Documente Academic
Documente Profesional
Documente Cultură
Water Treatment
Unit Processes
Physical, Chemical,
and
Biological
David Hendricks
TECHNIPCHE
INFORMATICMCL:! L'..; OTI SEK
UNIVERSITATS&SSLiOTHEK
HANIi-JGVEH
B
Publishing
CRC Press
Taylor fx Francis Group
Boca Raton
CRC Press Is
Taylor
an
& Francis
imprint
Croup,
London
New York
of the
an
Informs business
Contents
Preface
xxxiii
Acknowledgments
xxxv
Author
xxxvii
Downloadable Files
xxxix
ContentsDownloadable Files
PART!
Chapter 1
xli
Foundation
Water Treatment
1.1
1.1.1
1.1.2
Residuals
Organization
1.3
Unit Processes
1.3.1
Definitions
1.3.2
Technologies
1.3.3
1.3.4
Proprietary Technologies
1.3.5
1.3.6
Future of Treatment
1.3.7
Energy Expenditure
1.4
of Water Treatment
Tertiary
1.4.1.1
1.5
Technologies
for Treatment
8
8
Treatment
Cases
9
9
10
1.4.2.1
11
1.4.3
12
1.4.4
Hazardous Wastes
12
1.4.5
13
Cases
Design
13
Factors: Nontechnical
13
1.5.1.1
13
1.5.1.3
Operation Issues
Managing a Team
Expansion
1.5.1.4
Esthetics
13
1.5.1.5
Regulations
14
1.5.1.6
Institutions
14
1.5.1.7
Consulting Engineering
14
1.5.1.2
1.4.2
1.5.1
1.6
Knowledge
Treatment Trains
1.4.1
Chapter
1.2
Summary
13
13
17
Problems
17
Acknowledgments
18
Glossary
18
References
19
Water Contaminants
21
2.1
Water
Quality:
Definitions
21
2.1.1
Contaminants
21
2.1.2
State of Water
22
vi
Contents
2.1.3
Criteria
2.1.4
Standards
2.1.4.1
2.1.5
2.2
22
22
2.1.4.2
2.1.4.3
Standards
Targets
as
for Treatment
Surrogates
2.4
2.5
2.6
Legal
Regulations
2.2.3
Priority Pollutants
Maturation of Water Quality Knowledge
2.3.1
Knowledge of Contaminants
2.3.2
Measurement Technologies
Categorizations of Contaminant Species
2.4.1
Systems of Categorization
2.4.2
Illustrative System of Contaminant Categorization
of
Water Quality Data
Utility
26
2.5.1
31
Combinations of
Quality
Problems
26
26
27
27
28
28
28
28
31
31
34
Acknowledgments
Appendix 2.A: Organic
2.A. 1
Categories
2. A. 1.1
34
Carbon
of
as a
Organics
Contaminant
34
in Water
35
Color
37
2.A.1.2
2.A.3
Organic Carbon
2. A. 1.3
UV254
2.A.1.4
Synthetic Organic Carbon
Disinfection By-Products
Disinfection By-Products in Secondary
2.A.4
Disinfectant Selection
40
2.A.5
Other Notes
40
2.A.2
Chapter 3
24
25
Definitions
2.2.2
2.3
24
24
Federal Laws
2.2.1
22
37
37
37
37
Effluents
39
Glossary
40
References
41
Bibliography
42
Models
45
3.1
Unit Processes
45
3.2
Models
Categories
3.2.2
45
3.2.2.1
46
3.2.3
3.3
Physical
of Models
45
Plots
Models
46
3.2.3.1
Bench Scale
3.2.3.2
Pilot Plants
46
3.2.3.3
Demonstration Plants
47
3.2.4
Mathematical Models
3.2.5
Computer
3.2.6
Scenarios
Modeling
3.3.1
3.4
45
3.2.1
Models
Testing
46
48
48
49
Protocol
49
Spreadsheets
51
52
3.4.1
Units
52
3.4.2
Dimensions
52
Contents
vii
3.5
3.6
Chapter 4
Examples
Summary
of Models
54
Problems
54
Glossary
54
References
56
57
4.1
Unit Processes
57
4.1.1
57
4.1.2.1
57
4.1.2
4.2
57
57
4.2.2
Transport
4.2.2.4
4.2.2.5
4.2.2.6
4.2.3
59
59
59
59
59
59
60
Summary
62
Reactors
62
4.3.1
62
4.3.2
Examples of Reactors
Types of Reactors
4.3.3
Mathematics of Reactors
4.3.4
62
62
4.3.3.1
Materials Balance:
4.3.3.2
Comments
4.3.3.3
Materials Balance:
Concept
62
on Materials Balance
Special
63
63
Conditions
66
4.3.4.1
4.3.4.2
Steady
4.3.4.3
Zero Reaction:
4.3.4.4
4.3.4.5
4.3.4.6
Utility of Finite
State Reactor:
Complete
Complete
66
Mixed
66
Mixed
Difference
67
67
Equation
Kinetic Models
Equation
68
71
71
4.4.1
First-Order Kinetics
4.4.2
Second-Order Kinetics
4.4.3
Examples
of Kinetic
71
72
Equations
4.4.3.1
Example: Gas
4.4.3.2
4.4.3.3
72
Transfer
72
of Substrate
72
72
Problems
73
Glossary
74
References
76
Particulate
PART II
5
57
Sinks
4.2.2.3
4.4
Changes
4.2.1
4.2.2.2
4.3
Contextual
Principles
4.2.2.1
Chapter
52
Separations
Screening
79
5.1
Theory of Screening
Types of Screens
79
5.2.1
79
5.2
79
Bar Screens
5.2.1.1
Cleaning
5.2.1.2
Manually Cleaned
80
Bar Screens
80
Contents
7.3
Principles
Theory of
Chapter
Operation
7.3.2.1
7.3.2.2
Calculation of
7.3.2.3
Empirical
7.3.2.4
7.3.2.5
7.3.3
148
150
150
DL
Spiral Length,
Guidelines
151
151
Determination
Algorithm
150
151
for Calculations
152
154
7.3.3.1
154
7.3.3.2
Summary
7.3.3.3
Pressure in Header
7.3.3.4
Blower Power
Designs
