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Article history:
Received 29 September 2009
Accepted 15 May 2010
Keywords:
natural gas
compressibility factor (z-Factor)
viscosity
correlation
a b s t r a c t
This study proposed two new accurate simple explicit numerical methods for calculating the z-Factor and
viscosity of natural gases. Results of these correlations are compared versus experimental data. Proposed
correlation for z-Factor has 0.402 and 1.366 of Absolute Average Percent Error (AAE%) respectively versus
Standing and Katz chart and experimental data. The output of this correlation can be directly assumed or be
used as an initial value of other implicit correlations. In addition, this correlation is valid for gas coefcient of
isothermal compressibility (cg) calculations. The new method for viscosity accounts for the presence of
heptane plus and non-hydrocarbon components. This model was derived from 1260 experimental
measurement of gas viscosity of eleven different mixtures with AAE% of 2.083. This model is simpler and
more efcient than published correlations, and the comparisons indicate superiority of the proposed model
over other methods.
2010 Elsevier B.V. All rights reserved.
1. Introduction
Natural gas is a subcategory of petroleum that occurs naturally,
and it is composed of complex mixtures of hydrocarbons and a minor
amount of inorganic compound. Natural gasses physical properties,
and in particular, their variations with pressure, temperature, and
molecular weight are of great importance in petroleum and gas
engineering calculations.
Petroleum engineers need to predict pVT properties of petroleum
uids at given conditions of temperature and pressure. This can be
determined through pVT analysis of uid sample tests or can be
calculated by using Equations of State (EoS) based on computer codes
if the uid composition is known. This information is often
unavailable particularly at the early stage of eld development or
needs to be veried, supported and supplemented during the course
of eld development. Then it is the task of empirical correlations to
estimate the petroleum uid properties as a function of the reservoir's
readily available characteristics (Ahmed, 1989).
In the oil and gas industries, natural gas compressibility factor (zFactor) and viscosity are two of the most important parameters in
upstream and downstream and their importance cannot be overemphasized in material balance, gas reserve evaluation, gas reservoir
simulation, gas well testing and gas processing calculations. The
experimental measurements, EoS and empirical correlations are the
68
pV = znRT:
VActual
VIdeal
Fig. 1. z-Factor, plotted as a function of the pseudoreduced pressure for isotherms data
from (Poettmann and Carppenter, 1952).
T
TC
p
pr =
pC
1
z = f pPr ;
TPr
Tr =
T
n
i=1
p
n
0
1
A5
A9
A11
2
BA1 + A3 lnpPr + T + A7 lnpPr + T 2 + T lnpPr C
B
C
Pr
Pr
Pr
z = ln B
C:
A8
A10
@
A
A4
2
1 + A2 ln pPr + T + A6 lnpPr + 2 +
ln pPr
Pr
TPr
TPr
8
TPC = yi TCi
pPr =
pPC = yi pCi
i=1
Table 1
Tuned coefcients of Eq. (8).
Coefcient
A1
A2
A3
A4
A5
A6
A7
A8
A9
A10
A11
2.827793 10+ 00
4.688191 10 01
1.262288 10+ 00
1.536524 10+ 00
4.535045 10+ 00
6.895104 10 02
1.903869 10 01
6.200089 10 01
1.838479 10+ 00
4.052367 10 01
1.073574 10+ 00
3.252838 10+ 00
1.306424 10 01
6.449194 10 01
1.518028 10+ 00
5.391019 10+ 00
1.379588 10 02
6.600633 10 02
6.120783 10 01
2.317431 10+ 00
1.632223 10 01
5.660595 10 01
69
Table 2
Compositions natural gas mixtures collected for developing Eq. (10).
Comp.
