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Note: The source of the technical material in this volume is the Professional
Engineering Development Program (PEDP) of Engineering Services.
Warning: The material contained in this document was developed for Saudi
Aramco and is intended for the exclusive use of Saudi Aramcos employees.
Any material contained in this document which is not already in the public
domain may not be copied, reproduced, sold, given, or disclosed to third
parties, or otherwise used in whole, or in part, without the written permission
of the Vice President, Engineering Services, Saudi Aramco.
Chapter : Chemical
File Reference: CHE-104.06
Engineering Encyclopedia
Section
Page
INFORMATION ............................................................................................................... 4
INTRODUCTION............................................................................................................. 4
PRINCIPLES OF CRUDE OIL DESALTING ................................................................... 5
Background ..................................................................................................... 5
Source of Salts and Contaminants in Crude ................................................... 6
Contaminant Tests .......................................................................................... 8
Desalting Process ......................................................................................... 10
Theory ........................................................................................................... 14
Typical Desalter Performance ....................................................................... 19
DETERMINING desalter Process Variables and OPTIMUM Operating CONDITIONS. 21
Oil Feed Quality ............................................................................................ 21
Temperature.................................................................................................. 21
Pressure........................................................................................................ 22
Wash Water Rates, Quality, Injection Points, and Sources........................... 23
Wash Water/Oil Mixing.................................................................................. 24
Electric Field.................................................................................................. 28
Oil/Water Residence Times........................................................................... 32
Chemical Additives........................................................................................ 34
DESALTER DESIGN FEATURES................................................................................. 36
Conventional Low Velocity Units ................................................................... 36
Natco Dual Polarity ....................................................................................... 41
Petreco Bielectric Design .............................................................................. 42
Howe-Baker Edge Design ............................................................................. 45
Mud Wash System ........................................................................................ 46
Electrical Components .................................................................................. 47
Entrance Bushings................................................................................... 47
Transformers and Reactors ..................................................................... 49
Electrical Instrumentation......................................................................... 50
Interface Level Control .................................................................................. 51
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Addendum D:
Table of Figures
Figure 1. Basic Sediment and Water............................................................................. 9
Figure 2. Single-Stage Desalting Flow Diagram .......................................................... 11
Figure 3. Two-Stage Desalting Flow Diagram ............................................................. 12
Figure 4. Three-Stage Electrostatic Desalting System ................................................ 13
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Table
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INFORMATION
INTRODUCTION
This module addresses the importance of desalting in crude oil
production and refining. Crude oil desalting involves the process
separation of salt, sediment, and slugs of water. The module
begins by covering the principles of crude oil desalting. This
section provides some background on the desalting process,
the source of salts and contaminants in crude oil, and typical
desalter performance.
The second section covers the various process variables
affecting crude oil desalting and operating guidelines. These
variables are: oil feed quality, temperature, pressure, wash
water rates and quality, wash water/oil mixing, electric field,
gravity settling, and chemical additives.
The third section covers desalter design features. A description
of conventional low velocity units, electrical components, and
interface level control is presented. A procedure to estimate the
size of desalters based on Saudi Aramco data is also
presented.
The fourth section covers performance evaluation and
troubleshooting. The various performance indices and analytical
techniques are discussed. Common performance problems and
operating difficulties are described along with associated
corrective measures.
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Greater throughput
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Brine
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The three common salts found in crude oil and their typical
compositions are:
Volume %
Salt
Sodium Chloride (NaCl)
75%
15%
10%
wppm/ptb
45
3.56
35
3.36
25
3.04
10
2.85
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Contaminant Tests
Refineries classify contaminants into four major groups: water,
salt, sediment, and metals. It is the function of the desalter to
remove as much of these contaminants as possible. Poor
removal of these contaminants cause upsets throughout the
refinery. For instance, slugs of water can blow out crude tower
trays and reduce the effective tower pressure which can lead to
off-spec products. Salts cause exchanger fouling, furnace
coking and corrosion especially in the crude unit. Sediments can
cause fouling and erosion in high velocity areas such as piping
bends. Metals can poison catalysts.
Laboratory monitoring methods include the following:
Contaminant
Laboratory Test
Water
Salt
Conductivity
1. Titration, 2. Chromatography, 3.
Sediment
Metals
Spectroscopy
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Metals are not usually monitored in crude oil but are monitored
in refinery feed stocks to other units.
