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Academic Session: 2015-16

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PART : I MATHEMATICS

MATHEMATICS

SECTION – 1 : (Maximum Marks : 40)

This section contains TEN questions

Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct

For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS

Marking scheme :

MATHEMATICS

+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened 0 If none of the bubbles is darkened –1 In all other cases

1. Normals are drawn from the point (2, 4) to the parabola

y

2

8x . Then

(A)

the number of real normals is one

(B) the number of real normals is more than one

(C)

x + y – 6 = 0 is a normal

(D) x – y – 2 = 0 is a normal

2. If the equation of the curve which is reflection of the ellipse

(x

4)

2

16

(y

3)

2

9

straight line

x + y = 0 is

2

16x 9y

2

(A) k 1 is divisible by 24

(C)

k

3

/k

2

is integer

k x k y k

1

2

3

0 , then

(B)

(D)

(k

1

k

3

k

/k

1

2

)/ 24 is prime number

is integer

1

about the

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3.

Let

f(x)

lim

n

alog (2

e

 

2n

 

log (4

e

   

)

x

)

bx

x

 

a

bx

2n

1

MATHEMATICS

where a, b R, ab ≠ 0. Then

(A)

limf(x)

exists

(B)

limf(x)

does not exist

x

1

x

1

(C)

lim f(x)

exists

(D)

lim f(x)

does not exist

x

1

x

1

4. a, b satisfies equation a(b – 1) = 3 + b – b 2 , then a + b may be equal to

(A) –1

(B) 1

(C) 2

(D) – 2

MATHEMATICS

5. Let g(x) be a continuous function for all x, and f(x) = f( ) + (x – ).g(x) x R. Then

6.

(A)

f(x) is necessarily continuous at x = .

(B)

f(x) is necessarily differentiable at x = .

(C)

f(x) is necessarily continuous at all x R – { }

(D)

f '( ) g( )

The straight line x

1

way, then

y

2

z

2

turns through a right angle, passing through the positive x–axis on the

(A)

d.r. of the new straight line are in ratio 4:1:1

(B)

d.r. of the new straight line are in ratio 6: 2: 1

(C)

the new straight line is perpendicular to the plane 4x – y – z = 8

(D)

the new straight line is parallel to the plane x + 2y + 2z = 20

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MATHEMATICS

7. The number of isosceles triangles with integer sides if no side exceeds 2016 is

(A)

(B)

(C)

(D)

(1008)

2

2

3

(1008)

(1008)

(2016)

2

if equal sides do not exceed 1008 if equal sides exceed 1008 if equal sides have any length not exceeding 2016 if equal sides have any length not exceeding 2016

2

2

8. Which of the following function (s) have empty domain?

(A)

(B)

(C)

f (x) = log x 1 (2 – [ x ] – [ x ] 2 ) where [ x ] denotes the greatest integer function.

g (x) = cos 1 (2 – { x } ) where { x } denotes the fractional part function.

h (x) = log log (cos x)

(D) f (x) =

1

sec 1 ( sgn ( e x ) )

MATHEMATICS

9. Let f (x) and g(x) be two periodic functions defined over whole set of real numbers. Then which of the following functions are necessarily periodic?

(A) f (g (x))

(B) g (x) + f(g (x))

(C) f (x) + g (x)

10. A fair coin is tossed n times. Then

(D) f (x). g (x)

(A)

1

the probability of getting tails an odd number of times is 2

when n is odd.

(B)

1

the probability of getting tails an odd number of times is 2

when n is even.

(C)

the probability of getting at least one tail is more than 0.99 for n = 7.

(D)

the probability of getting at least one tail is more than 0.99 for n = 8.

