Sunteți pe pagina 1din 46

6/3/2016

PowerFromtheSun::Chapter12

Gmail for Work

Look more professional with


custom Gmail from Google

Start free trial

12.______________________________
Power Cycles for Electricity Generation
Mostofourdevelopmenttothispointhasbeenorientedtowardobtainingheatedfluidfromasolarcollector.
Often,theindustrialdemandtobesatisfiedbyasolarenergysystemisforthisheat.However,amorevaluable
formofenergy mechanicalorelectricalenergy(bothareequivalentinthethermodynamicsense) issometimes
desiredeitherexclusivelyorincombinationwiththermalenergy.Thedeviceusedtoproducemechanicalworkor
electricityfromsolargeneratedheatisapowerconversioncycle,orheatengine.

Severalconsiderationspeculiartosolarenergysystemsaffectthechoiceofthepowerconversioncycleandhow
thesolarenergysystemisdesignedtoincorporateit.Theseconsiderationsarediscussedinthischapteralong
withadetaileddiscussionofthethreepowercyclesusuallyconsideredforsolarapplications:theRankine,
Stirling,andBraytoncycles.

Thisdevelopmentwillfollowtheoutlinebelow:

SolarConsiderations
oModularity
oThermalEfficiency
oOptimumOperatingTemperature
oHeatTransferConsiderations
RankinePowerCycles
oCycleDescription
oComponents
oWorkingFluidSelection
oCycleThermalDesign
oCycleAnalysis
oExamplesofSolarRankineCycles
StirlingCycleEngines
oCycleDescription
oRealEngineAnalysis
oEngineDesignFeatures
oTheSolar495Engine
oFreepistonStirlingEngines
BraytonCycleEngines
oIdealBraytonCycles
oRealEngineProcesses
oCycleAnalysis
oTheSABCSolarEngine
oTheSAGTSolarEngine
SolarCombinedwithFossilFuelPowerCycles
oSolarEnergyforBoostingCombinedCycles
oMinimizingCO2Emissions
oElectricityYieldandCosts
oConclusions
12.1Solar Considerations
12.1.1Modularity
Forparabolictroughandcentralreceiverapplications,asinglepowercyclelargeenoughtosupplythefull
demandforelectricity(ormechanicalwork)isnormallyused.Inbothcases,allofthesolarproducedheatis
broughttoasinglepointwherethepowercyclecanbeplaced.
http://www.powerfromthesun.net/Book/chapter12/chapter12.html

1/46

6/3/2016

PowerFromtheSun::Chapter12

Inthecaseofparabolicdishcollectors,thesystemdesignerhasthechoiceofeithertransportingheatedfluid
fromafieldofdishestoasinglepowercycleorusingsmallenginesatthefocusofeachcollectorand
transportingelectricalpowertothepointofdemand.
Themajoradvantageofusingmanysmallenginesisthatitisofteneasiertotransportelectricalenergythan
thermalenergy.Notonlyistherelessenergylostinthetransmissionprocess,butitisalsoeasiertobring
electricalenergydownfromthemovingreceivertotheground.Otherbenefitsofmodularityarethat:(l)small
enginescanbereplacedbysparessothataplantcomprisedofnumerousunitscandeliverclosetoratedpower
evenwhileenginesarebeingrepaired,and(2)thepowersystemcanbeeasilyexpandedbyaddingmodulesto
accommodategrowth.
Themajordisadvantageofthismodularityschemeisthatmanysmallengines(inthel0l00kWoutputrange)
mustbeusedtherefore,theeconomiesandincreasedefficiencyoflargersizedunitsarenotapplicable.In
addition,incorporationofsignificantamountsofthermalstorageintothesemodulesisgenerallyconsidered
infeasible.Aconsiderationoflessimportanceisthatwhenlocatedatthefocus,enginesmustbedesignedto
operateatdifferentorientations,animportantconsiderationforengineswherephasechangetakesplaceandin
thedesignoflubricationsystems.Furthermore,maintenanceandadjustmentofanenginemodulelocatedoffthe
groundismoredifficult.
12.1.2ThermalEfficiency
CarnotLimitation.Apowercyclereceivesheatenergyatahightemperature,convertssomeofthisenergyinto
mechanicalwork,andrejectstheremainderatalowertemperature.Thethermalefficiencyofanyengineis
definedas
(12.1)
Theultimatelimitationplacedonthisprocessbythesecondlawofthermodynamicsisthatnopowercyclecan
convertmoreheatintoworkthantheCarnotcycle.ACarnotcycleisahypotheticalengineinvolvingfour
processes:anadiabaticreversiblecompressionandexpansionandaconstanttemperatureheatadditionand
rejection.Thethermalefficiencyortheratioofnetworktotheheatadded,foraCarnotcycleengineis
(12.2)
whereTHandTLaretheabsolutetemperaturesatwhichheatisaddedandrejected,respectively.Themajor
implicationhereisthatthethermalefficiencyofanengineisproportionaltothespreadbetweenthemaximum
temperatureofthecycleandtheheatrejectiontemperature.Thewiderthespread,themoreefficientthe
conversionfromheattowork.
BecauseitisverydifficulttobuildanengineoperatingontheCarnotcycle,mostrealenginesoperateonother
cycles.Thebestattainedefficienciesarealittleoveronehalfoftheideal(Carnot)engineefficiency.However,the
effectoftemperaturespreadonefficiencyrepresentedbyEquation(12.2)isstillvalidforrealengines.The
temperaturedependenceoftheefficiencyofarealenginecanthenberepresentedby
(12.3)
whereKe representsthefractionofCarnotefficiencyattainedbytherealengine.
12.1.3OptimumOperatingTemperature
Equation(12.1)indicatedthatengineefficiencyincreaseswithincreaseinmaximumoperatingtemperature.The
efficiencyofmostcombustionheatedenginesislimitedbythetemperaturelimitationsofthemetals(and
ceramics)usedtomaketheengine.Acounteractingfactorappearswhentheenginereceivesitsheatfroma
solarcollectorbecausetheefficiencyofasolarcollectordecreasesastheoperatingtemperatureincreasesasa
resultofreceiverheatloss.
AsdiscussedinChapter5,solarcollectionefficiencycolforaconcentratingcollectormaybedefinedintermsof
areceiverheatbalanceas

(12.4)
where
Aa=areaofcollectoraperture(m2)
http://www.powerfromthesun.net/Book/chapter12/chapter12.html

2/46

6/3/2016

PowerFromtheSun::Chapter12

CRg=geometricconcentrationratio
Ib,a=beam(direct)apertureirradiance(W/m2)
=rateofusefulheatdelivered(W)
Ta=ambienttemperature(K)
Tr=receiveroperatingtemperature(K)
Ul=receiveroverallheatlosscoefficient(W/m2K)
=emittance(effective)ofreceiver
B=StefanBoltzmannconstant(5.6696108)(W/m2K4)
Note:Thefourthpowertemperaturetermisincludedforcompletenessandmaybeeliminatedbysetting =0if
desired.
Theoverallefficiencyofasolarenergypowersystemistheproductoftheefficiencyoftheengineandthe
efficiencyofthesolarcollector.Sinceengineoperatingtemperatureapproximatelyequalsthereceiver
temperature,ananalysisoftheproductofEquations(12.2)and(12.4)willgiveanoptimumoperating
temperaturewherereceiverefficiencyismaximized.Ifitisassumedthattheenginerejectsheatatapproximately
ambienttemperature,itcanbeshownthat

(12.5)

wherethefollowingparametershavebeendefinedforsimplicity:

whereTr,max istheoptimumoperatingtemperatureformaximumcombinedcollector/engineefficiencyandthe
temperaturesmustbeinabsolutetemperatureunits(Stine,1984).
NotethatthepercentageofCarnotefficiencyterm,Ke inEquation(12.3)doesnotappearinthisexpression.This
indicatesthattheoptimumoperatingtemperatureofacollector/enginecombinationdependsonlyonthecollector
designandnotontheenginedesignaslongasKe isconsideredaconstant.
Asanexample,Figure12.1showsthecombinedenginecollectorefficiencyforaconcentratorhavinga
geometricconcentrationratioof1000withthelossparametersspecifiedinthefigure.Theoptimumoperating
temperatureforthisconcentratorwhencombinedwithanengineis780C(1436F).However,notethatthis
optimumdoesnotrepresentasharppeaksincea100Cchangeofoperatingtemperatureineitherdirection
decreasesthesystemoutputbylessthan2percent.

http://www.powerfromthesun.net/Book/chapter12/chapter12.html

3/46

6/3/2016

PowerFromtheSun::Chapter12

Figure12.1Combinedcollectorandengineefficiencyvariationwithoperatingtemperature.Nominalcollectorparameters:
CRg=1000Ib,a=1000W/m2Ta=298KUl =60W/m2Kopt =0.9 =0.9.

Theoptimumoperatingtemperatureisastrongerfunctionofthedesignoftheconcentrator.Figure12.2shows
thevariationoftheoptimumoperatingtemperaturewithgeometricconcentrationratio.Indicatedinthisfigureare
thetypicalpeakoperatingtemperaturesoftheenginecyclesdiscussedinthefollowingsections.Thisfigure
indicatesthereasonwhylowconcentrationratiocollectorsarenormallyselectedforenginesoperatingatlow
temperatureandhighconcentrationratiocollectorsforhightemperatureengines.

Figure12.2Optimumoperatingtemperaturechangewithgeometricconcentrationratio.Nominalcollectorparameters:Ib,a=
1000W/m2Ta=298KUl =60W/m2Kopt=0.9 =0.

12.1.4HeatTransferConsiderations
EngineCycles.Onlythoseenginecyclesthatlendthemselvestoexternalheatadditionarenormallyconsidered
forsolarapplications.Unlikeinternalcombustionengineswhereheatadditionoccurswithintheworkingfluid,
http://www.powerfromthesun.net/Book/chapter12/chapter12.html

4/46

6/3/2016

PowerFromtheSun::Chapter12

externallyheatedenginesrequirethatheatbetransferredtotheworkingfluidthroughcontainmentwalls(i.e.,a
heatexchanger).Notallenginedesignsfacilitatethisheattransferprocess.
Threetypesofenginewillreadilyacceptexternalheatexchangeandhavebeenusedwithsolarheatsources:
theRankine,theStirling,andtheBraytoncycles(seeRoschkeetal.,1979andBowyer,1984).TheRankineand
Braytoncycles
bothhaveconstantpressureheatadditionprocessesreadilyapplicabletoexternalheating.TheStirling,which
usesareciprocatingpistondesign,canincorporateexternalheatingforitsconstanttemperatureheataddition
process.Asyet,nofeasibledesignsofOttoorDieselcycleengineshavebeendevelopedthatallowexternalheat
addition.AsurveybyStine(1984)summarizesthecurrentlyavailable,small(10100kW)heatengines
applicabletosolarparabolicdishconcentrators.
IntermediateHeatTransferFluid.Onceanenginecycleandappropriateworkingfluidhavebeenselected,a
decisionmustbemadeastowhethertopumptheengine'sworkingfluidtothereceiverofthesolarcollectorand
heattheworkingfluiddirectly,ortoincorporateanintermediateheattransferfluidflowingbetweenthereceiver
andaheatexchanger,andheattheworkingfluidintheheatexchanger.
Incorporationofanintermediateheattransferfluidresultsintheadditionofanotherpump,aheatexchanger,and
asecondfluidtothesystem.Theadditionofcomplexitytothesystem,utilizinganintermediateheattransferfluid,
willoftenreducethesizeandweightofthereceiverbecauseofthelowervaporpressuresinvolved.Also,the
expenseofhighpressurefieldpipingiseliminatedforthesamereason.Whentheworkingfluidisagasorinthe
vaporphase,theuseofanintermediateheattransferfluidcausesreductioninheatlossfromthelargeducting
thatwouldotherwiseberequired.
Pumpingtheengineworkingfluiddirectlythroughthereceivercanmakethesystemdifficulttocontrolduring
solarirradiationtransients.ThisisespeciallytrueforRankinecyclesystemswherepreheating,evaporation,and
superheatingallmustoccurinthereceivertherefore,aspecificliquidlevelmustbemaintainedinthereceiver.
However,theconceptissimpleandtheenginecanoperateataslightlyhighertemperaturesincenotemperature
differenceisrequiredbyanintermediateheatexchanger.
12.2Rankine Power Cycles
12.2.1CycleDescription
ThemostcommonpowercycleusedinsolarpowersystemsistheRankinecycle.Thiscyclecombinesconstant
pressureheatadditionandrejectionprocesseswithadiabaticreversiblecompressionandexpansionprocesses.
Itutilizesaworkingfluidthatchangesphaseduringtheheattransferprocessestoprovideessentiallyisothermal
heatadditionandrejection.Theworkingfluidisusuallyeitherwaterororganicliquidshowever,liquidmetals
havealsobeenused.Thefollowingdescriptionassumeswater/steamastheworkingfluid.Differenceswhen
otherworkingfluidsareusedarediscussedinSection12.2.3.
SimpleCyclewithSuperheat.Themajorcomponentsofasimple,idealRankinecyclearedepictedinFigure12.3
alongwiththethermodynamicstatesoftheworkingfluidplottedontemperatureentropycoordinates.Onlyideal
processesaredepicted.Thepressureofsaturatedliquidleavingthecondenseratstate1israisedinan
adiabatic,reversibleprocessbythe(ideal)pumptostate2,whereitentersthevaporgenerator(alsocalleda
boilerorsteamgenerator).Thecompressedliquidisheatedatconstantpressure(oftencalledpreheat)untilit
reachesasaturatedliquidstate2'andthenatconstanttemperature(andpressure)untilalltheliquidhas
vaporizedtobecomesaturatedvaporat3'.Moreheatisaddedtosuperheatthesaturatedvaporatconstant
pressure,anditstemperaturerisestostate3.Thesuperheatedvapornowentersanidealexpansiondevice
(oftenaturbine)andexpandsinanadiabatic,reversibleprocesstothelowpressuremaintainedbythe
condenserindicatedasstate4.Thecondenserconvertsthevaporleavingtheturbinetoliquidbyextractingheat
fromit.

http://www.powerfromthesun.net/Book/chapter12/chapter12.html

5/46

6/3/2016

PowerFromtheSun::Chapter12

Figure12.3AsimpleRankinecyclewithsuperheat.

Oftenduringthisexpansionprocess,thevaporreachessaturationconditionsandamixtureofsaturatedliquid
andsaturatedvaporformsintheexpander.Therequirementtosuperheatthevaporfromstate3'to3isdefined
bytheamountofmoisturethatispermittedintheexpanderexhaustfromstate4to4'.Iftheexpanderisahigh
speedturbine,wetvaporproducesdestructiveerosionoftheblades.Sometypesofexpanderssuchaspiston
andcylinderexpanderspermitsomecondensationduringtheexpansionprocess.However,theamountof
superheatiskepttoaminimumsothattheboilingtemperatureandthustheaverageheatadditiontemperature
(seeSection12.2.4)canbemaximized.
Reheat.Inordertoreducetheamountofinitialsuperheatrequiredwhileraisingtheaverageheataddition
temperature,vaporreheatisoftenused.Thispermitsanincreaseinthetemperatureatwhichheatisaddedto
thesaturatedliquidbutstillprovidesforrelativelydryvaporleavingtheturbineatcondenserpressure.Asshown
inFigure12.4,partiallyexpandedvaporleavestheexpanderatstate7,goesbackintothevaporgenerator,
wheremoreheatisaddedtothevaporasitisheatedtostate8.State8isusuallyatthesametemperatureas
state6butmustbeatalowerpressure.Thereheatedvaporisreturnedtoasecond,lowpressureexpander
whereitproducesmoreworkasitexpandstothecondenserpressure.Thenetresultisanimprovementin
thermalefficiencybecausetheaveragetemperatureatwhichheatisaddedishigher.Largecentralsolarpower
stationsmayusetwoormorestagesofreheattoenhancetheirefficiency.