of Guidelines
155
Pipe
156
156
Problems
157
Acknowledgments
159
Glossary
159
References
160
Flotation
163
8.1
8.2
Development
of Flotation
163
8.1.2
163
Applications
163
8.2.1.2
Flocculation
163
8.2.1.3
Contact Zone
163
8.2.1.4
Saturator
163
8.2.1.5
Gas
164
8.2.1.7
Precipitation
Bubble-Floc Agglomerate
Float Layer
8.2.1.8
Clarified Water
164
8.2.1.9
Further
164
8.3.4
164
Processing
164
Gas Transfer
164
8.3.1.2
Henry's Law
Application of Henry's
8.3.1.3
Saturator
8.3.1.4
Gas Concentration
8.3.1.5
167
8.3.1.6
Saturator
167
8.3.1.7
8.3.3
164
of DAF Flotation
8.3.1.1
8.3.2
163
Coagulation
Principles
8.3.1
163
8.2.1.1
8.2.1.6
8.3
163
8.1.1
Hydraulic
Gas Precipitation
164
Law to Saturator
166
166
Nozzle
at
Depth
Packing
Grade Line
167
167
168
8.3.2.1
Bubbles
168
8.3.2.2
Bubble Size
170
8.3.2.3
170
8.3.2.4
Bubble Numbers
170
8.3.2.5
Nozzle Design
170
Contact Zone
171
8.3.3.1
171
8.3.3.2
8.3.3.3
Parameter Values
172
172
Separation Zone
172
8.3.4.1
172
Contents
xi
8.3.5
8.4
8.3.4.2
Rise
8.3.4.3
Bubble-Particle Ratio
174
8.3.4.4
Concentration
174
8.4.2
172
Expressions
178
8.3.5.1
178
8.3.5.2
179
by Spreadsheet
180
Design
Criteria
8.4.3
8.4.4
180
8.4.1.1
180
8.4.1.2
Flotation for
181
8.4.1.3
Air-to-Solids Ratio
Sludge Thickening
181
Pilot Plants
8.4.2.1
181
Pilot Plant
Study
181
Case:
Birmingham
Equipment
182
183
Problems
184
Acknowledgments
Glossary
186
References
187
186
Microscopic Particles
PART III
9
of Particle-Bubble
Practice
8.4.1
Chapter
Velocity
Coagulation
9.1
Coagulation In-a-Nutshell
9.1.1
Denning Coagulation
9.1.2
191
Particles to Be Removed
191
9.1.1.2
Coagulation
191
9.1.1.3
Microflocs
191
9.1.1.4
Rapid-Mix
191
9.1.1.5
Flocculation
191
9.1.1.6
Themes of
191
Coagulation
Coagulation Theory
Practice
191
Dosage
9.1.2.2
191
Coagulation
Effectiveness
192
192
9.2.1
Particle
192
9.2.2
Particle Characteristics
Variety
9.2.2.1
9.2.2.2
192
Particles
9.2.2.5
9.2.2.6
Particle Counts
9.2.2.4
9.2.3
192
Colloids
Microscopic
Natural Organic Matter
Total Organic Carbon
Turbidity
9.2.2.3
9.3
191
9.1.1.1
9.1.2.1
9.2
191
Turbidity
192
and Color
194
194
194
194
9.2.3.1
Spatial
9.2.3.2
Seasonal Variation
Compared
Chemistry
9.3.1
9.3.2
194
194
194
194
of
Chemistry
9.3.1.1
Key
194
195
9.3.1.2
Color
196
9.3.1.3
Modern Theory
196
Reactions
197
Coagulation
9.3.2.1
197
9.3.2.2
Two
197
Coagulation Mechanisms
xjj
Contents
9.3.2.3
9.3.2.4
NOM Removal
Organics
9.5
Coagulatants
199
Coagulation
Synthetic Organics
Double Layer Theory
9.4.1
Double Layer Description
200
200
200
9.4.1.1
Beginning
9.4.1.2
Surface Charge
200
Model
200
9.4.1.3
Gouy-Chapman
9.4.1.4
200
9.4.1.5
Fixed Layer
Effect of Ionic Strength of Solution
9.4.1.6
Electrostatic Potentials
201
9.4.1.7
DLVO
201
200
Theory
202
9.5.1
203
9.5.1.1
Hydration
9.5.1.2
Expressing Concentrations
9.5.1.3
Liquid Alum
Alkalinity
9.5.2.1
Role of Alkalinity as a Buffer
9.5.2.2
Effect of Alkalinity on Demand for Alum
Effect of Alum on pH
9.5.2.3
Reactions between Alum/Ferric Iron and Water
203
9.5.3.1
205
9.5.2
9.5.3
Waters of
9.5.3.3
Beginning
Sequential Hydrolysis
Species Equilibrium
9.5.3.4
Coagulation
9.5.3.2
204
204
204
205
209
209
9.6.1
210
Characteristics of PAC1
Description of PAC1
9.6.1.2
Electrophoretic Mobility: Comparing
Zeta Potential, Charge Density, and Streaming Current
9.7.1
Basic Notions of Electrophoretic Mobility
9.7.3
9.7.4
Electrophoresis
210
210
210
210
Alum and PAC1
210
Potential
211
211
211
9.7.2.1
Electrophoresis
211
9.7.2.2
Zeta Potential
212
214
9.7.3.1
214
Typical
Zeta Potentials
Colloid Titration
9.7.5
9.9
204
9.7.2
9.8
204
206
Zones
9.6.1.1
9.7
203
205
Reactions
9.5.3.5
9.6
197
199
of
9.3.2.5
9.4
Metal
by
in Wastewaters
Streaming Current
Physical Models
215
Monitor
215
216
9.8.1
Jar Tests
216
9.8.2
217
9.8.3
Pilot Plants
218
9.8.3.1
218
9.8.3.2
Independent Variables
Dependent Variables
9.8.3.3
218
218
Polymers
218
9.9.1
Definitions
218
9.9.2
Characteristics of Polymers
9.9.2.1
Charge Concentration
219
9.9.2.2
219
9.9.3
Specific Gravity
219
Polymers
in Wastewater Treatment
219
9.9.3.1
Sludge Conditioning
219
Contents
Xl"
9.9.4
Structure of
220
Polymers
Groups
9.9.4.1
Functional
220
9.9.4.2
Monomers
220
Polymers
