\79 / 2074

1,

fDnctio. V asqiated *ilh lh molion ol elermn in a hyd'ocn 'lom 'an Lx

exfrt\sr.t.onvcnisntly as a tunclion ot :
( ) Clir.si.n ..-drdinires r, y, z {B) sPheri.al Polar.o4Ydi@6 r,0, e
(c) cylindncal .o'ordnii6 r, +, z (D) Non of ihe

Tir wav.

tuf'

(c)

w&Ln$\ of lhd Molmlrr Mdh.nk\ mPlhod

lt iSnoid.h.trons
slow
The.alcuLtions .rc
'rlilircly
Givet Pooi nsulb ror llr sp.ctra

(D)

canRn b aFPtied ro

Th.

(A)
(B)

3,

Th ROIIr trtthorl is

(A) H2o

mlols

i.

wilh mor.lhan i00 arons

tor which ot lhe follo*ing molol6

o2 (riPrer)
(B)

urd

(c)

cII4

(D) Brl

seii emptj$l qudntum.hemical moldlar orbilil nclnon

(B)

RHF/STO. 3G'

orbitnl(s) tnrr

(u)
6.

h/dro8en.tm

zro

Wl ci of th tollowing sltbmenls

(C) AMBER

(c)
f.l6e aboul

has

(D)

AMI

ts:

one

Valfte Bo'd

Thory ?

(A) lt G a qudtun ltrhani.al aPPd'h

(B) The |inal rv.ve fun.rim or trial wave runction is the prxtu't of lhe individlal band
eigcn ,un.tiors

(g
(D)

ll nikes no .tremPt ro PPlicl lh thnF ot the mor6trLa3

Thc ind'viduility .a the aloms atu @inLined

7,

In lh Lyman seris of rhc atomic hydro8cn sFcttum, the allowed transitio' is :

(C) '?FJ'?P (o) Ndr ol the abov
(8) '?s tD
(^) 2PJ2s

8.

In

dt Hiict l ih6ry lh. Kular dtrminanr has:

(A) Resontn( inlcStals rs thc diasondl eleme s
(B) cdlomb integnls as ihc diaSonal lftnts
(c) F 8lh. diiSonal elerunts
(D) Exchinge lnlrgtal$ is th rliaSoml elements
lP.T.O,l

9.

mlNl,

thc

eftr

orEend lowards th lr8h

(c) P br.n(h (Dl

10.

The

Noneofl.'leabove

cn ra.ter tabl Io, NHrmotc.ulebErvenblow.

cr'

2cz

-1
E

-l

lrhi.h of rlE toUowinE srarcmre is @Rr

(A) The Ar mo<l i, tnfEred imctive
(B) Thr At rc.le b RaMn inactiv

(c) fte A1 hode is intraEd activ bdr Ramn imcrjve

(D)
1r-

Th Ar dode i! borh infrared

IlE vilue oI Kr

and Kc ar6

{A) Kr=I! (Rndn

12,

13.

(3)

(c)

(=5 ArF"

(D) \=rtr ("ttv,ll

A line ot @Elant compGiiion

of. pEess
(a) AIlis(+rAsb0
(c) aH G(,),4sh (+)
lhe .pontanelt

t4. Tlp

(B)
(D)

An ircpleth
Non of rhe.tbve

(3)

AH ls 0, As jr

(D)

aHis

ts

H.ltnholta - Snoluch@rki eguarid

(A) t=anrru/, 1"1 6-

rs.

.nd Ralrm adive

i.

(+)
),asis0

]-,7".

ro) .= 3*.'r,r

rhe Ueic equati\ is u*A

(C)
l7t/2tr1

(a) Dittrsion.urot
El4Eode porqrirl

(D)

Non of rhe .bove

16.