Figure12.4ARankinecycleincorporatingreheatandregenerationfeedwaterheatingbothopenandclosedfeedwater
heatersareshown(FWH,feedwaterheaterHP,highpressureLP,lowpressure).

Regeneration.Regenerationistheprocessofusingtheexpandingorexpandedvaportopreheatliquidbeforeit
entersthevaporgenerator.Althoughthereisnonetheatgaintothecycleindoingthis,theefficiencyofthecycle
isincreasedbecausetheexternalheattransfertotheworkingfluidnowoccursatahigheraveragetemperature.
RegenerationisaccomplishedintwowaysforRankinecycles.Inthefirst,someofthevaporthathaspartially
expandedthroughtheturbineisextractedandusedtopreheatthecompressedliquidbeforeitentersthevapor
generator.Thisiscalledfeedwaterheating.Inthesecond,theentireflowofvaporleavingtheturbineispassed
throughaheatexchanger(calledaregeneratororrecuperator)whereheatistransferredtothecompressed
liquidpriortoenteringthevaporgenerator.Thissecondtypeofregenerationrequiresthatthetemperatureofthe
vaporleavingtheturbinebehigherthanthecondensertemperature.
http://www.powerfromthesun.net/Book/chapter12/chapter12.html

6/46

6/3/2016

PowerFromtheSun::Chapter12

Twotypesoffeedwaterheatersareincommonuse,andbotharedepictedinthecycleshowninFigure12.4.
Theopenfeedwaterheaterpreheatsthecompressedliquidfromstate2tostate3bymixinginvaporextracted
fromtheturbineatpointb.Theextractedvapormustbeatthesamepressureastheoutletofpumpl.Asecond
pumpisalwaysrequiredontheoutflowsidetoincreasethepressureofthecompressedliquidtothevaporizer
pressure.
Aclosedfeedwaterheaterpreheatsthecompressedliquidfromstate4tostate5byheatexchangeacrossa
surface.Thisheaterusesvaporextractedfromaportintheturbinethatisatstatea.Thepressureofthe
extractedvapordoesnotneedtobethesameasthecompressedliquiditisheating.Oncecondensed,the
extractedliquid(calleddrips)isfedbackintothemaincompressedliquidstream,eitheratalowerpressure
openfeedwaterheater(asisshowninFigure12.4)oratthecondenser.
AfullflowregeneratorisincludedinaRankinecyclewhenthetemperatureofthevaporleavingtheexpansion
deviceishigherthanthecondensingtemperature.Thisisthecaseforaclassofworkingfluidsusedinsolar
RankinecyclesandotherlowtemperatureapplicationscalleddryingfluidswhicharediscussedinSection12.2.3.
Thisclassoffluidshasthecharacteristicthattheentropyofsaturatedvapordecreaseswithdecreasingpressure,
theoppositeofsteam.Figure12.5showsacycleusingfullflowregenerationwithadryingfluid.

Figure12.5ARankinecycleusingadryingtypeworkingfluidandincorporatingfullflowregeneration.

Whenthehighpressuresaturatedvaporofadryingfluidisexpandedinanadiabaticreversibleprocess,the
temperatureofthevaporwhenitreachescondenserpressureisabovethecondensertemperature.Becauseof
thistemperaturedifference,theregeneratorcanexchangeheatfromtheexhaustvapor(state5tostate6)tothe
compressedliquid,raisingitstemperaturefromstate2tostate3.
12.2.2Components
VaporGenerators.Asdiscussedpreviously,thedesignermustchoosewhethertogeneratevaporinthereceiver
ofthesolarcollectorortouseanintermediateheattransferfluidbetweenthereceiverandthevaporgenerator.
Thechoicegenerallydependsonthespecificdesign,butthereareseveralprimaryconsiderations.
Receivervaporgenerators.Generatingvaporinthereceiverofthesolarcollectorhastheadvantageofhaving
fewercomponentsandnolossoftemperaturerequiredwithanintermediatetransfer.Withbothliquidandvapor
inareceiver,however,extremecaremustbetakeninthedesignofthereceivertoensurethattheradiantflux
incidentonthatportionofthereceivercontainingvaporislessthanthefluxincidentintheregionswithliquidand
whereboilingistakingplace.Thisisbecausetheheattransfercoefficientintoaliquidissignificantlyhigherthan
intosuperheatedvapor.Forsimilarvaluesofsolarflux,burnoutofthereceiverwallscouldoccurintheregions
wherevaporexistsontheothersideofthereceiverwall.
Manyconcentratingcollectordesignsrequirethatthereceiverchangeattitudewhilethecollectortracksthesun.
Thischangeofattitudeincreasesthechancesofhighfluxonportionsofthereceivercontainingvapor.
TwoexamplesofsolarRankinepowersystemswheretheengineworkingfluidvaporisgenerateddirectlyinthe
receiveraretheSolarOnePilotPlantatBarstow,CAandthesolarorganicRankinecyclemodulebuiltbyFord
AerospaceandCommunicationsCorporation.BecauseSolarOneisacentralreceiversystem,theverticaltube
receiverremainsstationaryandliquidlevelcontrolisrelativelyeasy.Theverticaltubesofthereceiveraremade
ofamaterialwithahighmeltingpointandthuscanwithstandhightemperaturesintheupperregionswhere
vaporisbeingsuperheated.TubeburnoutisavoidedintheFordAerospacereceiverdesignbecausetheinner
wallofthereceiverisacoppershellwithtubeswoundarounditsexterior.Thehighthermalconductivityofthe
coppershellprovidesanaveragingeffectonreceivertemperature,andsuperheatisattainedwithoutburnoutof
thereceiverwalls.
http://www.powerfromthesun.net/Book/chapter12/chapter12.html

7/46

6/3/2016

PowerFromtheSun::Chapter12

Heatexchangevaporgenerators.Useofanintermediateheattransferfluidbetweenthereceiverandtheengine
addscomplexityandanotherfluidtothesystem.Typically,thisrequiresthatthreeseparateheatexchangersbe
usedapreheater,anevaporator,andasuperheater.ThistypeofvaporgeneratorisshowninFigure12.6.
Althoughthemassflowrateofengineworkingfluidisthesameforallthreeexchangers,theheattransferrates
aredifferent,notonlybecauseofthedifferentheattransfercoefficientsforliquid,boiling,andvaporheattransfer,
butalsobecauseofthevaryingtemperaturedifferencesbetweentheheattransferfluidandtheworkingfluidas
depictedinthetemperatureentropydiagraminFigure12.6.

Figure12.6Vaporgenerator(boiler)foraRankinecyclewhenanintermediateheattransferfluidisused.

Processabcddepictsthetemperaturechangeoftheheattransferfluid(typicallyanoil)asittransfersheatin
counterflowheatexchangerstothecycleworkingfluidgoingfromstatesl234.Ifthesuperheaterissized
properly,thetemperatureatawillbeveryclosetotemperatureat4(themaximumcycletemperature).
Apositivetemperaturedifferenceeverywherealonglinea b cdlineisrequiredforheatexchangetotakeplace.
Therefore,theheattransferfluidreturntemperatureatdcannotbeaslowasthecycletemperaturebecauseof
therequirementthattemperaturecbeabovethetemperatureat2.Theconditionatstateciscalledthepinch
point.
Asimplifiedheatbalanceofthepreheater,thevaporizerandthesuperheater,respectivelygives:

(W)(12.6)
where and arethemassflowratesofengineworkingfluidandheattransferfluid,respectively,h
representsenthalpiesTrepresentstemperaturesandc pistheheattransferfluidspecificheat.Theoverallrate
ofheattransferforeachheatexchangerisrepresentedby
transferredtotheworkingfluidisthesumofthesethreeterms.

and

.Thetotalrateofenergy

Condensers.Allpowercyclesmustrejectalargepercentageoftheheataddedinordertoproducemechanical
work.ForaRankinecycle,thisheatrejectionoccursinconjunctionwithcondensationoftheworkingfluidvapor
leavingtheturbineatlowpressure.Thelowertheheatrejectiontemperature,thegreaterthecycleefficiencyas
indicatedinEquation(12.1).
Heatrejectionfromthecondensertothesurroundingscanbeeitherdirectorthroughanintermediateheat
transferfluidloop(usuallywater).Thetypesofcondenserscommonlyusedinsolarpowersystemsareshownin
Figure12.7.Themostcommoncondenser,atubeandshellheatexchanger,requiresasupplyofcoolingwater
thatcomesfromeitheranaturalsource(river,well,orocean)orwaterthathasbeencooledbyacoolingtower.
Thethreecoolingtowerspicturedcouldbedesignedeithertocondensetheengineworkingfluiddirectlyorto
rejectheatfromanintermediatecoolingwaterloopthatalsocirculatesthroughatubeandshellcondenser.

http://www.powerfromthesun.net/Book/chapter12/chapter12.html

8/46

6/3/2016

PowerFromtheSun::Chapter12

Figure12.7Typesofcondenserand/orheatrejectionusedinRankinecyclesolarpowersystems:(a)tubeandshell
condenser(b)drycoolingtower(c)wetcoolingtower(d)naturaldraftcoolingtower.

Eachoftheseheatrejectionschemesrequireselectricalpowerforoperation.Thispower,consideredaparasitic
lossfromthecycle'soutput,mustbekepttoaminimum.Highestparasiticpowerrequirementsareusually
associatedwithdrycoolingtowerssincetheymakeuseonlyofthesensibletemperatureoftheairforcooling.
Thistypeofcoolingisoftenselectedforsolarpowersystemsbecausethesesystemsareoftenlocatedinhot,
aridregionswithminimalwaterresources.
WaterevaporationmaybeutilizedtoprovideadditionalcoolingforthecycleasinexamplescanddinFigure
12.7.Theseunitstypicallyprovidelowertemperaturecoolingforlessparasiticpowerthandodrycoolingtowers.
Theamountofwaterresourcerequiredmayberoughlyestimatedbyassumingthatmostoftheheatrejectedby
thecycleprovideslatentheatforevaporation.Therateofwaterusagebyawetcoolingtowermaybeestimated
by
(12.7)
where istherateofheatrejectionbythecycleandhfgtheenthalpyofvaporizationforwater(2450kJ/kgor
1054Btu/1b).
Expanders.ExpandersusedmostcommonlyforsolarRankinecycleapplicationsarcturbinesandreciprocating
pistoncylinderdevices.Scrollorscrewexpanders,rotarydisplacementmachines(Rootstype),andfluiddrag
discturbineshavealsobeenproposedforsmalloutputapplications.
Theefficiencyofanexpanderismeasuredrelativetoanidealadiabatic,reversibleexpander.Theexpansion
processofanidealexpanderoccursatconstantentropy(isentropic).Forarealexpander,withfriction,leakage,
andotherlosses,theentropyofthevaporleavingwillbegreaterthantheentropyofthevaporentering.This
producesasmallerenthalpychangethanwouldhaveoccurrediftheentropywereconstant.Theisentropic
efficiencyofanexpander,asdepictedinFigure12.8,iswrittenas

(12.8)
whereh2istheactualenthalpyofthevaporleavingtheexpanderandh2s,istheexitenthalpyiftheexpansion
processwereisentropic(constantentropy)tothesamelowpressure.Thepoweroutputofarealexpanderis
(12.9)
where isthemassflowrateofvaporthroughtheturbine.

http://www.powerfromthesun.net/Book/chapter12/chapter12.html

9/46

6/3/2016

PowerFromtheSun::Chapter12

Figure12.8Isentropicefficiencydefinitionforanexpander(turbine)andcompressor(pump):(a)expander(b)pumpor
compressor.

TurbineexpandersaremostcommonlyusedinsolarRankinecyclesystems.Twotypesofturbineareincommon
usetheradialflowturbineandtheaxialflowturbine.Inradialflowturbines,thevaporexpandsfromtheshaft
centerlinetotheoutsideperipheryofaturbinediscorfromoutsidein.Thistypeofturbineisusuallymoreefficient
forsmallpoweroutputapplications.Inaxialflowturbines,thevaporflowsalongtheaxisoftherotatingshaftand
passesthroughbladesattachedaroundtheperipheryofadisc.Forlargepoweroutputapplications,manyaxial
flowturbinerotorsarestackedtogethertoformamultistageturbine.
Positivedisplacement,reciprocatingexpandershavebeenproposedforsolarpowerapplications.Thisisthetype
ofexpanderusedinmostRankinecyclesacenturyagoconsistsofoneormorecylinderswithpistonsdrivinga
rotatingcrankshaft.Inreheatdesigns,exhaustvaporfromasmallhighpressurepistonandcylinderisreheated
inthevaporgeneratorandfedbacktoalowpressurepistonandcylinderwheremoreexpansionworkisdone.
Pumps.ThepumpinaRankinecycleisneededtoraisethepressureoftheliquidleavingthecondensertothe
pressureofthevaporgenerator.AmajoradvantageoftheRankinecycleisthattheworkingfluidisintheliquid
phasewhenitiscompressed.Sincepumpworkisinverselyproportionaltothefluiddensity,lessworkisrequired
topressurizealiquidthanavapororgas.Sinceliquidsareessentiallyincompressible,theidealpumppowermay
becalculatedas

(12.10)
where isthemassflowratethroughthepump,visthefluidspecificvolume,pisthepressure,andhisthe
enthalpy.State2srepresentstheoutletconditionsofanidealpump,thatis,aconstantentropyprocess.Notethat
thisexpressionwillgiveanegativequantityconsistentwiththesignconventionthatworkintothecycleis
negative.
Theidealpumpraisesthepressureofaliquidinanadiabatic,reversibleprocess.Realpumps,liketurbines,
produceanentropyincreaseinthefluid.Figure12.8bshowsthedifferencebetweenidealandrealpump
performance.Asdiscussedearlierforexpanders,thepowerrequiredtooperatearealpumpis
(12.11)
FeedwaterHeaters.Feedwaterheatersusepartiallyexpandedhotvapor,extractedfromtheexpanderto
preheattheworkingfluidbeforeitenterstheboilertherebyincreasingoverallcycleefficiency.Twotypesof
feedwaterheatersareincommonuse,theopentypeandtheclosedtype.
Anopenfeedwaterheaterissimplyaninsulatedmixingchamberwhereextractedhotvaporismixedwithaflow
ofcompressedliquid.Asthevaporcondenses,itsheatofvaporizationisaddedtotheliquid.Thechambermust
belargeenoughforthiscondensationtotakeplacebeforetheliquidreentersthesystempiping.
Aclosedfeedwaterheaterisatubeinshellheatexchangerinwhichvaporextractedfromtheturbinepasseson
theshellsideandcondenses,releasingitsheatofvaporizationtothecompressedliquidstream.Thecondensate
isthenreturnedtothecompressedliquidstreamatapointinthecyclewherethepressureislower.

http://www.powerfromthesun.net/Book/chapter12/chapter12.html

10/46

6/3/2016

PowerFromtheSun::Chapter12

Figure12.9Definitionofregeneratoreffectiveness.

