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Academic Session: 201516
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PART : I MATHEMATICS
MATHEMATICS
SECTION – 1 : (Maximum Marks : 40)
This section contains TEN questions
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
Marking scheme :
MATHEMATICS
+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened 0 If none of the bubbles is darkened –1 In all other cases
1. Normals are drawn from the point (2, 4) to the parabola
y
2
_{} _{8}_{x} . Then
(A) 
the number of real normals is one 
(B) the number of real normals is more than one 
(C) 
x + y – 6 = 0 is a normal 
(D) x – y – 2 = 0 is a normal 
2. If the equation of the curve which is reflection of the ellipse
(x
4)
2
16
(y
3)
2
9
straight line
x + y = 0 is
2
16x 9y
2
(A) k _{1} is divisible by 24
(C)
k
3
/k
2
is integer
k x k y k
1
2
3
0 , then
(B)
(D)
(k
1
k
3
k
/k
1
2
)/ 24 is prime number
is integer
1
about the
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3.
Let
f(x)
lim
n
alog (2 e 
2n 
log (4 e 
) 

x 
)
bx 

x 

a 
bx 2n 

1 
MATHEMATICS
where a, b R, ab ≠ 0. Then
(A) 
limf(x) 
exists 
(B) 
limf(x) 
does not exist 

x 

1 
x 

1 

(C) 
lim f(x) 
exists 
(D) 
lim f(x) 
does not exist 

_{x} 

_{1} 
_{x} 

_{1} 
4. a, b _{} satisfies equation a(b – 1) = 3 + b – b ^{2} , then a + b may be equal to
(A) –1
(B) 1
(C) 2
(D) – 2
MATHEMATICS
5. Let g(x) be a continuous function for all x, and f(x) = f( ) + (x – ).g(x) x R. Then
6.
(A) 
f(x) is necessarily continuous at x = . 
(B) 
f(x) is necessarily differentiable at x = . 
(C) 
f(x) is necessarily continuous at all x R – { } 
(D) 
f '( ) g( ) 
The straight line ^{x}
1
way, then
^{y}
2
^{z}
2
turns through a right angle, passing through the positive x–axis on the
(A) 
d.r. of the new straight line are in ratio 4:1:1 
(B) 
d.r. of the new straight line are in ratio 6: 2: 1 
(C) 
the new straight line is perpendicular to the plane 4x – y – z = 8 
(D) 
the new straight line is parallel to the plane x + 2y + 2z = 20 
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MATHEMATICS
7. The number of isosceles triangles with integer sides if no side exceeds 2016 is
(A)
(B)
(C)
(D)
(1008)
2
2
3
(1008)
(1008)
(2016)
2
if equal sides do not exceed 1008 if equal sides exceed 1008 if equal sides have any length not exceeding 2016 if equal sides have any length not exceeding 2016
2
2
8. Which of the following function (s) have empty domain?
(A)
(B)
(C)
f (x) = log _{x} _{–} _{1} (2 – [ x ] – [ x ] ^{2} ) where [ x ] denotes the greatest integer function.
g (x) = cos ^{–}^{1} (2 – { x } ) where { x } denotes the fractional part function.
h (x) = log log (cos x)
(D) f (x) =
1
sec ^{–}^{1} ( sgn ( e ^{–}^{x} ) )
MATHEMATICS
9. Let f (x) and g(x) be two periodic functions defined over whole set of real numbers. Then which of the following functions are necessarily periodic?
(A) f (g (x))
(B) g (x) + f(g (x))
(C) f (x) + g (x)
10. A fair coin is tossed n times. Then
(D) f (x). g (x)
(A) 
^{1} the probability of getting tails an odd number of times is 2 when n is odd. 
(B) 
^{1} the probability of getting tails an odd number of times is 2 when n is even. 
(C) 
the probability of getting at least one tail is more than 0.99 for n = 7. 
(D) 
the probability of getting at least one tail is more than 0.99 for n = 8. 
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MATHEMATICS
SECTION – 2 : (Maximum Marks : 16)
This section contains TWO questions
Each question contains two columns, Column I and Column II
Column I has four entries (A),(B), (C) and (D)
Column II has four entries (P),(Q), (R) and (S)
Match the entries in Column I with the entries in Column II
One or more entries in Column I may match with one or more entries in Column II
The ORS contains a 4 × 4 matrix whose layout will be similar to the one shown below :
(A)
(B)
(C)
(D)
MATHEMATICS
For each entry in Column I, darken the bubbles of all the matching entries. For example, if entry
(A) in Column Imatches with entries (P), (Q) and (R), then darken these three bubbles in the ORS. Similarly, for entries (B), (C) and (D).

