Documente Academic
Documente Profesional
Documente Cultură
ACKNOWLEDGEMENT like to
express
my
special
thanks of gratitude to my teacher Mr.A.K.Sharma as
well as our Principal Mr. Avdhesh Dubey who gave
me the golden opportunity to do this wonderful
project on the topic CATALYSTS, which also helped
me in doing a lot of Research and I came to know
about so many new things I am really thankful to
them.
Secondly I would also like to thank my parents and
friends who helped me a lot in finalizing this project
within the limited time frame.
CATALYSTS
A catalyst
enhances the
rate of a reaction. In other words, they allow a higher fraction of molecules
to reach the minimum energy required for the reaction; hence, leading to the
formation of more products. Catalysts are involved in the reaction, but are
Working
Catalysts dissociate the bonds in the reactants, promoting the recombination
of the reactant atoms and as a result speed the reaction. The catalyst itself is
eventually regenerated by the reaction.
This "catalytic power" is due to free bonding sites on the surface of the
catalyst that can form chemical bonds with one or more of the reactant
molecules, allowing the reactions to occur with greater ease. The actual
mechanisms depend on the reactants and catalysts involved.
readily. For example, hydrogen and oxygen gases can be mixed without
reacting to form water, but if a small amount of powdered platinum is added
to the gas mixture, the gases react rapidly. Hydrogenation reactions, e.g., the
formation of hard cooking fats from vegetable oils, are catalyzed by finely
divided metals or metal oxides. The commercial preparation of sulfuric acid
and nitric acid also depends on such surface catalysis. Other commonly used
surface catalysts, in addition to platinum, are copper, iron, nickel, palladium,
rhodium, ruthenium, silica gel (silicon dioxide), and vanadium oxide.
Mechanism of Catalysis
Catalysts work by changing the activation energy for a reaction, i.e., the
minimum energy needed for the reaction to occur. This is accomplished by
providing a new mechanism or reaction path through which the reaction can
proceed. When the new reaction path has a lower activation energy, the
reaction rate is increased and the reaction is said to be catalyzed.
If the activation energy for the new path is higher, the reaction rate is
decreased and the reaction is said to be inhibited. Inhibitors can provide an
interesting challenge to the chemist. For example, because oxygen is an
inhibitor of free-radical reactions, many of which are important in the synthesis
Heterogeneous catalysts
Heterogeneous catalysts act in a different phase than the reactants. Most
heterogeneous catalysts are solids that act on substrates in a liquid or
gaseous reaction mixture. Diverse mechanisms for reactions on surfaces are
known, depending on how the adsorption takes place The total surface area of
solid has an important effect on the reaction rate. The smaller the catalyst
particle size, the larger the surface area for a given mass of particles.
A heterogeneous catalyst has active sites, which are the atoms or crystal
faces where the reaction actually occurs. Depending on the mechanism, the
active site may be either a planar exposed metal surface, a crystal edge with
imperfect metal valence or a complicated combination of the two. Thus, not
only most of the volume, but also most of the surface of a heterogeneous
catalyst may be catalytically inactive. Finding out the nature of the active site
requires technically challenging research. Thus, empirical research for finding
out new metal combinations for catalysis continues.
For example, in the Haber process, finely divided iron serves as a catalyst for
the synthesis of ammonia from nitrogen and hydrogen. The
reacting gases adsorb onto active sites on the iron particles. Once physically
adsorbed, the reagents undergo chemisorption that results in dissociation into
adsorbed atomic species, and new bonds between the resulting fragments form
in part due to their close proximity. In this way the particularly strong triple
bond in nitrogen is broken, which would be extremely uncommon in the gas
phase due to its high activation energy. Thus, the activation energy of the
overall reaction is lowered, and the rate of reaction increases.Another place
where a heterogeneous catalyst is applied is in the oxidation of sulfur dioxide
on vanadium(V) oxide for the production of sulfuric acid.
Heterogeneous catalysts are typically "supported," which means that the
catalyst is dispersed on a second material that enhances the effectiveness or
minimizes their cost. Supports prevent or reduce agglomeration and sintering of
the small catalyst particles, exposing more surface area, thus catalysts have a
higher specific activity (per gram) on a support. Sometimes the support is
merely a surface on which the catalyst is spread to increase the surface area.
More often, the support and the catalyst interact, affecting the catalytic reaction.