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Desalting Process
Initial "oil treating" or dehydration of crude oil production usually
takes place in the oil field to reduce the volume of water moving
through the transportation system. Most crudes can be
electrostatically dehydrated to the 0.1% to 0.5% BS&W. Some
heavier (under 20 API) and more viscous crudes (greater than
18 cSt at operating temperature) can only be reduced to the
0.5% to 5.0% BS&W range. Depending on the crude oil source,
the amount of salt that is acceptable for export markets is
typically 10 ptb. While this is not low enough to achieve the
fouling and corrosion control desired in a refinery, it is low
enough for single-stage desalting at the refinery to achieve
acceptable salt levels.
Electrostatic desalting is used to remove salts and particulates
from crude oil. The crude oil-brine mixture is contacted with
wash water using a mix valve just upstream of the desalter
vessel. Salt is extracted from the brine into the wash water
droplets. The electric field in the desalter enhances water
droplet coalescence so that water/oil separation requires much
less residence time, and hence a smaller vessel, than is needed
for unenhanced settling. Small quantities of desalting aids are
often added to enhance contacting effectiveness, droplet
coalescence, and water separation. Desalted oil is removed
from the top of the desalter vessel and the briny water from the
bottom.
The most efficient place to remove salt from crude oil is usually
at the refinery because the desalting can be done at the
optimum temperature. Field desalters do not often have much
control over the operating temperature because heating the
crude adds a significant cost. Heating the crude for refinery
desalting adds no additional cost since the crude must be
heated to process it in the atmospheric crude column (Atm.
Col.).
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Theory
When two or more substances come in contact with one
another, they may:
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MACROSCOPIC
Factor/Property
Favors Demulsification
Favors Emulsification
density
time
vessel size
large vessel
small vessel
flowrates
low flowrates
light flowrates
temperature
high temperature
low temperature
pressure
--
--
droplet size
large size
small size
droplet attraction
opposite charges
same charges
MICROSCOPIC
Factor/Property
Favors Demulsification
Favors Emulsification
surfactants
small to none
large quantities
surface charge
little to no charge
high charge
contaminants
small to none
large quantities
pH
acidic to neutral in
most systems
Table 1. Emulsion/Demulsification Factors
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SGoil ) d2
SG
= specific gravity
d
V
= viscosity
= diameter of droplet
= settling velocity
Eqn. 1
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The water droplet has no net charge. When this water droplet is
placed in an electrostatic field, the droplet distorts (elongates).
In addition, the ions in solution migrate to one side as shown fin
Figure 8.
Where:
F=
K E2 r 6
a4
K
E
r
a
=
=
=
=
Eqn. 2
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Figure 8. Surfactants
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Temperature
For every desalter installation and crude blend processed, there
is an optimum desalter operating temperature. Crude is heated
to the desired refinery desalter operating temperature by the
portion of the crude preheat exchanger train upstream of the
desalter. The location in this preheat exchanger train is
determined by the desired desalter operating temperature.
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Pressure
Desalter operating pressure must be maintained at a sufficiently
high level to prevent vaporization. If a vapor space develops in
the vessel, a safety float switch or low level switch will
automatically de-energize the electrodes and effectively shut
down the desalter. Any vaporization results in erratic operation
and a loss in desalting efficiency by generating turbulence that
hinders coalesced water droplet settling in the desalter. The
required pressure depends on the desalter operating
temperature and crude type. Desalters typically operate at
pressures between 65 and 300 psig.
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Electric Field
The purpose of the electric field in the desalter is to dehydrate
(demulsify) the water/oil dispersion after the mixing operation.
This is accomplished by polarizing the water droplets, thereby
enhancing droplet coalescence and greatly increasing the
water-settling rate in the desalter. Most desalters employ ac
fields with an applied voltage in the range of 15,000-25,000 V.
There are actually two electric fields in a low velocity desalter.
The field between the lower electrode and the water interface is
where most of the dehydration occurs. The second field
between the two electrode grids provides a polishing action on
the dispersion. The voltage gradient in these fields is generally
between 1,000 and 5,000 V/in. A low interface level will result in
a significant reduction in the voltage gradient and poor
dehydration / desalting.
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K E2 r 6
a4
Eqn. 3
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Where:
F
attractive force
voltage gradient
droplet radius
Eqn. 4
Where:
CVG =
constant
surface tension
droplet radius
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The relation indicates that as the drop size becomes larger, the
voltage at which redispersion occurs becomes smaller. Low
values of interfacial tension between water and oil will also
increase the tendency for electrical dispersion. Practically,
gradients above 12,000 V/in. have been found to cause larger
droplets to redisperse and, therefore, are usually avoided in
commercial desalter operations. Some desalter designs use
high voltage gradients to promote mixing to replace some or all
of the mixing valve function.