Marking scheme : 
For each entry in Column I
+2 If only the bubble(s) corresponding to all the correct match(es) is (are) darkened
0 
If none of the bubbles is darkened 
0 
In all other cases 
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11. Consider the line L _{}
ax
+
by
+
c
=
0.
Match the
statements in Column II (which L = 0 represents)
MATHEMATICS
conditions / expressions in Column I with
Column – I 
Column  II 

(A) 
a + b + c = 0 & a ^{2} + b ^{2} + c ^{2} = ab + bc + ca 
(P) 
Lines parallel to the axes 
(B) 
a + b + c ≠ 0 & a ^{2} + b ^{2} + c ^{2} = ab + bc + ca 
(Q) 
Line equally inclined with the axes 
(C) 
ab = 0 & a ^{2} + b ^{2} + c ^{2} ≠ ab + bc + ca 
(R) 
Concurrent straight lines. 
(D) 
a + b + c = 0 & a ^{2} + b ^{2} + c ^{2} ≠ ab + bc + ca 
(S) 
The whole of 2 D plane 
MATHEMATICS
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12. Consider the conic S
Column– I
x
2
1
k
y
2
1
k
k
0
MATHEMATICS
Column  II
(A) 
For k = 2, the eccentricity of S = 0 is 
(P) 
3 
2

(B) 
For k = –2, the eccentricity of S = 0 is 
(Q) 
4
3


(C) 
For k = 2, the length of latus rectum of S = 0 is 
(R) 
2 

(D) 
For k = –2, the length of semilatusrectum of S = 0 is 
(S) 
8
3

MATHEMATICS
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MATHEMATICS
SECTION – 3 : (Maximum Marks : 18)

This section contains THREE paragraphs 


Based on each paragraph, there will be TWO questions. Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is correct 




For each question, darken the bubble corresponding to the correct option in the ORS 


Marking scheme : 

+3 If only the bubble corresponding to the correct option is darkened 0 If none of the bubbles is darkened –1 In all other cases 

Paragraph for Question Nos. 13 to 14 

Consider the quadratic equation 
az 
2 
bz c 0 where a, b, c are non – zero complex numbers. 

Now answer the following: 

13. 
The condition that the equation has both roots purely imaginary is 

^{a} 
^{b} 
^{c} 
^{a} 
^{b} 
^{c} 
^{a} 
^{b} 
^{c} 
a b 
c 

(A) 


(B) 

(C) 


(D) 