Regenerators.AswasshowninFigure12.5,whenadryingfluidischosenastheworkingfluid,thevaporleaving
theexpanderstillcontainsheatthatcanbetransferredtothecompressedliquidstreamsincetheturbineexit
temperatureisabovethecondensertemperature.Avaportoliquidheatexchanger,calledaregenerator,is
typicallyusedforthispurpose.Theeffectivenessoftheregeneratorisameasureofhowwelltheavailable
temperaturedifferenceisutilized.Effectivenessisdefinedastheratiooftheactualtemperaturechangeofthe
liquidstreamtothemaximumpossibletemperaturechange.Figure12.9showsaregeneratorandthe
thermodynamicstatesofbothstreamsastheyflowthroughtheregenerator.Theregeneratoreffectivenessinthis
caseisdefinedas
(12.12)
wherethetemperaturesaredefinedonFigure12.9.
12.2.3WorkingFluidSelection
TherearetwoimportantaspectstobeconsideredinselectingaworkingfluidforaRankinecyclesolarpower
system:(1)toselectaworkingfluidthatoptimizescycleefficiencyand(2)tomatchtheworkingfluidstateswith
thoseoftheintermediateheattransferfluidifoneisused.Theeffectsofdifferentworkingfluidsontheseaspects
ofcycledesignarediscussedinthefollowingparagraphs.
TheIdealWorkingFluid.AnidealworkingfluidwouldhavethetemperatureentropydiagramgiveninFigure
12.10.ThefollowingcharacteristicslistedbyAbbinandLeuenberger(1974)describethisfluid:
Theheatcapacityoftheliquidphaseshouldbesmall.Thismakesline2 2'inFigure12.10almostvertical.
Thecriticalpointshouldbeabovethehighestoperatingtemperaturetoallowallheattobeaddedatthat
temperature.
Thevaporpressureatthehighestoperatingtemperatureshouldbemoderateforsafetyreasonsandto
reducethecostoftheequipment.
Thevaporpressureatthecondensingtemperatureshouldbeaboveatmosphericpressuretopreventair
leakageintothesystem.
Thespecificvolumeofthevaporatstate4shouldbesmalltoavoidlargediameterturbinewheels,casings,
andheatexchangers.
Thesaturatedvaporline(follows34inFigure12.10)shouldbeverticaltoavoidexpansionintothewet
vaporregion(negativeds/dT)orexpansionintothesuperheatregion(positiveds/dT).
Forlowpowerturbineapplications,thefluidshouldhaveahighmolecularweighttominimizetherotational
speedand/orthenumberofturbinestagesandtoallowforreasonablemassflowratesandturbinenozzle
areas.
Thefluidshouldbeliquidatatmosphericpressureandtemperatureforeaseofhandlingandcontainment.
Thefreezingpointshouldbelowerthanthelowestambientoperatingtemperature.
Thefluidshouldhavegoodheattransferproperties,beinexpensive,thermallystableatthehighest
operatingtemperature,nonflammable,noncorrosive,nontoxic,andsoon.
Steam.BecauseitisthemostpopularRankinecycleworkingfluid,moreisknownaboutdesigningRankinecycle
componentsforsteamsystemsthananyotherliquid.Becauseithasacriticaltemperatureandpressureof374C
/22.1MPa(704F/3206psia),itcanbeusedforsystemsoperatingatfairlyhightemperatureswithmostofthe
heataddition(atconstanttemperature)andatmoderatepressure.Thelowtemperaturecharacteristicsofsteam
arenotquiteasidealsinceatambienttemperature,steamhasalowvaporpressure(0.03atm)andaverylow
http://www.powerfromthesun.net/Book/chapter12/chapter12.html

11/46

6/3/2016

PowerFromtheSun::Chapter12

density.Becauseofthis,itisamajordesignproblemtosealairoutofthelowpressurecomponents.

Figure12.10AnidealworkingfluidusedwithaRankinecycle.

Steamisawettingfluid,implyingthatsuperheatingisrequiredwhenaturbineisusedastheexpansiondevice.
Asdiscussedearlier,superheatingproducesalowerefficiencysincemostoftheheatsuppliedoccursata
temperaturelowerthanthemaximumcycletemperaturetherebyreducingtheaverageheataddition
temperature.
ThemajordisadvantageofusingsteamforsmallRankinecycles(<1000kWoutput)isitslowmolecularweight
(i.e.18).Asisdiscussedlater,inordertoattainhighturbineefficiencieswithlowmolecularweightfluids,very
highturbinespeedsarecalledforwithsmallinletnozzleandbladedimensions.
Becausesteamisinexpensivetouse(althoughboilergradewatermustbehighlydistilledandthuscostsmore
thantapwater),sealingofthehighpressureportionsofaRankinecycleusingsteamisnotcritical.Non
flammabilityandreadyavailabilityofsteamareadditionaladvantages.However,itsfreezingtemperatureiswithin
therangeofambientconditions.Furthermore,waterexpandswhenitfreezes,producinglargestressesonany
structurecontainingit.Becausesolarenergysystemsarelocatedoutdoorsandarenotoperationalatnight,
freezeprotectionordrainagecapabilitiesmustbeprovidedforallcomponentsinthecycle.
WettingVersusDryingFluids.Forsomefluids,theentropyofthesaturatedvaporincreaseswithincreasing
temperature.Thesefluidsarecalleddryingfluidsbecausemoisturedoesnotformwhenhighpressure
saturatedvaporisexpandedreversiblyfromahighpressure(i.e.,inanidealturbineornozzle).Anotable
exampleusedinmanysolarpowerapplicationsistoluene(CH3C6H5).Afluidwheretheentropyofthesaturated
vapordecreaseswithincreasingtemperatureiscalledawettingfluidbecausemoistureformswhenhigh
pressuresaturatedvaporisexpandedreversiblyinaturbineornozzle.Thewater steamcombinationisa
primaryexampleofawettingfluid.ThecharacteristicsofawettingandadryingfluidareshowninFigure12.11,
alongwithrealandidealexpansionprocessesfromsaturatedvapor.
Anidealfluid,aspointedoutinitem6inthelistintheprecedingsubsection,wouldbeneitherwettingnordrying.
Tabor(1962)didanextensivesearchforhighmolecularweightfluidsthatwouldhaveanalmostvertical
saturatedvaporlineontemperatureentropycoordinates(ds/dT=0).Atheoreticalstudyshowedthattheslopeof
theentropytemperaturecurvewasafunctionofthenumberofatomsinamolecule.Moleculeswith5 10atoms
showthistendency.Carbontetrachloride,tetrachloroethylene,andmonochlorobenzeneareallfoundtohave
verysmallds/dTslopes.
Asdiscussedearlier,dryingfluidscanproducecycleefficienciesalmostasgreatasfluidswhereds/dT=0if
regenerationisused.Thisisbecausethehighertemperatureheatremaininginthevaporonceithasexpanded
tothepressureofthecondenserisnotnecessarilylostbutmaybeusedtopreheatthecompressedliquidbefore
itentersthevaporizer.

http://www.powerfromthesun.net/Book/chapter12/chapter12.html

12/46

6/3/2016

PowerFromtheSun::Chapter12

Figure12.11Saturationcurvesforwettinganddryingtypefluidshowingidealandrealexpansionprocesses:(a)wetting
fluid(b)dryingfluid.

Wettingfluids,ontheotherhand,willalwaysgivelessefficientcyclesforagivenmaximumoperating
temperaturebecauseitisnecessarytosuperheatthevaporbeforeitenterstheturbine.Superheatisrequiredto
ensurethatliquiddoesnotforminthevaporasitexpandsthroughtheturbine.Ifmoisturedropletsform,they
slowdownastheypassthroughtheturbine,finallybeinghitwithgreatforcebytheblades.Thisimpactcauses
erosionoftheturbinebladesorimpeller.Superheatalsodecreasescycleefficiencybecauseoftheloweraverage
heatadditiontemperature.
MolecularWeight.Thedesireforusingaheaviermolecularweightfluidforsmallpowercycles(item7in
precedinglist)derivesfrombasicturbinedesignconsiderations.Themostimportantaretheturbinespeed,the
numberofstages,andthesizeoftheflowpassages.Properselectionoftheseisrequiredtodesignanefficient
turbine.AdetaileddevelopmentofturbinedesignparametersmaybefoundinBalj(1962).
ThedatainTable12.1showthatforturbinepowerlevelsoflessthan1to10MW,theisentropicefficiencyofa
steamturbineisconsiderablylowerthanthatofaturbinedesignedforheavymolecularweightfluids.The
reasonswhyhighturbineefficiencycannotbemaintainedforlowpowerleveldesignsusingalowmolecular
weightfluidare
1.Thefirststagenozzlespoutingvelocityisinverselyproportionaltothesquarerootofthemolecular
weight.Sincetheratioofbladespeedtofluidspeedmustremainrelativelyconstant,multiplestagingand
highrotationalspeedsarecalledforwhenlowmolecularweightvaporsareused.Theaddedcomplexity
andexpenseofmultistagingisinappropriateforsmallturbinesbecausediscfriction,leakage,and
windagelossesbecomeprohibitiveinsmalldesigns.
2.Thevolumetricflowsintheinitialstagesoftheturbineareproportionaltothesquarerootofthe
molecularweightandthereforelowwithlowmolecularweightvapors.Thisrequirestheuseofsmall
nozzles,blades,andflowpassages.Partialadmissionmaybeused,butthisreducesefficiency.Also,
bladetip,sealing,andboundarylayerlossesbecomesignificantinsmalldesigns.Evenwiththeuseof
precisionmanufacturingtechniques,smallturbinestagesresultinaturbinewithlowefficiency.

Table 12.1. Comparison of Turbine Isentropic


Efficiencies Using Steam (Low Molecular Weight) and
a High Molecular Weight Working Fluid
PowerLevel

TurbinelsentropicEfficiency(%)

Steam

HighMolecularWeight

>10MW

7080

75 80

15MW

5070

75 80

200500kW

3050

7580

10100kW

2550

6075

Source.Abbin(l983).

FluidProperties.AprimaryconsiderationinselectingaRankinecycleworkingfluidisthesaturationpressureat
thehighandlowoperatingtemperature.Atbothofthesetemperatures,thepressuremustbelessthanthe
criticalpressureandnotextremelyhighorlowasdiscussedinitems3and4intheprecedinglistfortheideal
http://www.powerfromthesun.net/Book/chapter12/chapter12.html

13/46

6/3/2016

PowerFromtheSun::Chapter12

fluid.Forsolarapplications,themaximumoperatingtemperaturevarieswidelydependingonthetypeofsolar
collectorbeingused.Table12.2presentsdataonsomeworkingfluidsthathavebeenusedorconsideredforuse
inRankinecycles.

Table 12.2. Physical and Thermodynamic Properties of Prime Candidate Rankine Cycle
Working Fluids

Property

Water

Methanol

2Methyl
Pyridine/H20

Fluorinol
85

Toluene

Freon
R11

Freon
R113

Molecular
weight

18

32

33

88

92

137

187

Atomsper
molecule

14

15

Boilingpoint(1
atm)(C)

100

64

93

75

110

24

48

Liquiddensity
(kg/m3)

999.5

749.6

934

1370

856.9

1476

1565

Specificvolume
(saturated
vaporatboiling
point)(m3/kg)

1.69

0.80

0.87

0.31

0.34

0.17

0.14

Maximum
stability
temperature
(C)

175230

370400

290330

400425

150175

175230

Wettingdrying

Both

Heatof
vaporization
at1atm(kJ/kg)

2256

1098

879

442

365

181

146

Isentropic
enthalpydrop
acrossturbine
(kJ/kg)

348
1160

162302

186354

70186

116232

2346

2346

Source.Marciniaketal.(1981).

Therelationshipbetweensaturationpressureandthesaturationtemperaturecanbeapproximatedas
(12.13)
TheboilingpressureatanytemperaturecanbefoundbyapplyingEquation(12.13)fromthecriticalconditions
andoneotherdatapoint.Figure12.12showsthesaturationlinesforawiderangeofpotentialRankinecycle
workingfluids.

http://www.powerfromthesun.net/Book/chapter12/chapter12.html

14/46

6/3/2016

PowerFromtheSun::Chapter12

Figure12.12SaturationpressuretemperaturerelationshipsforpotentialRankinecycleworkingfluids.

Forextremelyhightemperatureapplications,liquidmetalshavebeenusedasRankinecycleworkingfluids.A
liquidmetal"topping"cyclewouldrejectheattoasecond,lowertemperaturebottomingcycle.Ascanbeseen
inFigure12.12,thesaturationtemperatureofthisclassofworkingfluidsisveryhigh.However,theyareof
interesttothesolardesignerbothasaRankinecycleworkingfluidandasahightemperatureintermediateheat
transferfluid.
Tabulatedthermodynamicpropertydataforalargenumberofpotentialworkingfluidsareavailabletothe
designer,inReynolds(1979)orfromthecompaniesthatmanufacturethefluids.Becauseoftheirimportanceas
asmallpowersystemworkingfluid,thermodynamicpropertydataforsteamandtoluene(CH3C6H5)areincluded
intheAppendix.
Thermodynamicpropertiesmayalsobecalculated.Computercalculationofpropertiesisoftenusefulwhena
greatnumberofcyclesorfluidsaretobeanalyzed.Adescriptionofthesecomputationalproceduresisbeyond
thescopeofthisbook.TheinterestedreaderisreferredtoAbbinandLeuenberger(1974)forarelativelysimple
approachtoanalyticalpropertypredictionandtoReynolds(1979)formoreextensivealgorithms.
12.2.4CycleThermalDesign
Cyclethermaldesigninvolvesconstructionofacyclediagramonthermodynamiccoordinatesbylocatingthe
thermodynamicstatesoftheworkingfluidasitentersandleaveseachcomponent.Inordertodefinethese
thermodynamicstates,thedesignerhasfewchoicesoncethemaximumandminimumcycletemperatureshave
beendefinedandtheworkingfluidchosen.
AverageHeatAdditionTemperature.Onechoiceremainingistomaximizethe"average"heataddition
temperature.Thispseudotemperaturehelpsthedesignervisualizethecombinationofcycleheataddition
processes(preheat,boiling,andsuperheat)thatmaximizecycleefficiency.Theaverageheataddition
temperatureisdefinedasthetemperaturethatproducesthesameareaastheareaunderaheataddition
processcurveonTscoordinates.Inanalyticalterms,thistemperatureisrepresentedbythefollowing:
(12.14)
wherestates1and2representtheinitialandfinalstatesoftheheattransferprocess.
ThePinchPoint.Whenanintermediateheattransferfluidisused,heatadditiontotheworkingfluidtakesplace
inthreecounterflowheatexchangersasshowninFigure12.6.TheprocessesareagaindepictedonFigure
12.13withthescaledistortedforclarity.Theheattransferfluidatarepresentsthesolarfieldoutlettemperature
andatd,thefieldreturntemperature.Thedifferencebetweenthesecanbereducedbyincreasingtheflowrate
ofheattransferfluidthroughthefieldandthustheparasiticpumpingpower.

http://www.powerfromthesun.net/Book/chapter12/chapter12.html

15/46

6/3/2016

PowerFromtheSun::Chapter12

Figure12.13Theworkingfluidvaporizationprocessusinganintermediateheattransferfluidincountertlowheat
exchangers.