SG oil ) d 2
Eqn. 1
Where:
SG
specific gravity
viscosity, cP
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Chemical Additives
The final major control variable in the desalting process is the
desalter chemical additive. This additive may be referred to as
a demulsifier, emulsion breaker, or surface-active agent. The
desalting chemical works at the oil/water droplet interface,
disrupting the emulsion stabilizing film surrounding the droplets
and allowing them to coalesce more easily. It should be a
multifunctional additive, formulated to assist in removing solids
from the crude and produce oil-free effluent water and
adequately dehydrated crude. This distinguishes desalting
chemicals from oil-field demulsifies whose sole purpose is to
dewater crude oil.
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35
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Oil/Water Interface
Control
Transformer
Oil Outlet
Electrodes
Vessel
Water Outlet
Emulsion Inlet
Distributor
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Two designs of oil emulsion inlet are in use that reflects the
differing design philosophies of the vendors. Howe-Baker
prefers a drilled pipe distributor that discharges the crude as
horizontal jets into the primary coalescence zone located above
the water interface but below the lower electrode (Figure 16).
Petreco and Natco use an inverted trough flow distributor
located underneath the water-oil interface. The trough has
holes on the sides that allow the crude to trickle out (Figure 17).
Conceptually, the trough design can better handle water slugs in
the crude feed. However, the trough design also requires that
all oil in the feed pass through both the water phase and wateroil interface, possibly hindering water droplet settling.
Upper
Electrode
Lower
Electrode
Secondary
Coalescence
Region
Oil
Water
Crude
Emulsion
Inlet
Primary
Coalescence
Region
Brine Outlet
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Desalted
Crude Outlet
Upper
Electrode
Secondary
Coalescence
Region
Lower
Electrode
Primary
Coalescence
Region
Crude
Emulsion
Inlet
Brine Outlet
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Transformers
wyo
Secondary
Delta
Primary
Upper
Electrode
3-Segment
Lower
Electrode
AV Electrodes
DV Bushings
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Transformers
wye
Secondary
Delta
Primary
?V Electrode = 1.732
?V Bushings
3-Segment
Electrodes
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45
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Electrical Components
Desalters utilize electrical components that have been
developed specifically for desalter use, based on years of
operating experience and testing.
Entrance
Bushings
47
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48
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Transformers and
Reactors
49
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Electrical
Instrumentation
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for 0.04
50
Eqn. 6
Where:
BPD =
ft2
log10 =
/ =
55
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Analytical Procedures
Proper evaluation of desalter performance requires analysis for
BS&W and salt in the feed and desalted oil. The water
contained in this oil, as determined by distillation, may also be
desirable to differentiate between dissolved and entrained water
in the oil. Since serious errors can be introduced in the
efficiency calculations, and therefore the evaluation and
troubleshooting process, by inaccurate analytical results, it is
important that reliable procedures be carefully followed to obtain
the necessary data.
BS&W should be determined by the centrifuge method, using
water saturated toluene and demulsifier. The analysis should
be performed at about 140F. A comprehensive test procedure
is described in the Manual of Petroleum Measurement
Standards (MPMS). The elevated temperature and demulsifier
addition are essential to obtain reproducible results. BS&W
analyses determine only the entrained water in the sample at
the analysis temperature. Total, entrained plus dissolved, water
is best determined by the distillation method from the MPMS.
The most reliable method for determining the salt content in the
oil is by the extraction of samples with water in the presence of
suitable solvents, and analysis of the aqueous extract. The
salts of most concern to the refinery are the chlorides, because
they cause corrosion at crude unit conditions. The aqueous
extract is therefore analyzed for chlorides by titration with silver
nitrate solution.
Shutdown/Startup Procedures
Typical startup and shutdown procedures are shown in
Addendum A.
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SUMMARY
This module addressed the importance of desalting in crude oil
production and refining. The first section covered principles of
crude oil desalting. The following key points were discussed:
Salt removal.
Sediment removal.
Temperature.
Pressure.
Electric field.
Chemical additives.
Voltage gradient.
Drop size.
Desalter voltage.
-
15,000 to 25,000 V.
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Drop size.
Oil viscosity.
Oil:
15 to 20 minutes.
Water:
80 to 300 minutes.
Zones in a desalter.
-
Oil viscosity.
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Dehydration efficiency.
