Documente Academic
Documente Profesional
Documente Cultură
Institute of Refrigeration and Cryogenics, Shanghai Jiao Tong University, Shanghai 200240, China
Institute of Energy Engineering, Technical University Berlin, D-10587 Berlin, Germany
a r t i c l e
i n f o
Article history:
Received 18 May 2009
Accepted 10 January 2010
Available online 15 January 2010
Keywords:
Compound desiccant wheel
Modeling
Performance
Rotation speed
Desiccant cooling system
Simulation
a b s t r a c t
A mathematical model for predicting the performance of novel silica gel haloid compound desiccant
wheel is established. Both the gas side resistance and the solid side resistance are considered in the
model. It is found that the results of this model agree better to the experiments than the results of a former model which does not take the solid side resistance into account at all. Then the model is adopted to
analyze the effects of some main parameters on system performance. It is found that the compound desiccant wheel has a better performance in a climate with moderate temperature or in a climate with high
humidity ratio. Then under the basic conditions for the simulations (ambient air is of 35 C, 15 g/kg and
wheel thickness of 100 mm), an angle of the regeneration section between 100 and 160, a regeneration
temperature between 80 C and 95 C, a ow rate of process air between 2.0 m/s and 3.5 m/s and that of
regeneration air between 2.5 m/s and 3.5 m/s are recommended. Also, there exists an optimal rotation
speed to achieve the maximal moisture removal, which is about 12 r/h. At last, the inuences of the main
parameters on optimal rotation speed are discussed.
Crown Copyright 2010 Published by Elsevier Ltd. All rights reserved.
1. Introduction
The desiccant wheel is the key component in a solid desiccant
cooling system. Its performance is crucial to the capacity, size
and cost of the rotary desiccant cooling system. The desiccant
wheel is also known as dehumidication wheel, wheel dehumidier or rotary dehumidier in the literature. Normally, a desiccant
wheel consists of a large number of air ow passages whose walls
are constituted by matrix material (supporting material) and are
coated or impregnated with desiccant material (adsorbent). Its
cross-section is divided into two parts by the external ow sections
which are adhering to the wheel: one for process air and another
for regeneration air. Water vapor is adsorbed by the adsorbent
when moist air is passing through the process air side. Meanwhile
in the regeneration side, the water vapor is desorbed from the desiccant by the hot regeneration air. A motor is usually adopted to
drive the wheel rotating between process air side and regeneration
air side so that the desiccant wheel can operate continuously.
Several investigations have been performed to build mathematical models for predicting the performance of rotary desiccant
wheels. One-dimensional desiccant wheel models have been
established by Charoensupaya and Worek [1], Zheng et al. [25]
and Zhang et al. [6,7]. It was reported that the desiccant cooling
* Corresponding author. Tel./fax: +86 21 34206073.
E-mail address: baby_wo@sjtu.edu.cn (T.S. Ge).
1359-4311/$ - see front matter Crown Copyright 2010 Published by Elsevier Ltd. All rights reserved.
doi:10.1016/j.applthermaleng.2010.01.012
1006
Nomenclature
A
C
cp
D
DCOP
DG
DK
DO
DS
f
h
k
Ky
L
M
m
Nu
P
qst
R
r
RH
Sh
T
t
u
V
W
Y
z
Greek symbols
q
density (kg/m3)
a
convective heat transfer coefcient (kW/m2K)
d
thickness of matrix and desiccant material layer (m)
e
porosity
g
relative moisture removal efciency
h
central angle ()
U
volume ratio of desiccant material in layer (without desiccant U = 0)
u
volume ratio of haloids in composite desiccant (for silica
gel u = 0)
x
rotation speed (r/h)
Subscripts
0
initial state
a
air
d
desiccant
h
haloids desiccant (lithium chloride)
l
liquid water
m
matrix
p
process air
r
regeneration air
sg
silica gel desiccant
v
water vapor
1007
Regeneration air
dz
d
A, C
Process air
dr
One honeycombed
Adiabatic wall
i-1
/2
i+1
dz
/2
L
Matrix and desiccant
material layer
(7) The inlet air conditions are uniform in space, but may vary
with time.
(8) The thermophysical properties of the dry air and the properties of the dry desiccant material as well as of the matrix are
constant.
(9) The vapor enters the pores, diffuses in the pores, and meanwhile is adsorbed. The heat of adsorption is set free in the
desiccant layer immediately when water vapor enters the
porous layer.
(10) The pressure loss of the air stream in axial direction is negligible. It is, of course, relevant to calculate the fan power,
but it is less relevant for discussion of the heat and mass
transfer processes.