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MATHEMATICS

SECTION – 2 : (Maximum Marks : 16)

This section contains TWO questions

Each question contains two columns, Column I and Column II

Column I has four entries (A),(B), (C) and (D)

Column II has four entries (P),(Q), (R) and (S)

Match the entries in Column I with the entries in Column II

One or more entries in Column I may match with one or more entries in Column II

The ORS contains a 4 × 4 matrix whose layout will be similar to the one shown below :

(A)

(B)

(C)

(D)

will be similar to the one shown below : (A) (B) (C) (D) MATHEMATICS  For

MATHEMATICS

 For each entry in Column I, darken the bubbles of all the matching entries. For example, if entry

(A) in Column Imatches with entries (P), (Q) and (R), then darken these three bubbles in the ORS. Similarly, for entries (B), (C) and (D).

Marking scheme :

For each entry in Column I

+2 If only the bubble(s) corresponding to all the correct match(es) is (are) darkened

0

If none of the bubbles is darkened

0

In all other cases

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11. Consider the line L

ax

+

by

+

c

=

0.

Match the

statements in Column II (which L = 0 represents)

MATHEMATICS

conditions / expressions in Column I with

Column – I

Column - II

(A)

a + b + c = 0 & a 2 + b 2 + c 2 = ab + bc + ca

(P)

Lines parallel to the axes

(B)

a + b + c ≠ 0 & a 2 + b 2 + c 2 = ab + bc + ca

(Q)

Line equally inclined with the axes

(C)

ab = 0 & a 2 + b 2 + c 2 ≠ ab + bc + ca

(R)

Concurrent straight lines.

(D)

a + b + c = 0 & a 2 + b 2 + c 2 ≠ ab + bc + ca

(S)

The whole of 2 D plane

MATHEMATICS

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12. Consider the conic S

Column– I

x

2

1

k

y

2

1

k

k

0

MATHEMATICS

Column - II

(A)

For k = 2, the eccentricity of S = 0 is

(P)

3

2
2

(B)

For k = –2, the eccentricity of S = 0 is

(Q)

4 3
4
3

(C)

For k = 2, the length of latus rectum of S = 0 is

(R)

2

(D)

For k = –2, the length of semi-latusrectum of S = 0 is

(S)

8 3
8
3

MATHEMATICS

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MATHEMATICS

SECTION – 3 : (Maximum Marks : 18)

This section contains THREE paragraphs

 

Based on each paragraph, there will be TWO questions. Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is correct



For each question, darken the bubble corresponding to the correct option in the ORS

 

Marking scheme :

 

+3 If only the bubble corresponding to the correct option is darkened 0 If none of the bubbles is darkened –1 In all other cases

 
 

Paragraph for Question Nos. 13 to 14

 
 

Consider the quadratic equation

 

az

2

bz c 0 where a, b, c are non – zero complex numbers.

Now answer the following:

 

13.

The condition that the equation has both roots purely imaginary is

 
 

a

b

c

a

b

c

a

b

c

a b

c

 

(A)

(B)

 

(C)

(D)

 

a

b

c

a

b

c

a

b

c

a b

c

14.

The condition that the equation has one complex root such that

= 1, is

(A)

bc

ba

aa

cc

aa

cc

cb

ab

(C) (bc ba)(cb ab) (aa cc)

(B)

bc

ba

aa

cc

aa

cc

cb

ab

2 (D) None of these

MATHEMATICS

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MATHEMATICS

Paragraph for Question Nos. 15 to 16

Lines whose equation are x 3

2

=

15. The value of sin 1 sin is equal to

(B) – 3

(A) 3

y – 2

3

z –1

=

and

x 2

3

(C) 4

y – 3

=

2

=

3 – z

3

lie in same plane, then

(D) – 4

MATHEMATICS

16. Angle between the plane containing both lines and the plane 4x + y + 2z = 0 is

(A) 3

(B) 2

(C) 6

(D) cos 1

1 186
1
186

Paragraph for Question Nos. 17 to 18

A die is rolled and showing any number is directly proportional to that number. If prime number

appears then a ball is chosen from urn A containing 2 white and 3 black balls otherwise a ball is

chosen from urn B containing 3 white and 2 black balls Then

17. The probability of drawing a black ball is

(A)

53

105

(B)

52

105

(C)

49

105

(D)

18. If white ball is draw then the probability that it is from urn B

(A)

52 (B)
53

1

53

(C)

20

53

(D)

51

105

33

53

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  PART - II : PHYSICS         PHYSICS   SECTION – 1
 

PART - II : PHYSICS

 
   
 

PHYSICS

 

SECTION – 1 : (Maximum Marks : 40)

This section contains TEN questions

 

Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct

For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS

 
 

Marking scheme :

 

+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened

 

If none of the bubbles is darkened –1 In all other cases

0

 

19.