a 
b 
c 
a 
b 
c 
a 
b 
c 
a b 
c 

14. 
The condition that the equation has one complex root such that

= 1, is 
(A)
bc
ba
aa
cc
aa
cc
cb
ab
(C) (bc ba)(cb ab) (aa cc)
(B)
bc
ba
aa
cc
aa
cc
cb
ab
2 (D) None of these
MATHEMATICS
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MATHEMATICS
Paragraph for Question Nos. 15 to 16
Lines whose equation are ^{x} ^{–} ^{3}
2
^{=}
15. The value of sin ^{–}^{1} sin is equal to
(B) – 3
(A) 3
y – 2
3
z –1
_{=}
and
^{x} ^{–} ^{2}
3
(C) 4
y – 3
_{=}
2
^{=}
3 – z
3
lie in same plane, then
(D) – 4
MATHEMATICS
16. Angle between the plane containing both lines and the plane 4x + y + 2z = 0 is
(A) 3 ^{}
(B) 2 ^{}
(C) 6 ^{}
(D) cos ^{–}^{1}
Paragraph for Question Nos. 17 to 18
A die is rolled and showing any number is directly proportional to that number. If prime number
appears then a ball is chosen from urn A containing 2 white and 3 black balls otherwise a ball is
chosen from urn B containing 3 white and 2 black balls Then
17. The probability of drawing a black ball is
(A)
53
105
^{(}^{B}^{)}
52
105
^{(}^{C}^{)}
49
105
^{(}^{D}^{)}
18. If white ball is draw then the probability that it is from urn B
(A)
52 (B)
53
1
53
(C)
20
53
(D)
51
105
33
53
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PART  II : PHYSICS 

PHYSICS 

SECTION – 1 : (Maximum Marks : 40) 


This section contains TEN questions 


Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct 


For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS 


Marking scheme : 

+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened 

If none of the bubbles is darkened –1 In all other cases 0 

19. 
The figure shows two points sources which emit light of wavelength in phase with each other and 

are at a distance d = 5.5 apart along a line which is perpendicular to a large screen at a distance 

from the centre of the source. Assume that d is much less than L. Which of the following statement(s) is/are correct? L 



(A) 
Only five bright fringes appear on the screen 

(B) 
Only six bright fringes appear on the screen 

(C) 
Point y = 0 corresponds to bright fringe 

(D) 
Point y = 0 corresponds to dark fringe. 

20. 
If 
electron of the hydrogen atom is replaced by another particle of same charge but of double the mass, then:
(A) 
Bohr radius will increase 
(B) 
ionization energy of the atom will be doubled speed of the new particle in a given state will be lesser than the electron's speed in same orbit 
(C) 

