Anlisis con cido frmico

Analyze Experiment - Ef AF
File name: <Untitled>
Estimated effects for Ef AF (ef)
Effect
Estimate
Stnd. Error
average
0,27
0,0284898
A:Rel agua-precursor
-0,015
0,0348927
B:Rel etanol-precursor
-0,0475
0,0348927
C:Temperatura
0,0025
0,0348927
AA
-0,1075
0,0513607
AB
0,01
0,0493457
AC
-0,07
0,0493457
BB
-0,0625
0,0513607
BC
-0,115
0,0493457
CC
0,2075
0,0513607
Standard errors are based on total error with 5 d.f.

V.I.F.
1,0
1,0
1,0
1,01111
1,0
1,0
1,01111
1,0
1,01111

The StatAdvisor
This table shows each of the estimated effects and interactions. Also shown is the standard error of each of the effects,
which measures their sampling error. Note also that the largest variance inflation factor (V.I.F.) equals 1,01111. For a
perfectly orthogonal design, all of the factors would equal 1. Factors of 10 or larger are usually interpreted as indicating
serious confounding amongst the effects.
To plot the estimates in decreasing order of importance, select Pareto Charts from the list of Graphical Options. To test
the statistical significance of the effects, select ANOVA Table from the list of Tabular Options. You can then remove
insignificant effects by pressing the alternate mouse button, selecting Analysis Options, and pressing the Exclude button.

Analysis of Variance for Ef AF

Source
Sum of Squares
A:Rel agua-precursor
0,00045
B:Rel etanol-precursor
0,0045125
C:Temperatura
0,0000125
AA
0,0106673
AB
0,0001
AC
0,0049
BB
0,00360577
BC
0,013225
CC
0,0397442
Total error
0,012175
Total (corr.)
0,0938

Df
1
1
1
1
1
1
1
1
1
5
14

Mean Square
0,00045
0,0045125
0,0000125
0,0106673
0,0001
0,0049
0,00360577
0,013225
0,0397442
0,002435

F-Ratio
0,18
1,85
0,01
4,38
0,04
2,01
1,48
5,43
16,32

P-Value
0,6852
0,2315
0,9457
0,0905
0,8474
0,2152
0,2779
0,0672
0,0099

R-squared = 87,0203 percent

R-squared (adjusted for d.f.) = 63,6567 percent
Standard Error of Est. = 0,0493457
Mean absolute error = 0,0223333
Durbin-Watson statistic = 1,93545 (P=0,2531)
Lag 1 residual autocorrelation = -0,00166838
The StatAdvisor
The ANOVA table partitions the variability in Ef AF into separate pieces for each of the effects. It then tests the statistical
significance of each effect by comparing the mean square against an estimate of the experimental error. In this case, 1
effects have P-values less than 0,05, indicating that they are significantly different from zero at the 95,0% confidence
level.
The R-Squared statistic indicates that the model as fitted explains 87,0203% of the variability in Ef AF. The adjusted Rsquared statistic, which is more suitable for comparing models with different numbers of independent variables, is
63,6567%. The standard error of the estimate shows the standard deviation of the residuals to be 0,0493457. The mean
absolute error (MAE) of 0,0223333 is the average value of the residuals. The Durbin-Watson (DW) statistic tests the
residuals to determine if there is any significant correlation based on the order in which they occur in your data file. Since
the P-value is greater than 5,0%, there is no indication of serial autocorrelation in the residuals at the 5,0% significance
level.

Optimize Response
Goal: maximize Ef AF
Optimum value = 0,435494
Factor
Rel agua-precursor
Rel etanol-precursor
Temperatura

Low
3,0
10,0
200,0

High
4,0
20,0
250,0

Optimum
3,27899
10,0
250,0

The StatAdvisor
This table shows the combination of factor levels which maximizes Ef AF over the indicated region. Use the Analysis
Options dialog box to indicate the region over which the optimization is to be performed. You may set the value of one or
more factors to a constant by setting the low and high limits to that value.

Standardized Pareto Chart for Ef AF

CC

+
-

BC
AA
AC
B:Rel etanol-precursor
BB
A:Rel agua-precursor
AB
C:Temperatura
0

2
3
Standardized effect

Main Effects Plot for Ef AF

0,38
0,35

Ef AF

0,32
0,29
0,26
0,23
0,2
3

Rel agua-precursor

10

20

Rel etanol-precursor

200

250

Temperatura

Superficie de respuesta:

Ef AF

Estimated Response Surface

Rel etanol-precursor=15,0
Ef AF
0,13
0,16
0,19
0,22
0,25
0,28
0,31
0,34
0,37
0,4
0,43

0,43
0,38
0,33
0,28
0,23
0,18
0,13
3
3,2
3,4

3,6
Rel agua-precursor 3,8
4

200

210

230
220
Temperatura

240

250

Ef AF

Estimated Response Surface

Rel agua-precursor=3,5
Ef AF
0,13
0,16
0,19
0,22
0,25
0,28
0,31
0,34
0,37
0,4
0,43

0,43
0,38
0,33
0,28
0,23
0,18
0,13
10
12
14

16
Rel etanol-precursor 18
20

200

210

230
220
Temperatura

240

250

Ef AF

Estimated Response Surface

Temperatura=225,0
Ef AF
0,13
0,16
0,19
0,22
0,25
0,28
0,31
0,34
0,37
0,4
0,43

0,43
0,38
0,33
0,28
0,23
0,18
0,13
3
3,2
3,4

3,6
Rel agua-precursor 3,8
4

10

12

16
14
Rel etanol-precursor

18

20

Anlisis con azul de metileno

Analyze Experiment - Ef MB
File name: <Untitled>
Estimated effects for Ef MB (ef)
Effect
Estimate
Stnd. Error
average
0,2
0,0390085
A:Rel agua-precursor
0,0625
0,0477755
B:Rel etanol-precursor
0,13
0,0477755
C:Temperatura
-0,0175
0,0477755
AA
-0,0725
0,0703237
AB
0,03
0,0675648
AC
-0,065
0,0675648
BB
-0,0075
0,0703237
BC
-0,07
0,0675648
CC
0,2675
0,0703237
Standard errors are based on total error with 5 d.f.

