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BACHELOR OF TECHNOLOGY
In
Submitted by
THIRUVANANTHAPURAM- 695018.
SEPTEMBER 2015
CERTIFICATE
Certified that seminar work entitled MAGNETIC MATERIALS AND ITS
APPLICATIONS IN AUTOMOBILE COMPONENTS is a bonafide work carried
out in the seventh semester by AKHIL CHANDRAN (12402004) in partial fulfillment
for the award of Bachelor of Technology in MECHANICAL (AUTOMOBILE)
ENGINEERING from University of Kerala during the academic year 2015-16 who
carried out the seminar work under the guidance and no part of this work has been
submitted earlier for the award of any degree.
SEMINAR CO-ORDINATOR
SEMINAR GUIDE
E.JAYAKUMAR
GIJOY.S
Assistant professor
Department of Mechanical Engg.
Assistant professor
Department of Mechanical Engg.
Dr. S. H. ANILKUMAR
Professor,
Department of Mechanical Engg.
SCT College of Engineering.
Thiruvananthapuram-18
ACKNOWLEDGEMENT
I would also like to extend my gratefulness to all the staff members in the Department. I
also thank my team members, friends and well-wishers who greatly helped me in my
endeavor.
AKHIL CHANDRAN
~ iii ~
ABSTRACT
The discovery of magnets had revolutionized various industries like electrical, robotics,
aeronautics etc. In our day- to -day life, we are dealing with a lot components which are
made by magnets. From the discovery of magnetite, the first magnet discovered from
Turkey, magnets had influenced our life a lot.
Magnets have a wide range of applications from a small headphones to large machines.
Magnets has a great role in the development of the electronic industry. We can't find a
machine without magnets. That's why it is said that the discovery of magnets changed the
face of the world!
~ iv ~
TABLE OF CONTENTS
ACKNOWLEDGEMENT
iii
ABSTRACT
iv
NOMENCLATURE
vii
LIST OF FIGURES
viii
TITLE
PAGE NO:
1. INTRODUCTION
1
2
2.5 Ferromagnetic
2.6 Diamagnetic
2.7 Paramagnetic
~v~
4. AUTOMOTIVE APPLICATIONS
10
4.3 Actuators
11
4.4 Instrumentation
12
4.5 Loudspeakers
13
14
15
16
17
5.4 Al-Ni-Co
20
22
7. REFERENCES
23
8. ANNEXURE
24-33
~ vi ~
NOMENCLATURE
SYMBOLS
MEANING
TC
Curie temperature
Intensity of Magnetization
Magnetic Permeability
Magnetic Susceptibility
Volume
kJ
Kilo Joule
Celsius
Oe
Oersted
Area
Dipole Moment
Pole Strength
Henry
Newton
Megagauss-Oerstd
MGOe
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LIST OF FIGURES
PAGE NO.
1 : Power Steering Motor
11
11
12
4 : ABS
12
12
12
14
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Chapter 1
INTRODUCTION
Magnetic materials encompass a wide variety of materials, which are used in a diverse
range of applications. Magnetic materials are utilized in the creation and distribution of
electricity, and in most cases, in the appliances that uses that electricity. They are used for
the storage of data on audiotape and videotape and on computer disks. In the world of
medicine they are used in body scanners and in a wide range of applications where they
are attached to or implanted into the body. In home entertainment market relies on
magnetic materials such as PCs, CD players, Games consoles and Loudspeakers.
It is very difficult to imagine a world without magnetic materials and they are becoming
more important in the development of the modern society. The need of efficient
generation and use of use of electricity is dependent on improved magnetic materials and
designs. Non polluting electric vehicles will relay on efficient motors utilizing advanced
magnetic materials. The telecommunication industry is always striving for faster data
transmission and miniaturization of devices, both of which requires development of
improved magnetic materials.
~1~
Chapter 2
CLASSIFICATION OF MAGNETIC MATERIALS
Magnetic materials are classified on the basis of certain parameters. The parameters are
1. Permeability
2. Susceptibility
3. Intensity of magnetization
4. Curie Temperature
permeability
is
measured
in henries per
meter
(Hm1),
or Newton's per ampere squared (NA2). The permeability constant (0), also known as
the magnetic constant or the permeability of free space, is a measure of the amount of
resistance encountered when forming a magnetic field in a classical vacuum. The
magnetic
constant
has
the
exact
value 0 =
4 107 Hm1
~2~
~3~
~4~
repelled
by
magnetic
fields.
In
1845, Michael
Faraday demonstrated that it was a property of matter and concluded that every material
responded to an applied magnetic field. He adopted the term diamagnetism after it was
suggested to him by William Whewell.
