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p1 p0
.
Ra
Applying a similar argument to that in Section 2.5 gives the required stability
result.
2.6. 9.76 K km1 , 9.61 K km1 .
2.7. 9.62 min.
2.8. Taking logarithms of the expression for in solution 2.5, differentiating,
and multiplying by g gives
g d
1 dp
g d
=
g(1 )
.
dz
dz
p dz
The first term on the right is N 2 . Using the hydrostatic equation (2.12),
the ideal gas law (2.2) and the facts that 1 = 1 (Ra /cp ) = cv /cp
we then get the result. If the density decreases so slowly with height that
(g/)d/dz < g 2 /c2s we have N 2 < 0, implying static stability.
1
Chapter 3
3.1. (ii) 5800 K, 290 K. (iii) B = 2.25 108 W m2 steradian1 Hz1 , B =
2.7 1013 W m2 steradian1 m1 , 8.6%.
3.2. (i) Both surfaces are black bodies; the temperature of S2 is sufficiently
different from T1 that it has negligible emission in the passband ; there is
no absorption or scattering between the surface elements.
(ii) Fs = 1381 W m2 . (iii) T14 a2 (independently of h). (iv) The power
absorbed by the sphere is 2T14 a2 .
3.3. The factor (1 A)(rs /d)2 = 1.5 105 , so the maximum solar spectral
irradiance 3 108 W m3 and the maximum terrestrial spectral irradiance
3 106 W m3 . The irradiance curves are much closer than the radiance
curves of Figure 3.1, especially around 4 m: see Figure 1 for an accurate
plot. The irradiance is a more practical measure of the relative importance
of the solar and terrestrial radiation in a given spectral range than is the
radiance.
3.4. (i) 235 K, (ii) Fs /, (iii) white sphere: 227 K, black sphere: 333 K.
3.5. Strong-line limit: the integrand in equation (3.60), with q = 10, is given
by the solid curve in Figure 2; the dotted curve plots 1 exp(q/x2 ), and
is almost indistinguishable from the solid curve. In the weak-line limit, the
exponent is small for all x, so the exponential can be Taylor-expanded to
2
288 K
6
4
2
0
0.1
1
4 10
Wavelength / m
100
Integrand
1.0
0.8
q = 10
0.6
0.4
0.2
0.0
-20
-10
0
x
10
20
3.7. For weak-line limit r 1 note that 1 exp(rex ) rex for all x.
3.8. Pressure 4 hPa.
3.9. Last part: p = p(z)/2.
3.10. (ii) pm = 1 hPa, h(pm ) = 21 K day1 , (iii) 280 K.
3.11. The reflection and transmission coefficients are given below.
1
10
20
30
R
T
0.4987 0.4983
0.6635 0.3305
0.7449 0.2462
0.9255
1RT
0.002 994
0.005 970
0.008 920
Chapter 4
4.1. The mean separation is (n/V )1/3 3 nm. Taking 0.3 nm, the
mean free path 200 nm. The mean free path T /p, where T is fairly
constant, but p decreases exponentially with altitude; it is of the order of
several metres at p = 104 hPa, i.e., over 100 km altitude.
4.2. First part uses (u) u + u. Physical interpretation: mass
m = V is constant following blob, so
D(V )
D m
m D
m
=
= 2
=
u = V ( u) ,
Dt
Dt
Dt
where the third equality uses the Lagrangian form of the mass conservation
law. Hence
1 D
(V ) = u ,
V Dt
as required.
4.3. See Figure 3 for trajectories. In F 0 the circle has radius 0.6R and is
Figure 3: Motion of particle in inertial and rotating frame for Problem 4.3.