No. 1
No. 2
No. 3
No. 4
N2
CO2
He
C1
C2
C3
n-C4
i-C4
C5
C6
C+
7
Total
0.21
0.23
97.8
0.95
0.42
0.23
0.09
0.06
0.03
100
5.2
0.19
92.9
0.94
0.48
0.18
0.01
0.06
0.06
100
0.55
1.7
91.5
3.1
1.4
0.5
0.67
0.28
0.26
0.08
100
0.04
2.04
88.22
5.08
2.48
0.58
0.87
0.41
0.15
0.13
100
No. 5
No. 6
3.2
86.3
6.8
2.4
0.48
0.43
0.22
0.1
0.04
100
0.67
0.64
0.05
80.9
9.9
4.6
1.35
0.76
0.6
0.39
0.11
100
No. 7
No. 8
No. 9
No. 10
No. 11
4.8
0.9
0.03
80.7
8.7
2.9
1.7
0.13
0.06
0.03
100
1.4
1.4
0.03
71.7
14
8.3
1.9
0.77
0.39
0.09
0.01
100
0.3
95.6
3.6
0.5
100
0.6
73.5
25.7
0.2
100
15.8
0.8
73.1
6.1
3.4
0.6
0.2
100
1
Mwa
Mwa
2
3
+
B
+
B
B
+
B
+
B
+
B
B 1
C
2
3
4
5
6
T
T
B
C
= ln B
C 10
@
A
Mwa
Mwa 2
Mwa 3
+ B8
1 + B7
+ B9
+ B10
T
T
T
Fig. 2 shows the accuracy of Eq. (8) in compression with 4395 data
point of Poettmann and Carppenter's (1952) data in range of
0.2 pPr 15 and 1.2 TPr 3. Fig. 3 shows the Absolute Percent
Relative Error (AE%) contour plot of z in percent for Eq. (8). Statistical
parameters of Eq. (8) versus Poettmann and Carppenter's (1952) data
for each isotherm are showed in Table 5. Eq. (6) is not recommended
for predicting of z-Factor when TPr b 1.2, but its value could be used for
other implicit methods which are accurate in the vicinity of critical
isotherm. Another parameter that can be calculated through using zFactor correlations is gas coefcient of isothermal compressibility (cg)
(Ghedan et al., 1993). As it appears in Fig. 3, Eq. (8) is always valid for
cg calculations in its validity range.
1
= f ; ; Mwa
T
cg =
Table 3
Tuned coefcients of Eq. (10).
Coefcient
Tuned coefcient
B1
B2
B3
B4
B5
B6
B7
B8
B9
B10
1.022872 10+ 00
1.651432 10+ 00
5.757386 10+ 00
7.389282 10 02
8.389065 10 02
2.977476 10 01
1.451318 10+ 00
4.682506 10+ 00
1.918239 10+ 00
9.844968 10 02
1 V
V p T
11
Table 4
Validity ranges of Eq. (10).
Property
Max
Min
Pressure (psia)
Temperature (F)
Density (g/cm3)
Mwa
Viscosity (cp)
9580
340
0.3906
22.305
0.0543
116
77.7
0.0038
16.607
0.01042
Fig. 2. Accuracy of Eq. (8) versus 4158 point of data (Poettmann and Carppenter, 1952)
in range of 0.2 pPr 15 and 1.2 TPr 3.
70
Fig. 3. Absolute Percent Relative Error contour of z in percent for this study versus 4158
point of data (Poettmann and Carppenter, 1952) in range of 0.2 pPr 15 and
1.2 TPr 3.
Table 7
Statistical parameters for each z-Factor correlation versus experimental data.
Table 5
Statistical parameters of Eq. (8) versus SKC.
Isotherm (TPr)
APE%
AAE%
ERMS
1.2
1.3
1.4
1.5
1.6
1.7
1.8
1.9
2.0
2.2
2.4
2.6
2.8
3.0
Total
0.537
0.059
0.421
0.245
0.247
0.184
0.106
0.116
0.185
0.150
0.084
0.000
0.042
0.106
0.009
1.070
0.678
0.673
0.392
0.479
0.424
0.267
0.246
0.254
0.247
0.243
0.186
0.177
0.294
0.402
1.334
0.898
0.932
0.514
0.596
0.528
0.351
0.322
0.333
0.278
0.309
0.230
0.222
0.351
0.514
cg =
1 1 z
p z p T
12
Correlation
APD%
AAE%
ERMS
r2
Eq. (8)
Hall and Iglesias-Silva (2007)
Londono et al. (2005)
Heidaryan et al. (2010)
Papy (1968)
0.73258
1.06918
0.83831
0.3992
8.11641
1.366745
1.614423
1.791433
3.256481
8.724819
2.225004
2.541089
3.236726
3.999567
17.71223
0.979
0.977
0.956
0.951
0.899
Table 6
Compositions of experimental data for checking Eq. (8) and other z-Factor correlations.
Comp.