Paramagnetic
materials
include
most chemical
elements and
some
compounds; they have a relative magnetic permeability greater than or equal to 1 (i.e., a
positive magnetic susceptibility) and hence are attracted to magnetic fields. The magnetic
moment induced by the applied field is linear in the field strength and rather weak. It
typically requires a sensitive analytical balance to detect the effect and modern
measurements
on
paramagnetic
materials
are
often
conducted
with
a SQUID magnetometer.
Paramagnetic materials have a small, positive susceptibility to magnetic fields. These
materials are slightly attracted by a magnetic field and the material does not retain the
magnetic properties when the external field is removed. Paramagnetic properties are due
to the presence of some unpaired electrons, and from the realignment of the electron
paths caused by the external magnetic field. Paramagnetic materials include magnesium,
molybdenum, lithium, and tantalum.
~5~
~6~
Chapter 3
APPLICATION OF MAGNETIC MATERIALS
~7~
Servomechanisms
The attraction from a fixed strength magnet decreases with increased distance, and
increases at closer distances. This is unstable. For a stable system, the opposite is needed,
variations from a stable position should push it back to the target position.
Stable magnetic levitation can be achieved by measuring the position and speed of the
object being levitated, and using a feedback loop, which continuously adjusts one or
more electromagnets to correct the object's motion, thus forming a servomechanism.
Many systems use magnetic attraction pulling upwards against gravity for these kinds of
systems as this gives some inherent lateral stability, but some use a combination of
magnetic attraction and magnetic repulsion to push upwards.
Either system represents examples of Electromagnetic Suspension (EMS). For a very
simple example, some tabletop levitation demonstrations use this principle, and the object
cuts a beam of light to measure the position of the object. Such a simple system is not
very robust; far more effective control systems exist, but this illustrates the basic idea.
EMS magnetic levitation trains are based on this kind of levitation: The train wraps
around the track, and is pulled upwards from below. The servo controls keep it safely at a
constant distance from the track.
~8~
Chapter 4
AUTOMOTIVE APPLICATIONS
~9~
~ 10 ~
fig 3: OEM VW Headlight Horizontal Position Sensor For VW Passat B5, Golf MK4
fig 4: ABS
4.3 Actuators
1. Anti skid systems
2. Suspension (both active and self leveling)
3. Throttle
4.Airbag.
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4.4 Instrumentation
Dashboard instruments - including speed, engine speed, temperature, oil pressure etc.
~ 12 ~
~ 13 ~
Chapter 5
MAGNETIC MATERIALS USED FOR AUTOMOBILE
APPLICATIONS
The two materials historically used in Automotive applications are Al-Ni-Co & Sintered
Ferrite. Al-Ni-Co was traditionally used in sensing and instrument applications, but
escalating costs of Cobalt mean that other materials are commonly used today.
Sintered ferrites arcs are used in DC motors and are therefore probably the commonest
material currently in use in Automotive applications. Specific motor grades are available
which are able to offer high resistance to highly demagnetizing forces at start up, thus
retaining maximum magnetic strength.
Higher strength materials such as Samarium Cobalt alloys have been available for many
years, but their high price has precluded their use in all the most extreme applications.
The major development in the past few years has been the availability of cheaper
Neodymium Iron Boron magnetic materials both sintered and bonded types. Although in
the last few years of a patent license, NdFeB can offer competitive pricing. NdFeB can
offer up to ten times the magnetic performance of sintered ferrite, therefore allowing
miniaturization of components with higher efficiencies.
The two drawbacks of NdFeB of temperature stability and corrosion have now been
successfully dealt with. The alloying of trace quantities of additional metals to the NdFeB
mix has allowed the production of materials able to handle 200 deg. Celsius and at the
same time offering increased resistance to corrosion. Plating or coating after production
offers maximum corrosion resistance in the most extreme applications.
Over the past years there has been much development in injection or compression molded
magnetic materials offering easy manufacturing of complex shaped and magnetic pole
configurations to net shape, without additional machining. In the past injected ferrite was
successfully developed and today is in common usage.
~ 14 ~
Today bonded and injected NdFeB grades are available with high resistance to
demagnetization forces, allowing the material to easily replace Sintered Ferrite Arc
segments in motors. This is probably the largest application sector in the Automotive
market, and bonded NdFeB could offer both significant weight, coupled to higher
performance.
