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5.
Find the wavelength spread of a 10 fs (1fs =10-15 s) laser pulse from a Ti-Sapphire
laser, with a central frequency of 3.70 1014 Hz.
6.
State whether sin(3x) is an eigenfunction of the operator d2/dx2? If so, what is the
eigenvalue?
10. A 1 gm marble is considered to roll inside a tube of length L =1 cm. The tube is
capped at both ends. Modeling this as a 1D infinite square well, determine the
quantum number n, if the marble is initially given an energy of 1.0 mJ. Calculate
excitation energy required to promote the marble to the next available energy level.
12. An oxygen molecule is confined in a cubical box of volume 1 m3. Assuming the
average kinetic energy of the molecule to be 3/2 kT where k is the Boltzmann
constant, find the value of n = (nx2 + ny2 + nz2) for the molecule at T= 300 K.
13. Determine the degree of degeneracy of the energy level 17h2/8ma2 of a particle in
a cubic box.
16. Find the energies of E(311), E(222) and E(321) and construct an energy level
diagram for a three dimensional cubic well in terms of the ground state energy of
the one-dimensional infinite square well E(1). (Numbers in the bracket represents
the quantum numbers). Which of the states are degenerate? Indicate their
degeneracy.
17. Suppose the particle in problem 16 is an electron and L =0.1 nm. Compute the
energy of transition from the (311) excited state to the ground state.
18. The wavelength of the transition between n=3 to n=2 of ! ion is 164 nm.
Calculate the shift in wavelength for isotope ! for the same transition.