Selection of Polymers
9.9.5.1
Polymer Screening
9.9.5.2
Polymer Packaging
221
9.9.5.3
224
9.9.4.3
9.9.5
221
221
223
9.9.5.4
Specification Sheets
Prepared Batches
9.9.5.5
Feed of
9.9.5.6
Concentration: Convention
224
224
Polymer
(Adapted from AWWA B453-96)
224
Problems
226
Acknowledgments
Glossary
228
References
235
228
Chapter 10 Mixing
10.1
239
Definitions and
10.1.1
10.1.2
10.2
239
10.1.1.1
Mixing
239
10.1.1.2 Near-Synonyms
239
Application Categories
239
10.1.2.1
Liquid-Solid
Liquid-Gas
10.1.2.3 Immiscible Liquids
10.1.2.4 Miscible Liquids
239
10.1.2.2
239
240
240
10.1.3
Mixing
History
of
10.2.1
239
Applications
Definitions
Rate
as
239
240
240
240
Limiting
240
Mixing
Drinking
Water Treatment
240
10.2.1.1
Initial
240
10.2.1.2
Gas Dissolution
Mixing
10.2.2
Wastewater Treatment
10.2.3
Evolution of
10.2.3.1
241
241
242
Mixing Theory
Development
of Collision
Frequency Mathematics
Modifying Camp
Empirical Parameters
243
10.2.3.4
10.2.3.5
GandG
243
10.2.3.3
10.2.4
10.3
and Stein's G
Technologies
Mixing
243
244
of Mixing
244
Theory of
10.3.1
10.3.2
244
Mechanisms
Transport
10.3.1.1 Advection
245
10.3.1.2 Turbulence
246
10.3.1.3
252
Transport Regime
Navier-Stokes
10.3.2.1
10.3.2.2
10.3.3
242
243
10.2.3.2 Derivation of G
253
Equation
Mathematics of Navier-Stokes
Computational
Fluid
Equation
Dynamics
253
254
Similitude
254
10.3.3.1
255
Dimensionless Numbers
10.3.3.5
Experimental
Mixing
Plots
Fluid Similitude
Scale-Up by
Scale-Up Dilemma
256
256
256
258
xiv
Contents
10.3.4
10.4
260
10.3.4.1
Disparity of Flows
260
10.3.4.2
260
Mixing Technologies
10.4.1
Impeller Mixing
261
261
10.4.1.1
10.4.1.2
10.4.1.3
Time Ratio,
10.4.1.4
;/<2(reactor),
to Attain
to
10.4.2
Complete-Mix
Impellers
and Tanks
10.5
Chapter
Back-Mix Reactor
262
264
264
266
Impeller Variety
10.4.2.2 Impeller Characteristics
10.4.2.3 Impeller Pumping
266
10.4.2.4 Tanks
269
270
Jet Mixers
271
10.4.3.1
10.4.4
264
Reactors
10.4.2.1
10.4.3
0.99
in
Procedure (b)
10.4.1.5
261
Blending
266
267
270
276
10.4.4.1
276
General Principles
271
10.4.4.2 Baffles
276
10.4.4.3
277
Static Mixers
Summary
280
Problems
280
Acknowledgments
Glossary
284
References
288
Bibliography
290
283
11 Flocculation
11.1
Definitions
11.1.1
11.1.2
11.2
291
291
Floe
291
11.1.1.1
Biological
Floe
11.1.1.2
Chemical Floe
291
11.1.1.3
Primary Particles
291
Flocculation
291
11.1.2.1
Orthokinetic Flocculation
291
11.1.2.2
Perikinetic Flocculation
291
11.1.2.3
Flocculent
291
Applications
292
11.2.1
Conventional Filtration
292
11.2.2
Direct Filtration
292
11.2.3
Flotation
292
11.2.4
Activated
11.2.5
11.3
291
292
Softening
11.2.6 Tertiary Treatment
292
History
292
11.3.1
Practice
11.3.1.1
Quiescent Basins
11.3.1.2 Langelier's Paddle Wheels
11.3.1.3 Design Guidelines
11.3.1.4 Flocculation Practice, c. 1940
11.3.2 Evolution of Theory
11.3.2.1 Langelier
292
292
292
292
293
294
294
294
Contents
xv
11.4
Theory
11.4.1
11.4.2
11.3.2.2
Smoluchowski's Collision
11.3.2.3
Camp's
296
Kinetics
296
11.4.1.1
Frequency
11.4.1.2
of Particle Collisions
Particles, k
299
299
Characteristics of Floes
Breakup
304
Bioflocculation
Flocculents
11.4.4
Design Principles
304
305
11.4.4.1
Derivation of
11.4.4.2
Camp's Equation
Design
Procedure from
11.5.1.2
11.5.1.3
Camp
11.6
11.7
308
310
310
Calculations
310
11.5.2.2
Plots
310
Slip Factor
Plant Design
Other Technologies
313
313
315
11.5.4.1
Turbines
11.5.4.2
Baffles
315
Proprietary Technologies
319
11.6.1
Turbine Flocculators
320
11.6.2
320
11.6.2.1
320
Principles
11.6.2.2 Design Practice, Equipment, Operation
11.6.3 Super-Pulsators
11.6.4 Culligan Multi-Tech
Summary
321
321
321
321
323
of
Camp
323
324
326
Rapid
Filtration
12.1
Description
12.1.1
315
321
References
12.2
308
11.5.2.1
Acknowledgments
Appendix 1 LA: Derivation
Glossary
12
308
Problems
Chapter
306
308
Camp's Criteria
Camp's Guidelines
Spreadsheet Algorithm
11.5.2.3
11.5.4
306
308
Design
11.5.1.1
11.5.3
299
11.4.2.1
11.4.3
11.5.2
296
11.4.2.3
11.5.1
294
296
of Flocculation
11.4.2.2 Floe
11.5
Equations
329
of
Rapid Filtration
329
Filtration
Technology
329
12.1.1.1
In-a-Nutshell
329
12.1.1.2
Support Components
330
12.1.1.3
Filtration Mode
330
12.1.2
Applications
331
12.1.3
Variations....