The figure shows two points sources which emit light of wavelength in phase with each other and

 

are at a distance d = 5.5 apart along a line which is perpendicular to a large screen at a distance

from the centre of the source. Assume that d is much less than L. Which of the following statement(s) is/are correct?

L

 
   
 
 

(A)

Only five bright fringes appear on the screen

(B)

Only six bright fringes appear on the screen

(C)

Point y = 0 corresponds to bright fringe

(D)

Point y = 0 corresponds to dark fringe.

20.

If

electron of the hydrogen atom is replaced by another particle of same charge but of double the mass, then:

(A)

Bohr radius will increase

(B)

ionization energy of the atom will be doubled speed of the new particle in a given state will be lesser than the electron's speed in same orbit

(C)

(D)

gap between energy levels will Space now be for doubled. Rough Work

Space for Rough Work

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21.

22.

23.

24.

PHYSICS

An object is moving in the xy plane with the position vector is given by

vector is

decreasing, if

r xi ˆ y ˆ j

and velocity

origin in

v v

x

ˆ i v

y

ˆ j

. Consider a point

O

at

origin

r 0 .Distance of object from

(A)

v x > 0, v y < 0 & x < 0, y > 0

(C)

xv x + yv y < 0

(B) v x < 0, v y > 0 & x > 0, y < 0 (D) – xv x + yv y < 0

PHYSICS

Two concentric metallic shell’s of radius R and 2R, out of which the inner shell is having charge

Q and outer shell is uncharged. If they are connected with a conducting wire. Then,

(A)

(B)

Q amount of charge will flow from inner to outer shell.

Q/e number of electrons will flow from inner to outer shell, where e is charge of electron.

(C)

KQ

2

8R

amount of heat is produced in the wire

(D)

KQ

2

4R amount of heat is produced in the wire.

If one of the slit in a standard YDSE apparatus is covered by a thin glass slab so that it transmits only one half of the light intensity of the other. Select correct alternatives :

(A)

Resultant intensity at centre of screen will decrease

(B)

Resultant intensity at dark fringe will increase

(C)

The fringe width will remain unchanged

(D)

The fringe pattern will shift toward the covered slit.

A diminished image of an object is to be obtained on a screen 1.0 m from it. This can be achieved

by placing:

(A)

convex mirror of suitable focal length

(B)

A concave mirror of suitable focal length

(C)

A convex lens of focal length system 0.25 m

(D)

A concave lens of suitable focal length

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25.

PHYSICS

A solid spherical planet of mass 2m and radius 'R' has a very small tunnel along its diameter.

A small cosmic particle of mass m is at a distance 2R from the centre of the planet as shown. Both

are initially at rest, and due to gravitational attraction, both start moving toward each other. After some time, the cosmic particle passes through the centre of the planet. (Assume the planet and the cosmic particle are isolated from other planets)

and the cosmic particle are isolated from other planets) PHYSICS (A) (B) (C) Displacement of the

PHYSICS

(A)

(B)

(C)

Displacement of the cosmic particle till that instant is 4R

3

Acceleration of the cosmic particle at that instant is zero

velocity of the cosmic particle at that instant is

8Gm 3R
8Gm
3R

(D) Total work done by the gravitational force on both the particle is

2Gm

2

R

26.

A train is moving with constant speed along a circular track. If length of the train is one fourth of

length of circular track then which of the following is/are correct options (Assume that sound

source is at engine) :

(A) Frequency observed by a passenger who is sitting in the middle of train (equidistant from front

and rear end) will continuously increase.

