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BMAT 4/CPM/P(II)/Qns
16.01.2011
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A. General
1. This booklet is your Question Paper containing 57 questions. The booklet has 27 pages.
2. This question paper CODE is printed on the right hand top corner of this sheet and on the back page
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IIT/B.MAT4/CPM/P(II) - 1
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INSTRUCTIONS:
TEST-II
CHEMISTRY
PART-I
SECTIONI
Single Correct Choice Type
This section contains 6 multiple choice questions. Each question has four choices (A), (B),
(C) and (D) for its answer, out of which ONLY ONE is correct.
1.
KMnO 4 reacts with ferrous oxalate in acidic medium. Here, 30 ml of 0.1 M KMnO 4 is
equivalent to
(A) 30 ml of 0.5 M FeC 2 O 4
(B) 50 ml of 0.1 M FeC 2 O 4
(C) 50 ml of 0.5 M FeC 2 O 4
(D) 20 ml of 0.1 M FeC 2 O 4
2.
The radioactive potassium 40 isotope decays to argon 40 with a half life of 1.2 109 years.
A sample of moon rock is found to contain 10 percent potassium 40 and 90 percent argon 40
by mass. The age of the rock in years is
(A) 1.73 10 9
(B) 4 10 9
(C) 2.76 10 9
(D) 1.2 10 9
3.
Which of the following compound when added to warm acidic solution of copper sulphate
does not form a black precipitate?
(A) Na2S
(B) H2S
(C) CH3CSNH2
(D) NH 4SCN
4.
To prevent the formation of oxides, peroxides and super oxides, the alkali metals are some
times stored in an inert atmosphere. Which of the following gases should not be used for
storing lithium?
(A) Ne
(B) Ar
(C) N2
(D) Kr
5.
In the precipitation titration of KCl against AgNO3, K2CrO4 is used as an indicator since,
AgCl is white coloured. End point is detected by appearance of deep yellow coloured
precipitate of Ag2CrO4. The minimum concentration of chromate ion required for detection of
end point is [Ksp of AgCl = 2.5 1010 and Ksp of Ag2CrO4 = 1.8 1012.]
(A) 7.3 103 M
(B) 7.3 104 M
(C) 7.3 105 M
(D) 2.3 104 M
IIT/B.MAT4/CPM/P(II) - 2
6.
CH3
is H2C = C (CH3)2
CH2 C CH2 C
CH3
(B) Terylene is a thermosetting polymer
(C) Nylon-2-nylon-6 is a biodegradable polymer
(D) Natural rubber is all cis-polyisoprene
CH3
SECTIONII
Integer Type
This section contains FIVE questions. The answer to each question is a single-digit integer,
ranging from 0 to 9. The correct digit below the question number in the ORS is to be bubbled.
F
C
C
7.
CHO
and mandelic acid,
Br
Br
PhCH(OH)CO2H.
8.
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O
H5 C 2 O C
O
C OC2H5
9.
LiAlH4
H5 C 2 O C
H+
Heat
O
Find the number of bonds present in the molecule (A).
10.
An equation of state for a non-ideal gas can be written as PVm = A + BP + 2CP 2 ; where Vm
is the molar volume and P is the gas pressure in atmosphere. B = 2.879 102 litre and
C = 14.98 104 in litre/atmosphere unit. Under the experimental condition, the pressure at
which PV-P curve will attain minimum is x atmosphere. Find the nearest integral value of x.
11.
If number of isomers of C5H8 (excluding stereomers) containing cyclic ring(s) are (X) and
total tautomers of C4H8O are (Y) , then what is the value of [(X ) (Y )]?
SECTIONIII
Paragraph Type
This section contains 2 paragraphs. Based upon each of the paragraphs 3 multiple choice
questions have to be answered. Each of these question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.
[Q]
C11H12O2
1. NaOH
2. H+
NaH
[S]
1. CH3MgBr (excess)
[R]
2. HBr
C
H
BrO
13 19
C11H12O2
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12.
OH
CHO
OH (B)
(A)
13.
OH (C)
(A)
CHO
O
OH
(B)
CHO
(D)
(C)
14.
