Hard alloy IPC classes for russian patent Hard alloy (RU 2537469). ©22€29/10 - based on ‘Mianium carbide Another patents ‘same IPC classes i ‘Cermet b & valve and its fabrication / 2525965 Invention relates to powder metallurgy, particulary, to produc 6 ball valve trom ‘tkanium-carbide-based cermet, Ball valve cermet Structure consists of alternating zones of ontinuous metal matrix ané isolated uniformly distributed car) ane zones with continuous metal matrix and Uniformly distributed carbide grains that make @ continuous carcass Content of metal matrix in ‘makes 25-70 vel 9%. Ball valve mace, moulé with porous carbide semi withdrawn from the furna being maintained above liquidus temperature of impregnating metal. The Tatter is fused In crucible arranged in the sare chamber filed In the mould to contact with Catbide sem and maintained for time Interval required for omplete infiltration of metal melt and directed Expstalisation of metal in Wy es eer fanishing machines 2511226 Invention relates to metallurgy, and namely to production of carbice cast Fron with no pores in alloy volume, and can be used for production of working parts of planishing Involves mixing of powders af titanium carbide and eu) es Best in Class RO+ UV Purfication System, Get a Heme Dem Now! FIELD: metallurgy. SUBSTANCE: hard alloy contains the following, wt %: molybdenum 1,5-2.5, cobalt 1.0-2.0, nickel 4.0- 8.0, chrome 0.5-1.0, titanium nickelide 0.5-1.0, tungsten carbide 25.0-35.0, and titanium’ carbide Is the vest EFFECT: alloy has a binder capable of retaining its properties at operation under conditions of high temperatures; with thet, alloy is characterised by high wear resistance at operation under concitions of high temperatures. 2 tol Beet in Clase RO+ UY Puriction System. Get a Home ‘beme Now a oo The Invention relates to the fleld of powder metallurgy, In particular to solid alloys intended for the manufacture of wear-resistant products ‘The currently used solid alloys consist ofa refractory phase in the form of a metal-like compounds of transition metals with non-metals and metal phase, serving as a bundle As the refractory phase, typically used titanium carbide (see, for example, author's certificate of the USSR. No, 609338, 647348, 1753729 and others) or tungsten carbide (see, for example, allays of group VK ‘according to GOST 3882-90 and others), ang, in the case dvunserijnyj alloys, combinations thereof (see, for example, patent RF NP2307013, U.S. patent No, 5574954, alloys group TC according to GOST 3882- ‘90 and thers) ‘These alloys are characterized by high mechanical and corrosion properties, but have a low resistance when operating in canditions of high (from 600°C to 120°C) temperatures, due to insufficient heat resistance cords, losing at high temperatures, their properties, leading to rapid loss of the alloy grains of the solid phase. The closest to the essential features Is a solid alloy by RF patent No. 2255998 containing 12,0-of 45.0 WE% Nickel; 1,2-5.4 wt.%e aluminum; 0.8 to 3.9 wt.% chromium; of 0.1-0.9 wt.% titanium; 0.4 to 2.4 W% tungsten; 0.5 to 2-4 wt.% molybdenum; 40,0-85,0 wt-% carbide of the transition metal is selected from g is uppy Ti, Cy, 2%, W, Nb. This alloy does not provide the necessary wear resistance when working in high temperatures. Object of the present Invention Is to provide a hard allay having a bunch of, are able to maintain thelr properties when working in high temperatures, to obtain a technical result in the high wear resistance of the alloy in the temperature range from 600°C to 1200°C, without losing its main characteristics. The problem is solved due to the fact that in the known solid alloy containing Nickel, molybdenum, chromium and refractory component in the form of a caroide ofa transition metal selected from the group of T, Cy Zr, W, Nb, entered cobalt, nickelide titanium, with refractory component consists of titanium carbide and tungsten carbide in the following ratio of components (wt.