(B) Frequency observed by a passenger who is sitting in the middle of train (equidistant from front

and rear end) will remain constant but more than actual frequency.

(C) Frequency observed by a passenger who is sitting in the middle of train (equidistant from front

and rear end) will remains constant and equal to actual frequency.

(D) Wavelength observed by the Space person for who Rough is on Work the rear end of train is more than the actual

wavelength of sound wave.

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PHYSICS

27. Which of the following statements is/are correct for an x-ray tube ?

(A)

On increasing potential difference between filament and target, photon flux of x-rays increases

(B)

On increasing potential difference between filament and target, frequency of x-rays increases

(C)

On increasing filament current, cut–off wavelength increases

(D)

On increasing filament current intensity of x-rays increases

PHYSICS

28. In a radioactive decay reaction :

A B C

2

9

Select correct alternative/s at the instant the number of the particles of B is maximum :

(A)

Activity of A is equal to activity of B

(B)

No of atoms of A is 4.5 times of B

(C)

Activity of A is more then activity of B

(D)

Activity of A is minimum

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PHYSICS

SECTION – 2 : (Maximum Marks : 16)

This section contains TWO questions

Each question contains two columns, Column I and Column II

Column I has four entries (A),(B), (C) and (D)

Column II has four entries (P),(Q), (R) and (S)

Match the entries in Column I with the entries in Column II

One or more entries in Column I may match with one or more entries in Column II

The ORS contains a 4 × 4 matrix whose layout will be similar to the one shown below :

PHYSICS

(A)

(B)

(C)

(D)

be similar to the one shown below : PHYSICS (A) (B) (C) (D)  For each

 For each entry in Column I, darken the bubbles of all the matching entries. For example, if entry

(A) in Column Imatches with entries (P), (Q) and (R), then darken these three bubbles in the ORS. Similarly, for entries (B), (C) and (D).

Marking scheme :

For each entry in Column I +2 If only the bubble(s) corresponding to all the correct match(es) is (are) darkened

0

If none of the bubbles is darkened

0

In all other cases

Space for Rough Work

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PHYSICS

29. In the Column-I some arrangements are given and in Column-II some changes in some
29.
In the Column-I some arrangements are given and in Column-II some changes in some
parameters are given for short duration of time. Then match Column-I with Column-II.
Column-I
Column-II
(A)
(P)
‘d’ will increase
Initial velocity of both ‘O’ &
mirror are Zero and acceleration of both is same
and equal to a.
‘d’ is distance between pole and
image of the object.
‘m’ is the magnitude of magnification
of object.
(B)
(Q)
‘d’ will decrease
‘d’ is the momentum of sphere and ‘m’
is angular velocity of sphere
(C)
(R)
‘m’ will increase
Metal plate is moving up and down
without changing its orientation
between the plates. ‘m’ is the
capacitance and ‘d’ is the Space current for Rough Work
in circuit
(D)
A sample of helium gas in a container
undergoes a process PV 2 = constant.
If ‘d’ is the temperature of the gas and
‘m’ is the rotational kinetic energy of
molecules of gas then on increasing
the volume. (assume ideal gas behaviour)
(S)
‘m’ will remain constant
PHYSICS

Space for Rough Work

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PHYSICS

30. In column-I, some situations are given, and in column-II, their result are given. Assume the batteries and voltmeters used are ideal. Also assume that the resistance of bulb doesn't change

due to heating. Match the situations given in column-I according to proper results in column-II.

(A)

Column-I

Bulb A B R h V
Bulb
A
B
R h
V

If the resistance of rheostat between A and B is increased, then :

(B) If resistance of the bulb is gradually increased from 10 to 50 , then
(B)
If resistance of the bulb is gradually
increased from 10 to 50 , then :

Column-II

(P)

The brightness of the bulb will increase

(Q)

The brightness of the bulb will decrease.

PHYSICS

(C) (R) The reading of the voltmeter will increase Space for Rough Work
(C)
(R)
The reading of the voltmeter will increase
Space for Rough Work

Switch is on at t = 0. From t = 0 to the steady state

(D) (S) The reading of the voltmeter will decrease.
(D)
(S)
The reading of the voltmeter will decrease.