(D)
Br
(A)
OH
Br
(B)
Br
OH (C)
OH
Br
(D)
OH
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reveal that the molecular weight of carboxylic acids such as acetic acid when dissolved in benzene
are approximately twice as large as those expected from the usual formulae, suggesting that these
acids are associated into double molecules in this solvent.
15.
The vant Hoff factor (i), is a measure of association or dissociation. The vant Hoff factor
for 0.1 M aqueous sodium chloride is 1.87. In magnesium sulphate the ionic interactions
(A) are same as that observed in sodium chloride.
(B) are weaker than that observed in sodium chloride.
(C) are stronger than that observed in sodium chloride.
(D) are not responsible for the (i) value.
16.
Mercuric iodide is added to an aqueous solution of potassium iodide. Identify the correct
statement(s)
(1) freezing point is raised.
(2) freezing point is lowered.
(3) freezing point and boiling point does not change.
(4) boiling point is raised.
(A) only (1)
(B) (1) and (4)
(C) (3) and (4)
(D) (2) and (4)
17.
A protein has been isolated as a salt with the formula Na 20 P (this notation means that there
are 20 Na + ions associated with a negatively charged protein P20). The osmotic pressure of
a 10.0 ml solution containing 0.225 g of the protein is 0.257 atm at 25C. The actual molar
mass of the protein from these data is approximately
(A) 2 105 g mol1
(B) 4.6 106 g mol1
3
1
(C) 2.0 10 g mol
(D) 4.5 104 g mol1.
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SECTIONIV
Matrix Type
This section contains 2 questions. Each question has four statements (A, B, C and D) given in
Column I and five statements (p, q, r, s and t) in Column II. Any given statement in
Column I can have correct matching with one or more statement(s) given in Column II. For
example, if for a given question, statement B matches with the statements given in q and r,
then for that particular question, against statement B, darken the bubbles corresponding to
q and r in the ORS.
18.
Column I
Column II
(A)
HF
(p)
(B)
CH3COOH
(q)
Weak acid
(C)
H3BO3
(r)
(D)
H3PO2
(s)
(t)
Monobasic acid.
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19.
Column I
Column II
(A)
(p)
CH3CH2CN
(B)
(q)
CH3CH2CONH2
(r)
NCCH2CN
(s)
CH 3 COONH 4
(t)
PhCOONH 4
(C)
(D)
IIT/B.MAT4/CPM/P(II) - 8
PHYSICS
PART-II
SECTION I
Single Correct Choice Type
This Section contains 6 multiple choice questions. Each question has four choices (A), (B),
(C) and (D) out of which ONLY ONE is correct.
20.
21.
B
5m
A
7m
(D) 30 2305 N
Your physical education teacher throws a ping-pong ball to you at a certain speed and you
catch it. The teacher is next going to throw you a basket ball whose mass is ten times the
mass of the ping-pong ball. You are given the following choices. You can have the basket
ball thrown with
I.
The same speed as the ping-pong ball
II. The same momentum, or
III. The same kinetic energy. Rank these choices from easiest to hardest to catch i.e. in
order of impulse needed to apply
(A) I, II, III
(B) III, II, I
(C) II, III, I
(D) All 3 are equally easy
IIT/B.MAT4/CPM/P(II) - 9
10
22.
n identical charges, q each, are placed at the corners of a regular nsided polygon of side a.
One charge is released from its position. Repelled by others, when it has reached far away
its kinetic energy is found to be E. A neighbouring charge is now released. When this
(A) E
23.
Kq 2
a
(B)
E+
Kq 2
a
n 1 Kq 2
n
a
(C) E
(D) E
+q
n 2 Kq 2
n 1 a
+q
D
q
d
24.
(A)
3q 2 d 2
, attractive
4 0 D 4
(B)
3q 2 d 2
, repulsive
4 0 D 4
(C)
3q 2 d 2
, attractive
2 0 D 4
(D)
3q 2 d 2
, repulsive
2 0 D 4
(A)
R
3 0
(B)
2R
3 0
(C)
+ + ++
+A
+
2R
+
+
+
+
B
+
+
+
+ +
+++
+
+
+
+
+
+
+
++
4R
3 0
(D)
2R
0
IIT/B.MAT4/CPM/P(II) - 10
11
25.
