4/25/2016

www.unitoperation.com

Thermodynamics III

101. For a multicomponentsinglephase mixture, total enthalpy (H)may be expressed as,

.Is
a partial molar quantity?
(a)It is not a partial molar property.
(b)It is a partial molar enthalpy
(c)It is a partial molar free energy (Gibbs).
(d)It is a partial molar internal energy.

102. At constant temperature and pressure, for a pure substance the ratio of specific Gibbs free energy to the chemical
potential is equal to

(a)Zero.(b)Unity.(c)infinity.(d)< 0

103. Which of the following is Antoine equation?

A,Band C are Antoine constants

104. TheClapeyronequation
can be used for

(a)VLE(vapour liquid equilibrium only)

(b)SLE (Solid-liquid equilibrium only)
(c)SVE (Solid-vapour equilibrium only)
(d)Equilibrium between any two coexisting phases

105.TheClausius-Clapyeronequation
is applicable for
(a)VLE(vapour liquid equilibrium only)
(b)SLE (Solid-liquid equilibrium only)
(c)SVE (Solid-vapour equilibrium only)
(d)Equilibrium between any two coexisting phases

106. The SI unit of fugacity is

(a)kPa(b)kJ/kmol(c) kJ/kmol. K(d) dimensionless

107. Activity coefficient is measure of

(a)Departure of a liquid from the ideal solution behavior.

(b)Departure of gas phase from ideal gas law.
(c)None of the above.

108.Raoultslaw applies to

(a)Any liquid solution.(b)Ideal liquid solutions only.

data:text/htmlcharset=utf8,%3Cp%20class%3D%22MsoNormal%22%20align%3D%22center%22%20style%3D%22margin%3A%200in%200.5in%200.0001

1/7

4/25/2016

www.unitoperation.com

(c)Non-ideal liquid solutions.(d)Ideal gas mixture.

109. Which of the following assumption are inherent inClausiusClapeyronequation?

(a)Specific molar volume of the liquid is very small compared to specific molar volume of the gas and as a result can be
neglected
(b)Saturated vapor obeys ideal gas law.
(c)The molar heat of vaporization is independent of temperature.
(d)All of the above

110. Which of the following plots is expected to be linear?

(a)lnpvapvs. 1/T(b)lnpvapvs. T(c)pvapvs.lnT(d)pvapvs.ln(1/T)

pvapis the vapor pressure of the liquid

111. Antoines equation is generally valid in the pressure.

(a)1 200kPa.(b)1 2MPa.(c)atall pressures

112. As water is heated to steam, the value of specific heat of themixtureis

(a)0(b)1(c)(d)None of these.

113. During a phase change which of the following state variable is continuous and remains unchanged at the transition point.

(a)Specific enthalpy(b)Specificentropy
(c)Specific Gibbs free energy(d)molar volume

114. A phase is defined as

(a)acompletely homogeneous and uniform state of matter

(b)astate of matter, which may not be homogeneous but consists of a single component
(c)amulticomponentstate of matter, which may be wither homogenous or heterogeneous

115. The fugacity of a solid is approximately equal to

(a)1(b)0(c)

116. What is the change fugacity when a saturated liquid on heating is converted to saturated vapor?

(a)0(b)1(c)

117. ThePoyntingcorrection factor is used for calculation of fugacity of a liquid. The factor can be neglected if

(a)System pressure is close to vapor pressure at system temperature.

(b)System pressure is very small compared to the vapor pressure at system temperature.
(c)System pressure is very large compared to vapor pressure at system temperature.
(d)None of above.

118. Which of the following is the correct definition offugacity ?

data:text/htmlcharset=utf8,%3Cp%20class%3D%22MsoNormal%22%20align%3D%22center%22%20style%3D%22margin%3A%200in%200.5in%200.0001

2/7

4/25/2016

www.unitoperation.com

(c)botha and(b)(d)neither a nor b

119. The fugacity as defined in the above question is valid only for

(a)Solid(b)Liquid(c)Gas(d)All states ( solid, liquid and gas )

120.Formixtureof ideal gases , which of the following statements is NOT TRUE ?