(11) Based on the calculation and analysis of Jia [19], the adsorption heat of this composite silica gel is similar to that of silica
gel. Therefore the calculation equation of adsorption heat for
silica gel is adopted to evaluate the adsorption heat of the
composite desiccant materials to simplify the calculation
and analysis.
The control volume is separated into two parts, one is the humid air in the passage and the other is the desiccant layer. Four
governing equations including conservation of moisture and heat
in the air as well as in the desiccant material are established. The
moisture conservation in the air can be expressed as:
@Y a
@Y a
u
K y CY d Y a
@t
@z
qa fA
The rst term on the left hand side of the above equation is the
moisture storage term in the air and the second one represents
the change of moisture content in a control volume (dz) with
cross-section fA. The term on the right hand side expresses the rate
of moisture variation in the air caused by the convective mass
transfer between air and desiccant.
Moisture conservation in desiccant is given by:
@Y d
@W
qd 1 e1 f AU
@t
@t
@2Y d
@2W
qa e1 f ADG
qd 1 e1 f ADS
K y CY a Y d
2
@z2
@z
2
qa e1 f A
qa cpa Y a cpv fA
@T a
@T a
u
@t
@z
aCT d T a K y cpv CY d Y a T d T a
The left hand side of the equation describes the energy storage and
the rate of energy variation in the air. The rst term on the right
hand side of Eq. (3) expresses the convective heat transfer between
the air and solid desiccant. The second term on the right hand side
indicates the sensible heat transfer between the air and solid desiccant, which is related to the convective transfer of moisture. Heat
conduction in the air is neglected.
The phase change of water is accounted for in the last term of
the next equation which describes the energy conservation in the
desiccant:
@T d
q cpd 1 f A
@t ! d
2
@T d
kd @ T d
1 eU
aCT a T d
@t
cpd qd @z2
qm cpm 1 f A1 e1 U
K y cpv CY a Y d T a T d K y CY a Y d qst
1008
q
D0 1:6 1010 m2 =s
Ds D0 exp 0:974 103 st
T
The left hand side of the equation describes the energy storage
terms of matrix, desiccant material and the heat conduction in desiccant material. The right hand side describes the convective heat
transfer between the air and solid desiccant, the sensible heat transfer between the air and solid desiccant and the heat of adsorption
released to the desiccant layer.
qd U1 e1 W1 uqsg uqh
The initial temperature and humidity ratio of the air and of the
desiccant is assumed to be uniform:
cpd
8
T a z; 0 T a0
>
>
>
>
>
>
< T d z; 0 T d0
Wz; 0 W 0
>
>
>
Y a z; 0 Y a0
>
>
>
:
Y d z; 0 Y d0
Y a 0; t
14
qd
15
T a 0; t
13
Tr
Tp
Yr
Yp
@T d
@T d
0
@z z0
@z zL
@Y d
@Y d
0
@z z0
@z zL
8
9
W qd
kd U1 e 1 uksg ukh
kl
16
ql
1 RH 1 m 1RH m RHn1
The heat of adsorption can be calculated by the obtained equilibrium adsorption equations [25]:
Yd
0:62188Pv
0:62188RHd
Patm Pv
Patm =Pv s RHd
10
11
DG
1
1
DO DK
1
DO 1:735 10
1:685
9 T d
Pv
18
Nu Sh
19
0.8
Silica gel-haloid 25
Silica gel-haloid 30
0.6
Silica gel-haloid 40
Silica gel 25
W (kg/kg)
Silica gel 30
0.4
Silica gel 40
0.2
0:5
Td
DK 97r
m
12
0.0
0.0
0.2
0.4
0.6
0.8
1.0
RH
Fig. 2. Equilibrium adsorption curves of the composite desiccant and silica gel [18].
1009
NukC
4A
ShDC
4A
D 2:302 105
1:81
p0 T
p T0
21
D Y p;in Y p;out
D
Y p;in Y p;out
Y p;in
Y p;in
+9%
15
-9%
10
0
0
10
15
20
+8%
40
-8%
30
20
10
0
0
10
20
30
40
50
DCOP
Mp VD
Mp VY p;in Y p;out
24
22
where Yp,in and Yp,out are the humidity ratio of process air at inlet
and at outlet respectively.
Relative moisture removal efciency g is also adopted:
Simulated results of
air outlet humidity ratio (g/kg)
K y qa
20
20
Simulated results of
air outlet temperature (C)
23
g shows the ratio of moisture removal to inlet humidity ratio of process air. Its value is between 0 and 1. For constant inlet humidity ratio of process air, g increases with the increasing of moisture
removal D.
