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Euler-Euler modeling
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Introduction
Over the last years the impact of utilizing fossil fuels
on the environment (e.g. green house effect) and their
limited availability became a more addressed problem in
the scientific community and in ecopolitical discussions.
While it is well known that charcoal was one of the most
popular combustibles since the medieval times, there still
is a lack of fundamental understanding of the complex
phenomena taking place during pyrolysis and gasification of biogenic energy resources such as wood. This
might be connected to the fact that measuring physical
important variables in a reactive solidgas flow is still a
challenge. As an example, even for nonreacting dense
gase solid flow it is still an unsolved problem to simultaneously measure the velocities of the gas phase and
the particulate phase on timescales of the particle collison dynamics. Therefore the ability to simulate reactive
multiphase fluidized beds is an important issue to investigate fundamental physical questions and to increase the
efficiency of biomass conversion as wood and charcoal.
Since fluidized bed reactors has been widely used in industry for conversion of coal there is of course quite some
experience with pyrolysis and gasification in these kind
of reactors.
There are numerous models which intend to simulate
fluidized beds reactors on different scales of accuracy.
The simpler models such as zone/cell models and equilibrium models are suitable for design optimisation of
industrial size gasifiers, the more comprehensive models
such as Euler-Euler [9, 1, 13] are more targeted towards
fundamental investigations of the chemical and fluid mechanical aspects of fluidized beds.
Euler-Euler or continuum models models are comprehensive models suitable for fundamental investigations of
the chemical and fluid mechanical aspects of fluidized
beds. The advantage of applicability to real industrial
systems is partly caused by neglecting information on individual particle level With current and foreseeable computer resources it does not seem feasible to perform other
tions. Different models for pyrolysis and gasification reactions from the literature have been implemented. We
apply the method for the numerical simulation of wood
gasification and compare the results against experimental
data of a laboratory scale bubbling fluidized bed reactor.
Reasonable agreement between the numerical results and
measurements have been found for the exhaust gas compositions and the temperature.
where sm , sm , and v sm are the void fraction, the density, and the velocity of the solid phase m, respectively.
Here, w sml denotes the mass transfer term between solid
phases m and l (e.g. the conversion of fresh wood into
charcoal) and w smg is the mass transfer term between
solid phase m and P
the gas phase component . With (1)
we have w s = m w smg . The momentum balance
for solid phase m can be written as
Mathematical model
Gas Phase. The gas phase in the EulerEuler model is
treated as a continuum, which can be described by the
volume averaged Navier-Stokes equations.
The species mass balance equations in the gas phase
can we written as
where psm and sm are the pressure and the stress tensor of the solid phase m and I mg , I ml denote momentum
exchange terms between solid phase m and the gas phase
and the solid phase l. To close the system of mass and
momentum balance equations we solve an energy equation in temperature form for each solid phase m:
Tsm
+ v sm Tsm =
sm m cpm
t
q sm gm (Tm Tg ) Hsm .
g g Y
+ (g g Yu g ) = g w ,g + g w ,s . (1)
t
where Y denotes the massfraction of species in the
gasphase, w ,g is the net producton rate of species due
to gas phase chemical reactions, and w ,s is the mass exchange term between the solid phase and the gas phase.
Summing up equation 1 gives the global mass balance
for the gaseous phase in conservative form:
XX
g g
+ (g g u g ) =
g w ,s 0,
t
s
(2)
CO
2 CO
2 H2
CH4
+ (g g ug ug ) + g p
+ g ( g ) + g g g = I gs .
(3)
Nm
X
gm (Tsm Tg ) Hg .
(4)
[4]
[5]
[11]
[5]
H2
+ CO2
2 CO2
2 H2 O
CO
+ 2 H2 O
m=1
sm sm
+ (sm smv sm )
t
X
X
= sm
w sml + sm
w smg ,
The kinetic parameters for all reactions are from the cited
literature.
+ H2 O
+ O2
+ O2
+ 1.5 O2
(5)
2
C2 H 6 , C3 H 6 .