No. 1a
No. 2a
No. 3a
No. 4a
No. 5a
No. 6b
No. 7b
No. 8b
No. 9b
No. 10b
No. 11c
No. 12c
No. 13c
No. 14c
No. 15c
No. 16d
No. 17d
No. 18d
H2S
N2
CO2
C1
C2
C3
n-C4
i-C4
C5
C6
C+
7
Total
0. 53
5.06
89.77
4.64
100
0.57
10.13
85.2
4.1
100
0.52
20.16
74.58
4.74
100
10.91
75.93
13.16
100
12.92
58.41
28.67
100
6.5
87.1
6.4
100
9.8
83.1
7.1
100
4.7
83.6
11.7
100
9.3
80
10.7
100
19.7
71.3
9
100
0.28
0.4
98.5
1.3
100
0.56
0.52
94.53
0.96
1.55
0.79
0.3
0.41
0.24
0.144
100
6.77
10.6
81.83
0.96
1.55
0.25
0.05
0.07
0.26
0.11
100
2.09
4.52
76.01
4.94
6.49
2.89
1.21
1.18
0.54
0.13
100
2.15
1.05
68.8
9.41
12.54
3.76
0.78
1.28
0.24
0.09
100
0.19
0.92
75.12
8.57
4.53
1.28
1.71
1.07
0.87
5.74
100
24.19
11.91
8.49
38.36
6.29
2.61
1.54
1.23
0.98
0.67
3.73
100
40
9.43
6.72
30.36
4.98
2.07
1.22
0.97
0.77
0.53
2.95
100
a
b
c
d
71
zCalculated
zObserved
i
i
ER =
zObserved
i
i = 1; 2; 3; ::::; Nd
Absolute Percent Relative
Error (AE%)
jz
Calculated
zObserved
i
i
zObserved
i
AE % =
100
i = 1; 2; 3; ::::; Nd
Nd
zCalculated
zObserved
i
i
i=1
zObserved
i
100
APE% =
!
100
Nd
Nd
AAE% =
ERMS =
i=1
jz
Calculated
zObserved
i
i
zObserved
i
v
u Nd
u
u Ei2
t
Nd
!
100
i=1
Nd
2
exp
cal
zexp
zcal
1;i z1;mean
1;i z1;mean
i=1
!
!
2
2
Nd
Nd
exp
cal zcal
zexp
z
z
1;mean
1;mean
1;i
1;i
Nd
Correlation Coefcient
r2 =
i=1
the new correlation (Eq. (10)) is more accurate than other methods
and successfully estimated viscosity of 90% of experimental data. Fig. 6
shows the accuracy of each viscosity correlations at its validity ranges
in comparison with data (Lee, 1965; Gonzalez et al., 1970) and their
statistical parameters are showed in Table 8.
5. Conclusion
The simple accurate correlation based on the general gas
compressibility factor chart (SKC) was obtained for a quick estimation
of natural gas compressibility factor as a function of reduced pressure
and reduced temperature. The advantage of the proposed correlation
is that it is explicit in z and thus does not require an iterative solution
which is demanded by other methods developed from an EoS. The
outcome of this correlation can be directly assumed or be used for
initial value of other iterative correlations. Results of this correlation
were compared against experimental data. The proposed correlation
Table 8
Statistical parameters for each viscosity correlation versus experimental data.
Correlation
APE%
AAE%
ERMS
Eq. (10)
Sutton (2007)
Londono et al. (2005)
Lee, et al.(1966)
Shokir and Dmour (2009)
0.245
2.356
2.843
2.084
2.435
2.083
3.228
3.502
3.950
7.131
2.259
4.377
3.853
4.656
9.606
i=1
Nomenclature
A
tuning coefcient
B
tuning coefcient
cg
gas coefcient of isothermal compressibility, psi 1
Mwa
apparent molecular weight
n
number of moles of the gas
Nd
number of data points
p
pressure, psia
pC
critical pressure, psia
pPC
pseudocritical pressure, psia
pr
reduced pressure
pPr
pseudoreduced pressure
R
universal gas constant
T
absolute temperature, F
TC
critical temperature, R
TPC
pseudocritical temperature, R
Tr
reduced temperature
TPr
pseudoreduced temperature
V
volume, ft3
z
compressibility factor
yi
mole fraction of component i
density, g/ml
Viscosity, cp
Acknowledgements
The lead author would like to thank Dr. Thomas A. Blasingame and
Dr. Kenneth R. Hall for their insight, comments, and suggestions
regarding this work. The authors also wish to express their grateful
72
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