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Solutions are homogeneous mixtures, which means that the components form a
single phase. The major component is called the solvent, and the minor components
are called the solute. If both components in a solution are 50 percent, the term
solute can be assigned to either component. When gas or solid materials dissolve in
a liquid, it is referred to as a solute. When two liquids dissolve in each other, the
major component is called the solvent and the minor component is called the solute
For gaseous solutions, if the solvent is a gas, the gases are the solute that can only
be dissolved under a given set of conditions. An example of a gaseous solution is
air. If the solvent is a liquid, gases, liquids and solids can be dissolved. An example
of a liquid solution is an alcoholic beverage, such as vodka a solution of ethanol
and water. If the solvent is a solid, gases, liquids and solids can likewise be
dissolved. An example of a solid solution is an alloy, such as bronze or brass.
that large amounts of sugar can be added as the temperature keeps rising. The
reason this occurs is because as the temperature increases, the intermolecular
forces can be more easily broken, allowing more of the solute particles to be
attracted to the solvent particles. There are other examples, though, where
increasing the temperature has very little effect on how much solute can be
dissolved. Table salt is a good example: you can dissolve just about the same
amount of table salt in ice water as you can in boiling water.
For all gases, as the temperature increases, the solubility decreases. The kinetic
molecular theory can be used to explain this phenomenon. As the temperature
increases, the gas molecules move faster and are then able to escape from the
liquid. The solubility of the gas, then, decreases.
Looking at the graph below, ammonia gas, NH3, shows a sharp decline in solubility
as the temperature increases, whereas all of the ionic solids show an increase in
solubility as the temperature increases.
A graph for the solubility of oxygen gas, O2, would be very similar to the one for
NH3(g); in other words, oxygen gas would decrease in solubility as the temperature
rises. Conversely, the colder the temperature, the greater amount of O2(g) would
be dissolved.
The Effect of Pressure on Solubility
The second factor, pressure, affects the solubility of a gas in a liquid but never of a
solid dissolving in a liquid. When pressure is applied to a gas that is above the
surface of a solvent, the gas will move into the solvent and occupy some of the
spaces between the particles of the solvent. A good example is carbonated soda.
Pressure is applied to force the CO2 molecules into the soda. The opposite is also
true. When the gas pressure is decreased, the solubility of that gas is also
decreased. When you open a can of carbonated beverage, the pressure in the soda
is lowered, so the gas immediately starts leaving the solution. The carbon dioxide
stored in the soda is released, and you can see the fizzing on the surface of the
liquid. If you leave an open can of soda out for a period of time, you may notice the
beverage becoming flat because of the loss of carbon dioxide.
This gas pressure factor is expressed in Henrys law. Henrys law states that, at a
given temperature, the solubility of a gas in a liquid is proportional to the partial
pressure of the gas above the liquid. An example of Henrys Law occurs in scuba
diving. As a person dives into deep water, the pressure increases and more gases
are dissolved into the blood. While ascending from a deep-water dive, the diver
needs to return to the surface of the water at a very slow rate to allow for all of the
dissolved gases to come out of the blood very slowly. If a person ascends too
quickly, a medical emergency may occur due to the gases coming out of blood too
quickly. This is called having the bends.
This video serves a blackboard lecture on the factors that affect solubility (6c):
http://www.youtube.com/watch?v=1Hbkco6hyJ4 (4:33).
Lesson Summary
When a substance can dissolve in another it is said to be soluble; when it cannot, it
is said to be insoluble
Temperature affects the solubility of both gases and solids. With solids, generally
the solubility increases with increasing temperature. With gases, the solubility tends
to decrease with increasing temperature.
Pressure only affects the solubility of gases. Henrys law states that, at a given
temperature, the solubility of a gas in a liquid is proportional to the partial pressure
of the gas above the liquid.
Increasing the surface area increases the rate of solubility of a solid because a
larger number of molecules have contact with the solvent.
Concentrations of Solutions
There are a number of ways to express the relative amounts of solute and solvent in a
solution. This page describes calculations for four different units used to express
concentration:
Percent Composition (by mass)
Molarity
Molality
Mole Fraction
Percent Composition (by mass)
We can consider percent by mass (or weight percent, as it is sometimes called) in two
ways:
The parts of solute per 100 parts of solution.
