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Electrode
Electrode
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Migration of the cations
In the solvent
Photogeneration
Polaron
Soliton
Bi-polaron
Exciton- polaron
.
Exciton
Exciton: Bound electron-hole
pair due to Coulomb interaction
Wannier exciton
(typical of inorganic
semiconductors)
Frenkel exciton
(typical of organic
materials)
Inorganic semiconductor:
CB
small exciton
binding energy
VB
Transport gap
Optical gap
HOMO (IP)
Ground
state
of neutral
molecule
Nuclei pulled in
Electrons pushed away
Polarons
Ef=Ei + h
Ei=Ef + h
http://arxiv.org/pdf/1001.2330v1.pdf
http://arxiv.org/pdf/1001.2330v1.pdf