331
Hyatt Filter
331
331
331
331
Proprietary Filters
12.2.1.4 Fuller's Experiments
331
12.2.1.3 Other
332
Contents
xvi
12.2.2
12.2.3
12.2.2.1
334
12.2.2.2
Growth of Waterworks
334
Industry
334
in Filtration Practice
Progress
335
Dual Media
12.2.3.1
12.2.4
333
of Filtration Practice
Emergence
335
12.2.3.2
Breaking
12.2.3.3
335
335
335
12.2.4.1
335
336
Theory
12.3.1
12.3.2
Quest
of
336
Theory
12.3.1.1
Dependent
12.3.1.2
Definitions
Process
336
336
Description
Results of Eliassen
336
Results of Ives
337
12.3.2.2
Experimental C(Z),
Experimental C(Z),
12.3.2.3
12.3.2.4
12.3.2.5
12.3.2.6
Specific Solids
12.3.2.1
12.3.2.7
Clogging
12.3.2.8
Local
12.3.2.9
Rational
Adsorption
C{t)z=Zo Breakthrough
340
341
of Headloss
Filter
344
Iwasaki's
12.3.3.2
Filter Coefficient
344
Equations
346
346
Transport Coefficient
12.3.3.4 Attachment Coefficient
12.3.5
12.4
12.3.3.5
Effect of Attachment
12.3.3.6
Synthesis
Efficiency
12.4.2
12.4.3
349
on
Filter
Ripening
Expression
349
350
351
Model
12.3.4.1
Solids
Rate
12.3.4.2
Conditions at
12.3.4.3
Uptake
Equilibrium
351
352
353
353
Summary
353
Design
12.4.1
342
342
Cycle
Modeling
12.3.3.1
of
337
339
12.3.3.3
12.3.4
337
Curve
339
Deposit, ct(Z, /)
337
and Filtration
Front
12.3.3
336
Functions in Filtration
External Parameters
354
12.4.1.1
Design
354
12.4.1.2
Cost
Decisions
354
of Filter
Components
Design
12.4.2.1 Layout of Filters
12.4.2.2 Hydraulic Modes of Filtration
354
354
355
12.4.2.3
Water Distribution
355
12.4.2.4
Media
356
12.4.2.5
Pipe Gallery
356
12.4.2.6
Clear-Well
358
12.4.2.7
Control
359
Systems
Filter Box
359
12.4.3.1
Filtration Rate
359
12.4.3.2
Area of Filters
359
12.4.3.3
359
12.4.3.4
Depth
of Filter Box
359
Contents
xvii
12.4.4
360
Backwash
12.4.4.1
12.4.4.2
Manifold
Types
361
Systems
362
12.4.4.4
363
Backwash Water
12.4.4.5 Under-Drain
12.5
360
Principles
of Backwash
Troughs
363
Systems
365
12.4.4.7
Surface-Wash
368
12.4.4.8
Air-wash
369
369
12.4.4.10 Collapse
370
Pulsing
371
Operation
12.5.1
Filter
12.5.2
Filtration
372
Hydraulics
372
12.5.2.1
Clean-Bed Headless
372
Operating Cycle
12.5.3
Air
373
374
374
Binding
Backwash
374
12.5.3.1
375
12.5.3.2 Floc-to-Grain
375
Bonding
12.5.3.3 Practice
12.5.3.4
12.6
Operating
375
375
Protocol
Pilot Plants
375
12.6.1
376
Equipment
12.6.1.1 Contaminant
12.6.1.2
376
Injection
377
Filter Column
12.8
378
378
Wastewater Filtration
378
12.7.1
Background
378
12.7.2
Forms of Practice
12.7.2.1
As
12.7.2.2
As
378
Stand-Alone Process
Following Biological
Proprietary Equipment
12.8.1 Ancillary Equipment
12.8.2 Package Filtration Systems
12.8.2.1 Deep Bed FiltrationParkson DynaSand
12.8.2.2 Deep Bed FiltrationCulligan Multi-Tech
12.8.3
379
379
379
379
380
380
12.8.2.4
380
380
Evaluation of Products
381
382
in New York
382
385
391
References
395
395
Description
13.1.1
378
Acknowledgments
Appendix 12.A: Filtration
Glossary
13.1
378
12.8.2.3
Problems
Chapter
Treatment
Slow Sand
395
Technology
13.1.1.1
Filter B ox and
13.1.1.2
Sand Bed
395
13.1.1.3
Schmutzdecke
395
13.1.1.4
Design Approach
395
Appurtenances
395
xviii
Contents
13.1.2
13.1.3
13.2
Attributes
Selection Criteria
395
13.1.2.2
Effectiveness
395
13.1.2.3
Economy
396
13.1.2.4 Labor
396
13.1.2.5
Materials
397
13.1.2.6
Contextual Factors
397
History
13.2.2
397
13.1.3.1
James
13.1.3.2
Evolution of Practice
Slow Sand
13.2.1
as a
Slow Sand
399
Removal Mechanisms
399
13.2.1.1
399
Hydraulics
13.2.2.1 Darcy'sLaw
401
13.2.2.2 Instrinsic
401
400
401
Hydraulic Conductivity
403
403
Filter Box
13.3.1.2
Number of Cells
405
13.3.1.3
Layout
Depth of Box
Structural Design
405
13.3.1.5
13.3.3
404
13.3.1.1
13.3.1.4
13.3.2
398
398
Design
13.3.1
Area
404
405
406
Hydraulics
406
13.3.2.1
407
13.3.2.2
13.3.2.3
13.3.2.4
Drainage System
408
13.3.2.5
408
13.3.2.6
13.3.2.7
Sand Size
409
13.3.2.8
Gravel
Support
408
Energy
408
408
410
Support Systems
411
13.3.3.1
Flow Measurements
411
13.3.3.2
Piezometers
411
13.3.3.3
Turbidimeters
411
13.3.3.4
Flow Control
411
411
13.3.3.6
Pipe Gallery
412
13.3.3.7
Access
to Filters
412
13.3.3.8