The fraction of a solute in a solution multiplied by 100.
Top
Molarity
Molarity tells us the number of moles of solute in exactly one liter of a solution. (Note
that molarity is spelled with an "r" and is represented by a capital M.)
We need two pieces of information to calculate the molarity of a solute in a solution:
The moles of solute present in the solution.
The volume of solution (in liters) containing the solute.
To calculate molarity we use the equation:
Top
Molality
Molality, m, tells us the number of moles of solute dissolved in exactly one kilogram
of solvent. (Note that molality is spelled with two "l"'s and represented by a lower
case m.)
We need two pieces of information to calculate the molality of a solute in a solution:
The moles of solute present in the solution.
The mass of solvent (in kilograms) in the solution.
To calculate molality we use the equation:
Top
Mole Fraction
The mole fraction, X, of a component in a solution is the ratio of the number of moles
of that component to the total number of moles of all components in the solution.
To calculate mole fraction, we need to know:
The number of moles of each component present in the solution.
The mole fraction of A, XA, in a solution consisting of A, B, C, ... is calculated using
the equation:
Top
1 Introducing solutions
For the reason stated above, most chemical reactions that are carried out
in the laboratory and in industry, and that occur in living organisms, take
place in solution.
Solutions are so common; very few pure substances are found in nature.
2 Understanding concentrations
Concentration is a general term that expresses the quantity of solute
contained in a given amount of solution. Various ways of expressing
concentration are in use; the choice is usually a matter of convenience
in a particular application. You should become familiar with all of them.
Problem Example 1
The Normal Saline solution used in medicine for nasal irrigation, wound cleaning and
intravenous drips is a 0.91% (w/v) solution of sodium chloride in water. How would you
prepare 1.5 L of this solution?
Solution: The solution will contain 0.91 g of NaCl in 100 mL of water, or 9.1 g in 1 L. Thus
you will add (1.5 9.1g) = 13.6 g of NaCl to 1.5 L of water.
Percent means parts per 100; we can also use parts per thousand
(ppt) for expressing concentrations in grams of solute per kilogram of
solution. For more dilute solutions, parts per million (ppm) and parts
per billion (109; ppb) are used. These terms are widely employed to
express the amounts of trace pollutants in the environment.
Problem Example 2
Describe how you would prepare 30 g of a 20 percent (w/w) solution of KCl in water.
Solution: The weight of potassium chloride required is 20% of the total weight of the
solution, or 0.2 (3 0 g) = 6.0 g of KCl. The remainder of the solution
(30 6 = 24) g consists of water. Thus you would dissolve 6.0 g of KCl in 24 g of water.
Fish, like all animals, need a supply of oxygen, which they obtain from oxygen dissolved in
the water. The minimum oxygen concentration needed to support most fish is around 5 ppm
(w/v). How many moles of O2 per liter of water does this correspond to?
Solution: 5 ppm (w/v) means 5 grams of oxygen in one million mL (1000 L) of water, or 5
mg per liter. This is equivalent to (0.005 g) / (32.0 g mol1)
= 1.6 104 mol.
Problem Example 4
How would you make 120 mL of a 0.10 M solution of potassium hydroxide in water?
Solution: The amount of KOH required is (0.120 L) (0.10 mol L1) = 0.012 mol. The
molar mass of KOH is 56.1 g, so the weight of KOH required is
(.012 mol) (56.1 g mol1) = 0.67 g. We would dissolve this weight of KOH in a volume of
water that is less than 120 mL, and then add sufficient water to bring the volume of the
solution up to 120 mL.
Comment: if we had simply added the KOH to 120 mL of water, the molarity of the resulting solution would
not be the same. This is because volumes of different substances are not strictly additive when they are
mixed. Without actually measuring the volume of the resulting solution, its molarity would not be known.
Problem Example 5
Calculate the molarity of a 60-% (w/w) solution of ethanol (C2H5OH) in water whose density
is 0.8937 g mL1.