V.I.F.
1,0
1,0
1,0
1,01111
1,0
1,0
1,01111
1,0
1,01111

The StatAdvisor
This table shows each of the estimated effects and interactions. Also shown is the standard error of each of the effects,
which measures their sampling error. Note also that the largest variance inflation factor (V.I.F.) equals 1,01111. For a
perfectly orthogonal design, all of the factors would equal 1. Factors of 10 or larger are usually interpreted as indicating
serious confounding amongst the effects.
To plot the estimates in decreasing order of importance, select Pareto Charts from the list of Graphical Options. To test
the statistical significance of the effects, select ANOVA Table from the list of Tabular Options. You can then remove
insignificant effects by pressing the alternate mouse button, selecting Analysis Options, and pressing the Exclude button.

Analysis of Variance for Ef MB

Source
Sum of Squares
A:Rel agua-precursor
0,0078125
B:Rel etanol-precursor
0,0338
C:Temperatura
0,0006125
AA
0,00485192
AB
0,0009
AC
0,004225
BB
0,0000519231
BC
0,0049
CC
0,0660519
Total error
0,022825
Total (corr.)
0,1496

Df
1
1
1
1
1
1
1
1
1
5
14

Mean Square
0,0078125
0,0338
0,0006125
0,00485192
0,0009
0,004225
0,0000519231
0,0049
0,0660519
0,004565

F-Ratio
1,71
7,40
0,13
1,06
0,20
0,93
0,01
1,07
14,47

P-Value
0,2477
0,0417
0,7291
0,3498
0,6756
0,3802
0,9192
0,3477
0,0126

R-squared = 84,7426 percent

R-squared (adjusted for d.f.) = 57,2794 percent
Standard Error of Est. = 0,0675648
Mean absolute error = 0,0303333
Durbin-Watson statistic = 1,23076 (P=0,0217)
Lag 1 residual autocorrelation = 0,374726
The StatAdvisor
The ANOVA table partitions the variability in Ef MB into separate pieces for each of the effects. It then tests the
statistical significance of each effect by comparing the mean square against an estimate of the experimental error. In this
case, 2 effects have P-values less than 0,05, indicating that they are significantly different from zero at the 95,0%
confidence level.
The R-Squared statistic indicates that the model as fitted explains 84,7426% of the variability in Ef MB. The adjusted Rsquared statistic, which is more suitable for comparing models with different numbers of independent variables, is
57,2794%. The standard error of the estimate shows the standard deviation of the residuals to be 0,0675648. The mean
absolute error (MAE) of 0,0303333 is the average value of the residuals. The Durbin-Watson (DW) statistic tests the
residuals to determine if there is any significant correlation based on the order in which they occur in your data file. Since
the P-value is less than 5,0%, there is an indication of possible serial correlation at the 5,0% significance level. Plot the
residuals versus row order to see if there is any pattern that can be seen.

Optimize Response
Goal: maximize Ef MB
Optimum value = 0,478899
Factor
Rel agua-precursor
Rel etanol-precursor
Temperatura

Low
3,0
10,0
200,0

High
4,0
20,0
250,0

Optimum
4,0
19,9421
200,081

The StatAdvisor
This table shows the combination of factor levels which maximizes Ef MB over the indicated region. Use the Analysis
Options dialog box to indicate the region over which the optimization is to be performed. You may set the value of one or
more factors to a constant by setting the low and high limits to that value.

Standardized Pareto Chart for Ef MB

CC

+
-

B:Rel etanol-precursor
A:Rel agua-precursor
BC
AA
AC
AB
C:Temperatura
BB
0

2
Standardized effect

Main Effects Plot for Ef MB

0,37
0,33

Ef MB

0,29
0,25
0,21
0,17
0,13
3

Rel agua-precursor

10

20

Rel etanol-precursor

200

250
Temperatura

Superficies de respuesta:
Estimated Response Surface
Temperatura=225,0
Ef MB
0,0
0,05
0,1
0,15
0,2
0,25
0,3
0,35
0,4
0,45
0,5

0,5
0,4
Ef MB

0,3
0,2
0,1
0
3

3,2

3,4

3,6

3,8

10

20
18
16
14
12
Rel etanol-precursor

Rel agua-precursor

Estimated Response Surface

Rel etanol-precursor=15,0
Ef MB
0,0
0,05
0,1
0,15
0,2
0,25
0,3
0,35
0,4
0,45
0,5

0,5

Ef MB

0,4
0,3
0,2
0,1
0
3

3,2

230

3,4

3,6

3,8

Rel agua-precursor

200

210

240

250

220
Temperatura

Estimated Response Surface

Rel agua-precursor=3,5
Ef MB
0,0
0,05
0,1
0,15
0,2
0,25
0,3
0,35
0,4
0,45
0,5

0,5

Ef MB

0,4
0,3
0,2
0,1
0
10

12

14

16

Rel etanol-precursor

18

20

250
240
230
220
210 Temperatura
200