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The reaction between the Al metal powder and alkaline activator proceeds quickly,
during the reaction releases hydrogen (reaction (1)) [5].
2Al + 2NaOH +2H2O 2NaAlO2 + 3H2
(1)
(2)
Figure. 1
The liquid/solid and Al/solid ratio effect on the FAF pore distribution [5]
Based on the Figure 1 can be seen that the increasing amount of Al powder resulted
increasing of the pore size.
As it can be noticed in Fig. 1, the amount of Al metal powder has a less significant
effect on the pore structure than the amount of liquid activator [5].
The microstructure of perlite based geopolymer foam is presented in Figure 3.
Figure 3
SEM photos of foamy materials prepared with different H2O2 content in the
geopolymeric paste [9]
The cells are normally closed and almost spherical when the content of H2O2 in the
paste is low. If the content of H2O2 increase coalescence occurs among cells and the
cells geometrical shape change from spherical to oval [9].
The effect of H2O2 content in the perlite based geopolymeric paste on the mean cell
size shown in Figure 3.
Based on the experience observed in Figure 3 it can be stated that higher content of
H2O2 resulted higher mean cell size [9].
Figure 2.
Mean cell size as a function of H2O2 content in the geopolymeric paste [9]
PROPERTIES OF GEOPOLYMER FOAM
Mechanical properties
The geopolymer foam possess relatively high compressive strength (5.5-10.9 MPa)
[5, 6, 8], but increasing the liquid/solid ratio and amount of foaming agent (Al
powder or hydrogen-peroxide) in the geopolymer paste results in certain decrease in
compressive strength [7, 8]. Higher content of foaming agent in the paste results in
lower specimen density (Figure 4.) [5, 7, 8, 9]
Figure 4.
Apparent density and cell volume of foamy materials as a function of % w/w H2O2
content in the geopolymeric paste [9]
REFERENCES
[1] J. Davidovits: Geopolymer chemistry and application. Published by: Institut
Geopolimre 16 rue Galile F-02100 Saint-Quentin France (2011), ISBN:
9782951482050 pp. 283, 286.
[2] J. Davidovits: Geopolymers: inorganic polymeric new materials. J. Mater.
Educ. 16 (1994), pp. 91-139.
[3] G. Mucsi, B. Cske, Z. Molnr: Alkli aktivlt pernyealap ktanyag
vizsglata. Hulladkolnline elektronikus folyirat, 3. vfolyam 1. szm
http://folyoirat.hulladekonline.hu/1.%20sz%C3%A1m.%20(febru%C3%A1r)
2014.01.22.
[4] K. Komintsas, D. Zaharaki: Geopolymerisation: A review and prospects for
the mineral industry. Minerals Engineering 20 (2007) 12611277
[5] P. Hlavek, V. milauer, F. kvra, L. Kopeck, R. ulc: Inorganic foams
made from alkali-activated fly ash: Mechanical, chemical and physical
properties. Journal of the European Ceramic Society Vol. 35, Issue 2, (2015), pp.
703709.
[6] W. D.A. Rickard, A.van Riessen: Performance of solid and cellular
structured fly ash geopolymers exposed to a simulated fire. Cement and
Concrete Composites 48 (2014) 75-82.
[7] J. G. Sanjayan, A. Nazari, L. Chen, G. H. Nguyen: Physical and mechanical
properties of lightweight aerated geopolymer. Construction and Building
Materials 79 (2015) 236-244.
[8] Z. Abdollahnejad, F. Pacheco-Torgal, T. Flix, W. Tahri, J. Barroso Aguiar:
Mix design, properties and cost analysis of fly ash-based geopolymer foam
Construction and Building Materials Volume 80, 1 April 2015, Pages 1830.
[9] V. Vaou, D. Panias: Thermal insulating foamy geopolymers from perlite
Miner Eng, 23 (14) (2010), pp. 11461151
[10] M. S. Cilla, P. Colombo, M. R. Morelli: Geopolymer foams by gelcasting
Ceramics International 40 (2014), pp. 57235730
[11] J.L. Bell, W.M. Kriven: Preparation of ceramic foams from metakaolinbased geopolymer gels H.T. Lin, K. Koumoto, W.M. Kriven, E. Garcia, I.E.
Reimanis, D.P. Norton (Eds.), Developments in strategic materials, Ceram Eng Sci
Proc, John Wiley & Sons Inc., New Jersey (2009), pp. 97112.