The system has achieved steady state. Now the distance between the plates of the capacitor is suddenly halved. After that, as the time passes :

Space for Rough Work

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PHYSICS

SECTION – 3 : (Maximum Marks : 18)   This section contains THREE paragraphs
SECTION – 3 : (Maximum Marks : 18)
This section contains THREE paragraphs

Based on each paragraph, there will be TWO questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is correct 
For each question, darken the bubble corresponding to the correct option in the ORS
Marking scheme :
+3 If only the bubble corresponding to the correct option is darkened
0 If none of the bubbles is darkened
–1 In all other cases
Paragraph for Questions 31 and 32
The system shown in figure is initially at origin and is moving with velocity 5 m/s on a smooth
ˆ
horizontal xz plane. A force F = (120 t)
i
acts on mass m 2 , [where F in newton, t in sec]. The man
throws a light ball (at the instant when m 1 starts slipping on m 2 ) with a velocity 10 m/s vertically up
with respect to himself. Taking the mass of block and man as 60 kg each and assuming that man
never slips on m 2 . (neglect the dimensions of system, and g = 10 m/s 2 )
31.
Projection velocity of ball with respect to ground is :
(A)
10i ˆ 5k ˆ
(B)
1.5i ˆ 10 ˆ j 5k ˆ
(C)
3i ˆ 10 ˆ j 5k ˆ
(D) None of these
32.
The time of flight of the ball is
(A) 2s
(B) 4s
(C) 6s
(D) 8s
PHYSICS

Space for Rough Work

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PHYSICS

Paragraph for Questions 33 and 34

When the expansion of a liquid in a vessel is measured to obtain the coefficient of volume expansion ( ), what is actually obtained is apparent coefficient of expansion. This is due to expansion of container. The figure shown is an apparatus to find out correct coefficient of expansion without knowing coefficient of expansion of the container. It consist a U-shaped tube with long base and two limbs. Its two limbs are kept at 0°C and t°C with the help of melting ice and water at t°C. A liquid of unknown is taken in U-tube. For the given steady state there is no flow of liquid from one limb to other. Height of the liquid in two columns is h 0 and h t respectively.

PHYSICS

h t h 0
h t
h 0
is h 0 and h t respectively. PHYSICS h t h 0 Liquid of unknown water

Liquid of

unknown

and h t respectively. PHYSICS h t h 0 Liquid of unknown water at t°C Melting

water at t°C

Melting ice

33. The coefficient of volume expansion of liquid ( ) in the tube can be expressed as –

(A)

h

0

(h

t

h

0

)

(B)

(h

t

h

0

)

(h

0

t)

(C)

h

t

h

0

t

(D)

h

0

h t

t

34. For a liquid at t = 20°C h 0 and h t are measured to be 100 cm and 101 cm respectively. In this same

liquid in a vessel a solid cylinder is floating. If on increasing temperature of the system depth of submergence of cylinder is unchanged thermal coefficient of linear expansion of the cylinder is

(A)

5 × 10 4 per °C

(B)

1.67 × 10 4 per °C

(C)

2.5 × 10 4 per °C

(D)

10 3 per °C

Space for Rough Work

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PHYSICS

Paragraph for Questions 35 and 36

An Infinite large uniform charged non-conducting sheet having surface charge density is placed in an external uniform electric field E . Figure shows electric field lines near the sheet. Magnitude

of electric field in left side of sheet is 4N/C and electric field in right side of the sheet is at angle

tan 1 (2) from sheet.

PHYSICS

the sheet is at angle tan – 1 (2) from sheet. PHYSICS 35. What is magnitude
the sheet is at angle tan – 1 (2) from sheet. PHYSICS 35. What is magnitude

35. What is magnitude of uniform external electric field ?

(A) 4 N/C

(B) 5 N/C

(C) 2

2 N/C N/C

(D) 4

electric field ? (A) 4 N/C (B) 5 N/C (C) 2 2 N/C (D) 4 2

2 N/C

36.