(7)
900
inlet
150 mm
325 mm
500 mm
700 mm
900 mm
800
temperature [C]
700
600
500
400
300
200
100
0
20
40
60
80
100
time [min]
120
140
160
180
Figure 3: Experimental data of the exhaust gas composition sampled from 19 different experiments with different
wood charges.
88 min operating time are due to an interrupted fuel supply. Between t=100 min and t=120 min the reactor runs
at almost steady state conditions. We use the data from
this time window to compare with numerical simulations.
After 120 min of operating time several tests were performed leading to the unsteady temperature data seen in
Figure 2.
Heterogeneous reactions. Heterogeneous reactions of solid
Figure 3 shows minimum, mean, and maximal meachar with species in the gas phase are modeled using the
sured exhaust gas concentrations. The concentrations are
following overall reactions:
sampled values of timeaveraged data from 18 different
C + O2
CO2
[15]
experiments with different charges and types of wood.
C + CO2 2 CO
[2], [8]
Usually, the exhaust gas concentrations of CO are higher
C + H2 O CO
+ H2
[7], [8]
then those of CO2 as can be seen from Figure 3. HowC + 2 H2 CH4
[7]
ever, among the 18 different experiments their were also
Rate expressions and kinetic parameters are taken from two case with higher CO2 than CO concentrations. The
the cited literature.
huge variance of wood properties (density, water content,
structure, etc.) leads to big uncertainties in the modeling
Results and Discussion
of wood gasification and should be kept in mind when
Experimental Setup. The experimental data in this study comparing numerical results against experimental data.
were taken from a laboratory scale bubbling fluidized bed
reactor at the Institute of Energy Engineering at Berlin Computational Setup. The reactor shown in Figure 1
University of Technology. Figure 1 shows the reactor and has been discretised in the two-dimensional Euler-Euler
its dimensions. The freeboard area and the bubbling bed model with a grid spacing of 1 cm in radial and axial dizone have inner diameters of 134 mm and 95 mm, respec- rection. Due to the residence time of the wood particles
tively. The reactor is operated at atmospheric pressure. in the fuel supply the temperature of the wood entering
The bed material consists of pure wood and is fed in the the reactor has been assumed to be 150 C. The gas comlower part of the reactor with a feeding rate of 2 kg/h. position entering the reactor through the fuel supply with
Preheated air with a velocity of 0.25 m/s at a tempera- a velocity of 4.5 cm/s has been set to be 100% H2 O at
ture of 400 C enters the reactor from the bottom over the T = 150 C. This massflow corresponds to complete drywhole diameter of the reactor. Six thermocouples inside ing of wood in the fuel supply. Inflow conditions for the
the reactor at heights 5, 150, 325, 500, 700, and 900 mm air are taken from the experiments. Three solid phases
above the air intake are monitoring the temperature inside have been used in the continuum model: spherical wood
3
the reactor. Product gases concentrations at the exit of particles (diameter 3 mm, density 6.5 g/cm , water content
10%,
volume
fraction
0.35,
molar
mass
128 g/mol),
the reactor are analysed with a combination of gas chroand
two
classes
of
spherical
char
particles
(diameter
1
matography and laser mass spectroscopy, see [12] for de3
and
2
mm,
density
0.35
g/cm
,
volume
fraction
0.35,
and
tails.
Figure 2 shows experimental temperature data over molar mass 12 g/mol) with carbon being the only contime at different heights above the inlet in the reactor for stituent. The walls of the reactor are modeled isothermal
a complete experiment. The reactor was started with a with a temperature of Tw = 600 K.