Theslopeofcurveabcd(andtheparasiticpumppower)isdefinedbystates2and4ofthecycleworkingfluid.
Sinceaheatexchangermustalwayshaveapositivetemperaturedifferencetotransferheat,thetemperatureof
theintermediateheattransferfluidmustalwaysbeabovethetemperatureoftheworkingfluid.Pointarepresents
themaximumsolarcollectorfieldtemperatureandpoint4themaximumcycletemperature.Pointscand2,called
thepinchpoint,definethelowesttemperature(pointd)atwhichheattransferfluidcanbereturnedtothe
collectorfield.
Itisimportanttomakethedifference(Ta Td)largetoreducetheheattransferfluidflowrateandhencethe
parasiticpumpingpowerrequiredforthesolarcollectorfield.Thiscanbedonebyincreasingtheamountof
superheatgiventothecycleworkingfluid.Increaseintheamountofsuperheatforthecyclereducesthesolar
fieldpumpingpower.However,increaseinsuperheatforagivenmaximumcycletemperaturereducesthepower
cycleefficiencybutincreasesthesolarcollectorefficiencybyreducingtheaverageheatadditiontemperatureas
definedinEquation(12.14).Theresultisthatthecycledesignerisfacedwithatradeoffbetweencycleefficiency
andcollectorfieldefficiencyandmustfindanoptimumsolution.
CycleDesignProcedure.Thecycledesignprocedurediffersforwettinganddryingworkingfluid.Theprocedure
canbestbeexplainedonthetemperatureentropy(Ts)coordinatesinFigure12.14.Forsimplicity,thefinite
heatexchangetemperaturedifferencesrequiredatcanddarenotshown.

http://www.powerfromthesun.net/Book/chapter12/chapter12.html

16/46

6/3/2016

PowerFromtheSun::Chapter12

Figure12.14Cycledesignsequence:(a)forawettingtypefluid(b)foradryingtypefluid.

Wettingfluids.Forawettingfluidwhenanintermediateheattransferfluidisused,thecycledesignprocedure
followsthissequence(thelettersrefertostatesnotedinFigure12.14a):
aOncetheworkingfluidhasbeenselectedandthemaximumandminimumcycletemperatureshave
beendefined,themostimportantcycledesigncriterionistheamountofmoisturepermittedattheexitof
theexpander(turbine).Highmoisturecontent(lowquality)atthispointcauseserosionofthebladesor
impellerandinefficientoperation.ThispointisshowninFigure12.14aasstatea.
b,cTheisentropicturbineexitstateb,isthencalculatedas
(12.15)
wheretheturbineefficiencytmustbeknownandstatecwillbeattheintersectionofthemaximumcycle
temperatureandaverticallinefromb.Thisisaniterativeprocedurebutconvergesrapidly.Insome
http://www.powerfromthesun.net/Book/chapter12/chapter12.html

17/46

6/3/2016

PowerFromtheSun::Chapter12

designsituationssuchastotalenergysystemswherethecondensingtemperatureispurposelyhigh,the
pressureatimaybetoohighforreasonablecomponentdesign.Thisforcesthecycledesignertoanew,
lessefficientturbineinletconditioncandredefinespointsbanda.
dWiththedefinitionofpointc,thepressureatwhichheatadditiontakesplaceisdefined.Sincemostof
thisheattransfertakesplaceattheboilingtemperatured,theaverageheatadditiontemperature THis
nowfixed.Ifthelowerturbineinletpressureatc'(withmoresuperheating)hadbeenselected, THwould
havebeenlower,resultinginalessefficientcycle.
e,fThepumpexitconditionisnowdefinedbythevaporizerpressureandaverticallinefromthe
saturatedliquidpointatthecondensingtemperature(pointf).Actuallythisisnotaverticallineforreal
pumps,butitmakeslittledifferenceinthecycledesign.
gFinally,theheattransferfluidtemperaturelineisdrawnabovepointscandd.Itsslopeandthusthe
fluidreturntemperatureatgaredefinedbythemaximumcollectortemperatureandthepinchpoint
temperature.
Itshouldbenotedherethattheassumptionthatlinedgisacontinuationoflinecdisnotexactduetodifferences
inheattransferforthetwoprocesses.
Precisely,thetemperatureoftheheattransferfluidleavingtheheatexchangerwillbeslightlyhigherthangbut
lessthand.Itstruevaluemaybedeterminedbyanenthalpybalanceofthepreheatersectionoftheheat
exchangerhowever,thisisnotnecessaryincycledesign.
Ifthedifferencebetweenthefieldoutputtemperatureandthereturntemperatureissosmallthathighfieldflow
ratesarerequired,thecyclepressuremustbereducedtoc',andtheresultingfieldreturntemperatureatg'will
belower.Thiswillalsomakethecycleefficiencylower.
Dryingfluids.Whenthecycleworkingfluidisadryingfluidandanintermediateheattransferfluidisused,the
cycledesignprocedurereverses.Ideally,toobtainthehighestcycleefficiency,nosuperheatwouldbeusedand
THwouldbeveryclosetothemaximumcycletemperature.However,nowtheparasiticsolarfieldpumpingloss
andhencetheminimumfieldtemperaturerisebecomesthedeterminingfactorfortheentirecycledesignonce
themaximumandminimumtemperatureshavebeenset.Theprocessisasfollows(seealsoFigure12.14b):
Onaverticallinefromthecondensedliquidstate,definepointarepresentingthehighestcollector
fieldreturntemperaturepermittedwithoutrequiringexcessivepumpingpowerinthecollectorfield
loop.
Astraightlineisdrawnfrompointathatjusttouchesoneoftheconstantpressurelinesatband
againatc,whereitalsointersectsthemaximumtemperaturelinesimultaneously.Thereisonlyone
saturationpressurecurvethatwillmeetthesecriteria,andthiswillbethecyclehighpressure.At
excessivepressures,thepinchpointconditionwillbeviolatedandatinsufficientpressurethecycle
efficiencywillbereducedsincetheaveragetemperatureofheatadditionwillbelower.
Averticallineisnowdroppedfrompointctopointd,itsintersectionwiththecondensingpressure.
Thislinerepresentstheisentropicturbineexpansion.
Pointe,theactualturbineexitconditionisdefinedatthesamepressurebytheturbineexitenthalpy
from
(12.16)
andthecycleiscompletelydefined.Theactualcollectorfieldreturntemperaturewillbeslightly
higherthanaanditerativetechniquesmustbeusedforthefinalcycledesign.
AComparativeCycleDesign SteamversusToluene.Therearemanyinstancesinsolarsystemdesignwhere
certainorganicworkingfluidsofferadvantagesoversteam.Cycledesignswherethisistruearetypicallyeither
small(
Table 12.3. Comparison of Toluene and Steam Solar Power
System Design Parameters

Steam

Toluene

Hightemperature

340C

340C

Poweroutput

100kW

100kW

Idealefficiencya

40.8%

34.8%

Thermodynamiccycle:

Turbine:
http://www.powerfromthesun.net/Book/chapter12/chapter12.html

18/46

6/3/2016

PowerFromtheSun::Chapter12

Stages

Speed

25,000rpm

50,000rpm

Mediumbladediameter

19.1cm

11.3cm

Firststagenozzlearea

7.7cm2

0.58cm2

Isentropicefficiency

72.5%

68.0%

Powercycleefficiency:b

24.2%

20.1%

Overallplantefficiency:c

15.1%

12.5%

SOURCE:Schmidtetal.(1983).
a
IdealRankinecycle.
b
Includesenginecomponentefficiencies.
c
Includes73percentefficientcollectors,fieldheatloss,andtrackingandcontrolparasitics.

Anexampleofonesuchcomparisonbetweensteamandtoluenewasperformedforthedesignofapointfocus,
centralplantsolarpowersystemnowoperatinginKuwait(Schmidtetal.,1983).Thebasiccycledesign
parameterswerethatthesystemwastoproduce100kWofelectricalpowerwiththecollectorfieldproducinga
maximumtemperatureof340C(644F).Acomparisonofsomeoftheresultsofthisdesigncomparisonisgiven
inTable12.3.
ItcanbeseeninTable12.3thatthereareadvantagesintheuseoftoluene,bothinthethermodynamiccycle
designandinthedesignoftheturbine.Notethattheresultingturbineforthetoluenecyclewaslargerin
diameter,lowerinspeed,andlesscomplex(fewerstages).Thisresultsinhigherturbineefficiency(andprobably
alowercost).
Afterapplyingalltheparasiticenergylosses,thefinaltoluenecycleefficiencyishigher,givingahigheroverall
systemefficiency(whichincludescollectorandfieldpipinglosses).Inselectingthetoluenedesign,the
advantagesanddisadvantagesofeachfluidaresummarizedbelow:
1.Advantagestoluene:
Smallturbineheadallowsformoderateshaftspeedandasingleortwostagedesign.
Lowvolumeratiofacilitatestheflowpathdesign.
Highvolumeflowandlowvelocityofsoundresultsinreasonableflowareas.
Lowtemperaturedropduringexpansionreducesthermalstressproblems.
Dryexpansionavoidsbladeerosioncausedbyvaporwetness.
Lowsystempressurefacilitateshousingdesign.
2.Advantages steam:
Wellestablisheddesignproceduresavailable.
Wellknownfluidproperties.
Sealingofshafthousingnotcritical.
3.Problemareas toluene:
Limitationofturbineheadduetolowvelocityofsound(Machnumberofrotorblades).
Adequatesealingandventilationrequiredbecauseofflammabilityandtoxicityoffluid.
4,Problemareas steam:
Verysmallnozzledimensionscallforpartialadmissionandveryhighshaftspeed.
Highturbineheadcallsformultistageturbine.
Highvolumeratioimposesproblemsontheflowpathdesign.
Highperformanceturbinesnotavailable.
InamajorstudyofRankinecyclesusingdifferentfluids,Marciniaketal.(1981)concludedthatfortemperatures
below371C(700F),steamRankinecyclesbecomelessefficientandmoreexpensivethanorganicfluidcycles.
Nosignificanthealthorsafetyproblemswereforeseenfortheworkingfluidsstudied(methanol,2methylpyridine/
H2O,Fluorinol85,Toluene,andFreonR11andRIl3).Themajordisadvantagesofthesefluidsistheirrelatively
lowthermalstabilitytemperatureandpotentialmaterialcompatibilityproblems.
TheadvantageofusingorganicworkingfluidsinRankinecyclesofsmallsizesandoperatingatlowtemperature
http://www.powerfromthesun.net/Book/chapter12/chapter12.html

19/46

6/3/2016

PowerFromtheSun::Chapter12

canbesummedupintermsofthefollowingproperties(Abbin,1983):(1)highmolecularweightresultsinsimpler,
moreefficientlowpowerturbineexpanders(2)lowfreezingpointandnoexpansiononfreezing(3)highvapor
pressureatlowtemperaturereducesairleakagecontaminationand(4)heatadditioncharacteristicscanbe
closelymatchedtotheheatsourcecharacteristics.
12.2.5CycleAnalysis
Cycleanalysisistheprocessofdeterminingthepropertiesoftheworkingfluidasitpassesthroughthevarious
processesinthecycle.Oncethepropertiesateachstatehavebeendetermined,thesizeofthecomponentsmay
bedeterminedalongwiththerateofheattransferorworktoorfromeach.Theoverallthermodynamiccycle
efficiencymaythenbecalculated.
Thesequencerequiredforthisanalysisispresentedasanalgorithmthatcouldreadilybeincorporatedintoa
cycleanalysiscomputerprogram.However,amethodofinputtingworkingfluidthermodynamicpropertiesatthe
variousstatesmustalsobeincorporated.
SomethermodynamicpropertyalgorithmswerediscussedinSectionl2.2.4.Becausethesealgorithmsare
complexorrequiresignificantstorageandprocessingtime,afullcycleanalysiscomputerprogramisnotincluded
here.Theinteresteddesignercoulddevelopsuchaprogrambycombiningthecycleanalysisalgorithmgiven
herewithathermodynamicpropertiesalgorithmconsideredappropriatefortheapplication.Manycompanies
havedevelopedsuchprograms,andatleastonecode,hasbeenreportedbyAbbinandLeuenberger(1974).
Cycleanalysisusuallystartswithknowingthenetoutputpowerrequiredfromthecyclealongwiththevapor
generator(boiler)exitandcondenserexitstates.Thesearedeterminedbythecycledesignprocedures
discussedintheprevioussection.Turbineandpumpisentropicefficienciesareeitherknownorassumed.
Thenextstepsinvolvedeterminationofthethermodynamicstate(andproperties)oftheworkingfluidattheinlet
andoutletofeachcomponentinthecycle.Themostimportantpropertytobefoundistheenthalpy.
Atthispointthecyclethermodynamicefficiencymaybedeterminedsinceitdoesnotdependonthesizeofthe
components.Componentsizingisthendonebycalculatingthemassflowraterequiredforthedefinedoutput
power.Finally,therateofenergytransferforeachcomponentmaybecalculated.
Sincethisprocedurediffersforeachcycleconfiguration,eachconfigurationistreatedseparatelyinthefollowing
subsections.Noparasiticpressuredroporheatlossisincludedbutcouldbeaddedifconsideredsignificant.
TheSimpleRankineCycle.ThesimpleRankinecyclehasonlyfourcomponents,apump,avaporizer,an
expander,andacondenserasshowninFigure12.15.Theworkingfluidisawettingworkingfluid(thedryingfluid
usuallyincorporatesregenerationandisdiscussedlater).Thevaporleavingthevaporizerisshowntohe
superheated.Ifthevaporisnotsuperheated,thesaturatedvaporqualityattheturbineexitmustbespecifiedand
becomesthesecondpropertyforspecificationofstate3.Acompletecycleanalysisalgorithmforthiscycleis
givenintheAppendix.

Figure12.15AsimpleRankinecyclewithsuperheatedvaporattheturbineinlet.

RankineCyclewithReheat.ReheatisoftenincludedinlargeRankinecyclesusingwettingfluidssothatthe
boilercanoperateathighertemperaturesandstillprovideforlowmoisturecontentattheturbineexit.To
accomplishthis,twoturbinesareused,oftenonthesameshaft.AcyclediagramdepictingthisisshowninFigure
12.16.Vaporexitsfromthefirstexpanderreturnstothevaporizer,whereitisreheatedtoitsoriginaltemperature
(butatalowerpressure)andentersasecondexpander,wherethepressuredropstothecondenserpressure.
ThecompletecycleanalysisalgorithmforthiscycleisgivenintheAppendix.

http://www.powerfromthesun.net/Book/chapter12/chapter12.html

20/46

6/3/2016

PowerFromtheSun::Chapter12

Figure12.16ARankinecyclewithreheatofthepartiallyexpandedvapor.

RankineCyclewithOpenFeedwaterHeating.Withopenfeedwaterheating,asmallpercentageofpartially
expandedvaporisextractedfromtheturbineandmixeddirectlywiththecompressedliquid(feedwater)to
preheatitbeforegoingintothevaporizer.ARankinecycleincorporatinganopenfeedwaterheaterisshownin
Figure12.17.Theextractionflowat6isdeterminedbytheamountofheatrequiredtoraisethetemperatureof
thefeedwaterfromstate2tostate3.Becausethemassflowsaredifferentatdifferentpointsinthecycle,
analysisofthecyclebecomesslightlymoreinvolved.Thecompletecycleanalysisalgorithmforthiscycleisgiven
intheAppendix.

Figure12.17ARankinecyclewithopenfeedwaterheatingofthecompressedliquid.

RankineCyclewithClosedFeedwaterHeating.ARankinecyclewithaclosedfeedwaterheaterisshownin
Figure12.18.Againtherateofextractionflowat5isdeterminedbytheenthalpyriserequiredbetweenstates2
and3.Thecondensationfromthefeedwaterheater(calleddrips)inthisexampleisthrottledthroughaliquid
trapbackinthecondenserat8.Analternativeusedsometimeswouldbetoreplacethetrapwithasmallpump
andreinjectthecondensateatstate2.AcompletecycleanalysisalgorithmforthiscycleisgivenintheAppendix.

http://www.powerfromthesun.net/Book/chapter12/chapter12.html

21/46

6/3/2016

PowerFromtheSun::Chapter12

Figure12.18ARankinecyclewithclosedfeedwaterheatingofthecompressedliquid.