(D) 
gap between energy levels will Space now be for doubled. Rough Work 
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21.
22.
23.
24.
PHYSICS
An object is moving in the xy plane with the position vector is given by
vector is
decreasing, if
r xi ˆ y ˆ j
and velocity
origin in
v v
x
ˆ i v
y
ˆ j
. Consider a point
O
at
origin
r 0 .Distance of object from
(A) 
v _{x} > 0, v _{y} < 0 & x < 0, y > 0 
(C) 
xv _{x} + yv _{y} < 0 
(B) v _{x} < 0, v _{y} > 0 & x > 0, y < 0 (D) – xv _{x} + yv _{y} < 0
PHYSICS
Two concentric metallic shell’s of radius R and 2R, out of which the inner shell is having charge
Q and outer shell is uncharged. If they are connected with a conducting wire. Then,
(A)
(B)
Q amount of charge will flow from inner to outer shell.
Q/e number of electrons will flow from inner to outer shell, where e is charge of electron.
(C)
^{K}^{Q}
2
8R
amount of heat is produced in the wire
(D)
^{K}^{Q}
2
4R amount of heat is produced in the wire.
If one of the slit in a standard YDSE apparatus is covered by a thin glass slab so that it transmits only one half of the light intensity of the other. Select correct alternatives :
(A) 
Resultant intensity at centre of screen will decrease 
(B) 
Resultant intensity at dark fringe will increase 
(C) 
The fringe width will remain unchanged 
(D) 
The fringe pattern will shift toward the covered slit. 
A diminished image of an object is to be obtained on a screen 1.0 m from it. This can be achieved
by placing:
(A) 
convex mirror of suitable focal length 
(B) 
A concave mirror of suitable focal length 
(C) 
A convex lens of focal length system 0.25 m 
(D) 
A concave lens of suitable focal length 
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25.
PHYSICS
A solid spherical planet of mass 2m and radius 'R' has a very small tunnel along its diameter.
A small cosmic particle of mass m is at a distance 2R from the centre of the planet as shown. Both
are initially at rest, and due to gravitational attraction, both start moving toward each other. After some time, the cosmic particle passes through the centre of the planet. (Assume the planet and the cosmic particle are isolated from other planets)
PHYSICS
(A)
(B)
(C)
Displacement of the cosmic particle till that instant is ^{4}^{R}
3
Acceleration of the cosmic particle at that instant is zero
velocity of the cosmic particle at that instant is
(D) Total work done by the gravitational force on both the particle is
2Gm
2
R
26.
A train is moving with constant speed along a circular track. If length of the train is one fourth of
length of circular track then which of the following is/are correct options (Assume that sound
source is at engine) :
(A) Frequency observed by a passenger who is sitting in the middle of train (equidistant from front
and rear end) will continuously increase.
(B) Frequency observed by a passenger who is sitting in the middle of train (equidistant from front
and rear end) will remain constant but more than actual frequency.
(C) Frequency observed by a passenger who is sitting in the middle of train (equidistant from front
and rear end) will remains constant and equal to actual frequency.
(D) Wavelength observed by the Space person for who Rough is on Work the rear end of train is more than the actual
wavelength of sound wave.
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PHYSICS
27. Which of the following statements is/are correct for an xray tube ?
(A) 
On increasing potential difference between filament and target, photon flux of xrays increases 
(B) 
On increasing potential difference between filament and target, frequency of xrays increases 
(C) 
On increasing filament current, cut–off wavelength increases 
(D) 
On increasing filament current intensity of xrays increases 
PHYSICS
28. In a radioactive decay reaction :
A B C
2
9
Select correct alternative/s at the instant the number of the particles of B is maximum :
(A) 
Activity of A is equal to activity of B 
(B) 
No of atoms of A is 4.5 times of B 
(C) 
Activity of A is more then activity of B 
(D) 
Activity of A is minimum 
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PHYSICS
SECTION – 2 : (Maximum Marks : 16)
This section contains TWO questions
Each question contains two columns, Column I and Column II
Column I has four entries (A),(B), (C) and (D)
Column II has four entries (P),(Q), (R) and (S)
Match the entries in Column I with the entries in Column II
One or more entries in Column I may match with one or more entries in Column II
The ORS contains a 4 × 4 matrix whose layout will be similar to the one shown below :
PHYSICS
(A)
(B)
(C)
(D)
For each entry in Column I, darken the bubbles of all the matching entries. For example, if entry
(A) in Column Imatches with entries (P), (Q) and (R), then darken these three bubbles in the ORS. Similarly, for entries (B), (C) and (D).
Marking scheme :
For each entry in Column I +2 If only the bubble(s) corresponding to all the correct match(es) is (are) darkened
0 
If none of the bubbles is darkened 
0 
In all other cases 
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PHYSICS
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PHYSICS
30. In columnI, some situations are given, and in columnII, their result are given. Assume the batteries and voltmeters used are ideal. Also assume that the resistance of bulb doesn't change
due to heating. Match the situations given in columnI according to proper results in columnII.
(A)
ColumnI
If the resistance of rheostat between A and B is increased, then :
ColumnII
(P) 
The brightness of the bulb will increase 
(Q) 
The brightness of the bulb will decrease. 
PHYSICS
Switch is on at t = 0. From t = 0 to the steady state
The system has achieved steady state. Now the distance between the plates of the capacitor is suddenly halved. After that, as the time passes :
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PHYSICS
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PHYSICS
Paragraph for Questions 33 and 34
When the expansion of a liquid in a vessel is measured to obtain the coefficient of volume expansion ( ), what is actually obtained is apparent coefficient of expansion. This is due to expansion of container. The figure shown is an apparatus to find out correct coefficient of expansion without knowing coefficient of expansion of the container. It consist a Ushaped tube with long base and two limbs. Its two limbs are kept at 0°C and t°C with the help of melting ice and water at t°C. A liquid of unknown is taken in Utube. For the given steady state there is no flow of liquid from one limb to other. Height of the liquid in two columns is h _{0} and h _{t} respectively.
PHYSICS
Liquid of
unknown
water at t°C
Melting ice
33. The coefficient of volume expansion of liquid ( ) in the tube can be expressed as –
^{(}^{A}^{)}
h
0
(h
t
h
0
)
(B)
(h
t
h
0
)
(h
0
t)
(C)
h
t
h
0
t
(D)
h
0
h t
t
34. For a liquid at t = 20°C h _{0} and h _{t} are measured to be 100 cm and 101 cm respectively. In this same
liquid in a vessel a solid cylinder is floating. If on increasing temperature of the system depth of submergence of cylinder is unchanged thermal coefficient of linear expansion of the cylinder is
(A) 
5 × 10 ^{–}^{4} per °C 
(B) 
1.67 × 10 ^{–}^{4} per °C 
(C) 
2.5 × 10 ^{–}^{4} per °C 
(D) 
10 ^{–}^{3} per °C 
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PHYSICS
Paragraph for Questions 35 and 36
An Infinite large uniform charged nonconducting sheet having surface charge density is placed in an external uniform electric field E . Figure shows electric field lines near the sheet. Magnitude
of electric field in left side of sheet is 4N/C and electric field in right side of the sheet is at angle
tan ^{–}^{1} (2) from sheet.
PHYSICS
35. What is magnitude of uniform external electric field ?
(A) 4 N/C
(B) 5 N/C
(C) 2
2 N/C
(D) 4
2 N/C
36.
If
sheet then which of the following is correct statement :
E
L
is electric field in region left side of the sheet and
(A)
 E
L
E
R