Solution: One liter of this solution has a mass of 893.7 g, of which
0.60 (893.7 g) = 536.2 g consists of ethanol. The molecular weight of C2H5OH is 46.0, so
the number of moles of ethanol present in one liter (that is, the molarity) will be
Although molar concentration is widely employed, it suffers from one serious defect: since
volumes are temperature-dependent (substances expand on heating), so are molarities; a
Problem Example 6
What fraction of the molecules in a 60-% (w/w) solution of ethanol in water consist of H2O?
Solution: From the previous problem, we know that one liter of this solution contains 536.2
g (11.6 mol) of C2H5OH. The number of moles of H2O is
( (893.7 536.2) g) / (18.0 g mol1) = 19.9 mol. The mole fraction of water is thus
Thus 63% of the molecules in this solution consist of water, and 37% are ethanol.
Find the mole fraction of water in a solution prepared by dissolving 4.50 g of CaBr 2 in 84.0
mL of water.
Solution: The molar mass of CaBr2 is 200 g, and 84.0 mL of H2O has a mass of very close
to 84.0 g at its assumed density of 1.00 g mL1. Thus the number of moles of CaBr2 in the
solution is (4.50 g) / (200 g/mol) = .0225 mol.
Because this salt is completely dissociated in solution, the solution will contain 0.022 mol of
Ca2+ and (2 .0225) = .067 mol of Br. The number of moles of water is (84 g) / (18 g
mol1) = 4.67 mol.
The mole fraction of water is then
(.467 mol) / (0.067 + 4.67) mol = .467 / 4.74 = 0.98
Thus for every 100 particles in the solution, 98 of them concist of H 2O molecules, and the
remaining two are ions from the dissociation of the CaBr2.
A solution prepared by dissolving 66.0 g of urea (NH2)2CO in 950 g of water had a density of
1.018 g mL1.
Express the concentration of urea in a) weight-percent; b) mole fraction;
c) molarity; d) molality.
Solution:
a) The weight-percent of solute is (100%)
Problem Example 10
Ordinary dry air contains 21% (v/v) oxygen. About many moles of O2 can be inhaled into
the lungs of a typical adult woman with a lung capacity of 4.0 L?
Solution: The number of molecules (and thus the number of moles) in a gas is directly
proportional to its volume (Avogadro's law), so the mole fraction of O2is 0.21. The molar
volume of a gas at 25 C is
(298/271) 22.4 L mol1 = 24.4 L mol1
so the moles of O2 in 4 L of air will be
(4 / 24.4) (0.21 mol) (24.4 L mol1) = 0.84 mol O2.
Dilution calculations
These kinds of calculations arise frequently in both laboratory and
practical applications. If you have a thorough understanding of
concentration definitions, they are easily tackled. The most important
things to bear in mind are
Problem Example 11
Commercial hydrochloric acid is available as a 10.17 molar solution. How would you use this
to prepare 500 mL of a 4.00 molar solution?
Solution: The desired solution requires (0.50 L) (4.00 M L1) = 2.0 mol of HCl. This
quantity of HCl is contained in (2.0 mol) / (10.17 M L1) = 0.197 L of the concentrated acid.
So one would measure out 197 mL of the concentrated acid, and then add water to make
the total volume of 500 mL.
Problem Example 12
Calculate the molarity of the solution produced by adding 120 mL of 6.0 M HCl to 150 mL of
0.15 M HCl. What important assumption must be made here?
Solution: The assumption, of course, is that the density of HCl within this concentration
range is constant, meaning that their volumes will be additive.
Moles of HCl in first solution: (0.120 L) (6.0 mol L1) = 0.72 mol HCl
Moles of HCl in second solution: (0.150 L) (0.15 mol L1) = 0.02 mol HCl
Molarity of mixture: (0.72 + 0.02) mol / (.120 + .150) L = 4.3 mol L1.
Explain why the molarity of a solution will vary with its temperature,
whereas molality and mole fraction do not.
Given the necessary data, convert (in either direction) between any two
concentration units, e.g. molarity - mole fraction.
Concept Map
Chemical Stoichiometry
The Mole
Given the equation above, we can tell the number of moles of reactants and products.
A mole simply represents Avogadro's number (6.023 x 1023) of molecules. A mole is
similar to a term like a dozen. If you have a dozen carrots, you have twelv e of them.