Besides, another index, the dehumidication coefcient of performance (DCOP), which reects the dehumidication capacity and
1010
Table 1
Thermodynamic properties and geometrical parameters [18,19].
Specication of desiccant material
Specic heat of silica gel, cpsg (J/kg K)
Thermal conduction of silica gel, ksg (W/m K)
Density of silica gel, qsg (kg/m3)
Specic heat of matrix material, cpm (J/kg K)
Volume ratio of desiccant, U (%)
Pore diameter of compound adsorbent (nm)
Porosity, e
921
0.175
1201
880
48
4.0
0.4
3000
0.65
1200
625
15
194
0.002
4.9e6
7.1e3
0.1
0.002
81.6
0.00045
0.4
Table 2
Structural and operating parameters.
Parameters
Baseline
values
Parametric
variations
Rotation speed
Angel of regeneration air side
Temperature of ambient air, Tambient
Humidity ratio of ambient air, dambient
Inlet temperature of process air, Tp,in
Inlet humidity ratio of process, air dp,in
Flow rate of process air
Regeneration temperature, Tr,in
Inlet humidity ratio of regeneration air, dr,in
Flow rate of regeneration air
16 r/h
120
35.0 C
15.0 g/kg
35.0 C
15.0 g/kg
2.5 m/s
90.0 C
15.0 g/kg
2.5 m/s
440 r/h
60180
2540 C
10.025.0 g/kg
1.55.5 m/s
60110 C
10.025.0 g/kg
1.55.5 m/s
climate with lower temperature. This is mainly because the desiccant material is cooled to lower temperature at lower Ta,in, and
thus can adsorb more water vapor. The ux of process air and
regeneration heat needed by regeneration air keep constant
under this condition; therefore DCOP has the same trend as D
and g.
(c and d) Both moisture removal D and DCOP increases signicantly with the increasing of Ya,in. With other parameters
xed, higher Ya,in leads to better mass transfer and then the
moisture removal capacity is enhanced. As explained before,
DCOP has the same trend as D. Consequently, the desiccant
wheel can obtain a better absolute dehumidication capacity
and high DCOP with higher Ya,in. However, g decreases from
1.0
0.8
0.6
0.4
0.2
(a) 10
Moisture removal
Relative moisture removal efficiency
0.2
0.0
60
90
120
150
180
210
240
270
300
(b)1.0
DCOP
0.8
0.6
0.4
0.0
60
90
120
150
180
210
240
270
300
1011
Moisture removal
Relative moisture removal efficiency
0.8
0.6
0.4
0.2
0.0
0
20
25
30
35
(d)1.0
0.8
DCOP
1.0
(a) 10
0.6
0.4
0.2
0.0
40
20
25
30
(e) 10
Moisture removal (g/kg)
0.8
DCOP
15
0.6
0.4
0.2
1.0
Moisture removal
Relative moisture removal efficiency
0.8
0.6
0.4
0.2
0.0
20
25
30
35
40
0.0
1
0.8
0.6
0.4
0.2
0.0
10
15
20
25
30
(f) 1.0
0.8
DCOP
Moisture removal
Relative moisture removal efficiency
1.0
(c) 10
8
(b) 1.0
10
0.6
0.4
0.2
0.0
1
Fig. 5. Effect of temperature of process air on (a) dehumidication capacity (b) DCOP; effect of humidity ratio of process air on (c) dehumidication capacity (d) DCOP; effect
of ow rate of process air on (e) dehumidication capacity and (f) DCOP.
1012
Table 3
Total moisture removal rate with respect to different velocity of process air.
Velocity of process air (m/s)
1.5
2.5
3.5
4.5
5.5
1.85
2.41
2.66
2.78
2.88
Moisture removal
Relative moisture removal efficiency
0.8
0.6
0.4
0.2
0.0
50
60
70
80
90
100
110
(d)1.0
0.8
DCOP
1.0
(a) 10
0.6
0.4
0.2
0.0
120
10
25
(e) 10
Moisture removal (g/kg)
0.8
DCOP
20
0.6
0.4
0.2
0.0
1.0
Moisture removal
Relative moisture removal efficiency
0.8
0.6
0.4
0.2
0
50
60
70
80
90
100
110
0.0
1
120
Moisture removal
Relative moisture removal efficiency
0.8
0.6
0.4
0.2
0.0
15
20
25
(f) 1.0
0.8
DCOP
1.0
(c) 10
10
(b)1.0
15
0.6
0.4
0.2
0.0
1
Fig. 6. Effect of temperature of regeneration air on (a) dehumidication capacity (b) DCOP; effect of humidity ratio of regeneration air on (c) dehumidication capacity (d)
DCOP; effect of ow rate of regeneration air on (e) dehumidication capacity and (f) DCOP.