~ 15 ~
Samarium
Cobalt
rare-earth
(SmCo)
magnets
are
1:5 Grade
These samariumcobalt magnet alloys (generally written as SmCo5, or SmCo Series 1:5)
have one atom of rare earth samarium and five atoms of cobalt. By weight this magnet
alloy will typically contain 36% samarium with the balance cobalt. The energy products
of these samariumcobalt alloys range from 16 MGOe to 25 MGOe, what is approx. 128
kJ/m3 - 200 kJ/m3. These samariumcobalt magnets generally have a reversible
temperature coefficient of -0.05%/C. Saturation magnetization can be achieved with a
~ 16 ~
2:17 Grade
These alloys (written as Sm2Co17, or SmCo Series 2:17) are age-hardened with a
composition of two atoms of rare-earth samarium and 1317 atoms of transition metals
(TM). The TM content is rich in cobalt, but contains other elements such as iron and
copper. Other elements like zirconium, hafnium, and such may be added in small
quantities to achieve better heat treatment response. By weight, the alloy will generally
contain 25% of samarium. The maximum energy products of these alloys range from 20
to 32 MGOe, what is about 160-260 kJ/m3. These alloys have the best reversible
temperature coefficient of all rare-earth alloys, typically being -0.03%/C. The "second
generation" materials can also be used at higher temperatures.
~ 17 ~
Up to +150 degrees C, the Neodymium Iron Boron magnets are the strongest performers.
Between +130 degrees C and +160 degrees C, there is an overlap in performance
between NdFeB and SmCo. Above +150 degrees C SmCo provides the greater
performance. The "Neo" magnets are a first choice for many applications as they offer the
greatest performance with the smallest volume.
Neodymium Iron Boron, NdFeB, magnets exist in a variety of grades. These grades not
only vary in magnetic output performance but they also vary with temperature rating. The
maximum recommended temperature of operation for the Neo magnets is +200 to +230
degrees Celsius although the exact limit is actually dependent on the magnet shape and
the total magnetic circuit (so the recommended limits are really only crude guideline
values).
All the Neodymium Iron Boron, NdFeB, magnets are prone to corrosion (a method
similar to rusting). All Neodymium Iron Boron, NdFeB, magnets will require a form of
protective coating. The standard coating is a triple layer plating of Nickel-Copper-Nickel
(Ni-Cu-Ni). Unless requested otherwise, this Ni-Cu-Ni coating is always applied to the
magnets. It should be noted that the level of protection given by any coating depends on
the environment the magnet will be subjected to and how the coating is looked after.
The magnetic output from the "Neo" magnet varies with temperature. The output falls
with increasing temperature but usually returns as it cools (the degree of fall with rising
temperature is dependent on the reversible temperature coefficients). It is possible to
permanently reduce the magnetic output through too high a temperature (a permanent
demagnetization).
The level of permanent demagnetization depends on the magnet shape, the total magnetic
circuit and the actual shape of the BH curve (which will vary depending on the grade of
"Neo" chosen). Neodymium Iron Boron, NdFeB, magnets are also affected by external
demagnetization fields and by radiation, both of which can demagnetize the magnet, the
latter permanently demagnetizing.
The use of NdFeB magnets can allow very compact designs with high performance with
issues affecting the performance. If the magnet is kept in dry conditions at all times and
~ 18 ~
the plating is not broken and no external demagnetizing fields are applied to it, the
magnet theoretically can retain its magnetism indefinitely
Properties
Grades available - from about 3330 to 5311. (First 2 digits represent BH max, and
second two digits represent Intrinsic Coercivity, )
Sizes - off tool the largest die pressed blocks are about 4" cube, while isostatically
pressed blocks can be much longer in the orientation direction (up to 9 feet).
Advantages
Relatively low cost (by weight about 20 times Ferrite magnets, by "Dollars per
BHmax" about 1.5 times Ferrite magnets).
~ 19 ~
Disadvantages
NdFeB powder is very fine and when dry can ignite spontaneously - care must be
taken in handling NdFeB powder.
NdFeB magnets are very powerful - care must be taken in handling these magnets
to avoid injuries.
5.4 Al-Ni-Co
Alnico is an alloy containing Aluminium (Al), Nickel (Ni), Cobalt (Co) hence its name
Alnico. But Alnico actually contains more than just these three elements. It also contains
Iron and Copper with some versions also containing Titanium and even Niobium (the
Titanium versions were sometimes called Ticonal, derived from the elements TiCoNiAl).
Alnico magnets were developed in the 1930s and were the first Real performance
permanent magnets (the first magnets, called magnetic steels, were quickly replaced by
the vastly superior Alnico).
Alnico is produced by either a sintering method or, more commonly, a casting method.
The as cast or as sintered shape is acceptable for many applications but surfaces may
need to be ground for a smoother surface finish. The as cast look has darkened edges with
a slightly rough texture (due to the sand mold edges); a machined face of an Alnico
magnet has a bright silvery metallic surface and is usually extremely smooth as it is often
precision ground.
There are 29 grades of Alnico (17 cast grades, 10 sintered grades, 2 bonded grades).