Similarily, if you have a mole of carrots, you have 6.023 x 10 23 carrots. In the equation
above there are no numbers in front of the terms, so each coefficient is assumed to be
one (1). Thus, you have the same number of moles of Ag NO 3, NaCl, AgCl, NaNO3.
Developing a strategy can be difficult, but here is one way of approaching a problem
like this.
1. Count the number of each atom on the reactant and on the product side.
2. Determine a term to balance first. When looking at this problem it appears that
the oxygen will be the most difficult to balance so we'll try to balance the
oxygen first. The simplist way to balance the oxygen terms is:
Al +3 Fe3O4---> 4Al2O3+Fe
It is important that you never change a subscript. Only change the coefficient
when balancing an equation. Also, be sure to notice that the subscript times the
coefficient will give the number of atoms of that element. On the reactant side,
we have a coefficient of three (3) multiplied by a subscript of four (4), giving
12 oxygen atoms. On the product side, we have a coefficient of four (4)
multiplied by a subscript of three (3), giving 12 oxygen atoms. Now, the
oxygens are balanced.
3. Choose another term to balance. We'll choose iron, Fe. Since there are nine (9)
iron atoms in the term in which the oxygen is balanced we add a nine (9)
coefficient in front of the Fe. We now have:
Al +3 Fe3O4---> 4Al2O3+9Fe
4. Balance the last term. In this case, since we had eight (8) aluminum atoms on
the product side we need to have eight (8) on the reactant side so we add an
eight (8) in front of the Al term on the reactant side.
Now, we're done, and the balanced equation is:
8Al + 3Fe3O4 ---> 4Al2O3 + 9 Fe
Limiting Reagents
Sometimes when reactions occur between two or more substances, one reactant runs
out before the other. That is called the "limiting reagent." Often, it is necessary to
identify the limiting reagent in a problem.
Example: A chemist only has 6.0 grams of C2H2 and an unlimitted supply of oxygen
and desires to produce as much CO2 as possible. If she uses the equation below, how
much oxygen should she add to the reaction?
2C2H2(g) + 5O2(g) ---> 4CO2(g) + 2 H2O(l)
To solve this problem, it is necessary to determine how much oxygen should be added
if all of the reactants were used up (this is the way to produce the maximum amount
of CO2).
First, we calculate the number of moles of C 2H2 in 6.0 grams of C2H2. To be able to
calculate the moles we need to look at a periodic table and see that 1 mole of C
weighs 12.0 grams and H weighs 1.0 gram. Therefore we know that 1 mole of
C2H2 weighs 26 grams (2*12 grams + 2*1 gram). Since we only have 6.0 grams of
C2H2 we must find out what fraction of a mole 6.0 grams is. To do this, we use the
following equation.
Then, because there are five (5) molecules of oxygen to every two (2) molecules of
C2H2, we need to multiply the moles of C2H2 by 5/2 to get the total moles of oxygen
that would be used to react with all the C 2H2. We then convert the moles of oxygen to
grams in order to find the amount of oxygen that needs to be added:
Percent Composition
It is possible to calculate the mole ratios (also called mole fractions) between terms in
a chemical equation when given the percent by mass of products or reactants.
percentage by mass = mass of part/ mass of whole
There are two types of percent composition problems-- problems in which you are
given the formula (or the weight of each part) and asked to calculate the percentage of
each element and problems in which you are given the percentages and asked to
calculate the formula.
In percent composition problems, there are many possible solutions. It is always
possible to double the answer. For example, CH and C 2H2 have the same proportions,
but they are different compounds. It is standard to give compounds in their simplest
form, where the ratio between the elements is as reduced as it can be-- called
the empirical formula. When calculating the empirical formula from percent
composition, one can convert the percentages to grams. For example, it is usually the
easiest to assume you have 100 grams so 54.3% would become 54.3 grams. Then we
can convert the masses to moles which gives us mole ratios. It is necessary to reduce
to whole numbers. A good technique is to divide all the terms by the smallest number
of moles. Then the ratio of the moles can be transfered to write the empirical formula.
