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1 H20
0 FeCl3
m1=
m3= 2355
3155 kg/hr
x1 FeCl3
1-x1 H20
kg/hr
Evaporator
0.45 FeCl3
0.6 H20
c
Basis
The final product is assumed to have 40% concentration of Ferric Chloride
The upper stream only produce water
Assumption
The evaporation process produce 800kg/hr of water
m1 = m2 + m3
m1=
3155 kg/hr
m1x1 = m2x2 + m3x3
x1 = 0.335895
Concentration FeCl2 0.335895
Concentration H20 0.664105
m2=
785
0.4 FeCl3
0.6 H20
kg/hr
m1=
2355
0.4 FeCl3
0.6 H20
Recycle
m3=
Basis
The flow rate at final product is 1570 kg/hr
1/3 of the product produced from evaporator is recycled back to the reactor
Total production = 13000 ton per year
Shutdown days = 20 days
Operating days = 345 days
Mass flow rate per hr = 1570 kg/hr
m2=
m3=
785 kg/hr
2355 kg/hr
e reactor
kg/hr
1570 kg/hr
0.4 FeCl3
0.6 H20
kmol/hr
kg
Reactor
m2= 1411
kg/hr
0.245768 HCl
kg
0.754232 H20
kg
Assumption
Assume that the inlet for iron metal is 3000 kg/hr
Assume that the inlet for hydrochloric acid is 1000kg/hr
The hydrochloric acid contain 24% weight
mw hcl
mw h20
mw fe
mw Cl2
mol hcl
molh20
total
36.5 mw fecl2
18 mw fecl3
56
70.9 mw N2
9.500789 0.138447
59.1234 0.861553
68.62419
1
nH2=
Balance for H2
nin = nout + E
4.750395 kmol/hr
nfe=
Balance for Fe
nin = nout -E
195.2496 kmol/hr
balance solution
FeCl2
H20
126
162.2
28
m4= 259.1234
0.018333 FeCl2
0.228167 H20
0.7535 Fe
fecl2
h20
598.5497 0.359971
1064.221 0.640029
1662.771
kmol/hr
1= 259.1234 kmol/hr
0.359971 0.018333 FeCl2
0.228167 H20
0.7535 Fe
1
0.2465
mol
mol
0.987241
0.012759
Cyclone
2=
x2 0.006238
y2 8.06E-005
z2 0.999898
1.006217
1.2181415825
0.0157428122
1.2338843947
Assumption
63.87379 Assume that all the Fe Metal is recycled back to the stream 1
0.074372
0.925628
Fecl2 balance
Fe balance
1
m1x1=m2x2+m3x3
m1z1=m2z2+m3z3
x2= 0.006238 kg/hr
z2= 0.999898
m1 =m2+ m3
m2= 195.2695 kg/hr
H20 balance
m1y1=m2y2+m3y3
y2= 8.06E-005
mass
molar
598.5497
1064.221
10933.98
fecl2
H2O
fe
fecl2
H2O
fe
195.2496
nfecl2
nh20
total
598.029
1063.938
1661.967
1
2
3
12596.75 14341.055544787 1661.967
259.1234 195.2694810802 63.85392
mass fraction
0.047516
0.0107025483
0.359832 153.4858
0.084484
0.2268725478
0.640168 3253.592
0.868
0.7624249039
0
10933.98
1
1
mole fraction
0.018333
0.0062382589
0.07433
0.228167
0.000080621
0.92567
0.7535
0.9998982135
0
1
1.0062170933
1
m2=
3= 63.85392 kmol/hr
0.07433 FeCl2
4.746262
0.92567 H20
59.10766
0 Fe
0
m1= 63.85392 kg/hr
1
0
0.07433 FeCl2
195.2695 kmol/hr
0.92567 H20
FeCl2
195.2496 kg/hr
H20
0.019876
Fe
assume conversion
0.9
0.1
m4=
fecl2 out
fecl2 out
0.474626 0.007433 mol/mol
Fecl2 balance
nin = nout -E
E= -4.271636 kg/hr
e balance
=m2z2+m3z3
kg/hr
kg/hr
kg/hr
Chlorinator
H20 balance
m1y1=m3y3
m3y3 = 59.10766 kg/hr
y3= 0.92567 mol/mol
0.359832
0.640168
FeCl3 balance
nin = nout + E
nfecl3 = 4.271636 kg/hr
nfecl3 = 0.066897 mol/mol
mol/mol kg/hr
kg/kg
0.007433 59.8029 0.03292 fecl2
0.92567 1063.938 0.585675 h20
0.066897 692.8593 0.381404 fecl3
1
1816.6
1
6.000023
inert
TOTAL
0.982187
6.98221
mw
mw
mw
mw
hcl
h20
fe
Cl2
36.5 mw fecl2
18 mw fecl3
56
70.9 mw N2
126
162.2
28
nator
6.98221 kmol/hr
0.85933 Cl2
0.14067 inert
1
0.9821875
cl2 balance
nin = nout - 1/2E
ncl2= 3.864205 kg/hr
inert balance
nin = nout -1E
nin= 0.982187 kg/hr
m1
63.85392 kmol/hr
Evaporato
0.007433 Fecl2
0.92567 h20
0.066897 fecl3
1
Fecl2
0.474626
Fecl3
4.271636
fecl2
h20
fecl3
mw
output
h20
45.40766
total
50.15392
mw hcl
mw h20
mw fe
16
17
mass flow
1816.6
1570
molar flow 63.85392 50.15392
mass fraction
59.8029 FeCl2
0.03292 0.038091
1063.938 H2O
0.585675 0.520597
692.8593 FeCl3
0.381404 0.441312
1
1
mole fraction
FeCl2
0.007433 0.009463
H2O
0.92567 0.905366
FeCl3
0.066897 0.085171
1
1
m3
Evaporator
50.15392 kmol/hr
0.009463 Fecl2
0.905366 h20
0.085171 fecl3
m2
13.7 kmol/hr
1 h20
mol
kg/hr
kg/kg
0.009463 59.8029 0.038091
0.905366 817.3378 0.520597
0.085171 692.8593 0.441312
1570
31.30364 kg/kmol
1570 kg/hr
36.5 mw fecl2
18 mw fecl3
56
18
767.2
13.7
action
0
1
0
1
ction
0
1
0
1
0
767.2
0
126
162.2
1000 kg/hr
Reactor