Alnico has many trade names used for naming the grades such as Columax, Alcomax
3SC, Alni, Hycomax, Ticonal, etc. China has given them names starting with the letters
~ 20 ~
LNG followed by a number to try to give some clarity but this is not widely utilised.
Most people still know Alnico under its more common grade names such as Alnico 5,
Alnico 8, Alnico 9, Alnico 5DG, Alnico5-7, Alnico8HC, Alnico 6, Alnico 2, Alnico3,
Alnico 500, Alnico 400, Alnico 600 and Alnico 700, etc.
Most Alnico magnet grades are anisotropic (they can only be magnetized in a single axis
/ direction they are the more powerful magnet grades of Alnico. The others are isotropic
(they can be magnetized in any direction or directions) they are weaker but offer more
design and performance flexibility. The most commonly used Alnico is Alnico 5.
The complete range of grades is as follows:Alnico 5 (Alnico5_ACA34), Alnico 5 (Alnico5_ACA37), Alnico 5 (Alnico5_ACA40),
Alnico 5 (Alnico5_ACA44), Alnico 5 (Alnico5_ASA34),
Alnico 6 (Alnico6_ACA28), Alnico 6 (Alnico6_ASA28),
Alnico 5DG (Alnico5DG_ACA52),
Alnico 5-7 (Alnico5-7_ACA60),
Alnico 8 (Alnico8_ACA38), Alnico 8 (Alnico8_ACA40), Alnico 8 (Alnico8_ACA44),
Alnico 8 (Alnico8_ASA38), Alnico 8 (Alnico8_ASA44), Alnico 8 (Alnico8_ASA48),
Alnico 8 (Alnico8_ICA18), Alnico 8 (Alnico8_ISA18), Alnico 8 (Alnico8_ISA20),
Alnico 8HC (Alnico8HC_ACA36),
Alnico 9 (Alnico9_ACAT60),
(Alnico9_ACAT80),
Alnico
(Alnico9_ACAT72),
~ 21 ~
Alnico
CHAPTER 6
CONCLUSION AND FUTURE PERSPECTIVE
The magnetic material industry will continue to develop new grades to specifically suit
the Automotive industry. This will allow the industry to meet the increasing pressure
from manufacturers to design more efficient, lower weight high performance
components.
The biggest impact for many years on the use of magnetic materials in
Automotive components is the change of voltage from 12 V to 42 V. The change would
allow the use of combined starter-generators, saving the weight of one of the bulkiest
components and providing a much more efficient starting system. The increased voltage
will allow full electric steering to replace the current heavy hydraulic system of assisted
rams and engine driven hydraulic pumps.
The 42 V system also offers great advantages in networking the controls of the
cars and the extra performance will allow further multiple engine measurements to be
carried out to improve combustion, improve fuel efficiency, and reduce emissions. This
will mean totally new types of sensors probably utilizing the latest magnetic materials
such as multi pole bonded or injection molded Ferrite or NdFeB.
Another exciting new Automotive application is the influence of a magnetic field in the
combustion chamber of petrol engines. The magnetic aligning of the fuel charge
molecules in the combustion chamber has been known to produce positive effects for
many years. Some of the largest companies in the industry have researched this
phenomenon over many years, but it is only with the emergence of low cost sintered
ferrite NdFeB that the magnetic field can be produced effectively.
In short the future for magnetic materials for Automotive applications shows great
potential, with considerable growth forecast. The magnetic material industry has to keep
up with the Automotive industry's considerable technical demands for the future with
both new material and applications. Component manufactures should take care when
selecting magnetic material suppliers and chose partners that can not only offer good
quality at competitive pricing, but also offer strong technical and application backup.
~ 22 ~
REFERENCES
1., WANG CHENG, XU SHANZHEN, WU YONGHAI, "Thermal Analysis and Test
Research of the Magnetic Powder Clutch for Vehicles", Faculty of Transportation
Engineering, Huaiyin Institute of Technology, CHINA, 2014.
2., XU SHANZHEN, WANG CHENG, "Study on Clutch Control Technology and Shift
Control Strategy for Automated Mechanical Transmission with Magnetic Powder Clutch"
Faculty of Transportation Engineering, Huaiyin Institute of Technology, CHINA, 2014.
3.Automotive Applications for Magnetic Materials (www.mmgca.com/techalert/MMGauto-apps.pdf ).
4.Soft magnetic materials http://elektroarsenal.net
5. Magnetic particle clutch, Wikipedia.
6.Sensor Application for Magnetic Materials, by Ed Ramsden.
(http://www.sensorsmag.com/sensors/electric-magnetic/sensor-applications-magneticmaterials-899)
7.Introduction to Alnico magnets from www.alnicomagnets.com.
8.Introduction to Neodymium Magnets, www.Nd-Fe-Binfo.com.
~ 23 ~
ANNEXURE
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