Documente Academic
Documente Profesional
Documente Cultură
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High Resolution
NAPL source zone formation
Remedial desk studies especially in-situ treatment design studies require detailed
knowledge of the subsurface structure and the contaminant distribution applying in-situ
investigation techniques is therefore substantial in order to gain detailed knowledge about
the source and plume architecture.
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HRSC Approach
Direct Sensing
In Situ Profiling
In situ testing +
sampling
K-value (slug testing)
Soil samples
Groundwater samples
Monitoring
Direct-Push Installations
1
2
3
4
Sensor Response:
Geology
Contamination
Hydraulics
Support-tool:
Designing,
performing,
controlling
Depth [m]
Effective target
oriented in-situ
remediation
4
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CPT Rigs
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GEOPROBE 6610DT
20t-Minicrawler
Stand-Alone-CPT-Rig (15 t)
MIP-CPT
(Membrane Interface Probe connected to CPT)
MIP Detectors
FID (Flame Ionization Detector)
Corg.
MIP1
Cone Resistance [MPa] Friction Ratio [%]-Conductivity [mS/m*3,5]
10
20
30
40
50
60
70
10
0,0
DELCD [V]
0,2
0,4
0,6
PID [V]
0,8
1,0
0,0
0,1
0,2
0,4
0,5 0,0
0,2
0,4
0,6
0,8
1,0
0
1
10
10
11
11
12
12
13
13
14
14
15
15
16
16
17
17
18
18
19
19
20
20
21
21
22
22
23
23
24
24
25
25
26
26
27
27
28
28
29
29
30
30
31
31
32
32
33
33
34
34
35
35
36
36
37
37
MIP-CPT
Estimated VOCL-Concentration
in PCE-Equivalents
100,0
10
12
11
10,0
7
6
5
1,0
4
1
0,1
0
10
10,0
Tiefe in m u. GOK
FID [V]
0,3
Depth in m bgs.
Depth in m bgs.
0
1
1,0
20
25
30
35
0,1
8
15
10
Friction Ratio in %
10
0,01
0,10
Friction Ratio in %
Legend (Colors in Cone Resistance Profile)
1,00
DELCD [V]
very soft
very loose
soft
loose
firm
medium dense
stiff
dense
very stiff
very dense
hard
50 - 100 mg/l
1 - 10 mg/l
Project:
Test Location:
MIP1
Client:
X-Coord.:
Contractor:
Y-Coord.:
Processed by:
Level:
Test Date:
Depth:
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LIF-CPT
(Laser Induced Fluorescence, ROST or UVOST connected to CPT)
ROST
(Rapid Optical Screening Tool)
Nd-YAG-Laser/Dye-Laser
Excitation 290 nm
Emission Wavelengths
340 - 390 - 440 - 490 nm
New LIF sensor
TarGOST
(Tar-Specific Green Optical Screening
Tool)
UVOST
(UltraViolet Optical Screening Tool)
Excimer Laser
Excitation 308 nm
Emission Wavelengths
350 - 400 - 450 - 500 nm
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ROST1
Cone Resistance in MPa
10
20
30
40
50
60
Friction Ratio in %
70
ROST Fluorescence in %
10
10
100
150
200
250
10
10
11
11
12
12
13
13
14
14
15
15
16
16
ROST-CPT
100.0
2.0
10
12
11
10.0
7
6
5
1.0
4
1
0.1
0
1.0
10.0
Wavelength Shift
50
Depth in m bgs.
Depth in m bgs.
1.0
-2.0
0.1
8
10
0.0
-1.0
Friction Ratio in %
0.00
10
3.00
6.00
9.00
12.00
15.00
Depth in m bgs.
Friction Ratio in %
very soft
very loose
soft
loose
firm
medium dense
stiff
dense
very stiff
very dense
hard
Project:
Test Location:
Client:
X-Coord.:
Contractor:
Y-Coord.:
Processed by:
Level:
Test Date:
Depth:
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ROST1
0.004
10
20
30
40
50
60
Friction Ratio in %
70
ROST Fluorescence in %
10
10
0.0035
50
100
150
200
250
Depth in m bgs.
Depth in m bgs.