RankineCyclewithRegeneration.Whenadryingfluidisusedastheworkingfluid,theturbineexitstreamisata
highertemperaturethanthepumpexittemperature.Insteadofbeingplaceddirectlyinthecondenser,theturbine
exhaustcanfirstpassthroughaheatexchangerwiththewasteheatbeingusedtopreheatthecompressedliquid
beforeitentersthevaporizer.Thisheatexchanger,calledaregeneratororarecuperator,isshowninFigure
12.19.ThecycleanalysisalgorithmforthiscycleisgivenintheAppendix.

Figure12.19ARankinecyclewithfullflowregenerationusingadryingtypeworkingfluid.

12.2.6ExamplesofSolarRankineCycles
MostsolarpowercyclesinoperationorunderdevelopmenttodayareRankinecycles.Wediscusstheimportant
cycledesigncharacteristicsoffourofthesebelow.Eachrepresentsanoptimumsolutiontoadifferentdesign
problemintermsofmaximumtemperature,poweroutput,orexternaldemands.Theircharacteristicsare
summarizedinTable12.4.

Table 12.4. Characteristics of Selected Solar Rankine Power Cycles


Parameter
Tmax

Coolidge

Shenandoah

DishORC

SolarOne

268C

382C

400C

516C

http://www.powerfromthesun.net/Book/chapter12/chapter12.html

22/46

6/3/2016

PowerFromtheSun::Chapter12

Tcond

40.5C

110C

45C

43C

Power

240kW

430kWa

26kW

12,900kW

Workingfluid

Toluene

Steam

Toluene

Steam

Heattransfer
fluid

Heattransferfluid

Receiverboiling

Receiverboiling

Cycleefficiency

24%

17%b

24%

35%

PercentofCarnot

57%

41%

45%

58%

Turbineinletstate

50Cof
superheat

117Cof
superheat

103Cof
superheat

198Cof
superheat

Regeneration

Regenerator

1FWHc

Regenerator

4FWHc

Turbinestages

17

58.7cm

10.2cm

12.5cm

64.5 115.3cm

9300rpm

42,480rpm

60,000rpm

3600rpm

Heatadditionmethod

Meanturbine
diameter
Speed
a

Plusbleedprocesssteamandabsorptionchillerheat.

Notincludingbleedorchilling.
c
Feedwaterheaters(FWH).

CoolidgeIrrigationSystem.ThecycledesignedfortheCoolidge(Arizona)DeepWellIrrigationSystemisa
regenerativeorganicRankinecyclesimilartothatshowninFigure12.19(Rankinecyclewithfullflow
regenerationusingadryingtypeworkingfluid).Anintermediateheattransferfluidisusedfortransferofenergy
fromthecollectorfieldtothepowercycleandforthermalenergystorage.Thepowercycleproduces150kW
(net),withamaximumturbineinlettemperatureof268C(515F).Toluenesuperheatedby50C(90F)was
chosenastheworkingfluidforthiscyclebecauseofthelowoutputpowerofthesystemandtherelativelylow
temperaturecomingfromthefieldofparabolictroughconcentrators.Theturbine,aradialoutflowdesignhasa
maximumdiameterof58.7cm(23.1in.)andturnsat9300rpm.
Themaximumefficiencyofthiscycleis24percent,whichis57percentoftheefficiencyofaCarnotengine
operatingatthesamepeaktemperatures.ThepowercyclewasbuiltbySundstrand,Inc.andisamodified
versionofacommercialpowercycleusedforwasteheatrecovery.Thissolarenergysystemisdescribedfurther
inChapter16.

ShenandoahTotalEnergySystem.ThepowercycleattheShenandoah(Georgia)SolarTotalEnergyProjectis
aRankinecycleusingsuperheatedsteam.Heatissuppliedfromafieldofparabolicdishesbyanintermediate
heattransferfluid.OneopenfeedwaterheaterisusedinacyclethatresemblesthatshowninFigure12.17.
Operatingwithamaximumturbineinlettemperatureof382C(720F),thesystemisdesignedtoproduce430
kWofshaftpowerinadditiontoprovidingprocesssteamat173C(343F)andahighheatrejectiontemperature
tooperateanabsorptionchiller.
Therequirementforprocesssteamandahighcondensertemperatureforcedthedesigntowardtheuseofsteam
eventhoughthepoweroutputandoperatingtemperatureareintherangewhereorganicfluidsusuallyprove
optimum.Thesteamenteringtheturbinehasbeensuperheatedby117C(211F).Theturbinedevelopedforthis
systembyMechanicalTechnologies,Inc.consistsofatwostageaxialflowhighpressuresectionandatwo
stageaxialflowlowpressuresectionwithameanbladediameterofl0.2cm(4in.).Atmaximumpower,the
turbinerotatesat42,480rpm.
Theoverallpowercycleefficiencyis17percentwhichis42percentofthemaximumpossible.However,this
efficiencyvaluedoesnotincludetheusefulenergyinthesteambledforprocesssteamorthehightemperature
rejectedheatusedtopoweranabsorptioncooler.ThissolarenergysystemisdescribedfurtherinChapter16.

SmallCommunitiesProject.TheorganicRankinecycledesignedfortheU.S.DepartmentofEnergy'sSmall
CommunitiesProjectbyBarberNicholsEngineeringisdesignedtobeplacedatthefocusofasingleparabolic
dishconcentrator.ThissmallregenerativeunithasacyclesimilartothatpicturedinFigure12.19.Itisdesignedto
produce26kWofshaftpowerwithapeakoperatingtemperatureof400C(752F).Theworkingfluidistoluene.
However,theoperatingtemperatureapproachesthelimitsofthisfluid,andover100C(180F)ofsuperheatis
usedtotakeadvantageofthetemperaturecapabilityoftheparabolicdishheatsource.
http://www.powerfromthesun.net/Book/chapter12/chapter12.html

23/46

6/3/2016

PowerFromtheSun::Chapter12

Figure12.20Theturbine,alternator,andpumpassemblyfortheBarberNicholssolarRankinecycleenginemodule.

Inordertoenhancetheefficiencyofsuchasmallsystem,theturbine,pump,andalternatorareincorporatedon
thesameshaftaspicturedinFigure12.20.Thisconceptalsoeliminatesadynamicshaftseal,enhancingits
servicelife.Thesinglestage,axialflowturbinespinsat60,000rpmandhasameanbladediameterof12.5cm
(4.9in.).Thisenginehasathermalefficiencyof24percentwhichis45percentoftheidealCarnotefficiency.

SolarOnePilotPlant.ThedesignconditionsfortheSolarOnecentralreceiverpilotplant,meetthesteam
RankinecycleminimumofbothpowerandtemperaturediscussedinSection12.2.3.Operatingatamaximum
temperatureof516C(916F)andproducing12.9MWofshaftpower,theworkingfluidchoicewassteam.The
steamboilsandissuperheatedinthereceiver,thuseliminatingtheneedforanintermediateheattransferfluid
andresultingpinchpointmatchingproblems.Fourstagesoffeedwaterheatingareused,threeclosedandone
anopendeaeratorasdepictedinFigure12.21.TheturbineforSolarOnehas17axialflowstageswithblade
diametersof32.3to57.7cm(12.7to22.7in.),usingblades2.23to15.5cm(0.89to6.11in.)long.Theturbine
turnsat3600rpm,whichisthenormalspeedformostlargescalesteamelectricpowergeneratingplants.At
theseconditions,thiscyclehasanoverallefficiencyof35percent,whichis58percentoftheidealcycleefficiency
attheseoperatingconditions.AdditionaldetailsofthedesignofthissystemaregiveninChapter16.

http://www.powerfromthesun.net/Book/chapter12/chapter12.html

24/46

6/3/2016

PowerFromtheSun::Chapter12

Figure12.21Schematicofthel0MWesteamRankinecycleattheSolarOnepilotplantatBarstow,California.

12.3Stirling Cycle Engines


12.3.1CycleDescription
TheStirlingengineisbeingproposedformanysmall(10to100kW)solarpowerapplicationsbecauseofits
potentialhighcycleefficiency(seeBowyer,1984).Infact,ideally,aStirlingcycleenginecanbedesignedtohave
thesameefficiencyastheidealCarnotcycleengine.AsdiscussedinSection12.1.2,cycleefficiencyisofprime
importancetosolarpowercycledesignbecauseofthereductionincollectorarea(andthuscost)foragiven
poweroutput.MostproposedStirlingapplicationsareforsmall(10to100kW)enginesplacedatthefocusofa
parabolicdishconcentrator.Thisis,because,insmallmoduleapplications,therealefficiencyofRankinecycle
enginesisseriouslydegraded,drawingthesolarpowersystemdesignertowardthehighefficiencypotentialof
theStirlingengineinthissizerange.
TheIdealCycle.TheidealStirlingcyclecombinesfourprocesses,twoconstanttemperatureprocessesandtwo
constantvolumeprocesses.Theseprocessesareshownonpressurevolumeandtemperatureentropy
coordinatesinFigure12.22.Workisdoneon,orproducedbythecycleonlyduringtheconstanttemperature
processeshowever,heatmustbetransferredduringallfourprocesses.Ratherthanaworkingfluidthatchanges
phaseduringtheprocesses,gasesarenormallyemployedastheStirlingcycleworkingfluid.Theprocesslinesin
Figure12.22reflectthepropertiesofanidealgas.

http://www.powerfromthesun.net/Book/chapter12/chapter12.html

25/46

6/3/2016

PowerFromtheSun::Chapter12

Figure12.22ThefourprocessesofanidealStirlingenginecycle.

Intheidealcycle,heatisrejectedandworkisdoneontheworkingfluidduringtheisothermalcompression
process12.Forafixedmassofworkingfluid,theamountoftotalworkrequiredforthisprocessisrepresented
bythearea1 2 b aonthepressurevolume(pv)diagramandtheamountofheattransferredfromtheworking
fluid,byarea12baonthetemperatureentropy(T s)diagram.Thenextprocessistheconstantvolumeheat
additionprocess(2 3),wherethetemperatureisraisedfromTLtoTHandthereisnoworkdone.Theheat
additionisrepresentedbythearea2 3 c bintheT sdiagram.Followingthisistheconstanttemperature
expansionprocess(3 4),whereworkisdonebytheworkingfluidasheatisadded.Theworkisrepresentedby
theareab34 ainthep diagramandtheheatadditionbyareac 3 4 dintheTsdiagram.Thecycleis
closedbyaconstantvolumeheatrejectionprocess(4 1),wherenoworkisdoneandtheheatrejectedis
representedbyareaa 1 4 dintheTsdiagram.
Becausemoreworkisdonebyexpandingagasathightemperaturethanisrequiredtocompressthesame
amountofgasatalowtemperature,theStirlingcycleproducesanetamountofwork.Thenetworkis
representedbyarea1 2 3 4inthep vdiagraminFigure12.22.Bythefirstlawofthermodynamics,thisisalso
thenetamountofheatthatmustbeaddedtothecycletoproducethiswork.Thisnetamountofheatis
representedbythearea1 2 3 4intheTsdiagram.
TheonlydifferencebetweentheStirlingandCarnotcyclesisthatfortheCarnotcyclethereisnoheattransfer
duringprocesses2 3and4 1.Becausetheseprocessesrepresentanequalamountofheatingandcoolingof
theworkingfluidwithnoworkinvolved,aregeneratormaybeusedthatsavestheheatrepresentedbyarea1 4
eintheTsdiagramandtransfersittotheworkingfluidduringthecompressionprocess2 3asrepresentedby
area2 3 fonthesamediagram.Byeliminatingtheneedtotransferheatfromanexternalsourceat
temperaturesotherthanthemaximumandminimumcycletemperatures,theregenerativeStirlingcyclewillhave
(intheidealcase)thesameefficiencyasaCarnotcycle.
TheamountofworkandheattransferforeachprocessofanidealStirlingcyclewithregenerationmaybe
describedforafixedmassofanidealgas.Forthecompression heat rejectionprocess(1 2),theworkdoneon
thegasis

(12.17)
wherepisthepressure,Visthetotalvolume,TListhecyclelowtemperature, Ristheuniversalgasconstant,
themolecularweightofthegas,andmisthemass.Thevaluewillbenegativebecauseofthesignconvention
thatworkdoneonthecycleisnegative.Theamountofheattransferforthisprocessisthesamesincethereisno
changeoftemperatureofthegas:
(12.18)
Similarly,forthehightemperatureexpansionprocess

(12.19)
http://www.powerfromthesun.net/Book/chapter12/chapter12.html

26/46

6/3/2016

PowerFromtheSun::Chapter12

and
(12.20)
wherethistimethequantityispositivesinceEquations(12.19)and(12.20)representworkdonebythesystem
andheataddedtothesystem.
Thetotalheatthatmustbesavedandtransferredbytheregeneratoris
(12.21)
wherec v,isthespecificheatatconstantvolumeofthatparticulargasperunitmass.
Thenetworkproducedbythecycleis
(12.22)
anditcanbeshownbycombiningEquations(12.22)and(12.20),thatthecycleefficiencyreducesto
(12.23)
whichisexactlytheCarnotcycleefficiency.
12.3.2RealEngineAnalysis
ThedesignofamechanicaldevicethatperformsthecycledepictedinFigure12.22isnotaneasytask.Because
oftheconstantvolumecompressionandexpansionprocessesinvolved,areciprocatingpistoncylinder
arrangementisnormallyused.AccordingtoMartini(1980)traditionalStirlingengineshaveemployedoneofthree
basicarrangements(seeFigure12.23).

Figure12.23MaintypesofStirlingenginecomponentarrangements.

Thealphatypeusestwopistons.Thesepistonsmutuallycompresstheworkinggasinthecoldspacemoveit
througharegeneratortothehotspacewhereitisexpandedandthenmoveitbacktothecoldspace,completing
thecycle.AvariationcalledtheRiniaarrangementusesdoubleactingpistonswiththecompressionspace,which
isasealedchamberonthebacksideoftheadjacentpiston.Foursuchpistonsareconnectedtogetherinthe
http://www.powerfromthesun.net/Book/chapter12/chapter12.html

27/46

6/3/2016

PowerFromtheSun::Chapter12

UnitedStirlingModel495enginecurrentlybeingtestedforsolarpowerapplications.
Thebetaandgammatypesuseapowerpistonandadisplacerpiston.Thepowerpistondoesthecompression
andexpansionofthegas,andthedisplacerpushesthegasfromthehottothecoldspaceandback.The
displacerarrangementwiththedisplacerandpowerpistoninlineiscalledabetaarrangement.Whenthepower
pistonisoffsetfromthedisplacertoprovideasimplemechanicalarrangement,itiscalledagammatype.Inthe
exampleshownofthistype,theregeneratormovesthroughthegasratherthanusingadisplacertomovethe
gasthroughtheregenerator.
Inpractice,theprocessesoccurringintheenginesarenotideal.Figure12.24showsatypicalpressure volume
plotofarealcycleandhowthecyclemightbeimplementedbyuseofanalphatypearrangement.Thereare
threeimportantfactorsthatmaketheactualcyclediagramresembleFigure12.24morethanFigure12.22.These
aresinusoidalmotionofthepistons,imperfectregeneration,anddeadvolume.Theeffectsofthesefactorsonthe
cycledesignarediscussedintheparagraphsthatfollow.

Figure12.24CyclediagramshowingtypicalrealprocessesofaStirlingreciprocatingengine.Theexamplepicturedusesan
alphatypearrangement.