Tle nrmber asi.led

(A) Cold nunber
(() Reynold numbs
l

13,

TtF

dR obw of fltrid thi6!8h a PiF dl radius

he

dt

(B)
(D)

Th. inF n'tr vnroirv dnd

Nme or th tbovc

(D)

is

Detdnilation ot gold nunber

NoE ol lhe above

Mn* trdm0n* equatio stbws tlE Ebii@hiP b'twea

(A) vis.osity antl nass ol th Polvnct
(B) visirt and densllv or the poltho

((

(D) Nlmot tPabove

z4rk s,'r,6s is.ari.d

(A) Desilvdiation of lcad
(c) h'ificabd ot Sold

17.

19.
'-

rilh

nd'\ni

Plmrr

rhe

t
dnJ rne av.ra8 reld y ol th.
NTP, lhe vr*oqty ur hlJrogPn is a4^10 to'*
-"*"i"' 1- io'-i, p(l ;{ a,llur'rc rh" mean rT' odr\
Ar

'.

iet
icj
20,
'" oie

r.o.rZ"rOt
r.z.re rot

'

..
o"

{B)

(D)

mole ot an ide.l 8as is lEalcd rrcm 100

1s907t105
'm
3 6{7 : loro cn
to 300

Cal'utaia

AS

jr

(a)

$e volutu

is kPt

.otut'nr' Asumrhatcv=15R
(A) 22.s3 J K 'nol r;1370J K 'mol '
(B) 'l37olKLrul rr2283Jk rmolr

;".i;;fti";;;','.
I

,s

rPr

K rmolri2233JK'mor-r
(D) 22s3JK Lml r;l3mJK rmol'

(c)

13.70 J

_
mrtr di'i!"n; *rouPs irPrc'di ur
'r
21, ( l,<nlv 'hc rouowna sub'nto(nl' 'e udho PrE MdDn
b-.^;e rinA in a'oruhc cldhPhlc rubstituho
(iD 3r
lrv) solH
(i) cFr (ij) N=o

o'rho PaF (ii) meta (iii) mel' (i9 orrho

(ts) (D h.la (n) tuta {ill) o ho'Pd'(iv)meia

(A)

(i)

(c)

(i)
(i)

(D)
22. wnit

(ii) oflho - Fn (iii) neta (iv) ortho - PAn

oino PaF (n) onho _ Para {iii) odho Pdra {iv)

ftta

hcii

whs i MrP'und tN 9 Pai6 'r tr

'rcmticity
i' armati'' anti-'rcmric or nonaroni&
'onPouNt
(3) n=4' rnlluofrdt
ro) n=5' iromark

is ihc vahe ol n i, Huclel's tule ot

Prdi.r $h'thcr $ch a

;-;;l
lA) r=t, non-arcruri.

icj

- PaE

"=+,

-.^*i.

'19/2n14

23- lh
( l{1

loltowinB srd undogo hydrctysj. by D^c2

e(hanism.

cH' co_or3_ctl3

which of the folowing prcducrs.onrain

lhe ors Lbel

(A) Cfl3-C

(c)
24.

(8)

2_COOH

(-Hr_oH

(D)

rh. simpl6r ilkane which

(A) 2 - m.rhyl bdane

Cfi3-CH-OH
C4-COOH

(R) 3 - ftthrt
(D) 3, merhyl

(c) 2-@tlylhex.ne

wn^drk'll b. rn. m,,Fr pruducr when

ronownB.

(t
(ii)

2_

nethvt -

penrane

hqnne

Duren.,e..te kirh crrh or th

HgioAc)2, H:O ro owed by NaBrl an<t

NaOH
BH! THF toUowd by H2Ot md NaOH

{A) (i)2-nerhyl,t-brtdol

(ii) 3 , mthyl -

2, blranol

0,) i03 - dc(hyt 2- bnranot (ii)2-heo,yt -1 buranol

{c) (t3 m.lhyt-2-buranol (ji) 2 - nethyt . 2 - buranol

(D) (i)2-crhtl,2-burrnol
Thc

6'trr

(A)
(B)