Rotating frame F
2
1
y /R
y/R
Inertial frame F
2
0
-1
-2
-2
0
-1
-1
0
x/R
-2
-2
-1
0
x /R
winds blow anticlockwise, as shown by the arrows. The fronts are at the kinks
in the isobars, with the warm and cold fronts as shown. To make the connection with Problem 4.8 and Figure 4.17, imagine that in the warm front
the y-axis is along the front at the surface, towards the low-pressure centre,
and the x-axis points roughly towards the north-east. The x-component of
5
Chapter 5
5.1. The expression for u follows from simple geometry. Then = vx uy =
(V x/r)x + (V y/r)y = x(V /r)x + y(V /r)y + (2V /r) and use of f (r)/x =
f 0 (r)(r/x) = xf 0 (r)/r and a similar expression for the y-derivative gives
the result.
5.2. (a) 10 km, (b) 100 km.
5.3. Period ' 120 min, time taken ' 480 min, X ' 2.3 km, Z ' 115 m.
5.4. Minimum
p angular frequency = f0 . Horizontal wavelength = 2/k =
2NB /(|m| 2 f02 ), larger than 2NB /(|m|) for internal gravity waves.
5.5. P /K = ( 2 f02 )/( 2 + f02 ).
5.6. 2.6 days.
5.7. (a) 13 000 km, (b) 23 000 km. Length of latitude circle at 60 N =
20 000 km.
5.8. Cross-isobar flow is towards low pressure, in general. With h = 1 km,
5 m2 s1 . w 3 mm s1 . The direction of stress is 45 anticlockwise
from up , magnitude 0.07 N m2 .
5.9. 2.7 m s1 .
5.10. Angle = 7.4 104 radians.
5.11. 1.11 days, 3500 km, 2300 km.
Chapter 6
6.1. For one mole, reaction requires NA h 500 kJ, so 1.26 1015 Hz
and wavelength = c/ 238 nm.
6
6.2. The change of Gibbs free energy is + 72.1 kJ mol1 , so reaction cannot
take place spontaneously.
6.3. Equation (6.7) gives [A] = [B] 0 , where 0 = [B]0 [A]0 . Then
substituting for [B], we get
Z
Z
d[A]
= kAB dt .
[A] ([A] + 0 )
Using partial fractions, integrating, and using initial conditions gives
[A]
[A]0
[A]
=
=
exp (0 kAB t) z , say ,
[B]
[A] + [B]0 [A]0
[B]0
and so
z
([B]0 [A]0 ) .
1z
But z 1 since [B]0 [A]0 , and [B] [B]0 , so equation (6.8) follows.
[A] =
6.4. Ps = 6.1 1021 photons m2 s1 . (i) 0.56, (ii) 4 103 , (iii) 1.7 103 .
6.5. From Figure 1.3, take T = 220 K and p = 30 hPa. From Table 2.1
[O3 ] = 0.21[M], where [M] is the number density of the air, equal to p/(kB T )
by equation (2.6). Putting numbers into equation (6.16) gives [O3 ] 2
1019 m3 , significantly greater than the maximum in Figure 1.4. Catalytic
cycles and transport may reduce this in the real atmosphere.
6.6. The Chapman scheme is modified by including a term k4 [X][O3 ] on
the right of equation (6.12a) and a term k5 [XO][O] on the right of (6.12b).
Reactions (6.17) give two further equations,
[X]
[XO]
= k4 [X][O3 ] + k5 [XO][O] =
.
t
t
In equilibrium, set all time derivatives to zero. Equation (6.15) is found to
hold (approximately) as before, but elimination of [O] now gives a quadratic
equation for the ratio [O3 ]/[O2 ]. The required approximate solution holds
provided that k4 is small enough. The catalytic reactions decrease this ratio
compared with the Chapman scheme.
6.7. O decays rapidly (on a time scale of a few seconds) after sunset, the
amount of O3 stays close to its sunset value. X decays, XO tends to a constant
amount.
6.8. Consider a fixed box of volume V . The net rate of inflow of molecules A
is ([A]u)V , and this must equal the rate of increase of these molecules
in the box, ([A]V )/t. Cancel the (fixed) volume V .