OneofthemajorcausesofinefficiencyintheStirlingcycleistheregenerator.AswithRankinecycle
regeneration,aneffectiveness,emaybedefinedas
(12.24)
wherethesubscriptsH,L,andRrefertothehigh,low,andregeneratortemperatures,respectively.HereTRis
themassaveragedgastemperatureleavingtheregeneratorduringheating.Theheattransferfromthe
regeneratortothegasnolongerisexpressedasEquation(12.21)butbecomes
(12.25)
Theremainderoftheheatrequiredtoraisetheworkinggastoitshightemperatureissuppliedbytheexternal
heatsourceandis
(12.26)
ThetotalamountofheatinputtothecycleisthesumofEquations(12.26)and(12.20):
http://www.powerfromthesun.net/Book/chapter12/chapter12.html

28/46

6/3/2016

PowerFromtheSun::Chapter12

(12.27)
ThecycleefficiencyforaStirlingenginewithimperfectregenerationthenbecomes
(12.28)
wherekistheratioofspecificheats(c p/c v ).
RegenerationisnotnecessarilyrequiredforaStirlingcycle.ThiscanbeseenbyexaminingEquation(12.28)and
notingthattheefficiencydoesnotbecomezerowheneiszero.
TheothermajorcauseofStirlingcycleinefficiencyisthefactthatnotallthegasintheengineparticipatesinthe
cycle.Thisvolumeofgasiscalledthedeadvolume.Thisincludesthevolumeofgasremaininginthe
regenerator,heater,coolerandnecessaryclearancevolumes.TheeffectofdeadvolumeaccordingtoMartini
(1980)istodecreasetheworkdonepercycleinalmostlinearproportiontothepercentageofdeadvolumeinthe
cycle.Bowyer(1983)indicatesthatthereductionofcycleefficiencyalsovariesapproximatelywiththepercentage
ofdeadvolumeintheengine.Therefore,anenginewith20percentdeadvolumewouldproduceonly
approximately80percentofthepoweritwouldhaveproducedwithnodeadvolume,andatapproximately80
percentoftheefficiency.
CalculationofthecycleefficiencyandotherenginedesignparametersforaStirlingenginewithdeadvolumeand
anonidealregeneratortypicallyinvolvesanumericalanalysis,whichisbeyondthescopeofthistext.The
interestedreaderisreferredtoMartini(1980)andUrieliandBerchowitz(1983)fordetaileddesignprocedures
includingspecificexamples.

12.3.3EngineDesignFeatures
ThechoiceofaworkinggasforaStirlingcycleisbasedmostlyonthethermalconductivityofthegas.Ahigh
thermalconductivityisneededtoprovideadequateheattransferratestoandfromthegas.Intypicalengine
designs,eachofthefourprocessesmusttakeplaceinapproximately0.01seconds.Therefore,mostStirling
cycledesignstodayhavedeviatedfromthetraditionalworkinggas,air,tohydrogenorhelium.Hydrogenhasa
higherthermalconductivitythanair(40percentgreaterat500C)andwouldbeexpectedtobethedominant
choice.However,theratioofspecificheatsforhelium,whichisamonatomicgas,ishigherandtheeffectof
imperfectregenerationnotedinEquation(12.28)becomesless.Thesecounteractingfactorsmakethechoice
betweenthetwogassesapproximatelyeven,andotherfactorssuchasmaterialscompatibilityandsealing
becomethedecidingcriteria
IndevelopingtheStirlingcycleforautomotiveandsolarpowergeneratingapplications,itisnecessarytovarythe
enginepoweroutputrapidly.Thismaybedonebyreducingtheheatertemperature.However,astrategyto
maintainstabilizedenginetemperaturesandstillreducepoweristoreducethepressureoftheworkinggas.This
reducestheamountofgasineachprocessandhencethepoweroutput.
12.3.4TheSolar495Engine
TheSolar495StirlingenginewasdevelopedbyUnitedStirling,Inc.ofSwedenasanoutgrowthoftheir
automotiveenginedevelopmentprogram.Operatingonaparabolicdishconcentrator,thisenginehasproduced
22kWofshaftpoweratathermalefficiencyofapproximately38percent.TheengineispicturedinFigure12.25.

Figure12.25TheUnitedStirlingModel495solarStirlingengine.
http://www.powerfromthesun.net/Book/chapter12/chapter12.html

29/46

6/3/2016

PowerFromtheSun::Chapter12

The495enginehasfourdoubleactingpistonsinanalphatypeRiniaarrangementwherethetop(hot)chamber
worksinconjunctionwiththebottom(cool)chamberofanadjacentpistonthroughtheheater,regenerator,and
cooler.Theheaterconsistsof72smalldiametertubesshapedinaconethatformsthebacksideofacavity
receiver.Thesetubesconnectthecylindertotheregenerator.Concentratedsolarfluxisabsorbeddirectlyonthe
heatertubes,thusprecludingthenecessityofintermediateheattransfersurfacesorfluids.Theheateroperates
at720C(1328F).Coolingisprovidedbyacoolwatersupply.
Thecoolchamberbehindthepistonissealedfromthecrankcasewiththepistonrodpassingthroughalinear
seal.Linearmotionoftherodismaintainedbyacrossheadthatthenconnectstothecrankshaft,whichrotatesat
1800rpm.Eitherhydrogenorheliummaybeusedasaworkingfluid.Powercontrolisattainedbyincreasingor
decreasingthemeanpressureoftheworkinggasinthecycle.Constantheatertemperatureismaintained
throughthiscontrolsystemsincetheenginespeedisfixedbythe60Hzpowergrid.Atanoutputpowerof25
kW,themaximumgaspressureis18MPa(2611psia).
12.3.5FreePistonStirlingEngine
SealingofreciprocatingenginestopreventgasleakagehasbeenamajorStirlingenginedesignproblem.Inan
attempttocircumventthisproblemandtoeliminatethemechanicalfrictionassociatedwithbearings,crossheads,
andseals,thefreepistonStirlingenginehasbeendeveloped.Inthisdesign,apowerpistonandadisplacer
bouncebackandforthinaharmonicmotionwithmechanicalorgasspringscausingreversalofthemotion.The
requiredphaseangleof90degreesbetweenthemotionsofthetwopistonsismaintainedbymatchingthe
springswiththepistonmasses.Alinearalternatormaybeincorporatedonthepowerpistonandcontainedwithin
theenginegasspace,thuseliminatingrotatingorlinearseals.Onlyelectricalpowerpassesthroughtheengine
casingoninsulatedterminals.
Figure12.26showsanexampleofafreepistonStirlingengineincorporatingalinearalternator.Thepistonhasa
diameterof3.35cm(1.32in.)andastrokeof2.0cm(0.79in.).Whenheatedto650C(1202F),thisengine
produces100Wofalternatingcurrentelectricalpowerwithafrequencyof30Hz.Insolarapplications,theheater
endoftheengineisplacedatthefocalpointofaparabolicdishconcentrator.

Figure12.26AfreepistonStirlingenginemanufacturedbySunpower,Inc.

12.4Brayton Cycle Engines


http://www.powerfromthesun.net/Book/chapter12/chapter12.html

30/46

6/3/2016

PowerFromtheSun::Chapter12

Braytoncycleenginesarebeingconsideredforbothsmallandlargescalepowerapplications.Themajor
advantageofthistypeofengineisthepotentialforlowoperationandmaintenancecosts.Thisenginehasbeen
proposedforparabolicdishpowermodules,whereasmallengineismountedatthefocusoftheconcentrator,
andforcentralreceiversystemswherepressurizedgasisheatedinthecentralreceiver.Operatingatrelatively
lowpressures,theBraytonenginerequireslarge,hotgasreceivers.Themajordrawbacktotheirimplementation
isthehighreceiveroperatingtemperaturesrequiredtogetreasonableefficiencies.MostBraytonenginesarenot
selfsustainingatoperatingtemperaturesbelow480C(900F).
12.4.1IdealBraytonCycles
TheidealsimpleBraytoncycleshowninFigure12.27combinesfourthermodynamicprocessesfortheworking
fluid.Anadiabatic,reversible(andthusisentropic)compressionprocessfromstates1to2raisesthepressureof
theworkingfluidfromthecyclelowpressuretothehighpressure.Heatisthenaddedatconstantpressure(23)
untilthemaximumcycletemperatureisreached.Anadiabaticreversibleexpansionthentakesplace(34)
throughanexpander(usuallyaturbine),whereworkisproduced.Thelowpressuregasisthencooledat
constantpressuretotheinletconditionsofthecompressor(process41).

Figure12.27ThefourprocessesofanidealsimpleBraytoncycleengine.

Theheattransferfortheseprocessesmaybevisualizedonthetemperature entropycoordinatesgiveninFigure
12.27astheareaundertheprocesscurves.Theheataddedtothecyclebeingthetotalcrosshatchedareaand
theheatrejected,theareaunderprocess4 1.Thenetamountofheataddedtothecycleisrepresentedbythe
areaenclosedbytheprocesses.Similarly,thenetworkdonebythecycleisrepresentedbytheenclosedareaon
thepressurevolumecoordinates.
FortheidealsimpleBraytoncycle,cycleefficiencyisdeterminedonlybythepressureratioacrossthe
compressor(orturbine).Thecycleefficiencyis
(12.29)

Figure12.28showsthevariationofcycleefficiencywithenginepressureratioforbothadiatomicgassuchasair
andamonatomicgassuchashelium,argon,orneon.HeliumhasbeenproposedforsolarBraytoncycles
becauseofitsobviousefficiencyadvantageplusitshighheattransfercapabilityandbecauseitisinert.

http://www.powerfromthesun.net/Book/chapter12/chapter12.html

31/46

6/3/2016

PowerFromtheSun::Chapter12

Figure12.28TheidealsimpleBraytoncycleefficiencyformonatomicanddiatomicgases.

Figure12.29showsthephysicalarrangementofthecomponentsofaBraytoncycleengine.Whenairisthe
workingfluid,Braytoncyclesmaybeeitheropenorclosedcycles.Ifclosed,process41iscarriedoutinaheat
exchanger,whereheatistransferredfromtheworkinggastoambientconditions.Ifthecycleisopen,warmairis
dumpedfromtheturbineexhaustintothesurroundingsatstate4andcoolambientair(atstate1)isdrawninto
thecompressor.Forlargescale,openBraytoncycleengines,itisessentialfortheretobenaturalairmovement
pastthesitetoprohibitreinjectionofthewarmexhaust.Ifaworkinggasotherthanairisused,aclosedcycleis
required.

Figure12.29SimpleBraytoncycleengines.Bothopenandclosedcyclesareshown.

Insolarapplications,thereceiveristheheaterandhencewillbepressurizedtothecyclehighpressureifno
intermediateheattransferfluidisused.Sinceidealcycleefficiencyisonlyafunctionofthepressureratioandnot
http://www.powerfromthesun.net/Book/chapter12/chapter12.html

32/46

6/3/2016

PowerFromtheSun::Chapter12

theactualpressure,aBraytoncyclewithprocess2 3atatmosphericpressureandprocess41atsub
atmosphericpressurehasbeenproposed.Themajoradvantageofthiscycleconceptisthatthereceiverdoes
nothavetowithstandhighpressuredifferences,providingforlessstructureandthinnerheatoropticaltransfer
surfaces.Anexampleofthisconcept,theSABC,isdiscussedbelow.
Iftheturbineexittemperature(T4inFigure12.27)ishigherthanthecompressorexittemperatureT2,heatmaybe
transferredfromtheexhauststreamtopreheatthecompressedgasbeforeheataddition.Thisprocessiscalled
regenerationorrecuperation.TheregenerativeBraytoncycleisshowninFigure12.30.

Figure12.30AregenerativeBraytoncycle.RegenerationispossiblewhenT5isgreaterthanT2.

Themaximumpressureratioforwhichregenerationispossiblemaybedefinedintermsofthemaximumand
minimumcycletemperatureas

(12.30)
ThecycleefficiencyforanidealregenerativeBraytoncycleisnotonlyafunctionofthecyclepressureratio,but
alsotheratiooftheminimumtomaximumabsolutecycletemperatureasgivenby

(12.31)
Figure12.31comparestheefficiencyofanidealregenerativecyclewiththesimpleBraytoncycle.Itcanbeseen
thatforatemperatureratioof4andaworkinggaswithk=1.4,engineswithpressureratiosbelow11.31havea
higherefficiencywhenregenerationisused.Infact,forthelimitingcaseofengineswithapressureratioofunity,
theregenerativeenginewillattaintheCarnotcycleefficiencyforthattemperature(75percent).
TheconclusiononereachesfromthesestudiesisthatthehighestefficiencyBraytoncyclesareregenerative
cycleswithlowpressureratios.Ifregenerationisnotused,highpressureratiosarerequiredtoprovidehigh
efficiency.Finally,foragiventemperatureratio,thereisapressureratiobeyondwhichregenerationcannotbe
usedsincetheturbineexhausttemperatureislowerthanthecompressoroutlettemperature.Realengine
considerationsmodifytheseconclusionssomewhat,asisdiscussedbelow.

http://www.powerfromthesun.net/Book/chapter12/chapter12.html

33/46

6/3/2016

PowerFromtheSun::Chapter12

Figure12.31TheregenerativeBraytoncycleefficiencycomparedwiththesimplecycleefficiency.Regenerationisnot
possiblepastthepointwherethetwocurvesintersect.

InanattempttodevelopanenginebasedontheBraytoncyclethathasanefficiencyapproachingthatofthe
Carnotcycle,thesimpleBraytoncyclemaybemodifiedbycombininganumberofstagesofcompressionin
serieswithcoolers(calledintercoolers)betweeneachstage.Likewise,theexpansionprocessisstagedwiththe
gasbeingreheatedbetweeneachstage.Regenerationbetweenthelastturbinestageandthelastcompressor
outletisalsoused.Maximumefficiencyisattainedwhenequalpressureratiosaremaintainedacrosseach
compressorandeachturbinestage.
AnexampleofmultistagingisshowninFigure12.32,wheretwostagesareillustrated.Theendresultofmulti
stagingisthattheheattransferprocessesoccuratahigheraveragetemperature.Inthelimit,withalarge
numberofstages,theresultingcycleapproachesacycleconsistingoftwoconstantpressureprocessesandtwo
constanttemperatureprocesses.Thiscycle,calledtheEricssoncycle,hasthepotentialofattainingCarnot
efficiencyaslongasregenerationisused.

Figure12.32AmultistageBraytoncycleenginewithintercoolingandregeneration.
http://www.powerfromthesun.net/Book/chapter12/chapter12.html

34/46

6/3/2016

PowerFromtheSun::Chapter12

TheefficiencyofthemultistageBraytoncycleshowninFigure12.32isthesameastheefficiencyofeitherofits
sections.Theheattransferandworkaresimplythesumof'thatrequiredforeachsection.Themajoradvantage
ofmultistagingisthattheenginecanhavethehighefficiencyassociatedwithlowpressureratioregenerative
cycles(seeFigure12.31)withouttheextremelylargeregeneratorrequiredforasinglestagecycleofthesame
poweroutput.
12.4.2RealEngineProcesses
Sofarwehaveconsideredonlycyclesconsistingofidealcomponents.InactualBraytoncycleengines,thereare
threemajorlossesthathaveanimportanteffectontheactualengineefficiency:ductpressurelosses,
turbomachineefficiencies,andregeneratoreffectiveness.
BecausetheworkingfluidforaBraytoncycleisagas,veryhighvolumeratesarerequiredforproductionof
desiredpowerlevels.Thisrequireslargeductsbetweencomponentsandintheheaterandregenerator.With
mostdesigns,thereisasignificantpressuredropintheheater.Whenregenerationisused,thereisapressure
dropacrosstheregenerator.ThesedropsareshowninFigure12.33wherestates2,3,and4asdefinedin
Figure12.30areatdifferentpressures.Thisreducescycleefficiencybyreducingthepressuredropacrossthe
turbine.Similarly,theturbineexitmustbeatahigherpressurethantheinletinordertodrivethegasthroughthe
regeneratorandtocauseittoflowawayfromtheengine.Inanopencycle,theturbineexitpressurep5,is
significantlyaboveatmosphericpressureandthecompressorinletpressurep1,belowambientpressure.
Incycleanalysis,thesepressurelossesarecombinedintoasinglefactorcalledtheducting(orpumping)
efficiency.UsingthestatedesignationsofFigure12.33,wecandefinetheductingefficiencyisas
(12.32)
AsdiscussedforRankinecycles,theturbineorcompressorefficiencymaybeexpressedintermsoftheactual
enthalpydropacrossthemachinecomparedtotheenthalpydropforanisentropicprocessbetweenthesame
twopressures.TheefficiencyofthecompressorshowninFigure12.33maybevisualizedastheratiobetween
thelengthsofline12sandline12.State2willalwayshavehigherentropythanstate1unlesssignificant
quantitiesofheatareremovedduringthecompressionprocess.Likewise,theturbineefficiencyisrepresentedby
thedifferencebetweenlines4 5and4 5s.

http://www.powerfromthesun.net/Book/chapter12/chapter12.html

35/46

6/3/2016

PowerFromtheSun::Chapter12

Figure12.33Realengineprocessesshowingtheeffectsofductpressureloss,compressorandturbineefficiency,and
regeneratoreffectiveness.