{c)

(ii) 3 - merhyl - 2 , buraer

onl.r ot {dbrt v ot ihc fouo_ine crrboc ,o^. F

metliyt < prirury .lkyl < bniary a[yt <
bnzyt
@thyl < bt.zyl < primaFtkyt < l.rliary alkyl
tenidy alkyl < bcnzyt < pn@ry atklt < merhyl

(D) oelhyl

< prjmary

a&)t

<

bcn,yl < lerriary alkyl

27. thcptdv,rtreotp..htorcbcn,otr

(A)
23.

a.id E 3 oB.nd th.r ol hryor dcid

nr rurl tn, $e p b.tlqo grolp F

+0.21

Which of rhe foUowinB

(^)
(c)
r19/2014

Brcfromerhane

tsronoProP!.e

(3) -0 2l
.lryl

hali.le

lc)
wi

+0.0224

is4.i9 lhc!ahut

(D)

undrgo sN2 banolysb ,asrsr

-0.0224

(B) Brchmrh.ne
(D) 2, nethyl -1 - Bromo prcpane

rpd

29, l".dict

('r

the produ.t of

PheHlcocH:t

ltu lollowing EanangeRnl r'chons'

ffiA

(,i) PhcH(rcoc||1

-!+i!

(A) A=PhCH2CrtrCOOll,
(B) A=PhCH2COCHTOF,

A-PhCH(OH)COCIll
B-PhCI(OH)COCHT

(c)

A-B=PhcH(OH)CocH1
(D) A = B: PrtcH2CHrCooH

30.

The Lvou.ed.onfoflnation for 1,

(A)
(C)

G.!ch, mri,
Anti, gduche,

e.lip$d
diFcd

2'dichloethrnq

(B)
(D)

1, 2 - elh.nediol anLl PrcP'nal'tch,'le

EcliPseo galcho, ant'

Anti, difFd, gau.ha

mddlcs lvill mt shw inrnRi

5p.tnrm

31.

which oi lhe lollmin8

32,

Hov tuny lSR ljn6 ire obrained from lhe compdmd CDI

33.
34.

(A) Il,

(c) Hro

(B) llcl
(B) 4

(A) 3

rerjNMR ror llI'F2 inolecrle 0r=1/2) SivL::

(3) 3 Paks
( ) 2 pcats

35, Wli.h

(B)

(D) cHl
?

(c) 6

(D)

(c) a Fts

(o)

6 Pa*r

The numbr of degcneralc lev.ls Iot rcbtional

(^) s

lNcl lvilh rctltional qn'nlum nunbcr

(c) 33

i=4

(D) r0

df the iollowing tu noI a .omh@ detctor lor 8as chronatogrnPhy

lAJ lhema! condrctivity dtrtd (l) rlarc ionlztion dedd

(c) R.cactive indcx deredo. (D) Ma$ sP.tromcter

36, lIu polym*ic sPecics (sN)n 's

(A) Tht dimnsional conduttor (B)
(C) lwo

37,

dimcEional

Th princrpl

r*rvc

(^) clnc.*

(ondu.tor f))

Insulator

one dirumional conducrot

carbohydnte in animh i5

{R) Glycosen (c) snause

(D)

ladoso

rr9/2fi4
lP.T.O,l

33.

Myr@e blon8s ro:

(A) Acycli. nonore.pmoid
{c) Acyclk dnc'Tnold

(D)

Bktclic *sqrire.Fnoid

39,

(A) r,2

- cyclopnremphenanthrene

(3) 2'

mtnyl - t,

3'

(C)
(D)

3,

tydoFnr.nopheMthtme
hthyl - 1,2 - .yrropenhenophodtuoe

4,

2-

cy.lolenrenophnanlhftne

t0. ]}F hansparnr plastic is :

(A) PoryuErhane (3) pory.albomr.s
'llie conpoun<l that will behave

41,

{A) H2O
,r2,

The

(B)

CH3@oH

eldrcnca.riviry ,littMe

(A) Li,O

as an acid

tu

Fn

{c)

Epoxy

(9

HNq

{D)

KF

(D) L"F

highBr to. rlE

(c)

(B) N.,ct

43. AllMg &e tollowing obitals ot diatomi. ml<ule, rhe bonrlinE db .l !

(A) 1ou
(B) 2'"
(c) 1ru
(D)
44.

