sorrr016 Phosphae conversion costing Wikipedsa Phosphate conversion coating From Wikipedia, the free encyclopedia Phosphate coatings are used on steel parts for corrosion resistance, lubricity, or as a foundation for subsequent coatings or painting." II) It serves as a conversion coating in which a dilute solution of phosphoric acid and phosphate salts is applied via spraying or immersion and chemically reacts with the surface of the part being coated to form a layer of insoluble, crystalline phosphates." Phosphate conversion coatings can also be used on aluminium, zinc, cadmium, silver and tin.!4) The main types of phosphate coatings are manganese, iron and zinc.{] Manganese phosphates are used both for corrosion resistance and lubricity and are applied only by immersion. Iron phosphates are typically used as a base for further coatings or painting and are applied by immersion or by spraying. Zinc phosphates are used for corrosion resistance (phosphate and oil), a lubricant base layer, and as a paint/coating base and can also be applied by immersion or spraying UG] Contents = 1 Process = 2 Uses = 3 Seealso = 4 References Process The application of phosphate coatings makes use of phosphoric acid and takes advantage of the low solubility of phosphates in medium or high pII solutions. Iron, zinc or manganese phosphate salts are dissolved in a solution of phosphoric acid.) When steel or iron parts are placed in the phosphoric acid, a classic takes place which locally depletes the hydronium (H30°) ior ‘id and metal reac raising the pH, and causing the dissolved salt to fall mm out of solution and be precipitated on the surface. The acid and metal reaction also creates iron phosphate locally which may also be deposited. In the case of depositing zine phosphate or manganese phosphate the additional iron phosphate is frequently an undesirable addition to the coating, ‘The acid and metal reaction also generates hydrogen gas in the form of tiny bubbles that adhere to the surface of the metal. These prevent the acid from reaching the metal surface and slows down the reaction. To overcome this sodium nitrite is frequently added to act as an oxidizing agent that reacts with the hydrogen to form water. This chemistry is known as a nitrate accelerated solution. Hydrogen is prevented from forming a passivating layer on the surface by the oxidant additive.!® The following is a typical phosphating procedure:{*] cleaning the surface rinsing surface activation . phosphating rinsing - neutralizing rinse (optional) tpn wiped org Phospte_conversion coating 1% AaYaALREso Prospate conversion costing Wikipedia 7. drying 8. application of supplemental coatings: lubricants, sealers, oil, ete. The performance of the phosphate coating is significantly dependent on the crystal structure as well as the weight. For example, a microcrystalline structure is usually optimal for corrosion resistance or subsequent painting. A coarse grain structure impregnated with oil, however, may be the most desirable for wear resistance. These factors are controlled by selecting the appropriate phosphate solution, using various additives, and controlling bath temperature, concentration, and phosphating time.! A widely used additive is to seed the metal surface with tiny particles of titanium salts by adding these to the rinse bath preceding the phosphating. This is known as activation. Uses Phosphate coatings are often used to provide corrosion resistance, however, phosphate coatings on their own do not provide this because the coating is porous. Therefore, oil or other sealers are used to achieve corrosion resistance. Zinc and manganese coatings are used to help break in components subject to wear!"] and help prevent galling.) Most phosphate coatings serve as a surface preparation for further coating and/or painting, a function it performs effectively with excellent adhesion and electric isolation. The porosity allows the additional materials to seep into the phosphate coating and become mechanically interlocked after drying. The dielectric nature will electrically isolate anodic and cathodic areas on the surface of the part, minimizing underfilm corrosion that sometimes occurs at the interface of the paint/coating and the substrate." Zine phosphate coatings are frequently used in conjunction with sodium stearate (soap) to form a lubrication layer in cold and hot forging.!"] The sodium stearate reacts with the phosphate crystal which in turn are strongly bonded to the metal surface!7] The reacted soap layer then forms a base for additional unreacted soap to be deposited on top so that a thick three part coating of zinc phosphate, reacted soap and unreacted soap is built up. The resulting coating remains adhered to the metal surface even under extreme deformation. The zine phosphate is in fact abrasive and it is the soap which performs the actual lubrication. The soap layer must be thick enough to prevent substantial contact between the metal forming dies and phosphate crystal. See also Chromate conversion coating Phosphate Parkerizing Galvanization References 1. "Zine and Manganese Phosphates". www parkerhg.com. 4, Edwards, Joseph (1997). Coating and Surface Parker Rust-Proof of Cleveland. Retrieved 2014-09-30. Treatment Systems for Metals. Finishing Publications 2. "Phosphating ; Advanced Corrosion Protection”. Ltd, and ASM Intemational. pp. 214-217, ISBN 0- surfacepretreatment.com. Archived from the original on 904877-16-9. 2011-07-16 5. "Phosphate Coating: Zine, Iron or Manganese 3. Dufour, Jim (2006). An Introduction to Metallurgy, Sth Phosphate. United Plating, Inc. Archived from the ced, Cameron, pp. IX 11-12. original on 2011-07-17. tnipevionwikipediaorgtkiPhospbate_corversion coating 20sorrr016 Phosphae conversion costing Wikipedsa 6. Stauffer, J.L (1993). Finishing Systems Design and 7. https:s/web.archive.org/web/2009022816113 1/http://ww Implementation: A Guide for Product Parameters, ‘w.surfacepretreatment,com/default.asp?id=3, Archived Coatings, Process, and Equipment, SME. pp. 132-134. ‘from the original on February 28, 2009. Retrieved. ISBN 9780872634343. January 3, 2009, Missing or empty [title= (help) Retrieved from "https://en. wikipedia org/w/index.phptitle=Phosphate_conversion_coatingScoldid=738447506" Categories: Coatings | Corrosion prevention = This page was last modified on 9 September 2016, at 00:53. ‘ext is available under the Creative Commons Attribution-ShareA like License; additional terms may apply. By using this site, you agree to the Terms of Use and Privacy Policy. Wikipedia® is a registered trademark of the Wikimedia Foundation, Inc., a non-profit organization, tnipevionwikipediaorgtkiPhospbate_corversion coating 38