Ifaconstantspecificheatisassumed,theturbineefficiencymaybewrittenas
(12.33)
Asimilarexpressionmaybewrittenfortheisentropicefficiencyofthecompressor.
Thethirdsourceofdeviationbetweenidealandactualcycleprocessesistheregeneratoreffectiveness.Also
discussedindetailintheRankinecyclesectionabove,therealregeneratorwillnotraisethecompressedgas
streamtothemaximumpossibletemperatureT5.Instead,thetemperatureofthepressurizedgasstreamleaving
theregeneratorwillbesomevalue,T3,lessthanT5.FortheregeneratorshowninFigure12.33,theeffectiveness
ofregeneratoris
(12.34)
Toaccountfortheseeffectsinpredictingcycleefficiency,acycleanalysisisnormallyperformed.
12.4.3CycleAnalysis
AcycleanalysisalgorithmfortheBraytoncycleispresentedintheAppendix.AswithRankinecycleanalysis,the
cycledesignermustchoosethemethodofdeterminingthegaspropertiesaccordingtotheleveloraccuracy
http://www.powerfromthesun.net/Book/chapter12/chapter12.html

36/46

6/3/2016

PowerFromtheSun::Chapter12

desired.Thesimplestchoiceisaconstantspecificheat.Thisisusuallyadequateformonatomicgases(helium,
argon,andneon).Sincespecificheatsofdiatomicgases(i.e.,airandhydrogen)varywithtemperature,a
temperaturedependentfunctionshouldbeusedbasedondatagivenintheAppendix.
AnalysisofasimpleBraytoncyclestartswithdefinitionoftheinletconditions,thecompressorpressurerise,and
themaximumcycletemperature.Inaddition,thecomponentefficienciesmustbespecifiedalongwiththenet
powerrequiredfromthecycle.Temperaturesandpressuresarethencalculatedforeverypointinthecycle.The
cycleissizedbycalculatingtheworkinggasflowraterequiredforthedesiredpoweroutput.Theworkorheat
flowsforeachcomponentmaythenbecalculated.
Sincethecycleanalysisprocedureisalmostthesameforsimple,regenerative,andmultistageBraytoncycles,
onlyonealgorithmisgivenintheAppendix.Whenregenerationisnotusedaswiththesimplecycle,the
effectivenessoftheregeneratorissetequaltozero.Formultistagecycles,thecycleefficiencyisthesameasfor
eachcompressorturbinestageusingmaximumregeneration,andthecomponentenergyflowsaresummedfor
eachindividualstage.

12.4.4TheSABCSolarEngine
Aspartofthesolarparabolicdishdevelopmentprogram,twoBraytoncycleengineshavebeendesignedforuse
onparabolicdishconcentrators.Theenginemountsonareceiverthatprovidesairheatingforthecycle.Oneof
theseenginesisthesubatmosphericBraytoncyclecurrentlyunderdevelopmentbyGarrettAiResearch
Corporation.Itisaclosedcyclewhereheatisaddedatatmosphericpressure(0.1MPa)andrejectedatalower
pressure(0.045MPa).Thispermitsthereceivertooperateatatmosphericpressure,thusgreatlysimplifyingthe
receiverdesign.Italsoallowslargerbladeheightsintheturbineandcompressorresultinginhigherefficiency.
Acentrifugalcompressorandradialturbinearemountedonacommonshaftandrotateat71,000rpm.After
beingcompressedtoatmosphericpressure,theairisheatedto871C(1600F),whereitexpandsthroughthe
turbine.Aformedtubesheetcounterflowregeneratorisusedtorecoverheatfromtheturbineexhaust,witha
fancooledcrossflowheatexchangerrejectingtheremainingheattobringthetemperatureoftheairdownto
nearambienttemperature.Directlycoupledtoapermanentmagnetalternator,thecycleisdesignedtoproduce
11kWofelectricityatapeakcycleefficiencyof27percent.TheengineispicturedinFigure12.34alongwiththe
receiverproposedforusewiththeengine.

http://www.powerfromthesun.net/Book/chapter12/chapter12.html

37/46

6/3/2016

PowerFromtheSun::Chapter12

(b)solarmodule

Figure12.34AsolarsubatmosphericBraytoncycleenginecurrentlybeingdevelopedbyGarrettAiResearchforparabolic
dishapplications.

12.4.5TheSAGTSolarEngine
AsolarversionoftheGarrettTurbineEngineCompanysautomotivegasturbineengineiscurrentlyunder
development.Thisengine,whichusesacentrifugalcompressorandradialturbine,operatesat87,000rpmwith
ambientinletconditionsandapeakpressureof0.5MPa.Itisanopencyclewithregenerationprovidedbya
rotaryporousceramicwheelregenerator.Aceramicturbineandceramichotsectioncomponentsareunder
developmentforthisengine,permittingittooperatewithaturbineinlettemperatureapproaching1371C
(2500F).Attheseoperatingconditions,theengineisexpectedtoproduce75kWofpoweratacycleefficiencyof
47percent.Figure12.35picturesthisengine.

Figure12.35AsolarversionoftheGarrettTurbineCompany'sBraytoncycleautomotivegasturbineengine:(a)engine(b)
receiverenginemodule.

12.5Solar Combined With Fossil Fuel Power Cycles


http://www.powerfromthesun.net/Book/chapter12/chapter12.html

38/46

6/3/2016

PowerFromtheSun::Chapter12

Ninesolarthermalpowerplantsutilizingparabolictroughsolarfields,withatotalcapacityof354MWe,werebuilt
between1984and1990intheCaliforniaMojavedesert,representinganinvestmentofaboutUS$1.2billion.The
implementationoftheSolarElectricGenerationSystems(SEGS)inKramerJunctionCaliforniawasa
remarkablesuccessintheintroductionofarenewableenergytechnology.From1984to1990atleastonenew
30or80MWeplantwasconnectedtotheutilitygrideachyearincompressedprojectimplementationcycles
drivenbyattractiverevenuestructuresandgovernmenttaxincentives.
Onthelongestdayoftheyear,June21st,inordertorunaconversioncyclefor24hoursat100%loadata
southernEuropeanlatitude,thesolarcollectorsystemwouldhavetobe280%oversizedtocollectenough
thermalenergysurplusduringthedaytobebufferedinastoragesystemanddischargedduringthenight.Onthe
shortestday,December21st,the280%oversizedsolarcollectorsystemwouldonlycover16hoursoffullload
operation.For24hourfullloadoperationanoversizingorsolarmultiple,of500to700%wouldberequired.
Bothcasesareforcleardaysonly.Underrealweatherconditions,evenhigheroversizingandstoragecapacities
wouldberequired.
Withasolarmultipleof1.0andnostorageonly1,510annualfullloadhourscanbeachievedatalocationlike
AlmerainsouthernSpain.Withoutstorage,butwith20%fieldoversizing,thenumberoffullloadhourscanbe
raisedto2,460h/yr.Evenwithacostly6.0hoursofstorageandasolarmultipleof1.7only3,700annualfullload
hourscanbeachieved.Smallercentralreceiverprojectswith0.5hoursofthermalstorageachieveonlyabout
1,900fullloadhoursunderNorthAfricanmeteorologicalconditions.
Toachievethehighconversionefficienciesrequired,theabovementionedsolarthermalsteamcyclesforesee4
to7stagesoffeedwaterpreheatingandonereheatingoptionswhichconventionalfossilplantscanonlyaffordfor
midtobaseloadoperation,i.e.,for5,000to7,000fullloadhoursperyear.Puresolarthermalelectricity
generationof2,000to3,000fullloadhoursdoesnotonlyhavetobeartheinvestmentinsolarequipment,but
mustalsopayanextracostfortheimprovementoftheconventionalpowerblockequipment.Evenifthesolar
systemwerefreeofcost,anyclientelectricutilitywouldthereforeseektooperatethecostlypowerblockbeyond
puresolaroperationforasmanyhoursaspossiblewithadditionalfossilfiring.Forminimizegeneratingcosts,
fossilfiringwouldrangefrom2,000to5,000annualfullloadhours.
12.5.1SolarEnergyforBoostingCombinedCycles
Whendevelopmentofsolarthermalelectricitygenerationconceptsbegantwentyyearsago,steamcycleswith
over40%conversionefficiencyrepresentedthemostefficientwayofconvertingheatintomechanicalwork.Since
thesolarthermalgenerationofhighpressureandhightemperaturegasfordirectfeedingintogasturbinesis
prohibitivelycostly,mostpresentsolarthermalconceptslikeSolar100andPhoebusfocusonRankinesteam
cyclesforthethermomechanicalconversion.
Inthemeantime,gasturbineshavedevelopeddramatically,pushingefficienciesfrom27%toalmost38%by
increasinginlettemperaturesfrom800Ctoalmost1400Ctoday,whilegasturbineexhausttemperaturehas
simultaneouslyrisenfrom400Cto600C,whichcanbeeffectivelyusedinawasteheatrecoveryboiler.With
therecentlyannouncedABBGT24/26gasturbines,forexample,combinedcycleefficienciesofover58%are
expected.Thistrendindicates,thatcombinedcycleefficienciescouldpotentiallyreachalmost60%efficiency
beforethefirstcommercialSolar100orPhoebus100puresteamcyclecentralreceiversystemiseven
connectedtothegrid,andquestionstheadvantagesofthefuelsavingsandemissionreductionsofhybrid
solar/fossilsteamcycleplantsoverpuregasfiredcombinedcycleplants.
Likesolarthermalplants,coalplantsarealsofacedbythecombinedcyclechallenge.Theheatfromclassicalcoal
firingcannotbefedintogasturbinesascantheheatfromcurrentsolarthermalsystems,buthastobeutilizedvia
steamgeneratorsinsteamcyclesystems.However,newcombustionconceptsarenowbeingdevelopedand
demonstratedthatwouldovercometheresultingdisadvantagesofefficiencyandemissions,allowingthecoal
energytobefedintocombinedcyclesystems.
Figure12.36illustratesandcomparesrelativeCO2emissionsandtherebyrelativefuelconsumptionsofthe
variousfossilandhybridpowerplantconcepts.TheFERCregulationsinCalifornia,withtheirmaximum
additionalfossilfiringof25%ofthefuelconsumption,limitthecorrespondingemissionstowellbelowthelevelof
comparablefossilsingleandcombinedcycles.At7000annualfullloadhours,however,neitheraparabolic
troughnoracentralreceiversteamcycleplantwouldhaveasignificantfuelsavingorpollutionreduction
advantageoverafutureadvanced60%combinedcycle,providednaturalgasisusedasthebackupfuel.

http://www.powerfromthesun.net/Book/chapter12/chapter12.html

39/46

6/3/2016

PowerFromtheSun::Chapter12

Figure12.36RelativeCO2emissionsoffossilandhybridpowerplants.

Onlytheintegrationofsolarfieldsintocombinedcyclesystemswillalsomaintainthefuelsavingandemission
reductionadvantageofsolarthermalplantsoveranykindoffossilcycleinthefuture.Insuchaconfigurationthe
solarfieldwouldboostthehighfuelefficiencyoftheseupcomingcombinedcycleswithfurthersignificant
enhancement.
Figure12.37illustratesthetemperaturedifferencesbetweentheexhaustgashotstreamandthesteam/water
streamsalongtheflowpathofsingle,dualandtriplepressurewasteheatrecoveryboilers.Sincesolarsteam
generatorswithsinglephaseair,moltensaltandoilheattransfermediahavepinchpointproblemssimilartoa
wasteheatrecoveryboiler,theircurvesarealsoincludedinFigure12.37.

Figure12.37Heattransferinfossilfueled,combinedcyclepowerplantswithwasteheatrecoveryboilers.

Theapproachoftheexhaustgasorsolarheattransfermediumtothesaturationtemperaturethepinchpoint
stronglyinfluencesthemagnitudeofthearearequiredforheattransferintheunit.Inallthesesensibleheat
steamgenerators,6070%ofheattransferoccursinthesteamgenerationsection(s)ataboilingpointunder
400C,whileonly1520%oftheheattransferoccursabove400Cinthesuperheatersandreheaters.
http://www.powerfromthesun.net/Book/chapter12/chapter12.html

40/46

6/3/2016

PowerFromtheSun::Chapter12

InaconventionalcombustionturbinecombinedcycleplantsuchastheoneshowninFigure12.38thewasteheat
fromtheBraytoncycleisusedtogenerateandsuperheatsteamfortheRankinecycleinthewasteheatrecovery
system.Thesteamturbinemayoperateatanefficiencyaslowas24%duetosteampressureandtemperature
restrictionscausedbytheadmissiblemoisturecontentinthefinalexpansionstages.

Figure12.38Schematicflowdiagramofaconventionalfossilfueledcombinedcyclepowerplant

Inaconventionalsteamplant,muchhigherefficienciesarepossiblethroughhighsuperheatand/orreheating,but
inapurecombinedcyclesteampressureisrestrictedto4060baratsuperheattemperaturesof480500Cand
reheatingisnotpossiblesinceinsufficientenergyisavailableathightemperatures.Exhaustgastemperatures
exitingthewasteheatrecoverysystemmaybeundesirablyhigh(increasingexhaustheatlosses)dependingon
fueltypeandthenumberofsteampressurelevels(dualortriplelevelsaremorecomplex,butincrease
efficiency).Confrontedwiththisconstraint,wasteheatrecoveryboilersarefacedwithtradeoffsintheselection
ofthepinchpointinaparticulardesignorapplication.Typicalsteamoutletconditionsforwasteheatrecovery
heatexchangers(WHRHX)foraconventionalfossilfueledcombinedcyclepowerplantaregiveninFigure
12.39.

Figure12.39Steamoutletconditionsforwasteheatrecoveryheatexchangers(WHRHX)foraconventionalfossilfueled
combinedcyclepowerplant.

Ifasolarfieldisaddedinparallelwithawasteheatrecoveryboilerinacombinedcyclesystemasillustratedin
Figure12.40,feedingonlyintermediatepressuresteamintoacorrespondingsteamturbinesysteminlet,nothing
oftheclassicalpinchpointproblemhasbeenchanged.

http://www.powerfromthesun.net/Book/chapter12/chapter12.html

41/46

6/3/2016

PowerFromtheSun::Chapter12

Figure12.40Parallelconnectionofasolarfieldandawasteheatrecoveryboiler.

