an electron between energy
levels
The atomic emission/absorption spectra reveal the s of e-s inside atoms
1 1 When n(final)>n(initial), is absorbed (E>0) low to high state
E=2.178 1018 2 2 When n(final)<n(initial), is emitted (E<0) high to low state
ni works for hydrogen and hydrogen-like atoms
f
nONLY
Cannot adequately explain spectra of multi-electron atoms and ions
ionization (make e- free)
Movement of electrons is different from Bohrs predictions
e- emitting energy
possible transitions for
de Broglie: matter also behaves as both a particle and a wave
hydrogen
- De Broglie wavelength: =h/mv; = m, m = kg, v = m/s
This equation tells us the wave length of all moving particles
Matter Wave the wave associated with any particle
- Electrons behave like circular wave oscillating around nucleus
Implications: the state of the electron is described by a quantum number (n)
Standing Wave a wave confined to a given space (length L) where L=n (/2) ;
( )
n W
Same as Bohrs n. As n , orbital size(i.e. the e- is more likely to be further from the
nucleus). This means that the atom becomes larger. In general as n, Energy
n=1; l=0 ( s ) ; ml=0 only one 1 s orbital
Angular momentum (azimuthal) quantum number ( l )
- Defines shape. Value depends on n (0 l n-1).
n=2; l=0,1 ( s , p ) ; m l=0m l=1, 0,1 on
s, 1
p, 2
d, 3
f) >>> s, p, d, and f orbitals
l identified by letter (0
n=3; l=0,1, 2 ( s , p , d ) ; m =0m =1, 0, 1
-
ml )
(- l m l l ).
Fourth Quantum Number Spin Magnetic Quantum Number ( m s ) spin is either up or down (
)
Pauli Exclusion Principle: no 2 e-s in a multielectron atom can have the same 4 quantum numbers (each orbital can hold 2
-
e-s)
zero (| 2|=0 )
- To Draw: circle
A total of 3 p-orbitals, each lying along a different axis
- All have a node at the nucleolus
- To Draw: figure 8
A total of 5 d-orbitals
A total of 7 f-orbitals
The Periodic Table and Filling the Orbitals of Multi-electron Atoms
Aufbau Principle the method of building e- configurations of atoms by adding one e- at a time as
atomic number increases across the rows of the periodic table
Electron Affinity (EA) the when 1 mole of e-s combines with 1 mole of atoms/ions in the gas
phase
- Large negative EA means that it is favorable to form the anion
- Trends less regular
Group 1 metals increasing EA as you go down
In general, become more negative with increasing atomic number across a row
Halogens most negative
Endothermic for noble gasses, Be and Mg also slightly positive, N, too, because was
filled