1013
1.0
Moisture removal
Relative moisture removal efficiency
0.8
0.6
0.4
0.2
0.0
0
10
20
30
(a) 10
40
In the following chapter, the optimal rotation speed xopt to obtain the biggest moisture removal with respect to different parameters is calculated and analyzed.
4.3. Analysis of optimal rotation speed
4.3.1. Effect of central angles of regeneration side
The effect of rotation speed on moisture removal D for different
central angles of the regeneration section is shown in Fig. 8. We
rst see the trend of rising D with increasing hr from Fig. 4a. In
addition, there always exist optimal rotation speeds to obtain the
biggest D, as expected. The value of xopt increases from 6 r/h to
20 r/h when hr increases from 60 to 180. The results show that
the desiccant wheel needs a larger angle of regeneration to complete the desorption process if it rotates faster.
4.3.2. Effect of conditions of process air
Fig. 9 presents the dehumidication rate in dependence of the
rotation speed x for different conditions of process air (Ta,in, Ya,in, ua,in,). We observe the basic trends from Fig. 5a, c, and e, but a
change in rotation speed allows to improving the effectiveness:
(a) xopt increases about 6 r/h when Ta,in changes from 20 C to
40 C. The extent of adsorption of the desiccant wheel is less
at a higher temperature as shown in Fig. 2. Therefore xopt
increases to lead the desiccant material away from the equilibrium state.
(b) xopt increases a little from 12 r/h to 16 r/h when Ya,in
increases from 10 g/kg to 25 g/kg. The mass transfer capacity
on the process side is improved with higher Ya,in, which
means that the velocity of adsorption increases. Then the
time for achieving adsorption equilibrium state is shortened,
which results in higher xopt.
(c) The optimal rotation speed xopt increases from 12 r/h to
20 r/h when the ow rate of the process air ua,in varies
between 1.5 m/s and 5.5 m/s. The adsorption rate increases
with more process air, and thus the desiccant wheel needs
to rotate faster to let the process side of the wheel move into
the regeneration side in time.
4.3.3. Effect of conditions of regeneration air
Fig. 10 summarizes the impact of rotation speed on moisture removal with different conditions of regeneration air (Tr,in, Yr,in, ur).
The main results show the options to improve the results from
Fig. 6a, c, and d:
(b) 1.0
90
120
150
180
D (g/kg)
DCOP
0.8
0.6
0.4
2
0.2
0
4
0.0
10
20
30
40
12
20
28
36
1014
(a) 10
D (g/kg)
(a) 10
0
4
12
20
28
36
12
(b) 10
Process air inlet humidity ratio (g/kg)
10
15
20
25
36
D (g/kg)
D (g/kg)
28
(b) 10
0
4
12
20
28
36
12
20
28
36
(c) 10
(c) 10
Flow rate of process air (m/s)
1.5
2.5
3.5
4.5
5.5
D (g/kg)
D (g/kg)
20
0
4
12
20
28
36
12
20
28
36
investigate the inuences of the main parameters on system performance and optimal rotation speed. In conclusion, the main results from this paper are summarized below:
(1) There exists an optimal central angle of regeneration section hr
at which the dehumidication coefcient of performance
(DCOP) is maximum. On the other hand, both the absolute
moisture removal D and relative moisture removal capacity g
increases with the increasing of hr. Therefore, hr between
100 and 160 is recommended under the simulated condition.
(2) The compound desiccant wheel performs well in a climate
with moderate temperature. At higher humidity ratio, the
compound desiccant wheel can obtain higher moisture
removal D and higher DCOP, but lower relative moisture
removal capacity g. To make a tradeoff between D and DCOP,
velocity of process air between 2.0 m/s and 3.5 m/s is
recommended.
(3) The effect of the regeneration temperature is similar to that
of hr and a value in the range of 8095 C is recommended. A
velocity of regeneration air between 2.5 m/s and 3.5 m/s is
preferable for a wheel with a thickness of 100 mm.
(4) An optimal rotation speed exists to obtain the biggest moisture removal D. Under the baseline condition as shown in
Table 2, the value is about 12 r/h. This optimal value
increases with the increasing of hr, Ta,in, Ya,in, ur,in, Tr,in and
ur,in, but decreases if Yr,in increases.
In a following paper, the model will be adopted to predict the
performance of a solar driven two-stage desiccant cooling system.
Acknowledgement
The authors acknowledge the support from Chinese Scholarship
Council in the form of an investigation fellowship and the support
from Chinese 863 Program (No. 2008AA05Z420).
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