7
Chapter 7
7.1. Let R = a + d and let 2L be longest limb path for shaded region in
Figure 5. By Pythagoras we have L2 = R2 a2 2ad, since d a. Ratio
Figure 5: Figure for Problem 7.1.
where the subscript has been dropped for clarity and is used as the
dummy variable instead of 0 . Also
Z
T (z, ) = exp
k(z 0 )a (z 0 ) dz 0 = e(z)()
z
2c k
giving required result.
7.9. The electric field vectors of the incoming, reflected and transmitted
waves are all in the same (horizontal) direction. Normalise with respect to
the incoming wave, so that the three waves are given by
Ei = ei(tm1 z) ,
Er = Aei(t+m1 z) ,
Et = ei(tm2 z) ,
(real parts understood), where = cm1 /N1 = cm2 /N2 and c is the speed
of light in a vacuum. Then the boundary conditions at the interface (E and
E/z both continuous at z = 0, where E is the total electric field) give
1+A=B
and m1 (1 A) = m2 B .
7.10. Integrating the hydrostatic equation (2.12) w.r.t. z and using the ideal
gas law (2.2), we get
Z zm
g
(z 0 ) dz 0 = p(z) p(zm ) = Ra [(z)T (z) (zm )T (zm )] ,
z
and this can be rearranged to give the required solution. (zm )T (zm ) is
proportional to p(zm ) and so 0 as zm .
Chapter 8
8.1. GHE = (F0 Tt4 ) (T 1 1). Values of Tg and GHE are:
Tt = 245 K:
T
0.1
0.2
0.3
Tg /K
315
287
275
GHE/W m
321
143
83
Tt = 225 K:
T
0.1
0.2
0.3
Tg /K
373
323
300
GHE/W m2
852
379
221
Comment: for each T , both Tg and GHE are larger for the lower value of Tt .
8.2. Optical depths of the two gases add ( = 1 +2 ) so total transmittance
T = exp() = exp(1 )exp(2 ) = T1 T2 and total GHE (T1 T2 )1
1. This exactly equals (T11 1) + (T21 1) only when T1 = T2 = 1. Putting
Ai = 1 Ti , where the As are both small, we get equality to first order in
the As.
8.3. Substituting in equation (8.11) we get
F1 et/ et/t0
0
T =
.
1
C
t1
0
Given /t0 = 20, this is maximum when t/ = ln(20)/19 = 0.16. Maximum value of T 0 /F1 = 0.043. Figure 8.2(c) plots 20T 0 /F1 . Maximum
temperature response = 0.9 K.
8.4. Put T 0 = Im (Aeit ), where the complex number A = aei and sin t =
Im (eit ), to get
a = |A| =
F2 /
F2
=
,
2 + 2 C 2
1 + 2 2
10
= tan1 ( ) .
where x =
t1
.
(1)
g(x) is plotted in Figure 6: it implies that Teqm is just a little larger than
Figure 6: The function g(x) defined in equation (1).
5
g(x)
4
3
2
1
0
5
10
x = t1 /
15
20
significant underestimate of Teqm (cf. the dotted and dashed curves in Figure
8.3(b)).
Times in years to reach 90% and 99% of the equilibrium temperature:
90% 99%
10 74
97
30 109 178
70 199 360
8.7. (a) Albedo A varies from high values at low temperatures (ice-covered,
snowball Earth) and low values at higher temperatures (ice-free Earth).
(b) Using (Fs /4)(1 A) = 0.6 T 4 (where Fs is the TSI) at the cold end
(A = 0.6) gives T1 = 252 K and at the warm end (A = 0.3) gives T3 = 290 K.
An accurate plot is given in Figure 7. A rough sketch is sufficient, and makes
Figure 7: Plot of F and F for Problem 8.6.
300
F / W m-2
250
200
150
100
240 250 260 270 280 290 300
T/K
dQ
Fs dA
=
+ 2.4 T 3 ;
dT
4 dT
this is clearly > 0 at T1 and T3 , where dA/dT = 0, implying stability. The
slopes of the curves in the sketch show that dF /dT > dF /dT at T2 , so
=
12
13