0.003
0.0025
pV
0.002
0.0015
0.001
0.0005
50
100
150
200
250
0.3
300
ns
0.25
Background
0.2
pV
0.15
0.1
0.16
0.05
0.14
0.12
50
100
150
10
10
11
11
12
12
13
13
14
14
15
15
pV
200
250
300
ns
0.1
0.08
Kerosene
0.06
0.04
0.02
0
0
50
100
150
200
250
300
ns
0.008
Kerosene
0.007
0.006
pV
0.005
0.004
0.003
1
0.002
0.9
0.001
0.8
0.7
16
16
pV
0.6
50
100
0.5
150
200
250
300
ns
0.4
0.3
Weathered or degraded
Kerosene
0.2
0 .1
0
0
50
100
150
2 00
2 50
300
ns
0.008
0.007
100.0
7
6
1.0
4
1
1
0.003
0.002
0.0045
-2.0
0.1
8
10
Friction Ratio in %
0.001
0.0035
0.00
10
3.00
9.00
12.00
15.00
very soft
0.003
0.0025
soft
loose
firm
stiff
dense
very stiff
very dense
hard
50
100
150
200
2 50
3 00
ns
0.002
0.0015
very loose
medium dense
3 Clay
6.00
Depth in m bgs.
Friction Ratio in %
0.004
0.005
-1.0
0.004
0.1
1.0
0.0
pV
0.005
1.0
10.0
pV
11
Wavelength Shift
12
9
10.0
0.006
2.0
10
Cone Resistance in MPa
Kerosene LNAPL
0.001
0.0005
Dissolved Fraction
0
0
50
100
150
200
250
300
ns
Project:
Background
Test Location:
Client:
X-Coord.:
Contractor:
Y-Coord.:
Processed by:
Level:
Test Date:
Depth:
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B2
A9
0
10
20
30
40
50
60
Friction Ratio in %
70
ROST Fluorescence in %
10
10
20
40
60
80
pV
0.1
6
7
0.05
8
9
0
0
10
50
60
70
ROST Fluorescence in %
10
10
20
40
60
80
100
10
10
0.15
40
0
1
30
50
10
100
150
200
250
300
ns
11
11
11
11
12
12
12
12
13
13
13
13
14
14
14
14
15
15
15
15
16
16
16
16
17
17
17
17
18
18
18
18
19
19
19
19
20
20
20
20
21
21
21
21
22
22
22
22
23
23
23
23
24
24
24
25
25
25
Creosote (red)
24
0.045
25
0.04
26
26
26
27
0.035
27
27
27
28
0.03
28
28
28
29
0.025
29
pV
26
30
30
0.02
31
Depth in m bgs.
0.2
20
10
Friction Ratio in %
0
1
0
1
0.25
100
Depth in m bgs.
0
1
Depth in m bgs.
0.3
Depth in m bgs.
31
0.015
32
32
0.01
0.005
0
0
1.0
4
1
0.1
0
1.0
10.0
1.0
10
Friction Ratio in %
0.0
-1.0
very soft
18.00
24.00
30.00
12
11
8
7
6
5
1.0
2
2
1.0
10.0
1.0
10
firm
stiff
3 Clay
dense
very stiff
very dense
hard
0.00
10
6.00
12.00
18.00
24.00
Depth in m bgs.
Friction Ratio in %
Legend (Colors in Cone Resistance Profile)
0.0
-1.0
-2.0
0.1
8
Friction Ratio in %
very soft
very loose
soft
loose
firm
medium dense
stiff
dense
very stiff
very dense
hard
9
10.0
loose
medium dense
2.0
Depth in m bgs.
very loose
3 Clay
12.00
100.0
10
1
6.00
Friction Ratio in %
100.0
0.1
0.00
10
-2.0
0.1
8
Downgradient
300
250
Wavelength Shift
11
12
8
200
Dissolved
Fraction (blue)
2.0
150
100.0
10
10.0
100
ns
50
Wavelength Shift
Source Zone
Project:
Test Location:
Client:
X-Coord.:
Contractor:
Y-Coord.:
Processed by:
Level:
Test Date:
Depth:
Project:
Test Location:
Client:
X-Coord.:
Contractor:
Y-Coord.:
Processed by:
Level:
Test Date:
Depth:
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Probe Design
ED-XRF Sensor
(Energy Dispersive
X-Ray
Fluorescence)
XRF Window
XRF
Continuous Logging
of Heavy Metal
Concentration and
Lithology vs. Depth
Calibrated against
certified SRM
standards
CPT
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Test 1
Cone Resistance [MPa]
10
20
30
40
50
60
Zinc [mg/kg]
8
10
15000
30000
45000
Lead [mg/kg]
60000
75000
200
400
600
800
1000
0
6654
110
28315
15464
6450
184
1971
55
1576
32
2006
39
1594
47
1989
58
3745
70
3664
57
3404
40
5904
56
6844
42
7005
36
15142
56
23951
22
25279
43
Depth in m bgl.
Depth in m bgl.