Aparabolictroughsolarfieldwithabout400Coutlettemperaturecouldideallytakeoverthesteamgeneration
function,sothatthedesignofthewasteheatrecoveryboilerisnolongerdependentonthepinchpointasa
designconstraintandahigherheatrecoveryfactorcanbeachieved.Withnopinchpoint,thefluegasescanbe
cooleddowntoalowertemperature(116Cinsteadof180200C)andmoreenergycanbeextractedfromthem.
Exhaustheatfromthegasturbineisnowusedmoreeffectivelyfromtheviewpointofthe2ndlawof
thermodynamics,sinceitislargelyinputintothecycleatahighertemperature(superheatsection).Insucha
combinedcycleconfiguration,thehightemperatureadvantageofcentralreceiversystemsismuchlessimportant,
sincethesolarfunctionofsteamgenerationrequiresonlytemperaturesofabout400C,whiletherequiredhigh
temperaturesuperheatisprovidedmuchmoreeconomicallybythefreegasturbineexhaust.
Integrationofasolarsystemintoacombinedcycle,asshowninFigure12.41,improvesthesteamparameters
andpermitstheuseofareheatedsteamturbine.Consequently,steamcycleefficiencyincreasestowards40%,
theoverallplantefficiencyrisesandemissionsarereduced.Intheintegratedsolarcombinedcycleplant,thegas
turbinecycleisunchanged.However,steamconditionsaremetbyusingsolarheattogenerateandreheatthe
steamandcombustionturbineexhaustheattobothpreheatthefeedwaterandsuperheatthesteam.

Figure12.41Functionsharingbetweenasolarfieldandawasteheatrecoveryboiler.

Sincenosuperheatingisrequiredfromthesolarsystem,theevaporationtemperaturecanberaisedsothat
steampressureishigher,e.g.,100bar.Thecombustionturbineexhaustisthenusedtosuperheathighpressure
steamtoatemperatureashighas500C.Thesteamturbinecapacityofthecombinedcycleisincreased
considerablyduetotheadditionalenergyfromthesolarsystem.Forexample,aconventionalcombinedcycle
withagasturbinecapacityof60MWewouldutilizeasteamturbineofabout30MWecapacity,whereasinthe
ISCCSdesignsteamturbinecapacityisabout80MWe.Temperatureprofilesfora)aconventionalpowerplant
withwasteheatrecoveryandb)thewasteheatrecoverysysteminanintegratedsolarandcombinedcycle
systemareshowninFigure12.42.

http://www.powerfromthesun.net/Book/chapter12/chapter12.html

42/46

6/3/2016

PowerFromtheSun::Chapter12

Figure12.42Temperatureprofilesfora)aconventionalpowerplantwithwasteheatrecoveryandb)thewasteheat
recoverysysteminanintegratedsolarandcombinedcyclesystem.

Therefore,acombinedcyclesolarparabolictroughplantconfigurationiscurrentlyproposedbyPilkingtonSolar
InternationalforcommercialpowergenerationtheISCCS(IntegratedSolar
andCombinedCycleSystem)conceptshowninFigure12.43.

Figure12.43TheproposedPilkingtonintegratedsolarandcombinedcyclesystem(ISCCS)incorporatingagasturbineplus
100%solarfield.(courtesyPilkingtonSolarInternational,Cologne)

SEGSsteamcycleplantshavebeenconstructedincapacitiesrangingfrom15to80MWenet,andconceptual
designshavebeendevelopedupto200MWecapacity.Itisgenerallytruethatreasonablecostscanbeachieved
at30MWeandabove,thoughthelargersizedplantsclearlybenefitfromeconomiesofscale,andthusaremore
economicallyattractive.BasedonexistingplantdesignsandcurrentSEGSexperience,an80MWeplantis
consideredtobethereferenceconfiguration.Whenasolarsystemiscoupledwithacombinedcycleinthe
ISCCSconfiguration,overallplantcapacitiescanreachover200MWewithoutextendingbeyondthecurrent
experiencewithSEGStypesolarfields.Selectionoftheplantsizeateachsitedepends,ofcourse,onthe
capacityrequirementsandelectricalgridstructureinthatarea.
12.5.2MinimizingCO2Emissions
http://www.powerfromthesun.net/Book/chapter12/chapter12.html

43/46

6/3/2016

PowerFromtheSun::Chapter12

CO2emissionsfromfossilfiredpowerplantsaredirectlyproportionaltofuelconsumption,andarethusinversely
proportionaltotheefficiencyofthefossilfiredconversioncycles.Thecombinationofsolarfieldsandgasfired
combinedcyclesresultsintheminimizationoffueluseand,accordingly,theminimizationofCO2emissions.The
solarfieldmayberegardedasasubsystemenhancingfuelefficiencyinthesamewayclassicalimprovementsof
thermalcyclesdid,e.g.,economizers,preheating,feedwaterheaters,andreheat.
Figure12.44showsthekWhspecificCO2emissionsofvariousconversiontechnologiesforseveralfossilfuels
contributingtothe1990MediterraneanAreaaverageemissionsof0.92kgCO2perkWh.Evenwiththe40%
conversionefficiencyofmodernsteamcycles,coalplantsstillemit0.9kgCO2perkWh.Inordertofurther
decreasetheseemissions,newtechnologieswithenhancedconversionefficiencies,suchastheintegrationof
pressurizedfluidizedbedcoalcombustorsinthe305MWIGCCprojectinPuertollano,arebeingevaluated.
ThespecificinvestmentcostsofUS$1,920perkWinstalledforthisfirstofakinddemonstrationprojectare
beingsharedbyelectricitygeneratingcompaniesoffiveEUcountriesandtheEU.However,thelowestCO2
emissionsof0.4kgCO2perkWhareemittedby50%efficientnaturalgasfiredcombinedcycles.Evengreater
improvementcanbeachievedbytheintegrationofsolartechnologyintothiscycle.
Dependingonthesolarfieldsize,solarirradiationandoperationstrategy,averageemissionsfromthemixed
solar/fossilISCCSoperationcanyield0.1to0.3kgCO2perkWh,whilethepuresolaroperatedSEGShaszero
emissions.ParabolictroughsolarpowerplantshaveanaverageCO2reductioncapacityofapproximately150to
200kgCO2/yearperm ofinstalledsolarfield,dependingonsolarirradiationandoperatingmode.

Figure12.44ComparisonofspecificCO2emissionsofvariousconversiontechnologies.(CourtesyofPilkingtonSolar
International,Cologne)

Dependingonthesizeofthesolarfieldandtheresultingsolarshareofproduction,theequivalentsolarenhanced
fuelefficiency,thatis,annualnetelectricoutputdividedbythelowerheatingvalueofthefuelconsumedinthis
period,canberaisedtoover80%.Thusthecombinationofprovengasfiredcombinedcycletechnologywith
provenparabolictroughsolarthermaltechnologyoffersaparticularlyattractivefossilthermalpowerplant
technologyforthenextdecade.
12.5.3ElectricityYieldandCosts
TheSEGSprojectsinCaliforniaaredesignedandoperatedaspeakingplants,withmaximumoutput
correspondingtothesummerafternoonandeveningpeaksinsouthernCaliforniaduetotheairconditioning
demand.TheattractivenessofsuchparabolictroughplantsforthepowerplantparksofMediterraneancountries
likeSpainisbrieflydiscussedbelow.
Byintegratingprovensolarfieldtechnologyintothemostfuelefficientandadvancedcombinedcyclepower
conversiontechnology,hybridsolar/fossilfiredthermalpowerplantsareabletosupplybaseloadormidload
power.Performanceand,subsequently,electricitycostresultsdependontheplantcontractor'soperating
http://www.powerfromthesun.net/Book/chapter12/chapter12.html

44/46

6/3/2016

PowerFromtheSun::Chapter12

demandscenario.
Toillustratethis,arepresentativemidloaddemandtermedtheregionaldemand,ispresentedhere.Itistypically
comprisedoffullloadoperationduringtheweekdaydaylighthours,partloadonweekdayeveningsandnights,
andsolaronlyduringweekendsandholidays.Thisregionaldemandprofileresultsinuptoabout4,500hoursper
yearoffullloadoperation.PerformancerunsfortheMediterraneanregionwerecarriedoutusinganhourby
hoursolarplantmodeldevelopedbyFLAGSOL,andvalidatedwithoperatingdataobtainedfromtheSEGS
plantsoperatedbytheKramerJunctionCompany,comparingverywellatadetailedlevelbetweenprojectedand
actualresults.
TheperformanceofthesolarfieldsandISCCSplantsvarysomewhatdependingonsizeandsite,butingeneral
intheMediterraneanregionannualsolarfieldthermalefficiencyisabout45%,anannualsolartoelectric
efficiencybasedonnormaldirectsolarirradiationofabout1415%,andanannualsolarenergyproductionof
about800900kWh/m2(thermal).ThissamesolarfieldperformanceisfoundintheISCCSplants,withthe
electricaloutputdependentoncombinedcycleperformanceasafunctionofload.Standardmethodswereused
tocalculatetheLEC(LevelizedElectricityCost)e.g.theLECwasbasedontheInternationalEnergyAgency
methodwiththefollowingeconomicboundaryconditions:6.1%discountrate,1%insurancerate,38%income
tax,6.7%depreciation,3%interestrateonloansduringconstruction,4%fuelandgeneralcostescalationrate
and3%electricitytariffescalationrate.
Levelizedelectricitycostsforan135MWeISCCSsysteminsouthernSpainareestimatedtobe8.3UScents/
kWhintheregionaldemandcase(3500equivalentfullloadhours)and6.8UScents/kWhinthebaseloadcase
(6000equivalentfullloadhours).Forcomparison,astandard80MWeSEGSstationinMorocco,wetcooled
withoutstorage,isestimatedtoproduceelectricityat10.5UScents/kWh.TheLECrisesslightlywiththeaddition
ofthreefullloadhoursofthermalstorageto11.6UScents/kWh.
12.5.4Conclusions
Puresolarthermalelectricitygenerationof2000to3000fullloadhoursmustnotonlybearthesolarequipment
investment,butalsopaytheextracostofimprovingtheconventionalpowerblockequipment.Evenifthesolar
systemwerefreeofcost,anyclientelectricutilitywouldthereforeseektooperatethecostlypowerblockbeyond
puresolaroperationforasmanyhoursaspossiblewithadditionalfossilfiring.Fossilfiringjusttominimizethe
powerblockrelatedgeneratingcosts,isbetween2000and5000annualfullloadhours.
Theintegrationofasolarfieldintoacombustion/steamturbinecombinedcycleincreasestheeffectivenessof
solarinputintheintegratedmode,enhancesthethermodynamicefficiencyofthecombinedcycleandreduces
theemissionsperMWoutputoftheoverallsystemcomparedtoaconventionalcombinedcycle.Thesolarenergy
itselfisusedinsteamturbineswithcomparableefficiencies,butthefossilfuelcontributionismuchmoreeffective
inthecombinedcycleandthustheannualperformanceissignificantlyenhancedinthemidandbaseload
operation.Dependingonthesizeofthesolarfield,solarirradiationandoperatingstrategy,averageemissions
fromthemixedsolar/fossilISCCScanyieldaslittleas0.1to0.3kgCO2perkWh.
Thesolarfieldmayberegardedasasubsystemwhichenhancesfuelefficiencyjustasclassicalthermalcycle
improvements,suchaseconomizers,preheating,feedwaterheaters,andreheat.Theequivalentsolarenhanced
fuelefficiency,thatis,annualnetelectricoutputdividedbythelowerheatingvalueofthefuelconsumedinthis
period,canberaisedtoover80%.Levelizedelectricitycostsforthe135MWeISCCSsysteminsouthernSpain
are8.3UScents/kWhintheregionaldemandcase(3500equivalentfullloadhours)and6.8UScents/kWhin
thebaseloadcase(6000equivalentfullloadhours).

HRandPayrollSystem
OnlinePayslips,PF/ESI/TDS&more30DaysFreeTrial,SignupNow

References
Abbin,J.P.andW.R.Leuenberger(1974),ProgramCYCLE:ARankineCycleAnalysisRoutine,Sandia
NationalLaboratoriesReportSAND740099(revised).
Abbin,J.P.(1983),privatecommunication.
Balj,O.E.(1962),AStudyOnDesignCriteriaandMatchingofTurbomachines:PartsAandB,"Transactions
oftheASMEJournalofEngineeringPower,83 114,January.
Bowyer,J.M.(1983),privatecommunication.
Bowyer,J.M.(1984),TheKinematicStirlingEngineasanEnergyConversionSubsystemforParaboloidalDish
SolarThermalPowerPlants,JetPropulsionLaboratoryReportJPL8430(DOE/JPL106073),April15.
Harrigan,R.W.(1978),"SolarTotalEnergySystemsDesign",SandiaNationalLabs,ReportSAND780449,
August,
http://www.powerfromthesun.net/Book/chapter12/chapter12.html

45/46

6/3/2016

PowerFromtheSun::Chapter12

Marciniak,T.J.,J.L.Krazinski,J.C.Bratis,H.M.Busby,andE.H.Buyco(1981),ComparisonofRankine
CyclePowerSystems:EffectsofSevenWorkingfluids,ArgonneNationalLaboratoryReportANL/CNSVTM
87,June.
Martini,W.R.(1980),StirlingEngineDesignManual,"NASACR135382,May.
Reynolds,W.C,(1979),ThermodynamicPropertiesinSlGraphs,TablesandComputationalEquationsfor
Over40Substances,DepartmentofMechanicalEngineering,StanfordUniversity,Stanford,California.
Roschke,E.J.,L.Wen,H.Steele,N.ElGabalawi,andJ.Wang(1979),APreliminaryAssessmentof'Small
SteamRankineandBraytonPointFocusingSolarModules,"JetPropulsionLaboratoryPublication7921
(DOE/JPL106016),March1.
Schmidt,G.,P.Schmid,H.ZewenandS.Moustafa(1983),DevelopmentofaPointFocusingCollectorFarm
System,"SolarEnergy31(3)299311.
Stine,W.B.(1984),"SurveyofManufacturersofHighPerformanceHeatEnginesAdaptabletoSolar
Applications,"JetPropulsionLaboratoryReportJPL8446(DOE/JPL106075),June15.
Tabor,H.(1962),SolarUtilizationandDevelopmentinIsrael,inProceedingsofSixthWorldPowerConference,
Melbourne,pp.31203138,October2027.
Urieli,I.,andD.Berchowitz(1983),StirlingCycleEngineAnalysis,HaydenandSons,NewYork.

Related Studies and References


Anonymous(1988)"SolarElectricityGeneratingSystems"PilkingtonSolarInternational,Kln1988.
Geyer,M.,H.Klai(1989)"194MWSolarstrommitRinnenkollektoren"BWKNr.6,Seite288/95.
Aringhoff,R.(1990)"SolarthermischeKraftwerkeinKalifornien",ET(EnergiewirtschaftlicheTagesfragen,Nr.4).
DeLaquil,P.,Kearney,D.,Geyer,M.,Diver,R.(1993)"SolarThermalElectricTechnology",Chapter5in
RenewableEnergySourcesforFuelsandElectricity,IslandPressISBN1781559631396.
Klai,H.,Stai,F.(1993)SolarthermischeKraftwerkefrdenMittelmeerraum,SpringerVerlag.
Anonymous(1993)WorldEnergyOutlookInternationalEnergyAgency(IEA),ISBN9264139044,Paris.
Anonymous(1993)EnergyforTomorrow'sWorld,WorldEnergyCouncil(WEC)NewYork.
Anonymous(1994)"SEGSTechnologyAssessmentandTransferabilitytotheMediterranean,FinalReportfor
theCommissionoftheEuropeanUnion,Brussels"PilkingtonSolarInternational.

http://www.powerfromthesun.net/Book/chapter12/chapter12.html

46/46

S-ar putea să vă placă și