Figure 4 and 5 show the spatially averaged outlet tembed of pure charcoal and a pure heated nitrogen mass
perature
and volume fractions of H2 , CO, CO2 and H2 O
flow below the fluidization velocity to heat up the sysover
time
for the first secondary pyrolysis model. Both
tem. After the heating period of approximately 60 min
temperature
and volume fractions become statistically stathe reactor has been operated with heated air entering the
reactor with a velocity of 0.25 m/s and a temperature of tionary after a few seconds and show therefore that the
400 C. The temperature peaks seen in Figure 2 at about approximated initial conditions of the simulation are close
3
The introduction of an inert tar species is quite questionable since at higher temperature or longer hold-up time
one would expect to crack all the tar which evolves from
the primary pyrolysis but for this work we accepted this
components to be consistent with the used literature.
520
to the steady values. The model seems to have some difficulties to predict the experimental values shown in figure
3. Especially the CO concentration is to low copared to
the experimental data - a problem which is investigated
in recent simulation at the department. The concentration
of the species shown in figure 5 depend on various term.
Using different approaches for the main gasification reaction which result in the formation of water and carbon
monoxide shows mostly higher rates and, as these reaction are endothermic, higher cooling rate too. At the end
the bed would become coulder, less C02 and more CO
would evolve. Examples for different gasification kinetics are given in [8] and [10] where both of them using
kinitics which depend on the grade of conversion. This
problem is currently under investigation.
Figure 6 and 7 show again middled outlet temperature
and volumefractions of H2 , CO, CO2 and H2 O for the
second secondary pyrolysis approach. The result are similar but more Water evolves and even less carbon monoxide. The Temperature of the outlet gas is almost equal for
both models.
To show the strong connection of fluidmechanics and
chemistry we show the snapshots given in figure in 8. The
left picture in figure 8 shows bubbles rising in the bed
while both of the right pictures show a high concentration of CO2 in the bubble but a low concentration of CO.
The CO2 essentially evolves only from the wood and in
the very lowest part directly above the inlet, since only
there is oxygen. The bubble transport the CO2 through
the bed and constricts the CO2 to react with the charcoal
of the fluidized bed. Therefore less carbon monoxide is
in bubble.
Temperature [C]
500
300
350
400
450
200
250
time [s]
300
350
400
450
Temperature [C]
mole fraction []
450
500
mole fraction []
H2
CO
CO2
H2O
0.1
50
100
150
200
250
time [s]
300
350
400
450
500
References
[1] K. Agrawal, P. N. Loezos, M. Syamlal, and S. Sundaresan. The role of meso-scale structures in rapid
gas-solid flows. J. of Fluid Mechanics, 445:151
185, 2001.
0.05
150
400
Acknowledgements We gratefully acknowledge the Deutsche Bundestiftung Umwelt (DBU) for financial support
of this work and York Neubauer for the provision of the
experimental data shown in this article.
H2O
100
350
500
CO
CO2
50
300
Conclusions We have presented an EulerEuler modeling approach of wood gasification in a dense fluidized
bed. We have shown two different models for the secondary pyrolyis in a complex simulation of a polydispers fluidized bed reactor with homogeneous and heterogeneous reaction. The necessary time to simulate the
shown results was in the order of one week on two processor cores of an AMD Opteron running at 2.4 GHz clock
speed. Parallelization is done by are shared memory approach. Results given in this article agree partially well
with shown experimental data. In an upcoming publication we will present results of more pyrolysis and gasification models and a systematic investigation of the influences of grid resolution and boundary conditions.
0.1
0
0
250
H2
0.15
200
0.15
0
0
150
0.05
420
250
time [s]
100
0.2
440
200
50
460
150
time [s]
480
100
440
400
500
50
460
420
520
400
0
480
500
[2] M. J. Biggs and P. K. Agarwal. The CO/CO2 product ratio for a porous char particle within an incipiently fluidized bed: A numerical study. Chemical
Engineering Science, 52(6):941952, 1997.
[3] M. L. Boroson, J. Howard, J. P. Longwell, and W. A.
Peters. Product yields and kinetics from vapor phase
Figure 8: Snapshots of the volumefraction of the gas, volumefraction of CO and CO2 (from left to right)- pyrolysis
model 2, dark stays for higher gas, C02 and CO fractions