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6. Chem II dont do. Not all liquid-liquid solutions are ideal. Those that are
usually have
a. solute-solvent interactions that are weaker than the
interactions in pure liquid
b. solute-solvent interactions that are stronger than the
interactions in pure liquid
c. similar liquids with an enthalpy of solution near zero
d. an observed vapor pressure lower than that predicted by
Raoults law
e. high dipole-dipole interactions between solute and solvent
molecules
7. Mole fraction is a method of expressing concentration that is
needed in several kinds or problems, such as those dealing with
vapor pressure of a solution. To calculate the more fraction, it is
necessary to
a. divide the total number of moles of solution by 2
b. divide the moles of solute by moles of solvent
c. divide the moles of one component by the sum of the moles
of all components
d. divide the mass of the solute by the mass of the solution
e. divide the mass of the solute by 1000 g of solvent
8. Chem II dont do. Refer to the two diagrams above. Osmotic pressure
may be defined as
I the excess pressure shown by different liquid levels on the two sides
II. The pressure which must be applied to stop osmosis
III. Flow through a semipermeable membrane
a. I only
b. II only
c. III only
d. I and II only
e. I, II, and III
2
Boiling Temperature
Lower
Lower
Lower
Higher
Higher
Freezing Temperature
Lower
Lower
Higher
Lower
Lower
Vapor Pressure
Lower
Higher
Lower
Higher
Lower
10. Toluene has half the molecular mass (g/mol) of glucose. If 100. g of each
of these two substances are mixed and all of the glucose dissolves in the
toluene, the mole fraction of toluene in this solution would be
a. 1/3
b. 1/2
c. 2/3
d. 3/2
e. 6/6
Answers
1. D
2. D
3. A
4. C
5.
6.
7.
8.
A
C
C
D
9. E
10.C
Cliffs
1. A 10.0% sucrose solution has a density of 2.00 g/mL. What is the
mass of sucrose dissolved in 1.00 L of this solution?
a. 1.00 x 102 g
b. 2.00 x 102 g
c. 5.00 x 102 g
d. 1.00 x 103 g
e. 1.00 x 104 g
2. How many mL of a 50.0% (by mass) HNO3 solution, with a
density of 2.00 g/mL, are required to make 500. mL of a 2.00
M HNO3 solution?
a. 50.0 mL
b. 63.0 mL
c. 100. mL
d. 200. mL
e. 250. mL
3. Dont do (deals with normality, which isnt on the AP test)
3
5.
6.
7.
8.
A
B
C
D
9. A
10.D
11.C
Barrons
1. The solubility of cadmium chloride, CdCl2, is 140 grams per 100
mL of solution. What is the molar solubility (molarity) of a
saturated solution of CdCl2?
a. 0.765 M
b. 1.31 M
c. 7.65 M
d. 12.61 M
e. 0.131 M
7. To make a solution, 3.45 mol of C6H13Cl and 1.26 mol of C5H12 are
mixed. Which of the following is needed, but not readily available,
to calculate the molarity of this solution?
a. the density of the solution
b. the densities of C6H13Cl and C5H12
c. the temperature
d. the molar masses of C6H13Cl and C5H12
e. the volumes of C6H13Cl and C5H12
8. Which of the following when added to 1.00 kg H2O is expected to give
the greatest increase in the boiling point of water? (kb = 0.052 oC m-1)
a. 1.25 mol sucrose
b. 0.25 mol iron (III) nitrate
c. 0.50 mol ammonium chloride
d. 0.60 mol calcium sulfate
e. 1.00 mol acetic acid
9. Chem II dont do. Ethyl alcohol, C2H5OH, and water become
noticeably warmer when mixed. This is due to
a. the decrease in volume when they are mixed
b. smaller attractive forces in the mixture than in the pure liquids
c. the hydrogen bonding of the two liquids
d. the change in vapor pressure observed
e. stronger attractive forces in the mixture than in the pure
liquids
10.Chem II dont do. Which is the most appropriate method for
determining the molar mass of a newly discovered enzyme
(enzymes are relatively nonpolar)?
a. Freezing-point depression
b. osmotic pressure
c. boiling-point elevation
d. gas density
e. vapor pressure
11. A polluted pond contains 25 ppb of lead ions. What is the
concentration of lead ions in molarity units?
a. 1.2 x 108 M
b. 1.2 x 10-7 M
c. 2.5 x 10-8 M
d. 0.121 M
e. 1.2 x 10-10 M
8. A
9. E
10.B
11.B
12.C
13.B
14.B
15.B
16.D
17.E
18.B
19.E
20.A
Petersons
1. An aqueous solution of potassium iodide is heated from 25 oC to
85 oC. During the time period while the solution is being heated,
which of the following is true?
a. the mole fraction of solute decreases
b. the mole fraction of solvent increases
c. the density of the solution is constant
d. the molarity of the solution is constant
e. the molality of the solution is constant
2. If you were trying to increase the amount of dissolved carbon
dioxide gas in water, which set of conditions would allow you the
highest levels of dissolved CO2?
a.
b.
c.
d.
e.
PCO2 above
Water
10.0
10.0
5.0
5.0
1.0
Temp
90
10
90
10
10
10
11
5.
6.
7.
8.
C
E
D
D
9. D
10.C
11.B
12.D
Kaplans
1. Which pair of liquids will be miscible?
I. C6H6(l) and CCl4(l)
II. C4H10(l) and H2O(l)
III. CH3COOH(l) and H2O(l)
a.
b.
c.
d.
e.
I only
II only
III only
I and III only
I, II and III
12
I
II
III
I and II only
II and III only
13
I only
I and III only
I and IV only
II and III only
II and IV only
14
5.
6.
7.
8.
A
B
D
D
9. A
10.E
Princeton Review
Questions 1-4
a. molarity
b. molality
c. density
d. pH
e. pOH
1. Has the units moles/kg
2. Chem II dont do. This is the negative logarithm of the hydrogen ion
concentration
3. Can have the units grams/L
4. Has the units moles/L
15
I and II
II and IV
I, II and III
I, II and IV
I, II, III and IV
following aqueous solutions has the highest boiling point?
0.5 m NaCl
0.5 m KBr
0.5 m CaCl2
0.5 m C6H12O6
0.5 m NaNO3
1.8 x10 10 M
16
17
18
I only
III only
I and II
II and III
I, II and III
Answers
1. B
2. D
3. C
4. A
5. E
6. C
7. E
8. B
9. E
10.E
11.B
12.C
13.A
14.C
15.B
16.C
17.A
18.B
19.D
20.C
19