Plumbing Functions
13.3.3.9 Hydraulic Profile
412
13.3.3.l0Headroom
412
13.3.3.11
13.4
Process
13.2.2.3
13.3
395
13.1.2.1
Designing
to Avoid
412
Freezing
412
413
13.4.1
414
13.4.2
Case
414
Study
13.4.2.1
Context
Results
13.4.2.4 Discussion
413
414
Setup
414
415
415
Contents
x'x
13.5
415
Operation
13.5.1
Plant
13.5.2
Operating
415
Start-Up
415
Tasks
415
13.5.2.1
13.5.3
Chapter
Scraping
13.5.2.2 Rebuilding the Sand
Monitoring and Reporting
416
Bed
416
Problems
416
Acknowledgments
Glossary
418
References
420
14 Cake Filtration
423
14.1
418
423
Description
14.1.1
423
423
Applications
14.1.1.1
423
14.1.1.2 Definitions
14.1.1.4 Process
14.1.1.5
14.1.2
Operation
Description
424
424
DE Selection
425
Media
14.1.2.1
Kinds of Media
425
14.1.2.2
Sources of Media
425
of Media
426
427
14.1.3
Attributes
427
14.1.4
History
Manufacturing
14.1.2.3
14.2
424
Phases of
14.1.1.3
428
Use of DE Filtration
14.1.4.1
1940s'
14.1.4.2
1950s'
14.1.4.3
Research
Military
Adaptation of DE for Municipal
428
Use
430
431
431
431
and Bacteria
14.2.1.1
Turbidity
14.2.1.2
Particle Counts
432
14.2.1.3
Iron and
432
Manganese
432
Biological Particles
432
14.2.1.5
14.2.2
433
Removal Mechanisms
433
Straining and
14.2.2.1
Embedding
Body Feed
Adsorption
Comparisons between Filtration
Hydraulics
433
433
14.2.2.3
14.2.2.4
14.2.3
14.2.3.1
14.3
Diatomite
14.3.1.1
14.3.1.2
14.3.1.3
14.3.2
14.3.3
14.4
Processes
433
433
434
437
Design
14.3.1
429
Design
Technologies
Equipment
System Components
Layout
Parameters
437
438
439
440
441
14.3.2.1
Variables
441
14.3.2.2
441
Design Examples
14.3.3.1
14.3.3.2
Plant
Operation
14.4.1
Operating
Descriptions
442
442
442
445
Protocol
445
xx
Contents
14.4.1.1
Pre-Coat
Deposit
14.4.3
14.4.4
14.5
Operation
Monitoring
446
447
14.4.2.2
Headloss
versus
Time
447
14.4.2.3
Turbidity
versus
Time
447
14.4.2.4
447
Cleaning
and
447
14.4.3.1
Protocol
447
14.4.3.2
Start-Up
447
Disposal
of Waste Diatomite
447
14.4.4.1
Waste
Storage
447
14.4.4.2
Waste
Disposal
447
Questions
14.5.1.1
14.5.2
446
14.4.2.1
Start-Up
447
for
447
448
Cases
14.5.2.1
14.5.2.2
PART IV
445
446
448
SR
Ranch, Colorado
100 Mile House, British
448
Columbia
449
Problems
450
Acknowledgments
Glossary
450
References
453
451
Chapter 15 Adsorption
15.1
457
Description
15.1.1 Adsorption In-a-Nutshell
15.1.1.1
15.1.2
15.1.3
15.1.4
15.1.5
15.2
457
457
Definitions
457
458
15.1.1.3
Operation
458
15.1.1.4
Performance Measures
45 8
Adsorbents
458
15.1.2.1
Kinds of Adsorbents
458
15.1.2.2
459
15.1.2.3
Manufacturing
459
of Activated Carbon
459
15.1.2.5
463
Shipping
Data
Adsorbates
463
15.1.3.1
Organic Compounds
463
15.1.3.2
464
Applications
History
464
15.1.5.1
465
464
Lore
15.1.5.2 Science
465
15.1.5.3
465
Practice
466
Equilibrium
466
15.2.1.1
Reaction
15.2.1.2
Langmuir
15.2.1.3
Freundlich Isotherm
466
Isotherm
Multicomponent Equilibria
466
469
470
470
Contents
xxi
15.2.2
Kinetics
471
15.2.2.1
471
Graphical Depiction
15.2.2.2 Rate of Uptake: Theoretical
15.2.2.3 Empirical Rate Equation
15.2.3 Reactor Theory for Packed Beds
473
473
473
15.2.3.1
Mathematics
473
15.2.3.2
Advection Kinetics
474
15.2.3.3
Simulation
476
Modeling
15.2.3.4 Characteristics of Output Curves
15.2.4 Rational Design
15.2.4.1 Quick-and-Dirty Mass Balance
15.2.4.2 Empirical Data for Lwf and vwf
15.2.4.3 Theoretical Results for Lwf and vwf
15.2.5
481
15.2.5.2
15.2.5.3
Bacterial Colonization
482
482
483
Plant
Study
483
15.3.1.1
Isotherm Determination
483
15.3.1.2
Determine
483
15.3.1.4
v(wave front)
L(wave front)
Breakthrough Curve
15.3.1.5
484
15.3.1.6
Backwash
484
15.3.1.7
Assess
15.3.1.8
Discover Effects of
15.3.1.9
Fabrication
Velocity
Competitive
484
484
Unanticipated
Problems
484
484
484
Demonstration-Scale Plants
15.3.2.1
Pomona
15.3.2.2
484
484
485
486
Design
15.4.1
Design
Variables
486
15.4.1.1
Independent
15.4.1.2
Process Variables
486
488
489
15.4.2.1
489
15.4.2.2
490
15.4.3
Spreadsheet Layout
Spreadsheet Scenarios
Design Examples
15.4.3.1 Examples of Sites
490
490
15.4.3.3
Chemicals in
490
15.4.3.4
Operation
Drinking Water