Now we try to get an even ratio between the elements so we divide by the number of
moles of sulfur, because it is the smallest number:
So we have: C3H8 S
Example: Figure out the percentage by mass of hydrogen sulfate, H 2SO4.
In this problem we need to first calculate the total weight of the compound by looking
at the periodic table. This gives us:
(2(1.008) + 32.07 + 4(16.00) grams/mol = 98.09 g/mol
Now, we need to take the weight fraction of each element over the total mass (which
we just found) and multiply by 100 to get a percentage.
This is essentially 100 so we know that everything has worked, and we probably have
not made any careless errors.
So the answer is that H2SO4 is made up of 2.06% H, 32.7% S, and 65.2% O by mass.
When we divide, we did not get whole numbers so we must multiply by two (2). The
answer=P2O5
Calculating the molecular formula once we have the empirical formula is easy. If we
know the empirical formula of a compound, all we need to do is divide the molecular
mass of the compound by the mass of the empirical formula. It is also possible to do
this with one of the elements in the formula; simply divide the mass of that element in
one mole of compound by the mass of that element in the empirical formula. The
result should always be a whole number.
Example: if we know that the empirical formula of a compound is HCN and we are
told that a 2.016 grams of hydrogen are necesary to make the compound, what is the
molecular formula? In the empirical formula hydrogen weighs 1.008 grams. Dividing
2.016 by 1.008 we see that the amount of hydrogen needed is twice as much.
Therefore the empirical formula needs to be increased by a factor of two (2). The
answer is:
H2C2N2.
Density
Density refers to the mass per unit volume of a substance. It is a very common term in
chemistry.
Concentrations of Solutions
The concentration of a solution is the "strength" of a solution. A solution typically
refers to the dissolving of some solid substance in a liquid, such as dissolving salt in
water. It is also often necessary to figure out how much water to add to a solution to
change it to a specific concentration.
The concentration of a solution is typically given in molarity. Molarity is defined as
the number of moles of solute (what is actually dissolved in the solution) divided by
the liters of solution (the total volume of what is dissolved and what it has been
dissolved in).
Molarity is probably the most commonly used term because measuring a volume of
liquid is a fairly easy thing to do.
Example: If 5.00 grams of NaOH are dissolved in 5000 mL of water, what is the
molarity of the solution?
One of our first steps is to convert the amount of NaOH given in grams into moles:
Now we simply use the definition of molarity: moles/liters to get the answer
It is possible to convert between molarity and molality. The only information needed
is density.
Example: If the molarity of a solution is 0.30 M, calculate the molality of the solution
knowing that the density is 3.25 g/mL.
To do this problem we can assume one (1) liter of solution to make the numbers
easier. We need to get from the molarity units of mols/Liter to the molality units of
mols/kg. We work the problem as follows, remembering that there are 1000 mL in a
Liter and 1000 grams in a kg. This conversion will only be accurate at small
molarities and molalities.
Practice Problems
1. If only 0.25 molar NaOH and water are available, how much NaOH needs to be
added to make 10 liters of 0.2 molar solution of NaOH?
Check your work
2. If 2.0 moles of sucrose weighing 684 grams is put in 1000 grams of water and is
then dissolved, what would be the molality of the solution?
Check your work.
3. If you have a 0.25 molar solution of benzene with a density of 15 grams/liter,
calculate the molality of the solution.
Check your work
4. If the density of mercury is 13.534 g/cm2 and you have 62.5 cm3 of mercury, how
many grams, moles, and atoms of mercury do you have? (Mercury has a mass of
200.6 g/mol.)
Check your work
Stoichiometry Solution:
If 2.0 moles of sucrose weighting 684 grams is put in 1000 grams of water
and is then dissolved, what would be the molality of the solution?
Answer=2.00 m
In this problem we use the equation for molality.
Molality=mols of solute/kilograms of solvent
We know the mols of solute =2 and the solvent weighs 1.00 liters. Therefore
2/1.00=2.00 m
Density Solution:
If the density of mercury is 13.534 g/cm3 and you have 62.5 cm3 of mercury, how
many grams, moles, and atoms of mercury do you have? (Mercury has a mass of
200.6 g/mol.)