Molcule wilh hi8hesr dipote

(A)

!5.

C|LCI

mjMt

Jolh Tella ffecr aftcls the geomer,y of

Opti.al

i$mrisn

Icu(NHr{lr+

(c)

cHcl3

(q

tMnalt,-

(c)

tN(co)L

is shown by :

(a) {Ni(cN){1,- (B)

tP(NHr).F+

TlE hyb.idis.tjd of X in )CF6 it i

(A) dsp3
(B) sprd

[o r |fue of acPted valu. js :

(B) Accda.y (c) Median

E5un

rr9/mr4

1"s

js:

(3) CHrCt:

(a) INi(NHJ6F+ G)

HC|O4

tDl

cct4

49,

Thc

@ti]

(A)

ri

which

lom lrt

(3)

rc9oly acid rs :

(c)

zn

inrensity of absorytton
Whir\ of lhe fdllowjng.oinPlcx ionc sho{s the maximum

i^] ;ali\:,;l:l:1' p) rv(H:ou'?+ (c) r{n(H,o)r'?r

(D)

{Mncr,e6r'?+

(!)
(q cnl

(D) ^lc\
Irco{co)1

ctl=cIr?

{B) l'h

(c)

GYcloFe.iailienYD

i'on

8is (cycloFntadicnyI) i'on

s3,

EAN value ol Ni(co)i ts

54.

whll

is th.

(c)

J7

(D)

34

r))

furtion ol.Ylfthrco6

Melal ion PPs..t in ChloioPhyll is

Mc
(A)

(Bl

Fe

lhe cqualton for ciget

Nulttll

(A)

(c)

(B) M=Z(MH)+A'Z
(D) losR=I(A+B)

(c)

Mo centc

rh(t el(lron

{c)

ktu.h Or8dobod$

58.

5t. Whkh

(D) rlre cntrc &o

(B)
(D)

is the

fl.jn omPoncnl

ckcuon

tc Dvolttd I

lteifrer _'lierunn teacton

ttetrY Fad'on

of Ponl.nd Ccmml clink r ?

(B) caklum sirkate
(D) zir..ium rilicalc
119 /2014

lP,T.o.l

60.

cive th. genml

(A) Si.
51, Namstncrue

(c) l@.nd
52.

tmrta ot SilaR :
(B) Si,Hrn{

have siz in

berwrn

1000 nm

Th prcb. of S.anninS tunneling Mi@eope js

(A) Marmd rhetip

Quantum Dors aF

crcwn -

iA) Lj'

sharp as :

(A) 1 ditusioml
12 -

(B) hany.lonr at |he rip

(D) noneotrhe,bov

(c) a nedle
53.

(3)

dinMsionrl (Ct O d,llHr@l (D) 3 dituiml

eledively bind with

{3)

(c)

Na+

K*

CiIuF'E ar.omlbun& rha! bton8 ro

(a) crown erhB (B) cryPl,nd3

,@n herJ in pohoring

The.nti-bioric wnich behaves Lte

(^) Notucrin

(B)

Pencj in

The intrior oi cl,clodex lrins .

(A) Hydmphiri. (3)

63_

59.

70.

rJydroPhobic

crown er\s dc best used .s

(A) HomoSemus c.rarrst
(C) Phase rnrotd caialFr

TlE riEt ionjc tiqrid which is used

(A) Etnyl Amoonilo Nir6ie

(c)

(A)

(c)
119/2014

(B) llciros@s
a

Ihptupyl Ammo.iud Nirral.