If

sheet then which of the following is correct statement :

E

L

is electric field in region left side of the sheet and

(A)

| E

L

E

R

|

=

2

0

(B)

| E

L

(C)

| E

L

E

R

|

=

2

0

(D)

| E

E

R is electric field in region right side of the

L

E

R

E

R

|

|

=

=

0

2

2

0

Space for Rough Work

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CHEMISTRY

PART- III : CHEMISTRY

Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27,

Si = 28, As = 75,

Zn = 65,

P = 31, S = 32, Cl = 35.5,

K = 39, Ca = 40, Cr = 52,

Mn = 55, Fe = 56, Cu = 63.5,

Br = 80, Ag = 108, I = 127,

Ba = 137, Hg = 200, Pb = 207]

CHEMISTRY

SECTION – 1 : (Maximum Marks : 40)

This section contains TEN questions

 

Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct

For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS

Marking scheme :

 

+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened

If none of the bubbles is darkened –1 In all other cases

0

 

37.

Which of the following reagents does not give oxygen as one of the product during oxidation with ozone.

(A)

Hg

(B) SO 2

(C) SnCl 2 /HCl

(D) H 2 S

38.

Oxide of a transition metal is heated. Some of its oxygen (O 2 )is escaped. What is/are true about the kind of defect created in the solid ?

(A)

defect is of cation excess type (B) defect is of anion excess type

(C)

F-centers are created

(D) solid acquires characteristic colour

39.

Large quantity of KMnO 4 , on treatment with cold conc. H 2 SO 4 forms a compound (X) which decomposed explosively, on heating forming (Y). Select the correct option :

(A) X = Mn 2 O 7

(B) Y = MnO 2

(C) X = MnSO 4

(D) Y = MnO 2

(Space

for

Rough

Work)

40. Which of the following statement are correct

(A)

(B) Strength of H-bonding : F H

(C) Boiling point :

(D) Dipole moment :

Strength of H-bonding : HF > H 2 O > NH 3

O

H O HF NH

2

3

HF H O NH

2

3

O H

O

F H

F

CHEMISTRY

CHEMISTRY

41. A solution is prepared by mixing 4 mole of liquid A, 6 mole of liquid B, 0.4 mole of non-volatile solute C and 0.2 moles of non-volatile solute D. If C undergoes 40% dimerisation while D undergoes 30% binary dissociation, then select correct statement(s) : (Given, vapour pressure of pure solvent A & B are 500mm & 600mm of Hg respectively).

(A)

(B)

(C)

(D)

the vapour pressure of solution is 490.3mm

4

mole fraction of A = 10

the vapour pressure of solution is 529.3mm

0.32

0.26

6

mole fraction of B = 10

0.32

0.26

42. Select the correct statements out of I, II and III for zero order reaction

(A)

Quantity of the product formed is directly proportional to time

(B)

Larger the initial concentration of the reactant, greater the half-life period

(C)

If 50% reaction takes place in 100 minutes, 75% reaction take place in 150 minutes.

(D)

If 50% reaction takes place in 100 minutes, 75% reaction take place in 250 minutes.

43. A teritary alcohol

(A) O 2

(C) Ketone

in 250 minutes. 43. A teritary alcohol (A) O 2 (C) Ketone can be prepared by

can be prepared by grignard reagent and :

(B) Epoxide

(D) Acid derivatives (specially acid halide)

(Space

for

Rough

Work)

CHEMISTRY

44. Choose the correct options : (A) The number of ether metamers of C 4
44. Choose the correct options :
(A)
The number of ether metamers of C 4 H 10 O is three.
(B)
Sec. butyl alcohol has a one chiral atom.
(C)
Geometrical isomerism results because the molecule has two dissimilar groups attached to both
ends of double bond.
(D)
The configurations of the carbon atoms C 2 and C 3 in the following compound
are 2R
CHEMISTRY

& 3R.

45. Correct statement about peptide linkage in a protein molecule is/are correct ?

(A)

It is amide linkage

(B)

It has partial double bond character.