(A)
W
( 6 )
(B)
W
( 12 )
Rope
r
R
(C)
W
( 10 )
SECTION II
Integer Type
This section contains FIVE questions. The answer to each question is a single-digit integer,
ranging from 0 to 9. The correct digit below the question number in the ORS is to be
bubbled.
26.
27.
72
(Given = and l =
meters)
3
7
The system shown in the figure is in equilibrium and all
the blocks are at rest. Assume that the masses of the
strings, the pulley and the spring are negligible w.r.t. the
masses of the blocks and friction is absent. Find
acceleration of the block C, just after cutting the string 1.
(g = 10 m/s2)
B
h
String2
1kg B
5kg String1
C
g=10m/s2
Spring (massless)
2kg A
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12
28.
29.
A convex lens of focal length 15 cm is split into two halves and the two halves are placed at
a separation of 120 cm. Between the two halves of convex lens a plane mirror is placed
horizontally and at a distance of 4 mm below the principal axis of the lens halves. An object
AB of length 2 mm is placed at a distance of 20 cm from one half lens as shown in figure.
n
The final image of the point A is formed at a distance of mm from the principle axis.
3
Determine the value of n.
f=15 cm
B
2 mm
A
f=15 cm
20 cm
4 mm
120 cm
30.
l1
l2
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13
SECTION III
Paragraph Type
This section contains 2 paragraphs. Based upon the paragraph 3 multiple choice questions
have to be answered. Each of these questions has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.
U
A
U1
32.
33.
C
V
V0
31.
2V0
(D) 4R.
(D)
U1 U 0
log e 2
2
Assuming that the gas consists of a mixture of two gases, the gas is
(A) Monatomic.
(B) Diatomic.
(C) A mixture of mono and diatomic gases
(D) A mixture of di- and tri-atomic gases
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14
34.
35.
36.
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15
SECTION IV
Matrix Type
This section contains 2 questions. Each question has four statements (A, B, C and D) given
in Column I and five statements (p, q, r, s and t) in Column II. Any given statement in
Column I can have correct matching with one or more statement(s) given in Column II. For
example, if for a given question, statement B matches with the statements given in q and r,
then for that particular question, against statement B, darken the bubbles corresponding to
q and r in the ORS.
37.
y
T
m
m
Column I
Column II
zero
> mg
(r)
< mg
(s)
= mg
(t)
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16
38.
y
Q
R
v
z P
(A)
Column I
B1 = 2i + 2 j + 4k, B2 = 0
Column II
(p)
potential VQ > VP
(B)
B1 = i + 3 j 2k, B2 = 0
(q)
potential VP > VQ
(C)
B1 = 0, B2 = 4i + 2 j + 9k
(r)
no induced current
(D)
B1 = 0, B2 = i 2 j 2k
(s)
(t)
IIT/B.MAT4/CPM/P(II) - 16
17
MATHEMATICS
PART-III
SECTION - I
Single Correct Choice Type
This Section contains 6 multiple choice questions. Each question has four choices (A), (B),
(C) and (D) out of which ONLY ONE is correct.
39.
The number of positive integers that divides 101005 but not 101004 is
(A) 2012
(B) 2010
(C) 2009
(D) 2011
40.
The sides of a triangle are the roots of the cubic equation x 3 13 x 2 + 54 x 72 = 0 then the
area of the triangle in square units is
(A)
41.
1
455
2
(B)
1
455
4
(C)
1
394
2
(D)
1
394
4
4z 2 8z + 3
2
= is
6z + z 2 4
3
2
,z=
2
3
3
2
(B) The straight line joining the point z =
,z=
2
3
(A) The straight line joining the point z =
3
2
and z =
2
3
3
2
and z =
2
3
IIT/B.MAT4/CPM/P(II) - 17
18
/ 2
42.
Given
sin x
dx = k , then the value of the definite integral
1 + sin x + cos x
/ 2
dx
dx
1 + sin x + cos x
is
(A)
43.
44.