Ihebcst

@rarFt

(B)
(D)

Methyl Anmonium Nithte

None of rhe.bov

(3)

SuPs Crirical co2

glM $tvenr i,:

Cdtiol NO?
Slper criri.rt Nr jJ
Super

the

l0

7r.

A gdrl siFhfi. learh is .h.6ci(tizd by

(A) It rcquirer.lir irli.Dlation or ! goal
(B) lt lolLow sadili Plan and gredurc
(c) Ir acccpb @tain fiitical $sunPtions

{D)
?2.

lnddldd htmn bhavi6r md reasds @er. lmg

(3) Quasi
(A) Hisioricat srudy

To

(g
73,

All rhc.}ove

Longitudinal

study

$ully

in

sdtll

{lr) seminar (q

?ll,

Oirs.-tly

75,

lvhi.h of the lolloeing qlaliti6

urcfll a?Plication of *inlific

albll

(C) Inbllelually
?6,

{c)
77-

foll

gbupc? thal aE stnctued to Producc

confden

r,gical and eyslemati.

hmst

Lature ncthod
Di$u$jon rerhod

Wtn h oI thu

(c) t{hnolo9/

(B)

lhe lno d

Thc mGt dae.rive hachina m.rhod th.t

(A)

has to do

PrinciPls l'o Prcductid is

(A) Kno,l.d6 0l) s<iece

Curious

tin" m.

(D) ctus

Teachina.fldleaming iranSem.nb,
a.liv. pa.ti.iPation in

(A)

pdod ol

ins k

the

msuE mnrifrlm psnioPation

(B) rexr boor ndhod
(D) Dmnsh' j'n m'rhod

ot sludenE

nGt ihPotunt indi(alor of qu.lity oI ducarion in a *hml

(A)
(B)

lnhidructurslracilxies
Qu:hrkatim ot lc..he6
(c) L)lscipLin minlained in lh school
(D) SiDdcnL{ a.hiaem.rns

78,

W'hi.h of llrc

(A)
(B)

(c)
(D)

folh{ing

is not

qualily oI eff..{ivc lca.hr

Les i.telaction in the.las

Adopt i.tertctiv method oI tdchin8
of strld.ntt
Redu( tne inxiely
'vl
Molivat |he students ro lak initiativ

779/2014
lP.T.O.l

Whi.h of the following

(A)
(C)
40,

ca

a.hi.ved rlhuEh latE erld<arjon ?

To inalcate ol litus
(B) Dvetopjobskills
AwaF on physi.al l n6
(D) D*lopnMr ot p$orErity
be

Iactun8 @thod whrF purpo*tul dchv,ry rlul wi Emd". rsogn,ad djtA.ulry or

FrpFrrq in \ituat,m lhrolgh fie pns oi Fsonrns i.
(D) ftobld $lvirg rethod

31,

of The constitution ot Ind'a difdr rhe si,te b oladi4 vit ge

Frch,Ft! and
and aurhdfty to fthcrion as uniti; stf-8ov;;db,

'

rdo, thm with pows

or_rhe G)shtutjon ot rndj" hpo!6.

1:l..l:_
". p|Wr
me evE anry, un y ,nd jnbgifty oi IndD

(A)

33.