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WORK AIDS
Work Aid 1:
Figure 1A.
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Work Aid 2:
Work Aid 2A:
D30
314
D29
SH
GOSP-3
SH
GOSP-4
SH
GOSP-6
Plant 15
G.26
G.57
RT REF.
Safaniya
Natco
Natco
Natco
Petrolite
1000 B/SD
330
330
330
250
Diameter, ft
14
14
14
16
Plant No.
Vendor
Crude Oil Capacity,
64B
U20
Safaniya
ABQ
GOSP-2
ABQ
GOSP-6
Petreco
Natco
Mitsubishi
Natco
162
162
(per train)
(per train)
165
220
14
14
12
12
Length (T-T), ft
148
148
148
140
148
148
87
118
Operating Temp., F
90
90
90
250
142
142
90
175
API at 60F
35.3
35.3
35.3
28.1
27.7
27.7
0.8374
0.8374
0.8374
0.82
0.860
5.4
5.4
5.4
2.62
2(2)
2(2)
2(2)
single volt
Crude Gravity,
Viscosity, cP
at Cond.
41
35
(at cond.)
(at
cond.)
0.860
0.82
0.85
8.75
8.75
4.3
6.4(1)
3(3)
3(3)
2(2)
2(2)
single volt
single volt
Single volt
150
100
100
75
9963
34807
25540
3-10
20947
20947
9180
< 10
< 10
< 10
< 10
< 10
< 10
< 10
15
30
30
0. 5
30
30
17.4
16.5
No. of Vessels
- in series
- in parallel
(no. of trains)
Electrical Config.
single volt
Transformers
- number
- size, kVA
Salt Content, ptb
- inlet
- outlet
Inlet Water Content,
vol%
Notes:
(1) Estimated viscosities.
(2) One electrostatic dehydrator vessel and one desalter vessel in series.
(3) One electrostatic dehydrator vessel and two desalter vessels in series.
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Refinery
Jeddah
Rabigh
Ras Tanura
Riyadh #1
Riyadh #2
Yanbu
Plant No.
CDU-2
5300
15
RCD
R110
J103
Vendor
Petreco
Petrolite
Petreco
Howe-Baker
Howe-Baker
Petreco
42
82 x 4
275
60
100 (1)
85 x 2 (2)
12
10
14
12
12
12
36
80
86
60
100
61
No of Vessels
- in series
Single
Single
Dual
Single
Single
Single
- size, kVA
60
60
75
40
60
60
- Fahrenheit
220-240
230
280-310
185
195
255-275
- Celsius
105-116
232
138-155
85
90
125-135
32
33
34
33
33
33
0.85
0.86
0.746-0.8
0.845
0.845
0.859
1.3
1.2
0.94
1.9
1.7
1.0
2-6
1-3
2-6
2-6
2-6
1-3
0.2-0.8
1-2
1-3
1-4
4-10
1-2
- Crude Charge
0.05
0.05
0.5
0.5
0.05-0.1
- Wash Water
4-5
4.5-6
2-3
3-5
3-4.5
- Crude Outlet
0.2-0.4
0.1-0.2
0.05
0.1
0.1
0.2-0.4
Electrical Configuration
Transformers
Operating Temp., F
Notes:
(1) Design capacity 100 MBD Operating capacity 146 MBD.
(2) Design capacity 85 X 2 MBD Operating capacity ranges from 60 x 2 MBD to 110 x 2 MBD.
(3) Viscosities are approximate.
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Figure 2B.
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Figure 2C.
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Figure 2D.
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Work Aid 3:
Index
Desalting Efficiency
Dewatering Efficiency(1)
Symbol
Definition
Si So
x 100
Si
> 90%
W w + Wi Wo
x 100
Ww + Wi
> 95%
Mixing Efficiency(2)
Optimum Salt Content(3)
Mixing Index
Process Efficiency
Good
Performance
Value
S
Wo i 1
So
x 100
W
W o (S i + 0.01 W w S w
Ww + Wi
MI
A
So
Si So
x 100
Si A
> 0.90
Where:
Si = Salt content of crude oil charge, ptb of NaCl
So = Salt content of desalted oil, ptb of NaCl
Sw = Salt content of wash water, ptb of NaCl
Wi = Water content of crude oil charge, vol%
Wo = Water content of desalted oil, vol%
Ww = Wash water rate, vol% of crude oil charge rate
Notes: (1)
(2)
(3)
Use fresh water rate and salt content for Ww and Sw, respectively.