and Costs
15.5.1
Operation
15.5.2
Costs
Characteristics
Sources
492
494
496
496
496
15.5.2.1
496
15.5.2.2
Virgin GAC
Regeneration
496
15.5.2.3
Problems
496
497
Acknowledgments
Appendix
Glossary
490
15.4.3.2
15.4.3.5
15.5
481
481
481
15.3.1.3
15.4
480
15.3.2
479
Problems
15.2.5.1
15.3
477
15.A:
499
Freundlich Isotherm Coefficients
499
499
References
507
Further
510
Readings
Contents
xxii
511
Chapter 16 Ion-Exchange
16.1
511
Description
16.1.1
Ion-Exchange In-a-Nutshell
511
16.1.1.1
511
Definitions
16.1.1.2 Process
16.1.1.3
16.1.2
512
512
Science
512
Applications
16.1.3.1
16.2
512
Use
Municipal
16.1.3.2 Removals of
16.1.4
511
History
16.1.2.1
16.1.3
511
Description
Operation
Phases of
513
Ions
Specific
16.1.3.3 Deionization
513
Media
513
16.1.4.1
Mineral
16.1.4.2
Clays
16.1.4.3
Zeolites
513
Ion-Exchangers
16.1.4.4
Synthetic
16.1.4.5
Aluminas
513
513
516
Resins
519
520
Ion-Exchange Theory
16.2.1
Capacity
520
of Media
520
Capacity
Expressions
Upper Limit of Capacity
16.2.2 Equilibria
16.2.1.1
of
520
16.2.1.2
16.2.2.1
16.2.2.2
Isotherm
16.2.2.3
16.2.3
521
Equilibrium Equations
Expression of Equilibrium
522
Kinetics
16.2.3.1
522
Rate-Determining Step
522
523
Design
16.3.1
523
Selection of Ion-Exchangers
16.3.1.1
523
Resins
523
16.3.1.2 Zeolites
16.3.1.3
16.3.2
16.3.3
Range of Ion-Exchangers
and
524
524
Pretreatment
524
16.3.2.3
525
Regeneration
Design
16.3.3.1 Summary of Design
525
Reactor
Data
525
526
526
Operation
16.4.1
Operating Cycle
527
16.4.1.1
Production
527
16.4.1.2
Regeneration
Disposal
527
Nitrate Removal at
Glendale, Arizona
527
528
Problems
Acknowledgments
Appendix 16.A: Ion-Exchange
Glossary
527
527
Case Studies
16.5,1
523
16.3.2.1
16.4.1.3
16.5
Properties
System Design
521
521
of Counterions
Selectivity
521
529
Conversions
529
532
References
537
Bibliography
538
Contents
Chapter 17
xxiii
Membrane Processes
539
17.1
539
Description
17.1.1
Membranes In-a-Nutshell
17.1.1.1
Analysis:
539
Flow Balance
Principle
539
17.1.1.2 Definitions
539
539
17.1.1.5 Membrane
Technology
540
17.1.1.6 Racks
17.1.1.7
541
Treatment Train
541
17.1.1.8 Operation
Global Capacity
541
542
17.1.4
Membrane Types
Membrane Materials
17.1.5
Membrane Structure
543
17.1.5.1
543
17.1.2
17.1.3
542
Microporous Membranes
17.1.5.2 Asymmetric Membranes
17.1.6 Manufacturing
17.1.7
Flat Sheets
544
17.1.6.2
Tubes
544
545
17.1.7.1
Plate-and-Frame Modules
17.1.7.2
Spiral-Wound Membrane
17.1.7.3
Hollow-Fiber Modules
545
17.1.7.4
547
17.1.7.5
Ratings
547
17.1.7.6
548
545
Modules
545
548
17.1.8.1
Particle Removals
17.1.8.2
Removal of
17.1.8.3
549
Organics
549
549
549
17.1.9.1
549
Advantages
Disadvantages
17.1.9.2
549
History
17.2.1
549
Membranes in Science
17.2.1.1
17.2.2
17.3
544
17.1.6.1
Applications
17.1.9
543
543
Packaging
17.1.8
17.2
539
549
17.2.1.2
Beginnings
The Development
17.2.1.3
Modern Period
550
Period
550
550
550
Theory
550
17.3.1
Performance Variables
550
17.3.2
Solute/Particle Rejection
550
17.3.3
Models
17.3.4
Describing Water
a
through
Membranes
551
551
17.3.4.1
How Balance
551
17.3.4.2
552
17.3.4.3
Water Flux
17.3.4.4
552
17.3.4.5
Transmembrane Pressure
552
"
Density
552
17.3.5
Poiseuille Law
552
17.3.6
Osmosis
554
17.3.6.1
Osmotic Pressure
17.3.6.2
Reverse Osmosis
17.3.6.3
554
554
on
Water Flux
Density
555
Contents
xxiv
17.3.7
17.3.8
17.4
17.4.2
556
Applications
556
Fouling
17.3.8.1
557
17.3.8.2
Natural
Organic
557
17.3.8.3
Particle
Fouling
17.3.8.4
Inorganics
557
17.3.8.5
Concentration Polarization
557
Matter
557
559
559
Pretreatment
Filters
559
17.4.1.1
Cartridge
17.4.1.2
Microfilter
559
17.4.1.3
Conventional Treatment
559
17.4.1.4
Other Pretreatment
559
Layouts
559
17.4.2.1
First Stage
560
17.4.2.2
Second
560
17.4.2.3
Third
560
17.4.2.4
Concentrate
560
17.4.2.5
Recoveries
560
Membrane
Stage
Stage
Operation
17.5.1
Integrity Testing
560
17.5.1.1
Breaches
561
17.5.1.2
Testing
561
17.5.2
17.6
556
17.3.7.1
Design
17.4.1
17.5
Electrodialysis
561
561
Cleaning
561
Pilot Plants
17.6.1
Utility
561
of Pilot Plants
17.6.1.1
Pilot Plant
561
Design......