40951
5
44851
56702
5
22
31412
20917
6
10736
2816
1441
3395
7
97
155
62
7
31
95
8
233
690
1662
1163
9
623
347
279
329
10
291
10
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XRF Cone
Detectable Elements and Operation Modes
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Water injection
MIP-CPT-HPT
cone
HPT
Hydraulic
Membrane
Pump (CF)
Pressure
transducer
- HPT = Hydraulic
Filter
- EC = Lithology + Salinity
- MIP = Contaminants
- Heater + Thermocouple
- CPT = Lithology
- Dynamic Pore Pressure
Constant water flow (200 1000 ml/min)
Pressure transducer inside probe
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MIP-CPT-HPT: Results
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MIP-CPT-HPT: Calibration
Validation of HPT-data by depth-discrete testing
TASK-Demonstrationsstandort Voigtlnder
1,00E-04
y = 3E-05Ln(x) + 1E-05
2
K (m/s)
R = 0,8783
1,00E-05
1,00E-06
0
10
12
14
16
18
Q/p (ml/min/kPa)
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MIP-CPT-HPT: Results
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b)
c)
Sampling interval up to 1 m
Average depth 20-30 m
Cost effective
Ungesttigte Bodenzone
Hydropunch
(depth discrete sampling)
1.5 Rods
Verrohrung
Wassergesttigte Bodenzone
Small machines
Screen
Filter
Rammspitze
Lost Tip
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Bypass
Flow-Trough Cell
Groundwatertable
1.5 Rods
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Example: Prove of high permeable layer above clay aquitard (identified by HPT)
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Dual--Tube System
Dual
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Sampling:
Low flow sampling
Small size foot-valve pump required
Peristaltic pump
Filter pack
0,4 - 1,0 m
Bentonite
min. 1,0 m
Samplingport
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Point data
Block Diagrams
Fence Diagrams
Contamination
Lithology
1,00E-04
K (m/s)
y = 3E-05Ln(x) + 1E-05
R2 = 0,8812
1,00E-05
Hydraulics
1,00E-06
0
10
12
Q/p (ml/min/kPa)
K -values
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A H41
H27
H53
H51
H15
H37 A
Legend
60.0
60.0
Integral Fluorescence
0-5
10 - 25
55.0
55.0
5 - 10
2D Overview
25 - 50
H37
H 16
H 01
H 19
H18
H 17
H 20
H14
H 13
H 11
H 09
H38
50 - 75
H 07
H08
H06
H 21
H51
H 39
H52
H 05
H22
H35
H 34
H49
H 50
H40
H 33
H 32
H 53
75 - 100
H 47
H45
H 03
H 04
H48
H 54
H 46
H 02
H15
H 12
H 10
H 23
H 31
H 24
H29
H30
H44
H27
H 28
H 26
H 25
H43
H 41
Wavelength shift
H 42
Legend
H27
H53
H51
H15
-1.1 - -1.0
55.0
-1.0 - -0.5
-1.1 to -1.0
H37
background
-1.0 to -0.5
Light compounds
-0.5 - 0.1
0.1 - 0.5
0.5 - 1.0
55.0
60.0
H41
60.0
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H18
Legend (%):
H16
H01
H19
H23
H17
H47
H02
H20
H12
H10
H45
H15
H14
H13
0-5
H03
H11
5 - 10
H09
H38
H07
H08
H05
H06
H04
10 - 25
H35
H21
H39
H51
H52
H48
25 - 50
H54
H46
H34
H22
H49
H50
H40
50 - 75
H33
H32
H53
75 - 100
H31
H24
H29
H30
H44
H27
H28
H26
H25
H43
H41
H42
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Mass Calculation
Volume: 70000 m3
Volume: 85000 m3
Vedere tridimensionala
Threshold:
2000 mg/kg
Threshold:
500 mg/kg
Vedere tridimensionala
Volume: 35000 m3
Vedere tridimensionala
Volume: 12000 m3
Vedere tridimensionala
Threshold:
25000 mg/kg
Volume: 1000 m3
Vedere tridimensionala
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Mass Calculation
100
90
80
70
60
50
40
30
20
10
0
0
10
20
30
40
50
60
70
80
90
100
HPT04
HPT05
HPT06
HPT07
HPT08
HPT09
HPT10
HPT11
75.0
HPT02
75.0
HPT01
70.0
65.0
60.0
60.0
65.0
70.0
GWStand
55.0
55.0
TonOK
0-1
1 - 20
10.0
50.0
50.0
20 - 50
X
50 - 100
15.0
20.0
25.0
30.0
35.0
40.0
45.0
50.0
100 - 250
55.0
60.0
65.0
70.0
75.0
250 - 500
500 - 750
750 - 1,000
1,000 - 1,250
1,250 - 1,500
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03
37
7 14
14 35
35 70
70 107
107 140
140 178
178 214
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100
90
80
70
60
50
40
30
20
10
0
0
10
20
30
40
50
60
70
80
90
100
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Permanganate
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Thank you
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