=
2
0
(B)
 E
L
(C)
 E
L
E
R

=
2
0
(D)
 E
E
R is electric field in region right side of the
L
E
R
E
R


=
=
0
2
2
0
Space for Rough Work

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CHEMISTRY
PART III : CHEMISTRY
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27,
Si = 28, As = 75,
Zn = 65,
P = 31, S = 32, Cl = 35.5,
K = 39, Ca = 40, Cr = 52,
Mn = 55, Fe = 56, Cu = 63.5,
Br = 80, Ag = 108, I = 127,
Ba = 137, Hg = 200, Pb = 207]
CHEMISTRY
SECTION – 1 : (Maximum Marks : 40)

This section contains TEN questions 


Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct 


For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS 


Marking scheme : 

+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened 

If none of the bubbles is darkened –1 In all other cases 0 

37. 
Which of the following reagents does not give oxygen as one of the product during oxidation with ozone. 

(A) 
Hg 
(B) SO _{2} 
(C) SnCl _{2} /HCl 
(D) H _{2} S 

38. 
Oxide of a transition metal is heated. Some of its oxygen (O _{2} )is escaped. What is/are true about the kind of defect created in the solid ? 

(A) 
defect is of cation excess type (B) defect is of anion excess type 

(C) 
Fcenters are created 
(D) solid acquires characteristic colour 

39. 
Large quantity of KMnO _{4} , on treatment with cold conc. H _{2} SO _{4} forms a compound (X) which decomposed explosively, on heating forming (Y). Select the correct option : 