(C)

It is hydrophilic in nature

(D)

It connects protein molecules through H-bonds.

46. Which of the following statements is/are incorrect about the given carbohydrate :

CH OH

2

O H H OH H
O
H
H
OH
H

HO

about the given carbohydrate : CH OH 2 O H H OH H HO H OH

H

OH

H

O OH H H
O
OH H
H

H OH

H

: CH OH 2 O H H OH H HO H OH H O OH H

CH OH

2

O
O

(A)

It anomerizes in solution phase.

(B)

It is a reducing sugar.

(C)

It shows the phenomenon of inversion of sugar in acidic medium.

(D)

It shows mutarotation.

(Space

for

Rough

Work)

SECTION – 2 : (Maximum Marks : 16)

This section contains TWO questions

Each question contains two columns, Column I and Column II

Column I has four entries (A),(B), (C) and (D)

Column II has four entries (P),(Q), (R) and (S)

Match the entries in Column I with the entries in Column II

One or more entries in Column I may match with one or more entries in Column II

The ORS contains a 4 × 4 matrix whose layout will be similar to the one shown below :

(A)

(B)

(C)

(D)

will be similar to the one shown below : (A) (B) (C) (D) CHEMISTRY CHEMISTRY 

CHEMISTRY

CHEMISTRY

For each entry in Column I, darken the bubbles of all the matching entries. For example, if entry (A) in Column Imatches with entries (P), (Q) and (R), then darken these three bubbles in the ORS. Similarly, for entries (B), (C) and (D).

Marking scheme :

For each entry in Column I

+2 If only the bubble(s) corresponding to all the correct match(es) is (are) darkened

0

If none of the bubbles is darkened

0

In all other cases

(Space

for

Rough

Work)

47. Match the following :

Column-I

(A) Borax

(B) B 2 H 6 + H 2 O

(C)

(D)

B 2 H 6 + NH 3 (excess) BCl 3 + LiAlH 4

Column-II

(P) BN

(Q) B 2 H 6

(R) H 3 BO 3 (S) NaBO 2 + B 2 O 3

CHEMISTRY

CHEMISTRY

48. Column - I

(A)

Ph

OH N CH 3
OH
N
CH 3

H

O CH 3 C N Ph
O
CH 3
C
N
Ph

H

(B)

(C)

(D)

OH OH
OH
OH

H

O

Ph OH N CH 3 H O CH 3 C N Ph H (B) (C) (D)

O

OH N CH 3 H O CH 3 C N Ph H (B) (C) (D) OH

H

OH

N CH 3 H O CH 3 C N Ph H (B) (C) (D) OH OH
N CH 3 H O CH 3 C N Ph H (B) (C) (D) OH OH
i Hg OAc ) / H O 2 2 ii NaBH ) 4 OH (Space
i Hg OAc
)
/
H O
2
2
ii NaBH
)
4
OH
(Space
for
Rough
Work)

Column - II

(P)

Rearrangement reaction

(Q)

Isomerization reaction

(R)

Elimination reaction

(S)

Addition reaction

CHEMISTRY

SECTION – 3 : (Maximum Marks : 18)

This section contains THREE paragraphs

Based on each paragraph, there will be TWO questions.

Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is correct

For each question, darken the bubble corresponding to the correct option in the ORS

Marking scheme :

+3 If only the bubble corresponding to the correct option is darkened

0 If none of the bubbles is darkened –1 In all other cases

Paragraph for Question Nos. 49 to 50

CHEMISTRY

Energy that is transmitted from one system to another in such a way that difference of temperature is

not directly involved is known as work. It is a path function.

This definition is consistent with our understanding of work as dw = Fdx. The force F can arise from

electrical, magnetic, gravitational & other sources.

49.

50.