(a)partialmolar volume of a species in the mixture is equal to the specific volume at the same temperature and pressure

(b)partialmolar enthalpy of a species in the mixture is equal to the specific enthalpy at the same temperature and pressure

(c)chemicalpotential of a species in the mixture is equal to the molar Gibbs free energy at the same temperature and
pressure

(d)partialmolar entropy of a species in the mixture is equal to the specific entropy at the same temperature and pressure

121.Foran ideal gas

(a)fugacityis equal to pressure

(b)fugacitycoefficient is equal to pressure
(c)fugacityis always equal to 1

122.Fora real gas at very low pressure

(a)fP(b)P(c)f1(d)all of the above

123. In an ideal gas mixture, the fugacity of a component in the mixture is equal to

(a)Mole fraction(b)Totalpressure(c)Partial pressure(d)Chemical potential

124. Inagaseousmixture, the fugacity of any component in the gaseous mixture can be described by Lewis Randall rule,
which is

yi= mol fraction of the species in the mixture

fi= fugacity of the pure species
gi=molar Gibbs free energy of the pure species

125. Fugacity and pressure are numerically equal when a gas

(a)In standard state.(b)At high pressure.(c)At low pressure.(d)An ideal gas.

126. The GibbsDuhemequation is applicable for

(a)molarGibbs free energy ONLY
(b)molarGibbs free energy and excess Gibbs free energy ONLY
(c)chemicalpotential, molar Gibbs free energy and excess Gibbs free energy ONLY
(d)anypartial molar property

127(i).Which one of the following is the GibbsDuhemequation?

data:text/htmlcharset=utf8,%3Cp%20class%3D%22MsoNormal%22%20align%3D%22center%22%20style%3D%22margin%3A%200in%200.5in%200.0001

3/7

4/25/2016

www.unitoperation.com

127(ii).Pick out theWRONGGibbsDuhemequation?

arethe partial molar internal energy, enthalpy, entropy and chemical potential respectively

127(iii).Pick out theWRONGequality?

arethe partial molar volume, enthalpy, entropy andgibbsfree energy respectively

128. What is the change in fugacity when a saturated liquid on heating is converted to saturatedvapour?
(a)unity(b)infinity(c)0

129. The partial molar volume of a species in a liquid mixture becomes nearly equal to its pure component molar
volume when the mole fraction of the species (xi) in the mixture

130. For a cyclic process which of the following statement is true?

(a)Only mechanical energy can be completely converted to thermal energy

(b)Only thermal energy can be converted completelytomechanical energy
(c)Both (a) & (b) are true
(d)Both (a) & (b) are false.

131. Match the usefulness of the following diagrams fortheproblemsgiven below.

(i)Turbine / Compressor problem

(ii) Refrigerator problem
(iii) Engines and Cycles

(a)h-s(b)h-P(c)T-s

132. Match the following schematic representations

data:text/htmlcharset=utf8,%3Cp%20class%3D%22MsoNormal%22%20align%3D%22center%22%20style%3D%22margin%3A%200in%200.5in%200.0001

4/7

4/25/2016

www.unitoperation.com

(i) Refrigeration cycle

(ii) Heat engine
(iii) Heat pump
(iv) Thermodynamicallynot possible

133. For a heat pump the coefficient of performance is defined as

134. An engine receives heat at 700F and rejects it to an environment at 180F. What is the maximum thermo dynamic
efficiency?

(a)100%(b)44%
(c)67%(d)Dependson construction of engine.

135. The inside of a home is to be maintained at 22C with a heatpump ,while the outside temperature in the winter 2C.
Calculate the amount the energy requires for the heat pump?

