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2 out of 2 points
FALSE
Correct Answer:
FALSE
Temperature measures the average kinetic energy of molecules in a
substance.
Response
Feedback:
Question 2
2 out of 2 points
Two objects in contact are in thermal equilibrium if their particles possess the same
average kinetic energy.
Selected Answer:
TRUE
Correct Answer:
TRUE
When objects are in thermal equilibrium, they are at the same
temperature.
Response
Feedback:
Question 3
3 out of 3 points
Question 4
2 out of 2 points
If the change in enthalpy is negative, H is negative and heat is released during the
change.
Selected Answer:
TRUE
Correct Answer:
TRUE
Response
Feedback:
Question 5
2 out of 2 points
TRUE
Correct Answer:
TRUE
Response Feedback:
Question 6
2 out of 2 points
The specific heat of a substance is the heat that must be absorbed to increase the
temperature of 1 gram of a substance by 1 degree Celsius.
Selected Answer:
TRUE
Correct Answer:
TRUE
Response Feedback:
Question 7
3 out of 3 points
Given 13.5 grams of substance Z, if the substance absorbs 36 kilojoules of energy and the
temperature increases by 25 degrees Celsius, what is the specific heat of the substance?
Selected Answer:
Using the equation, q = mcT, and by rearranging the equation, you can
determine the specific heat of the substance. It is important to make sure units
cancel, which includes the need to convert from kilojoules to joules.
Question 8
3 out of 3 points
Given 16.2 grams of substance Y, if the substance absorbs 2722 joules of energy and the
specific heat of the substance is 9.22 J/gC, what is the final temperature of the substance
44C
Correct Answer:
44C
Response
Feedback:
Using the equation, q = mcT, and by rearranging the equation, you can
calculate the change in temperature. From this and the initial temperature,
you can then determine the final temperature.
Question 9
Needs Grading
A calorimeter is used in an experiment. The initial temperature of the system was found to
be 32 degrees Celsius. The final temperature was found to be 48 degrees Celsius. Discuss
the direction of transfer of energy and the resulting change in enthalpy (if any).
Selected
Answer:
Correct
Answer:
Metal fragments released heat into the water raising the temperature of the
water.
Question 10
2 out of 2 points
Two substances have different Hvaporization values. If given the same number of moles of
each substance, and assuming the same amount of heat is applied to both substances, the
substance with a higher Hvaporization value will convert from a liquid to a gas more quickly.
Selected Answer:
FALSE
Correct Answer:
FALSE
Response The Hvaporization is the amount of heat necessary per mole of substance to
Feedback: convert a substance from a liquid to a gas (or Hcondensation for gas to
liquid). The substance with a higher Hvaporization will absorb more heat before
converting from a liquid to a gas.
Question 11
0 out of 3 points
What amount of heat is exchanged when 16.02 grams of substance Y goes from a gas at
62 degrees Celsius to a liquid at 62 degrees Celsius? Boiling point of substance Y = 62
degrees C; Hvaporization = 9.22 J/mol; Hfusion = 2.77 J/mol. MWsubstance y = 14.77 g/mol.
Selected Answer:
3.00 x 100 J
Correct Answer:
10.0 J
Response
Feedback:
Using the equation, q = H*mol, one can determine the amount of heat
absorbed or released to allow phase change to occur.
Question 12
2 out of 2 points
The equation, DF
Selected Answer:
TRUE
Correct Answer:
TRUE
Response
Feedback:
When heat is added as a product, the reaction is exothermic. We also see heat
written on the reactant side, but with a negative sign indicating it must be
removed in order for the reaction to proceed in the forward direction.
Question 13
3 out of 3 points
Which of the following statements concerning the reaction shown below are true?
P4 (s) + 3O2 (g)
P4O6 (s)
H = 1640 kJ
heat is absorbed
heat is released
rxn is exothermic
rxn is endothermic
products have higher enthalpy content than reactants
reactants have higher enthalpy content than products
Selected Answer:
Question 14
3 out of 3 points
Which of the following statements concerning the reaction shown below are true?
AgBr (s) + Cl2 (g)
AgCl (s) + Br2 (l)
H = 27.6 kJ
Heat is absorbed.
Heat is released.
Rxn is exothermic.
Rxn is endothermic.
Products have higher enthalpy content than reactants.
Reactants have higher enthalpy content than products.
Selected Answer:
Question 15
3 out of 3 points
The enthalpy change for the reaction, 3CO (g) + 2Fe2O3 (s)
Fe(s) + 3CO2 (g), can be
calculated from Hf values for each reactant and product. Which substance or substances
in this equation have a Hf value equal to 0.0 kilojoules?
Selected Answer:
Fe(s)
Correct Answer:
Fe(s)
Response
Feedback:
Every element in its standard state has its enthalpy of formation value set to
zero kilojoules. Pure solid metals and diatomic gases, such as O2 and Cl2, are
in their standard states.
Question 16
3 out of 3 points
Given the enthalpies of reaction below, determine the enthalpy change for the reaction:
N2O (g) + NO2 (g)
3NO (g).