Calculate the work done (in J) when 4.5 g of H 2 O 2 reacts against a pressure of 1 atm at 25°C ? 2H 2 O 2 ( ) O 2 (g) + 2H 2 O ( )

(A)

1.63 10

2

(B)

4.5 10

2

(C)

3.2 10

2

(D)

6.1 10

2

If

reversible expansion processes. (assume expansion to be from same initial points to same final volume wherever applicable) The correct order will be

(A)

for an ideal gas are magnitude of work done in isothermal, adiabatic, isobaric, isochoric

w ,w ,w ,w

1

2

3

4

w

1

w

2

w

3

w

4

(B)

w

3

w

2

w

1

w

4

(C)

w

3

w

2

w

4

w

1

(D)

w

3

w

1

w

2

w

4

(Space

for

Rough

Work)

CHEMISTRY

Paragraph for Question Nos. 51 to 52

According to crystal field theory, a stronger ligand produces larger . Due to this electrons get paired up in the presence of strong ligands. Hence, a metal ion in a complex with same coordination number show different magnetic behaviour in the presence of different ligands. The splitting of d orbitals along with presence of empty orbitals and electrons may result into colour of complexes.

CHEMISTRY

51. Which of the following complexes is a paramagnetic inner orbital complex?

(A) [Fe(CN) 6 ] 4

(B) [CoCl 4 ] 2

(C) [Cu(NH 3 ) 4 ] 2+

(D) [Fe(CO) 5 ]

52. Which of the following pair of species is coloured in aqueous solution?

(A)

CuSO 4 , CaCl 2

(B) CuSO 4 , CuCl

(C)

CuSO 4 , Cr 2 (SO 4 ) 3

(D) TiCl 3 , ZnCl 2

Paragraph for Question Nos. 53 to 54

CH COONa/ 3 SOCl NH (P) 2 3 (Q)
CH COONa/
3
SOCl
NH
(P)
2 3
(Q)

Br / KOH/

2

(Q)

(R) + CO 2

(P) + CH 3 COOH

(Space

for

Rough

Work)

53. The compound (P) is :

(A)

53. The compound (P) is : (A) (B) (C) (D) 54. The compound (R) is :
(B) (C) (D) 54. The compound (R) is : (A) An aromatic primary amine. (B)
(B)
(C)
(D)
54. The compound (R) is :
(A)
An aromatic primary amine.
(B)
An aliphatic primary amine.
(C)
It is an aromatic cyanide.
(D)
It is an aromatic acid salt.

(Space

for

Rough

Work)

CHEMISTRY

CHEMISTRY

PPAAPPEERR--22

FFUULLLL SSYYLLLLAABBUUSS TTEESSTT ((FFSSTT)) ((JJEEEE AADDVVAANNCCEEDD PPAATTTTEERRNN)) CCOOUURRSSEE :: VVIIJJEETTAA ((JJPP)) && VVIISSHHWWAAAASS ((JJFF))

CCOODDEE --

 

DDAATTEE :: 0033--0011--22001166

0

Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose. GENERAL %

1. The sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so.

2. The question paper CODE is printed on the right hand top corner of this sheet and the right hand top corner of the back cover of this booklet.

3. Use the Optical Response Sheet (ORS) provided separately for answering the question.

4. Blank spaces are provided within this booklet for rough work.

5. Write your Name and Roll Number in the space provided on the below cover.

6. After the open booklet, verify that the booklet contains all the 54 questions along with the options are legible.

QUESTION PAPER FORMAT AND MARKING SCHEME :

7. The question paper has three parts : Mathematics, Physics and Chemistry. Each part has three sections.

8. Carefully read the instructions given at the beginning of each section.

9. Section 1 contains 10 multiple Choice question with one or more than one correct option. Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.

10. Section 2 contains 2 "match the following" type question and you will have to match entries in Column I with the entries in Column-II. Marking scheme : for each entry in Column I, +2 for correct answer, 0 if not attempted and 0 in all other cases.

11. Section 3 contains 3 "paragraph" type questions. Each paragraph describes an experiment, a situation or a problem. Two multiple choice questions will be asked based on this paragraph. Only one option can be correct.

Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.

OPTICAL RESPONSE SHEET :

12. Darken the appropriate bubbles on the original by applying sufficient pressure.