so20r016 Zine phosphate - Wikipedia
Zinc phosphate
From Wikipedia, the free encyclopedia
Zinc phosphate (Zn,(PO,)9) is an inorganic chemical
compound used as a corrosion resistant coating on metal
surfaces either as part of an electroplating process or applied as
a primer pigment (see also red lead). It has largely displaced
toxic materials based on lead or chromium, and by 2006 it had
become the most commonly used corrosion inhibitor." Zine
phosphate coats better on a crystalline structure than bare metal,
soa seeding agent is often used as a pre-treatment, One common
agent is sodium pyrophosphate.|2]
Natural forms of zine phosphate include minerals hopeite and
parahopeite, Zn,(PO,)3°4H,0. A somewhat similar mineral is
natural hydrous zine phosphate called tarbuttite, Zn,(PO,)(OH).
Both are known from oxidation zones of Zn ore beds and were
formed through oxidation of sphalerite by the presence of
phosphate-rich solutions. The anhydrous form has not yet been
found naturally.
Zine phosphate is formed from zine phosphate cement and used
in dentistry. Zine phosphate dental cement is one of the oldest
and widely used cements, and is commonly used for luting
permanent metal and zirconium dioxide! 1516171181
restorations and as a base for dental restorations. Zine phosphate
cement is used for cementation of inlays, crowns, bridges, and
orthodontic appliances and occasionally as a temporary
restoration. It is prepared by mixing zine oxide and magnesium
oxide powders with a liquid consisting principally of phosphoric
acid, water, and buffers. It is the standard cement to measure
against. It has the longest track record of use in dentistry. It is
still commonly used; however, resin-modified glass ionomer
cements are more convenient and stronger when used in a dental
setting
References
1. Kalendov‘a, A.; Kalenda, P; Vesel’y, D. (2006). "Comparison of
the efficiency of inorganic nonmetal pigments with zinc powder
in anticorrosion paints". Progress in Organic Coatings. Elsevier.
57: 1-10. doi:10.10164}.porgcoat.2006.05.015.
2. Menke, Joseph T. "Zine Phosphate Coatings on NonFerrous
Substrates -- Part I". PFOnline. Retrieved 2006-08-07.
3. Raab D: Befestigung von Zirkonoxidkeramiken.
DENTALZEIZUNG 2007: 6; 32-34. http://www-2wp-
hipsstonikipodiaoriwikiZine_ phosphate
Zine phosphate
‘Names
TUPAC name
Zine phosphate
Tdentifiers
CAS Number |7779-90-0 (http//www.commo
chemistry org/ChemicalDetal
aspx?ref=7779-90-0) ¢
ChemSpider 22927 (hupi/iwww.chemspider.
‘com/Chemical-Structure,22927.
‘html) ¥
ECHA InfoCard |100,029.040 (hutps:i/echa.europ
a.eu/substance-information/-isu
‘bstanceinfo/100.029.040)
Jmol 3D model Interactive image (htp://chema
‘pps.stolaf.eduljmoljmol. php?
lodel-%4SBZn942B2%SD.%SBZ
1%2B2%SD.%SBZn942B2%S
'D.%45B0-%45DP%28%45B0-%
5D%429%28%43D0%29%SBO-
'%SD.%5B0-%4SDP%28%SBO
-%51%29%428%SBO-%SD%2
9%3D0)
PubChem 24519 (hitpsiipubchem.nebi.nl
im.ni,gov/compound/24519)
RTECS number [10590000
UNIT 1E2MCT2MG2 (htp:/fasis
'm.nih. gov/ss/srsdirectjsp?regn
‘o=1E2MCT2M62)“
Inch
SMILES
Properties
Chemical formula [Zny(POs)p
Molar mass 386.11 gimol
Appearance white crystals
Density 3.998 glem*
2so20r016 Zine phosphate - Wikipedia
Melting point
‘Solubility in water
Refractive index
(mp)
Crystal structure
NFPA 704
Flash point
900 °C (1,650 °F; 1,170 K)
insoluble
1,595
Structure
‘monoclinic
Hazards,
\Non-flammable
Except where otherwise noted, data are given for
‘materials in their standard state (at 25 °C [77 °F],
100 kPa),
S verify (what is “* 2)
Infobox references
online info/archiv/pubpim/dz!2007/dz0607/dz607_032_034_hoffimann.pdf
Raab D: Befestigung von Vollkeramiken aus Zirkonoxid. ZAHNARZT WIRTSCHAFT PRAXIS 2007: 12; 98-101.
|ittp:{Awwnw.2wp-online.info/archiv/publ gim/2wp/2007/zwp1207/zwp1207_098_101_hoffimann. pdf
Raab D: Befestigung von Zirkonoxidkeramiken. ZAHN PRAX 2008: 11; 16-19.
DENTAL INC Chinese Edition 2008: Sonderdruck.
Raab D: Fixation of all ceramic restorations — the advantages of cementation, DENTAL INC 2008: March / April 50-53.
Raab D: Fixation of full ceramic restorations — the advantages of cementation. 4° 85425 (#52 — AI TIT HRA.
8. Raab D: Konventionelle Befestigung von Vollkeramikrestaurationen. ZAHN PRAX 2009: 12; 84-86.
External links
Retrieved from “https://en.wikipedia.org/w/index.php’title=Zine_phosphate&ol
1-735391020"
Categories: Phosphates | Zine compounds | Inorganic pigments | Corrosion inhibitors | Dental materials
Inorganic compound stubs
= This page was last modified on 20 August 2016, at 11:30.
= Text is available under the Creative Commons Attribution-ShareAlike License; additional terms may apply.
By using this
of the Wikimedia Foundation, Inc., a non-profit organization.
hipsstonikipodiaoriwikiZine_ phosphate
fou agree to the Terms of Use and Privacy Policy. Wikipedia® is a registered trademark