N2 (g) + O2 (g)
2NO (g)
H = +180.7 kJ
H = -113.1 kJ
2N2O (g)
O2 (g)
H = -163.2 kJ
2N2 (g) +
Selected Answer:
155.6 kJ
Correct Answer:
155.6 kJ
Response To complete this problem, it is necessary to reverse equation two, which
Feedback: changes the sign of the enthalpy value. Then, it is also necessary to divide
equation two and three by 2, in order to obtain the given equation. This will
reduce both their enthalpy values by half.
Question 17
2 out of 2 points
According to the first law of thermodynamics, energy can be transferred as heat or work.
Selected Answer:
TRUE
Correct Answer:
TRUE
Response
Feedback:
Question 18
2 out of 2 points
Heat flow transfer cannot occur between two objects with the same molecular average
kinetic energy.
Selected Answer:
TRUE
Correct Answer:
TRUE
Response
Feedback:
If two objects possess the same molecular average kinetic energy, then
heat will not transfer from one object to the other.
Question 19
3 out of 3 points
II only
Correct Answer:
II only
Response
Feedback:
Heat will transfer between objects only if there is a difference in the molecular
average kinetic energy between the two objects, and the object transferring
the heat has greater thermal energy.
Question 20
2 out of 2 points
The law of conservation of energy maintains that the total amount of energy in the
universe remains the same during all energy changes.
Selected Answer:
TRUE
Correct Answer:
TRUE
Response
Feedback:
In regards to this law, energy cannot be created nor destroyed, but only
transferred.
Question 21
0 out of 2 points
FALSE
Correct Answer:
TRUE
Response
Feedback:
Question 22
3 out of 3 points
can provide free energy that can be used for work elsewhere
Correct Answer:
can provide free energy that can be used for work elsewhere
Response In spontaneous reactions, the reactants generally possess more concentrated
Feedback: energy and more thermal energy than the products. The energy is released into
the surroundings and can be used as energy to drive another reaction that
might be non-spontaneous.
Question 23
2 out of 2 points
TRUE
Correct Answer:
TRUE
Response
Feedback:
Question 24
3 out of 3 points
Question 25
2 out of 2 points
A reaction will only be spontaneous if the change in enthalpy is more negative than the
product of TS is positive.
Selected Answer:
TRUE
Correct Answer:
TRUE
Response
Feedback:
Question 26
3 out of 3 points
II and III
Correct Answer:
II and III
Response
Feedback:
Question 27
0 out of 2 points
If reactant particles collide in the proper orientation, the collision will be effective and the
reactants will form products.
Selected Answer:
TRUE
Correct Answer:
FALSE
Response
Feedback:
Question 28
2 out of 2 points
Pulverizing a solid reactant from chunks into a powder can affect the rate of the chemical
reaction.
Selected Answer:
TRUE
Correct Answer:
TRUE
Response
Feedback:
By pulverizing the solid from chunks into powder form, you are increasing
the surface area, which increases the rate of the chemical reaction.
Question 29
Needs Grading
Explain how changing the pressure can affect the rate of reaction.
Selected Increasing the pressure on a reaction involving reacting gases increases the rate of
Answer: reaction. Changing the pressure on a reactoin which involves only solids or liquids has no
effect on rate.
Correct
Answer:
Question 30
2 out of 2 points
In an energy diagram for an exothermic chemical reaction, the total energy change is the
difference in energy between the energy of the reactants and the energy of the products.
Selected Answer:
TRUE
Correct Answer:
TRUE
Response
Feedback:
The overall energy (or enthalpy) change is the difference between the energy
of the products and the energy of the reactants. The activation energy does
not affect the overall energy change.
Question 31
3 out of 3 points
Using the enthalpy diagram below, determine which of the following is true.
Selected Answer:
The reactants possess more energy than the products. This describes an
exothermic reaction.
Question 32
3 out of 3 points
Question 33
3 out of 3 points
Correct
Answer:
Response
Feedback:
Question 34
2 out of 2 points
An increase in pressure will cause a shift of equilibrium towards the side of the reaction
with the least moles of gas.
Selected Answer:
TRUE
Correct Answer:
TRUE
Response
Feedback:
Question 35
3 out of 3 points
For this equilibrium reaction, which of the following describes how the given stress affects
the equilibrium position?
2SO3 (g) + heat
Selected Answer:
Removal of SO2 reduces the concentration of SO2. In this case, the shift of
equilibrium will be to the right, so that the system can replace the lost SO 2.
Question 36
3 out of 3 points
For this equilibrium reaction, which of the following describes how the given stress affects
the equilibrium point?
N2 (g)+ O2 (g)
2NO (g)
Selected Answer:
change in pressure will not affect the position of equilibrium because the moles
of gas in the reactants and products are equal.
Question 37
2 out of 2 points
FALSE
Correct Answer:
FALSE
Response Because the term, concentration, is not used for solids or liquids, neither solids
Feedback: nor liquids are included in the equilibrium expression. The concentration of
Question 38
3 out of 3 points
Given the following information, determine the Keq for the following reaction: COCl2 (g)
CO (g) + Cl2 (g)
Substance
Concentration (M)
equilibrium
CoCl2
1.8 x 10-3
CO
1.2 x 10-2
Cl2
1.2 x 10-2
Selected Answer:
8.0 x 10-2
Correct Answer:
8.0 x 10-2
Response The equilibrium expression should be written using only compounds in aqueous
Feedback: solution or gas phases. The coefficients shown in the balanced chemical