(a)4.18 X 109kJ(b)1.20 X 103kJ

(c)6.78 X 104kJ(d)Need additional data

136. Two refrigerators operate in reverseRankinecycle rejecting the same amount if heat to a high temperature
reservoir.The heat is pumped in both casestolargereservoir maintained at 300 K.First refrigerator (I) pumps heat
from a heat source at 250 K while the second refrigerator (II) pumps heat from another heat source at 275 K.The ratio
of energy supplied to the two refrigerators (WI/WII)is

(a) 1.0(b) 2.0(c) 0.5(d) 0.91

137. When two ideal gases are mixed the change in molar enthalpy is equal to

(a)Zero.(b)Unity.(c)0.5.
(d)Zero or non-zero depending on the property change being considered.

138. Pure component molar volume is equal to partial molar volume in a binary mixture

(a)Always false.(b)Always true.(c)True only for a mixture of ideal gases.

139.Which one of the following is the correct definition of activity coefficient of a species in a liquidmixture

data:text/htmlcharset=utf8,%3Cp%20class%3D%22MsoNormal%22%20align%3D%22center%22%20style%3D%22margin%3A%200in%200.5in%200.0001

5/7

4/25/2016

www.unitoperation.com

(d) all of the above

140. Which of the following statements is true forMargulesone-constant model for estimation of activity coefficients of
species in a binary liquid mixture?

(a)i1.0 when xi1.0

(b)
when xi1.0
(c)1and2as functions of composition are mirror images of each other.
(d)all of the above

141.The activity coefficient of benzene in abenzenetoluenemixture can be assumed to be equal to

(a)vapourpressure of benzene
(b)criticaltemperature of benzene
(c)molefraction of benzene in the mixture
(d)unity

142. The partial pressure( p1) of a species in a gas mixture is defined as the mole fraction of the species (y1) and the
total pressure of the system (p1=yiP).This definition is valid for

(a)Ideal gas mixture only

(b)Non-ideal gas mixture only
(c)Both ideal and non-ideal gas mixtures.

143. For an ideal solution which of the following equationsisNOTTRUE

(a)partialmolar enthalpy of a species is equal to its pure molar enthalpy

(b)partialmolar entropy of a species is equal to its pure molar entropy
(c)chemicalpotential of a species is equals pure molar Gibbs free energy
(d)noneof the above

144. A mixture of two ideal gases forms an ideal solution

(a)Always true.(b)Always false.

(c)May be true orfalsedependingon the mixing conditions.

145.A mixture of ideal gases is an ideal solution

(a)Never.
(b)Only at low pressure.
(c)Only at low pressure and temperature well above critical point.
(d)Always.

146. The reference state for molecular oxygen where the values of enthalpy and specific Gibbs free energy are set equal to
zero is

(a)25C and 1.013 bar(b)0C and 1.013 bar(c) 373 K and 101kPa

147. For the reaction H2+ O2= H2O, what is the value of thestochiometriccoefficient O2?

(a)(b)(c)1(d)2

data:text/htmlcharset=utf8,%3Cp%20class%3D%22MsoNormal%22%20align%3D%22center%22%20style%3D%22margin%3A%200in%200.5in%200.0001

6/7

4/25/2016

www.unitoperation.com

148. For the reaction N2+ O2= 2 NO when the molar extent of reaction for N2= 0.5, what is the value of molar extent of
reaction for H2?

(a)0.5(b)1.0(c)0.25

149. At a particular instant, the molar extent of reaction () calculated on the basis of moles of H2is 0.3. What would be
the value of if calculated on the basis of moles of N2?

(a)0.1(b)0.3(c)0.9(d)1.0

150. The molar extent of reaction is

(a)Always greater than unity.(b)Always less than unity.

(c)Can be greater than, equal to, or less than unity.dependingon the reactionstochiometry

data:text/htmlcharset=utf8,%3Cp%20class%3D%22MsoNormal%22%20align%3D%22center%22%20style%3D%22margin%3A%200in%200.5in%200.0001

7/7