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FORM TP 2016166
TEST CODE
CARIBBEAN EXAMINATIONS
O2II2O2O
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MAY/JUNE 20I6
COUNCIL
CHEMISTRY
UNIT I -Paper02
2 hours 30 minutes
This paper consists of SIX questions in TWO sections. Answer ALL questions.
2.
J.
4.
Where appropriate,
5.
6.
7.
If you
need to rewrite any answer and there is not enough space to do so on the
original page, you must use the extra lined page(s) provided at the back ofthis booklet.
Remember to draw a line through your original answer.
If you
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0211202003
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SECTION A
AnswerALL questions.
MODULE
FUNDAMENTALS IN CHEMISTRY
1.
(a)
(i)
[2 marks]
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0211202004
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(ii)
Later developments in science led to the modification of the atomic theory. Explain
the modification of ONE of the postulates.
[2 marks]
(b)
The dichromate(Vl) ion reacts in an acidic medium according to the following half-equation:
CrrO,2
(i)
(aq)
Ct'.(aq) + 7 H,O(l)
I
(ii)
mark]
Given that the sulfate(lV) ion, SO.2-, is converted to the sulfate(Vl) ion, SOo2 , in
the presence of wateg deduce the balanced equation for the redox reaction between
CrrOr2 (aq) and SOr'-.
[4 marksl
(iii)
[1 mark]
GO ON TO THE NEXT PAGE
02r12020tcAPE 20t6
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0211202005
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-6(c)
l.
(i)
(ii)
Inference
Observation
Test
[5 marks]
Total 15 marks
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MODULE
2.
(a)
(i)
Weak acid
I
(ii)
mark]
Ku
[2 marks]
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0211202007
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-8(b)
In aqueous solution, carbonic acid forms a weak acidic solution containing the hydrogen
carbonate ion.
(i)
[2 marks]
(ii)
I
(iii)
mark]
[4 marks]
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o211202008
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-9(c)
A student was given a particular brand of club soda (carbonated beverage) to determine
the carbonic acid content. Outline the experimental steps required for the investigation if
the student is given 200 cm3 of 0.100 moldm-3 sodium hydroxide solution.
[5 marks]
Total 15 marks
021r2020lcAPE 2016
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-10MODULE
3.
Figure
2000
1500
EL
1000
o0
500
NaMgAlSiPSCl
Ar
(i)
[2 marksl
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0211202010
(ii)
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[2 marksl
(iii)
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-12(b)
The reactions ofthe oxides of magnesium and phosphorous with waterare to be summarized
in Table 2.
pH of Resulting Liquid
Mgo
Poo,o
(i)
Complete Table 2 by describing the reaction of EACH oxide with water and
suggesting a pH value for the resulting liquid.
[2 marks]
(ii)
Write the equation which represents the reaction of water with PoO,o.
[2 marksl
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0211202012
(c)
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13 -
Write equations to show what happens when EACH of the following chlorides reacts with
water.
(i)
sicl4
::Ii+
NH
i-Ei
.-E{
---.r\:
]E
-:.El
.-'.E'
:I{
---.*r-.
,rf,l
[2 marksl
(ii)
Alct3
[2 marksl
Total 15 marks
r]$
,.._.+
..$.
rl*l
:i(:
'-'--'.--'--s-
,-:E
:-.I*T
:ti.
--Jx,l
:.!d
1fr:
i-i:
..Qi.
..e
..s
:G.
.-]-t-
i::
02112020/0APE 2016
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-14SECTION B
AnswerALL questions.
MODULE
FUNDAMENTALS IN CHEMISTRY
4.
(a)
(i)
Describe how the bonds are formed in EACH of the solids, potassium chloride
and iodine.
[4 marksl
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(ii)
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::.
'-.tfi
--'J{l
12
.-_ltii
---l!*
:,'Iii
Properties
Melting/Boiling point
KCI
l2
High
Low
Electrolyic conductivity
i:.
:,:*
its
i.fi
Solubility in water
[2 marks]
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0211202015
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-16(b)
(i)
.*-.
.rii.
.*i
it*.
:-ea-'.
.'Jr1--
,:ts:
it.iil
ikr
:\-..I+-
-hi:tiiij
,:*::
rB---
!fui:
jii
iE
.si
.a;
[3 marks]
(ii)
,R'l
iol
is:
:.t
..Ei::,Sf
..H.
:-}t+i:le-
[3 marks]
GO ON TO THE NEXT PAGE
02t12020lcAPE 2016
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0211202016
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..t*i.
-.4--\t.
l..a
...9
tft
-17
(c)
-|
[3 marks]
Total 15 marks
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18 -
MODULE
The following equation represents the reaction between hydrogen and iodine.
5.
H,(g) + I,(g)
kJ mol-l
(a)
(i)
in'dynamic equilibrium'.
[4 marks]
(ii)
Write the expression for the equilibrium constant in terms of partial pressures, Ko,
for the reaction shown by the equation above.
[2 marksl
(iii)
State TWO factors which would NOT affect the equilibrium of the reaction shown
by the equation above.
[2 marks]
GO ON TO THE NEXT PAGE
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0211202018
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-19(b)
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(i)
[2 marksl
(ii)
[2 marks]
(c)
When 0.5 mol of hydrogen and 0.5 mol of iodine are allowed to reach equilibrium in a
I .00 dm3 flask at 500 "C and l.0l x 105 N m-2, the amount of hydrogen iodide at equilibrium
is 0.78 mol. Calculate K^ at 500 "C if the total pressure is I pa.
[3 marksl
Total 15 marks
GO ON TO THE NEXT PAGE
02112020/CAPE 2016
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MODULE
(a)
6.
[4 marks]
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(b)
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(i)
Write the electronic configuration using the s, p and d orbitals of the titanium ion
[1 mark]
(ii)
[4 marks]
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0211202021
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-22(c)
(i)
::]s
.ICl
.:.ft
ni+
rla
JIE:
.F
iIIj
iE
..I+
[1 markl
(ii)
jH
.!ii
jfigl
IFi.-
,Qi
.E
:H
..-*r-
,.4
[2 marksl
(iii)
Using the concept of stability constant, explain the changes observed in (c) (ii).
iE
ifil
--Gr
-\
,!(
.'*
.t
iH
.-!
-:t
ts
-.e
:.....
::+
,f(
::R
..{d
.']'|r1
.-E
:-trt
[3 marksl
Total 15 marks
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i:E
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END OF TEST
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IF YOU FINISH BEFORE TIME IS CALLED, CHECK YOUR WORK ON THIS TEST.
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