(B)

51-A(b)

All-Ift1ia sNiG can

Consbturio ot tndia.

be

{^)

26

51,A(j)

a,ricl

312-A (c) Ani.te

27

uphold,nd

(c)

28

.l

Th

313

prtnnmt of b6 ior pMotion ot rn, parri.xijr retigion

of Tlle Coctituhon .f rndn

IB)

ro

{D) 51Ao

.F.red by lhe PdlDmenr d mpoweFd und.r

(a)
!o

dur!,upon.,ben(

(D)

Eurni.d unds
2e

35.

sdan sinSn v New oelni MunEjprLry AtR t9a9 5c 1938, The suppm coun w* .att.d
upd to (t<jde khethm _
.
{AJ Muicip.l rrhoird cm inpo* reh nG on ltru8hh hous und6 Air,ch r9{O
rDl Lmpbu* tud . tundohmrJt riBhl to rsod b 3rnte w(hour nDrie
(C) Ldrl anlhoritfts en lel, a raa reh6p6riv+
0) HJwre6 \d.l a tundanmht irghr ro ldry o. |h.n trade d pavedhts m6nr ror

36.

FiBt atpel undq S<tim 190) or Thp RBhr io Inlomhon A.t 2006 hd!
to be ,Eteftd
within
days frcm rhe c\piry ol pnGl ror Keipr ot irJotuhon or tro; dde of

In

(B)
't19/2or4

rh,rry

Naliontl cren Tnbunar

full-rime cxFd nmb.F

4(l )G) or Thc

cl 2010, The rribunal shall.otuist ol

cor

shall
22(1Xb) ol The TFnsPlantalion df I lrman O8ans a.t 1994, no
ol rn ol,ene exGPt on conPlaint ailed by. p6on who has giv.n nohce of
Arlhorily, of th alleged otfeh.e and his

33.

39,

of The s.hdule.t c.st6 and Scheaukl liibes (l'Ev.!rid or

^saxts.clionl0(1)
Acr l%9, a spttial court can paes an exrernment ord.. agtinst a ltrso^ lik.ly

.iIene, and

dir{r him nor ro phm

!o the McrNn
be spe.iaied in OE order,

(Bl
90,

one

(D)

(c) rwoyds

yed

lo.o@11

not cKeednS

rivc

YaE

Acconlins lo Rule 2(j) of Tne Noik Pollutid

'Nighl rimc' hd bcen &fitud

ds the

(cl

91.

s!.h Fnod

aPa for

Abditi6)

p.riod

(D)

9.30

(D)

sahodara! AYlaPPan

pn and

6 30

an

h'ho \v.5 the rountter nf s.dhu ]anr

Narayad clru
chatlamFi swamikal

(A) sR

(c)
92.

Tie

was ed.blirhed in ih. Ycar

sdd org.ni*laon n

r\)

1336

93. wlich rdong fie

(D)

(q

1351

tollowing is not \rriItn by C Stnkara

(c)

vhwa Ddsanam

(B)
(D)

(A)

K.P.

(lr)

(c)

P.K

(D)

r3r5

(EP

1893

Ninishah

'f.R Krhhnaswani lycr

Kunnimanikal

1r9/2014

l?.T.o,l

9s,

95.

nam'Kumra Cm
(B) ?ampadi lohn JRph

The Renai$atre teader in Kerara, who gor th

(^)

tlanpur.m

rhinsal
Yohann.n

((:)

Poikayil

(l))

M@r(oth Kumarnn

Ihe name givrn to the Airiorce's rescue op.ralion p.ovided to

Hope
(c) opdarion Gansn Prahar
(A)

opelarion surya

(3)
(D)

OFFtion Bl@m sprin8

r(trrlly d{laftd bt l,rN Ceneral Asmbly

(A)

2014

(B)

Ranga Rajan

colmhsion

(C) s@ Kiithm comi$ion

'lnlematimal year or ramily

(c) 2006

2010

'nE ommision ,pPointed lor studying rhe .onhibutory

(A)

as

(B)
(D)

ptrsiq

(D)

2009

sysrem in KEla

Haziri commission
ahaltachary. comnirsion

Which Constitutional Amendmenl incorporate.l P:nch.yati Raj syrim in our

100. nF nodal agency for estiution of povlry at tne national and 3tah level m India
(A) Ruar Ministry
(B) Plannins Colujssion
(D) HomeMinhtry
(c) Findce conmissid

r79/2Or4

t4