562
562
Case
17.7.1
City
of
Brighton
Background
17.7.1.2 Brighton Pilot Plant
17.7.1.3 Design Parameters
17.7.1.4 Plant Layout
Chapter
562
562
17.7.1.1
562
562
563
Problems
564
Acknowledgments
Glossary
565
References
569
565
18 Gas Transfer
18.1
571
571
Description
18.1.1
18.1.2
18.1.3
571
Mass-Transfer Processes
571
571
571
571
572
18.1.3.2
Stream Aeration
572
18.1.3.3
572
18.1.3.4
18.1.3.5
Turbine Aeration
572
18.1.3.6
Grid Diffusers
573
18.1.3.7
Air
573
Stripping
572
Contents
xxv
18.2
573
18.2.3
573
Henry's
573
Law
573
Kinetics
18.2.2.1
Diffusion
18.2.2.2
573
to
Two-Film
Theory
579
18.2.2.4 Kxjx
580
as
Design
Parameter
580
18.2.3.1
583
583
Continuous-Flow
18.3
Aerator
18.4
Oxygen Transferred
588
588
589
Energy Expenditure
591
591
Reactor
592
Types
592
18.3.2.3
594
Diffused Aeration
597
Operation
Case Studies
597
18.4.1
Fine-Bubble Diffusers
597
18.4.2
Air
597
Stripping
18.4.2.1
Sydney Mine
at
Valrico, Florida
18.4.2.3
18.4.2.4
Hyde
Park
597
597
599
599
Problems
599
Acknowledgments
601
Appendix
18.A:
18.A.1
602
Onda Coefficients
602
Onda Correlations
18.A.2 Onda
Chapter 19
per Unit of
Equipment
18.3.2.1
18.3.3
585
589
Design
18.3.1.1 Algorithm for Aerator Sizing
18.3.1.2
18.3.2
584
589
Design
18.3.1
575
602
Equations
Glossary
603
References
604
Disinfection
607
19.1
19.2
607
Fundamentals
19.1.1
Microorganisms
19.1.2
Disinfectants
607
and Diseases
607
607
History
19.2.1
607
Chlorine
19.2.1.1
Story
607
of Chlorine
19.2.1.2 Disinfection
Byproducts
Issue
610
19.2.2
Ozone
610
19.2.3
Chlorine Dioxide
611
19.2.4
Ultraviolet Radiation
611
19.2.5
Other Disinfectants
612
19.2.5.1
Iodine
612
19.2.5.2
Bromine
612
19.2.5.3
Silver
612
xxvi
Contents
19.3
Theory
19.3.1
19.3.2
19.3.3
19.3.4
612
Inactivation
613
19.3.1.1
Factors
613
19.3.1.2
Mathematics
613
19.3.1.3
Ct's
614
19.3.1.4
614
19.3.1.5
Inactivation
614
Application
Compiled
by Ozone
of Chick-Watson Relation
614
19.3.2.1
Examples
of C -t Relation
Chlorine
Chemistry
617
19.3.3.1
Chlorine
617
19.3.3.2
Chlorine Demand
617
Properties
618
Chloramines
622
19.3.4.1
622
Chlorine-Ammonia Reactions
622
19.3.5
Ozone
622
19.3.6
Chlorine Dioxide
Chemistry
622
19.3.6.1
19.3.6.2
Characteristics of
as a
Disinfectant
C102
19.3.7.2
19.4
UV
624
Log R's by UV
625
625
628
629
Chlorine
19.4.1.1
19.5
624
by
Design
19.4.1
623
623
Ultraviolet Radiation
19.3.7.1 Disinfection Rate
622
629
Chlorine Feed
629
630
19.4.2
Hypochlorite
630
19.4.3
Ozone
630
19.4.4
Chlorine Dioxides
631
19.4.5
UV Reactors
631
19.4.5.1
631
Hydraulics
631
19.4.5.3
Lamps
19.4.5.4 Lamp Components
19.4.5.5 UV Design Guidelines
632
19.4.6
Costs
633
19.4.7
Case
633
19.4.8
Summary
633
UV
Operation
632
633
633
19.5.1
Chlorine Operation
19.5.2
Ozone
19.5.3
Ultraviolet
633
Operation
633
Lamps
634
Problems
634
Acknowledgments
Glossary
635
References
640
635
Chapter 20 Oxidation
20.1
643
Description
20.1.1 Applications of Oxidation Technology
20.1.2 History of Oxidation Technology
20.1.2.1
Oxidation Based
on
Electromotive Potential
643
643
643
643
Contents
xxvii
20.2
20.1.2.2 Wet-Oxidation
644
20.1.2.3
644
Oxidation Theory
20.2.1
644
Fundamentals
644
20.2.1.1
645
20.2.2
Definitions
645
20.2.1.3
645
Half Reactions
646
20.2.1.5
646
Thermodynamic Relations
Oxidants
647
20.2.2.1
20.2.3
Chlorine
647
649
20.2.2.4
649
Permanganate
649
650
650
650
20.2.3.2
SCWO In-a-Nutshell
20.2.3.3
Chapter
21
650
to
Engineering
651
652
653
653
20.2.3.7
20.3
647
20.2.2.2 Ozone
Practice
653
655
Problems
655
Acknowledgments
Glossary
656
References
658
Further Reading
659
Precipitation
661
21.1
656
Description
21.1.1 Precipitation
21.1.1.1
661
In-a-Nutshell
661
Definitions
661
with Other Processes
21.1.1.2
Comparison
Process Description
21.1.2 Applications
21.1.2.1 Softening
21.1.1.3
661
661
661
662
History
662
21.1.3.1
Softening
Sewage Treatment
21.1.3.3 Heavy Metals
Precipitation Theory
21.2.1 Equilibria
21.2.1.1 Solubility Law
21.2.1.2 Application of Solubility Law
21.2.1.3 Listing of Solubility Products
21.2.1.4 Solubility pC-pH Diagrams
21.2.1.5 pe-pH Diagrams
21.2.1.6 General Rules of Solubility
662
21.1.3.2
662
21.2.2
667
21.1.3
21.2
661
Hardness
21.2.2.1
Occurrence of Hardness
of Hardness
662
663
663
663
663
665
665
666
667
667
21.2.2.2
Expressing
21.2.2.3
as
CaC03