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Work Aid 4:
Work Aid 4A:
Possible Causes
Corrective Action
Decrease throughput.
Increase operating temperature.
Blend heavy oil with lighter oil.
Inadequate mixing.
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Possible Causes
Corrective Action
P.
Electrical failure.
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Possible Causes
Corrective Action
P.
Sludge in desalter.
Excessive asphaltenes in
crude.
Insufficient or ineffective
demulsifier addition.
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Possible Causes
Corrective Action
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Possible Causes
Corrective Action
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Possible Causes
Corrective Action
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Possible Causes
Corrective Action
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GLOSSARY
Atm. Col.
APS
BS&W
Demulsification/
breaking an emulsion
Demulsifying
Desalting
Efficiency
dewatering
efficiency
Emulsification/
creating an emulsion
Emulsifying
kVA
Kilovolt-ampere.
kW
Kilowatt.
Mixing Efficiency
Mixing Index
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Oil-In-Water
Emulsion
Optimum Salt
Content
Process Efficiency
ptb
Stable Emulsion
Water-In-Oil
Emulsion
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REFERENCES
(1)
Bartley, D., "Heavy Crudes, Stocks Pose Desalting Problems, Oil & Gas Journal,
February 1, 1982.
(2)
(3)
(4)
(5)
Vendor Brochures.
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ADDENDUMS
Section ...................................................................................................................... Page
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Make a thorough inspection of the drum before it is closed up. Check all
instrument taps to be sure they are not plugged.
2.
3.
Check that man way cover has been installed and all blinds removed.
4.
Steam to atmosphere for at least one hour to remove air and warm up.
5.
6.
8.
Vent desalter at high point; slowly fill with crude. When full, open inlet valve wideopen and close vent valve. Vent valve control may have to maintain a minimum
pressure in the desalter to prevent vaporization.
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9.
10. Slowly close desalter bypass and let pressures and temperature stabilize.
12. Start wash water to Desalter and start Desalter Water Booster Pump to preheat
train.
13
Close mix valve to give the desired pressure drop for optimum desalting.
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1.
Open the Desalter bypass valve and when pressure and temperature stabilize,
close the Desalter inlet valve.
2.
3.
Displace brine water from Desalter to the oily water sewer. Monitor this closely to
prevent putting oil to the sewer.
4.
5.
Close Desalter outlet valve and pump the crude out through the pump out system.
Do not pump water into the pump out system. Vent steam into the Desalter while
pumping out to prevent pulling a vacuum.
6.
After all oil is pumped out, steam to Oily Water Sewer for about two hours.
7.
Block off Safety Valve to isolate vessel from Hot Flash Drum.
8.
Open high point vent and steam to the atmosphere for two hours.
9.
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Install blinds in inlet and outlet lines, safety valve line, steam line, water line, and
pump out line..
2.
Open man way for visual inspection from outside for cleanliness.
3.
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Natco
Natco, Inc.
P. O. Box 1710
Tulsa, OK 74101
Telephone: (918) 663-9100
Telex: 49-2427
Cable: Natco Tulsa
Paris, France
Telephone: 225-0167
Telex:
650225
Howe-Baker
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Petreco Division
P.O. Box 2546
Houston, TX 77001
Telephone: (713) 926-7431
Telex:
775 248
Petrolite GmbH
P.O. Box 2031
Kaiser-Friedrich-Promenade 59
6380 Bad Homburg 1, West Germany
Telephone: 49-6172-12930
Fax: 49-6172-28260
Petrolite-France S.A.
25 Rue Beranger
75003 Paris, France
Fax: 33-14-804-9337
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Symbol
Seawater,
ppm
Aquifer,
ppm
Sodium
(Na+)
12,600
696
Calcium
(Ca++)
545
222
Magnesium
(Mg++ )
1,660
82
Sulfate
(SO 4--)
3,260
418
(Cl-)
22,800
1,280
(HCO3-)
164
195
Silica
(Si)
2.8
12.9
Boron
(B)
8.2
0.72
Strontium
(Sr)
9.6
5.5
Copper
(Cu)
<0.5
< 0.5
Zinc
(Zn)
<0.5
0 - 11
Manganese
(Mn)
<0.5
< 0.5
Barium
(Ba)
<0.5
< 0.5
Lead
(Pb)
0.76
< 0.5
(TDS)
41,000
2,890
7.9
7.0
1.0315
1.0024
Ions
Chloride
Bicarbonate
Total Dissolved
Solids
pH
Specific Gravity
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PART 1:
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Addendum D:
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94