%): molybdenum (1.5 to 2.5), Cobalt (1.0 to 2.0), Nickel (4,0-8,0), chramium (0,5-1,0), nickelide titanium (0,5-1,0), tungsten carbide (25,0-35,0), titanium carbide - rest. In the known solid compositions of the alloys specified set of essential features have been identified that allows us to consider this solution meets the enterion of “novelty” Hard alloys must possess a number of properties: primarily hardness and wear resistance at relatively high strength, heat resistance, scaling resistance, low to the ratio of friction, a small loss of strength at elevated temperatures. The most farnous of hard alloys consist of a solid and a binder phase. In the solid phase, usually present carbides of tungsten or titanium, and a mixture of these carbides. As a binder used Cobalt, Nickel, Nickel-molybdenum allay, ete Structure adnokursnik alloys (for example, WC4Co) cansists of a solid solution material ligament in carbide and excess free grain carbide, representing a skeleton tied grains of carbide in the gaps which isin the form of end-to-end grid) solid solution on the basis of material igaments, filing the spatial skeleton carbide and forming thus two Interlaced frame connecting the carbide grains in a single system. Structure dvuhseriynogo alloy (for example, WC+TIC+Co) is somewhat different and consists of a solidarey cast iron SCh20 in YYolume ratio of 50 1 50, Dressing of the obtained mixture under pressure of 0:5, movement of the pressed part at a melting et bottom ane heating Up fo the temperature of 1250-1350°C in contact with 3 cast iron ingot, whieh is arranged on it Sane has the same grade as the powder, tl it fully molten; exposure at the same temperature with neous saturation with titanium carbide, the particles of which rise to the surface in liquid cast iron as the ingot is being molten, ang quick cooling. Invention relates t ponder metallurgy, articular to production of wear-resistant arcles from titanium carbide~ based composite material I can be used for producing ball gate valves lane plain bearing sleeves. Sintered porous carbide half stuffs produced by vibration compaction of titanium carbide powder ane sintering it in furnace with non-oxidising Stmosphers. sintered half Stuff if subjected to infiltration by metal mets in heating chamber formed by graphite mutes closed by top and Bottom graphite covers Heating ef muffle ana extra heating of impregnating metal is performed by high Frequeney currents in variable electromagnet field of inductor par7s3 Alloy contains, mas.% nickel 5-10; molybdenum 5-10; niobium 5-10; titanium carbide 75-80 Tha method of manufacturing abrasive solution of one of the carbides in the other (for example solid solution of tungsten carbide in the titanium Carbide), solid solution material igament in carbides and excessive grains of carbides. Thus, there are several intertwined with each other skeletal frames, binding free grain carbides in a single system. Dvuhkabinnye alloys comparec to odnokorennye have the best performance wear, but at a sufficiently high temperature is above 900°C) used in these ligaments lose their viscosity, thereby weakening the skeleton, rapid loss of carbide grains and, consequently, a sharp decrease in wear resistance. Hard alloy according to the invention is made using ttanium carbide and tungsten carbide in ratios, providing education of a sufficient number of free grains, and has a multi-component link that allows you to shape the structure of many intertwined skeletal frames, securely locking the grain carbide. In ‘mukicomponent bundle, made on the basis of Nickel, with the oreatest propensity to penetrate between the carbide grains are also molybdenum, Nickel and chromium. Thelr presence allows you to create frames that provide the necessary physico-chemical properties of the alloy (corrosion resistance, strength), raises the temperature of softening of the ligaments than increases wear resistance. Introduction to a bunch of UUtanium nickelide suppresses the precipitation of free carbon and gives the alloy porosity conducive to the creation of complex and extensive framework that, In conjunction with the above, ensures the ‘achievement of the claimed technical result. The claimed set of distinctive features is expressed as a combination of quantitative and qualitative characteristics of the solid ingredients of the alloy, the patent and scientific and technical information is not