(A) X = Mn _{2} O _{7} 
(B) Y = MnO _{2} 
(C) X = MnSO _{4} 
(D) Y = MnO _{2} 
(Space
for
Rough
Work)
40. Which of the following statement are correct
(A)
(B) Strength of Hbonding : _{F} _{} _{H}
(C) Boiling point :
(D) Dipole moment :
Strength of Hbonding : HF > H _{2} O > NH _{3}
O
H O HF NH
2
3
HF H O NH
2
3
O H
O
F H
F
CHEMISTRY
CHEMISTRY
41. A solution is prepared by mixing 4 mole of liquid A, 6 mole of liquid B, 0.4 mole of nonvolatile solute C and 0.2 moles of nonvolatile solute D. If C undergoes 40% dimerisation while D undergoes 30% binary dissociation, then select correct statement(s) : (Given, vapour pressure of pure solvent A & B are 500mm & 600mm of Hg respectively).
(A)
(B)
(C)
(D)
the vapour pressure of solution is 490.3mm
4
mole fraction of A = _{1}_{0}
the vapour pressure of solution is 529.3mm
_{0}_{.}_{3}_{2}
_{0}_{.}_{2}_{6}
6
mole fraction of B = _{1}_{0}
_{0}_{.}_{3}_{2}
_{0}_{.}_{2}_{6}
42. Select the correct statements out of I, II and III for zero order reaction
(A) 
Quantity of the product formed is directly proportional to time 
(B) 
Larger the initial concentration of the reactant, greater the halflife period 
(C) 
If 50% reaction takes place in 100 minutes, 75% reaction take place in 150 minutes. 
(D) 
If 50% reaction takes place in 100 minutes, 75% reaction take place in 250 minutes. 
43. A teritary alcohol
(A) O _{2}
(C) Ketone
can be prepared by grignard reagent and :
(B) Epoxide
(D) Acid derivatives (specially acid halide)
(Space
for
Rough
Work)
CHEMISTRY
& 3R.
45. Correct statement about peptide linkage in a protein molecule is/are correct ?
(A) 
It is amide linkage 
(B) 
It has partial double bond character. 
(C) 
It is hydrophilic in nature 
(D) 
It connects protein molecules through Hbonds. 
46. Which of the following statements is/are incorrect about the given carbohydrate :
CH OH
2
HO
H
OH
H
H OH
H
CH OH
2
(A) 
It anomerizes in solution phase. 
(B) 
It is a reducing sugar. 
(C) 
It shows the phenomenon of inversion of sugar in acidic medium. 
(D) 
It shows mutarotation. 
(Space
for
Rough
Work)
SECTION – 2 : (Maximum Marks : 16)
This section contains TWO questions
Each question contains two columns, Column I and Column II
Column I has four entries (A),(B), (C) and (D)
Column II has four entries (P),(Q), (R) and (S)
Match the entries in Column I with the entries in Column II
One or more entries in Column I may match with one or more entries in Column II
The ORS contains a 4 × 4 matrix whose layout will be similar to the one shown below :
(A)
(B)
(C)
(D)
CHEMISTRY
CHEMISTRY
For each entry in Column I, darken the bubbles of all the matching entries. For example, if entry (A) in Column Imatches with entries (P), (Q) and (R), then darken these three bubbles in the ORS. Similarly, for entries (B), (C) and (D).
Marking scheme :
For each entry in Column I
+2 If only the bubble(s) corresponding to all the correct match(es) is (are) darkened
0 
If none of the bubbles is darkened 
0 
In all other cases 
(Space
for
Rough
Work)
47. Match the following :
ColumnI
(A) Borax
(B) B _{2} H _{6} + H _{2} O _{}_{}_{}
(C)
(D)
_{}_{}_{}
B _{2} H _{6} + NH _{3} (excess) BCl _{3} + LiAlH _{4} _{}_{}_{}
_{}_{}_{}
ColumnII
(P) BN
(Q) B _{2} H _{6}
(R) H _{3} BO _{3} (S) NaBO _{2} + B _{2} O _{3}
CHEMISTRY
CHEMISTRY
48. Column  I
(A)
Ph
^{H}
H
(B)
(C)
(D)
H
O
O
H
OH
Column  II
(P) 
Rearrangement reaction 
(Q) 
Isomerization reaction 
(R) 
Elimination reaction 
(S) 
Addition reaction 
CHEMISTRY
SECTION – 3 : (Maximum Marks : 18)
This section contains THREE paragraphs
Based on each paragraph, there will be TWO questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is correct
For each question, darken the bubble corresponding to the correct option in the ORS
Marking scheme :