Supports are porous materials with a high surface area, most
commonly alumina, zeolites or various kinds of activated carbon. Specialized
supports include silicon dioxide, titanium dioxide, calcium carbonate,
and barium sulfate.
Homogeneous Catalysts
Nanocatalysts
Tandem catalysis
Electrocatalysts
In the context of electrochemistry, specifically in fuel cell engineering,
various metal-containing catalysts are used to enhance the rates of the half
reactions that comprise the fuel cell. One common type of fuel cell
electrocatalyst is based upon nanoparticles of platinum that are supported on
slightly larger carbon particles. When in contact with one of the electrodes in
a fuel cell, this platinum increases the rate of oxygen reduction either to
water, or to hydroxide or hydrogen peroxide.
Enzymes (Biocatalysts)
Significance
Energy processing
Petroleum refining makes intensive use of catalysis for alkylation, catalytic
cracking (breaking long-chain hydrocarbons into smaller pieces), naphtha reforming
and steam reforming (conversion of hydrocarbons into synthesis gas). Even the
exhaust from the burning of fossil fuels is treated via catalysis: Catalytic
converters, typically composed of platinum and rhodium, break down some of the
more harmful byproducts of automobile exhaust.
o 2 CO + 2 NO 2 CO2 + N2
With regard to synthetic fuels, an old but still important process is the FischerTropsch synthesis of hydrocarbons from synthesis gas, which itself is processed
via water-gas shift reactions, catalysed by iron. Biodiesel and related biofuels
require processing via both inorganic and biocatalysts.
Fuel cells rely on catalysts for both the anodic and cathodic reactions.
Catalytic heaters generate flameless heat from a supply of combustible fuel.
Bulk chemicals
Some of the largest-scale chemicals are produced via catalytic oxidation, often
using oxygen. Examples include nitric acid (from ammonia), sulfuric
acid (from sulfur dioxide to sulfur trioxide by the chamber process), terephthalic
acid from p-xylene, and acrylonitrile from propane and ammonia.
Many other chemical products are generated by large-scale reduction, often
via hydrogenation. The largest-scale example is ammonia, which is prepared via
the Haber process from nitrogen. Methanol is prepared from carbon monoxide.
Bulk polymers derived from ethylene and propylene are often prepared via ZieglerNatta catalysis. Polyesters, polyamides, and isocyanates are derived via acid-base
catalysis.
Fine chemicals
Many fine chemicals are prepared via catalysis; methods include those of
heavy industry as well as more specialized processes that would be
prohibitively expensive on a large scale. Examples include the Heck
reaction, and Friedel-Crafts reactions.
Because most bioactive compounds are chiral, many pharmaceuticals are
produced by enantioselective catalysis (catalytic asymmetric synthesis).
Food processing
One of the most obvious applications of catalysis is the hydrogenation (reaction
with hydrogen gas) of fats using nickel catalyst to produce margarine.[19] Many
other foodstuffs are prepared via biocatalysis (see below).
Catalytic reforming uses metal alloys such as platinum to boost the octane ratings
of gasoline by reforming the carbon chains in petroleum.
Hydrotreatment is the process of adding hydrogen gas in the presence of mixed
metal sulfides on a carrier to improve gas qualities, protect downstream catalysts
and improve emissions by saturating bonds in long hydrocarbons.
Catalytic cracking uses a silica-alumina matrix with zeolite crystals (crystalline
alumino silicates) to reduce the length of hydrocarbon chains into usable shorter
chains, such as octane.
Alkylation is the process of reacting shorter unsaturated hydrocarbon chains in the
presence of a catalyst to produce high octane branched hydrocarbons, gasoline.
REFERENCES
I.
II.
https://en.wikipedia.org/wiki/Catalysis
III.
web.mit.edu/cheme/research/areas/catalysis.html
IV.
cheme.scripts.mit.edu/green-group/heterogeneous-catalysis/
V.
https://www.google.co.in/imgres?imgurl=http%3A%2F
%2Fch302.cm.utexas.edu%2Fimages302%2Fchem1.jpg&imgrefurl=http%3A
%2F%2Fch302.cm.utexas.edu%2Fkinetics%2Fcatalysts%2Fcatalystsall.php&docid=nDGQpMicP5j6kM&tbnid=Lnv_nY95x-OYfM
%3A&w=780&h=526&bih=721&biw=1600&ved=0ahUKEwj0reaWpITQAhWLP
o8KHfzgDS8QMwgbKAAwAA&iact=mrc&uact=8