667
668
xxviii
Contents
21.2.3
21.3
Softening Reactions
668
Lime-Soda Process
669
Chemistry
of Metals
669
Practice
21.3.1
21.3.2
21.3.3
PART V
21.2.2.4
21.2.2.5
670
Lime
Softening
Precipitation of Heavy Metals
670
21.3.2.1
670
21.3.2.2
Case: Mine
671
670
Drainage
Precipitation of Anions
21.3.3.1 Phosphate Precipitation
21.3.3.2 Cyanide Precipitation
671
671
672
Problems
672
Acknowledgment
Glossary
672
References
675
Biological
Chapter 22 Biological
22.1
Treatment
679
22.1.1
1880-1980
679
22.1.2
Practice
679
22.1.3
Theory
679
22.1.4
Definitions
680
22.1.4.1
Reaction Classifications
680
22.1.4.2
BOD Nomenclature
22.1.4.3
681
681
22.1.5.1
Municipal Wastewaters
681
22.1.5.2
Industrial Wastes
681
22.1.5.3
Contaminants
683
683
Metabolic Reactions
684
22.2.1.1
Catabolism
684
22.2.1.2
Anabolism
685
22.2.1.3
Cell Division
686
22.2.1.4
Photosynthesis
Energy Principles
686
686
687
687
22.3.1.1
Compounds
Composition of Cells
22.3.2.1
22.3.3
681
Wastewaters
22.2.1.5
687
688
688
Cells
Biological Reactions
688
688
22.3.3.1
Substrate
22.3.3.2
Heterotrophic
Autotrophic Involving Nitrogen
689
22.3.3.4
Anaerobic
690
22.3.3.5
691
22.3.3.3
22.4
Cell Metabolism
22.2.1
22.3
679
Background
22.1.5
22.2
672
to
Cells
Cell Yield
22.4.1
Cell-Yield Calculation
22.4.2
688
689
692
692
Endogenous Respiration
693
Contents
xxix
22.4.3
22.5
22.4.2.1
Cell Maintenance
22.4.2.2
Endogenous Respiration
693
22.4.2.3
694
y(net)
694
22.4.3.1
694
22.4.3.2
694
22.4.4
Decline in
22.4.5
Cell-Yield Data
Degradable
VSS
695
695
Monod
22.5.2
Ks
22.5.3
Net
as
Description
of
695
Biological
Reactions
695
695
22.5.4
Specific
Temperature
Effect
697
22.5.5
697
22.5.5.1
697
Data
Andrews/Haldane
22.5.7
Kinetic Parameters
22.5.8
Specific
22.5.7.2
F/M
22.5.7.3
Conversion
22.5.9
697
698
Substrate Utilization
Rate,
698
Ratio
700
F/M
to U
700
Monod Kinetics to U
701
22.5.7.5
Relating
Sludge Age, 9C
22.5.7.6
Minimum Cell
Relationship
701
Regeneration Time, 0
between U and
Nitrification/Denitrification
22.5.8.1 Nitrification: NH4+
22.5.8.2
696
22.5.7.1
22.5.7.7
u.(net)
Kinetic Constants
on
22.5.6
22.5.7.4
Denitrification:
701
0C
701
701
to
N03~
N03~
N2 Gas
701
to
702
Phosphorous Uptake
702
22.5.9.1
702
Occurrence in Wastewaters
22.5.9.2
to Cells
Uptake
Theory
Technologies
22.5.9.3
22.5.9.4
22.6
693
702
702
703
Summary
703
Problems
703
Acknowledgments
Appendix 22.A: Proteins
22.A.1
704
Protein Molecules
704
705
22.A.3
705
ATP
22.B:
22.B.1
23
704
22.A.2 Urea
Appendix
Chapter
Michaelis-Menten
Enzyme
Equation
Kinetics
705
705
Glossary
707
References
718
Biological
Reactors
23.1
Biological
23.2
Activated
23.2.1
Reactor
Spectrum
721
Sludge
History
23.2.1.1
23.2.2
721
721
721
23.2.1.2
Beginnings
From Empiricism
23.2.1.3
Milestones
23.2.1.4
Modern
History
Activated-Sludge
Reactor
721
to
Science
724
724
725
Analysis
725
23.2.2.1
Materials Balance
726
23.2.2.2
727
23.2.2.3
Extended Aeration
729
xxx
Contents
23.2.3
729
Numerical
732
23.2.3.1
23.2.4
23.2.4.1
734
Empirical
Experience
733
Guidelines
with Plants
737
Operation
737
Bulking Sludge
738
23.3.2
739
Biofilms
23.3.1.1
739
Structure
739
739
739
Empirical Equation
Trickling-Filter Spreadsheet
739
Model.....
741
Anaerobic Reactors
741
23.4.1
741
23.4.2
Design
Criteria
23.4.2.1
23.4.3
23.4.4
742
High-Rate Digestion
742
742
23.4.3.2
744
743
Kinetics
23.4.3.3 Influences
23.5
733
Biofilm Reactors
23.3.1
23.4
Concept
733
23.2.5.1
23.3
Modeling
Numerical Model
23.2.5
730
on
Reaction
Velocity
744
745
23.4.3.6
Environmental Conditions
746
23.4.3.7
746
23.4.3.8
Practice
746
Operation
and
745
Monitoring
Upsets
747
23.4.4.1
Process
23.4.4.2
23.4.4.3
747
747
Suspended
Solids
748
23.5.1
748
23.5.2
Parameters
748
Problems
749
Activated
Sludge
749
Bio-Filters
750
Anaerobic
750
Acknowledgments
Appendix
23.A:
23 .A. 1
751
Biofilm Reactor Model
751
751
23.A.1.1 Mathematics
23.A.1.2
752
Model
by "Lumping"
Coefficients
753
754
References
754
Tables
Appendix
International
Appendix B
Approximation
Glossary
Pre-Appendix
A
747
Summary
Physical
757
System of
Constants and
Units
765
Physical Data
773
xxxi
Contents
Appendix
Miscellaneous Relations
Appendix
783
Topics
791
Appendix E
819
Appendix F
833
Appendix G
Dimensionless Numbers
847
Appendix
Dissolved Gases
851
Index
871