+3 If only the bubble corresponding to the correct option is darkened
0 If none of the bubbles is darkened –1 In all other cases
Paragraph for Question Nos. 49 to 50
CHEMISTRY
Energy that is transmitted from one system to another in such a way that difference of temperature is
not directly involved is known as work. It is a path function.
This definition is consistent with our understanding of work as dw = Fdx. The force F can arise from
electrical, magnetic, gravitational & other sources.
49.
50.
Calculate the work done (in J) when 4.5 g of H _{2} O _{2} reacts against a pressure of 1 atm at 25°C ? 2H _{2} O _{2} ( _{} ) O _{2} (g) + 2H _{2} O ( _{} )
(A)
1.63 10
2
(B)
4.5 10
2
(C)
3.2 10
2
(D)
6.1 10
2
If
reversible expansion processes. (assume expansion to be from same initial points to same final volume wherever applicable) The correct order will be
(A)
for an ideal gas are magnitude of work done in isothermal, adiabatic, isobaric, isochoric
w ,w ,w ,w
1
2
3
4
w
1
w
2
w
3
w
4
(B)
w
3
w
2
w
1
w
4
(C)
w
3
w
2
w
4
w
1
(D)
w
3
w
1
w
2
w
4
(Space
for
Rough
Work)
CHEMISTRY
Paragraph for Question Nos. 51 to 52
According to crystal field theory, a stronger ligand produces larger . Due to this electrons get paired up in the presence of strong ligands. Hence, a metal ion in a complex with same coordination number show different magnetic behaviour in the presence of different ligands. The splitting of d orbitals along with presence of empty orbitals and electrons may result into colour of complexes.
CHEMISTRY
51. Which of the following complexes is a paramagnetic inner orbital complex?
(A) [Fe(CN) _{6} ] ^{4}^{–}
(B) [CoCl _{4} ] ^{2}^{–}
(C) [Cu(NH _{3} ) _{4} ] ^{2}^{+}
(D) [Fe(CO) _{5} ]
52. Which of the following pair of species is coloured in aqueous solution?
(A) 
CuSO _{4} , CaCl _{2} 
(B) CuSO _{4} , CuCl 
(C) 
CuSO _{4} , Cr _{2} (SO _{4} ) _{3} 
(D) TiCl _{3} , ZnCl _{2} 
Paragraph for Question Nos. 53 to 54
Br / KOH/
2
_{(}_{Q}_{)}
(R) + CO _{2}
(P) + CH _{3} COOH
(Space
for
Rough
Work)
53. The compound (P) is :
(A)
(Space
for
Rough
Work)
CHEMISTRY
CHEMISTRY
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Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose. GENERAL %
1. The sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so.
2. The question paper CODE is printed on the right hand top corner of this sheet and the right hand top corner of the back cover of this booklet.
3. Use the Optical Response Sheet (ORS) provided separately for answering the question.
4. Blank spaces are provided within this booklet for rough work.
5. Write your Name and Roll Number in the space provided on the below cover.
6. After the open booklet, verify that the booklet contains all the 54 questions along with the options are legible.
QUESTION PAPER FORMAT AND MARKING SCHEME :
7. The question paper has three parts : Mathematics, Physics and Chemistry. Each part has three sections.
8. Carefully read the instructions given at the beginning of each section.
9. Section 1 contains 10 multiple Choice question with one or more than one correct option. Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
10. Section 2 contains 2 "match the following" type question and you will have to match entries in Column I with the entries in ColumnII. Marking scheme : for each entry in Column I, +2 for correct answer, 0 if not attempted and 0 in all other cases.
11. Section 3 contains 3 "paragraph" type questions. Each paragraph describes an experiment, a situation or a problem. Two multiple choice questions will be asked based on this paragraph. Only one option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
OPTICAL RESPONSE SHEET :
12. Darken the appropriate bubbles on the original by applying sufficient pressure.
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