revealed, that confirms the compliance of the proposed technical solution the eriterion of "inventive step Table 1 shows the formulations of the compositions of the alloy of the prototype, and similar present invention, in the versions; table 2 ~ physical an¢ chemical characteristics of the alloy and performance wear at diferent temperatures, To verify the claimed technical result were prepared with several options alloy with medium end boundary values of the proposed proportions of ingredients (see table 1). ‘The charge for the alloy was received, mixing in the planetary mill the powders of the components mixed In the stated proportions. The resulting mixture was extruded laboratory samples, further sintered by known techniques. Comparative laboratory tests were carried out by standard methods and showed that the values of the main physical-chemical characteristics of the proposed alloy is higher than that of the characteristics of analogue and prototype (see table 2). Testing the wear resistance was carried out according to GOST 23208-83 at temperatures from 200°C to 4200°C in the real working conditions of small-section mill 250, on iron and steel works Evraz ZSMK" Novokuznetsk. Tests showed (see table 2) that the wear resistance of the products of the proposed CPF Is considerably higher than analogue ane prototype. The essential features stated in the clelms, interrelated, and changing them Is outside the specified limits leads to deterioration of characteristics of solid alloy. ‘The molybdenum content of 1.5-2.0 wt.% ‘The molybdenum content is less than 1.5 wt.%h reduces the heat resistance of the alloy. When the content is more than 2.0 wt.96, worse mechanical properties, reduced the period of t lattice of titanium carbide. ‘The content of cobalt: 1.0 to 2.0 wt.9% The content of cobalt is less than 1.0 w.% reduces impact strength, and its increase of more t WL reduce the hardness of the alloy. The Nickel content: 4.0 to 8.0 wt.% The content less than 4.0 w.9% affects the Flexural strength and the cantent of more than 8.0 wt.%% adversely affects heat resistance. The chromium content: 0.5 to 1.0 w.% The content less than 0.5 w.% reduces the corrosion resistance. When the content is more than 1.0 w% worse mechanical properties. The content of titanium nickelide: 0.5 to 1.0 wt.%e The content of titanium nickelide less than 0.5 wt.% not enough to accept binding of free carbon, the content is more than 1.0 wt.% reduced strenath characteristics of the alloy. The content of tungsten carbide: 25,0-35,0 wt.% When the content is less than 25 wt.% decreases the hardness of the alloy, the content of more than 35, WL increases density and ilichivets inertia, The content of titanium carbide: rest When the content of titanium carbide is less than the minimum reduces the hat hardness of the alloy, when the content is greater than the maximum reduced specific strength. Alloy No. 2 of the present invention was made an experimental batch roller mill No. 10-17 small-section ‘mill 250. A production test was conducted on iron and steel works Evraz ZSMK", Novokuznetsk in the range of operating temperatures up to 1200°C and showed that the wear resistance and the number of basic physico-chemical characteristics of the proposed alloy is much higher then the existing ones.powder / 2196537 ‘Thus, the results of laboratory studies, comparative and production tests show that the proposed alloy ‘The invention relates to.» Provides high performance when operating in high temperature environments and allow us to consider this Solution meets the evterion of “industrial applicability”. sakes ane Crocs Tare ote | Te Sod composton Fs Nees baer twiées | Someone soy Lt) MBarsearthesreae | The placeholder | The number ie(750) | SuBseeed ceunkengenss°”— aysaenan (aay 2 os as Sionartscrsubgraupe, abot (o2) : : topos | 20 Shariccceinte Famer ws wae es a Sestccvicaomn ee SEEDS 7 : aa ee fae reducing agent Wickeide titanium : - os [or | 10 a ,A method (NTH) ar EN ae : === 4 Sbuainina a anim oe : eo en agaten 1 : = composite memset [ungetencartie 500 = [250 | 300 | 350 smpetyeaa! fo TReprodttin edreleyy -Starscnitic, = wa trode of eb se eta i 2 3 component Farnese, RC 5 eee