1
k
2
k
2
(B)
dx 2 dx 2
(A) 1, 4
(B) 4, 2
(C)
degree
2k
2
(D)
respectively
of
the
(C) 4, 4
+k
2
differential
equation
(D) 4, 1
(A) 7 f (3) 26
(B) 4 f (3) 15
(C) 1 f (3) 20
(D)
28
35
f (3)
3
3
SECTION II
Integer Type
This section contains FIVE questions. The answer to each question is a single-digit integer,
ranging from 0 to 9. The correct digit below the question number in the ORS is to be
bubbled.
45.
46.
(x
)(
19
)(
8
+ px 2 + 2 x 5 x 2 + qx 41 x 4 x 3 + x 7 = x 97 + 391x 96 + a 95 x 95 + a 94 x 94 +
a1 x + a 0 be an identity, where p, q, a95 ... a 0 are integers. Compute the smallest positive
value of p.
Let
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19
47.
Two rays begin at point A and form an angle of 43 with one another. Lines l1 , l 2 , l 3
(no two being parallel) each form an isosceles triangle with the original rays. If is the
largest angle of triangle formed by l1 , l 2 and l 3 then find value of 8 cos 2 ( 9 ) .
48.
I1 =
49.
The ordered pairs of number (a, b) such that | a + bt + t 2 | 1 for 0 t 1 fill a certain
region in the a b plane. If A is the area of this region such that
SECTION - III
Paragraph Type
This section contains 2 paragraphs. Based upon the paragraph 3 multiple choice
questions have to be answered. Each of these questions has four choices (A), (B), (C) and
(D) out of which ONLY ONE is correct.
Paragraph for Question Nos. 50 to 52
Using three basic colours (Red, Blue, Green) different colours are made by mixing these
two or more colours in equal proportion. The n vertical stripes are painted by all colours
available, such that no two consecutive stripes have the same colour.
50.
(A) t n+1 = 6t n
51.
(B) t n+1 = 7t n
(C) t n+1 = 3t n
(D) t n+1 = 2t n
The number of ways of painting n stripes such that only alternate stripes are painted by a
basic colour (n is odd) is
(A) 3
n +1
2
.4
n 1
2
(B) 7.12
n +1
2
(C) 3
n 1
2
.4
n +1
2
(D) 7.12
n 1
2
IIT/B.MAT4/CPM/P(II) - 19
20
52.
If n stripes are painted such that no two consecutive stripes have any basic colour common,
then number ways of painting n stripes is
n 1
n 1
n 1
n 1
1
1
(A) 1 + 2
+ 1 2
(B)
1 2
1+ 2
2
2
(C)
) + (1 2 )
1
1+ 2
2
) (1 2 )
3
1+ 2
2
(D)
The value of x 2 is
(A) 3
54.
(C)
15
2
(D)
17
2
(A) (3, 1)
55.
(B) 4
xn
is
n 2 n
(A) 4
15
(B) , 1
2
31
(C) , 1
4
(B) 0
(C) 1
(D) 2
The lim
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21
SECTION - IV
Matrix Type
This section contains 2 questions. Each question has four statements (A, B, C and D)
given in Column I and five statements (p, q, r, s and t) in Column II. Any given statement
in Column I can have correct matching with one or more statement(s) given in Column II.
For example, if for a given question, statement B matches with the statements given in q
and r, then for that particular question, against statement B, darken the bubbles
corresponding to q and r in the ORS.
56.
Column I
(A)
(B)
(C)
For the points A(0, 0), B(1, 0), C(0, 2), D(3, 4), there exist a (r) 4
point P such that PA + PB + PC + PD is minimum. The
number of such point P may be
(D)
P is a point on the plane of the square ABCD such that each (s) 7
of PAB, PBC, PCD and PDA is an isosceles triangle.
(t) 9
The number of such point P can be
Column II
IIT/B.MAT4/CPM/P(II) - 21
22
57.
Column I
2010
(A)
Column II
(p) 2
r =1
to
(B)
(C)
(D)
f(
2 n 1
r =1
2r
( 3)
can be (where n N )
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24
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25
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27
Name: .
Enrollment No.:
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
IIT/B.MAT4/CPM/P(II) - 27