Fearon, °C 300 Hosa | tan Fo Hard alloy jear resistance, for high fh " pooee x0 z ex10°%| 5x10 [axt0% 300°C - - x10°6] 9x10" |12x10°4) tempera 00% eo oh ‘i lates p200°C a a x10°515x10°4| 3x10°° powder metallurgy and flexural strength 1280 11so__| 1500] 1800 | 2900 manufacture of parts of = ~ 3 2. i2 rolling bearings operating —_[inertia, kg/cm? - 6,2 58 6,5 7,2 under conditions of ‘Solid alloy containing Nickel, molybdenum, chrome and carbide of the transition metal, characterized in exposure to high that it further contains cobalt and nickelide titanium, and as a carbide of the transition metal it contains temperatures: carbides of titanium and tungsten in the following ratio of components, wt.%: Fraebaenan (ap TEES sobalt (Co) |Nicket (Ni) chromium (Cr) 4nd alow TY Beg alee jrickelide Gtaniam (Wi | Biidiiton Rungstencatie (WC TS manod’” [odes (rc 7 4 i ‘The . © powder metallurgy and ean Usee for the manufacture of various metalworking tools ©" material / 2062813 The invention relates to metallurgy, i particular to matetials with high Fesistance to abrasive wearWear- resistant "sintered ‘material / 2. 2088099 The Invention relates to powder metallurgy, in articular to materials with high resistance to abrasion ‘ane corrosion, and can be tsee, for example, when manufacturing sectors Fefiner filings isk rill for making wood-sern= finished products ‘Sintered hard alloy / 2327759, Alloy contains, mas. 9 nickel 5-10; malybcenum 5-10; niobium 5-20; fitanlum carbide 75-80. somposite/ 2201719 Invention relates to powder metallurgy, articular to production OF wear-resistant articles from titanium carbide~ based composite material Ican be used for producing ball gate valves ‘ané plain bearing sleeves, Sintered porous carbide half stuffs produced by vibration compaction of tanium carbide powder {ang sintering it in furnace ‘with non-exidising ‘atmosphere. Sintered half ‘Stuff if subjected to infiltration by metal mets in heating chamber formed by graphite mules closed by top and Bottom graphite covers, Heating ef muftie ana extra heating of impregnating metal is performed by nigh- frequency currents in vanable electromagnetic field of inductor.2511226 Invention relates to metallurgy, and namely to production of carbice cast Iron with no pores in alloy volume, and can be used {or production of working parts of planishing machines. A method involves mixing of powders ‘of titanium carbide and ‘rey cast iron SCh20 in Yolume ratio of 50 : 50, Dressing of the obtained mixture under pressure of 0.5 t, movement of the Dressed part at a melting pot bottom anc heating up fo the temperature of 1250-1350°C in contact swith a east iron ingot, Which is arranged on it land has the same grade as ‘the powder, tilt is Fully, molten; exposure at the same temperature with ‘Smultaneous saturation ‘with titanium carbide, the particlas of which rise to ‘the surface In liquid cast iron as the ingot is being molten, and quick cooling. iL (Sermat at method of its fabrication / 2525905 Invention relates to powder metallurgy, particularly, to production ‘of ball valve from ‘kanium-carbide-based ‘ermet, Bal valve cermet SRrucure consists of alternating zones of ‘continuous metal matric ‘and isolated uniformly ‘distributed carbide grains ‘and zones with continuous metal matrix and Uniformly distributed ‘carbide grains that make a ‘continuous carcass Content of metal matrix in ‘cermet makes 25-70 vol Sj Ball valve mace, moule with porous carbide semi ‘after sintenng Is not twithdravin from the urmace, its temperature being maintained above liquidus temperature of impregnating metal. The latter is fused In crucible arranged in the same ‘cramoer filed in the ‘mould to contact with ‘arblde semi and maintained for time interval required for ‘complete infiltration of metal melt and directed ‘eystallsation of metal in semi pores. Hard alloy / 2537469 Hard alloy contains the following, wt %:molybdenum 1.5-2.5, ‘cobalt 1,0-2.0, nickel 4.0 18.0, chrome 0.5-1.0,, Lutanium niekelde 0 tungsten carbide 25.0- 35.0, and titanium carbide is terest 1.9, © 2013-2015 Russian business network RussianPatents.com fling in Enalish ‘Special Russian commercial information project for world wide, Forelgn