Curva de diagrama P-V para Etano con ecuacin de estado SoaveRedlich-Kwong.

Para la construccin del diagrama P-V mediante el uso de ecuaciones de

estado, en este caso en especfico de la ecuacin de estado de Soave-Redlichkwong.
Su forma generalizada tiene la siguiente presentacin:

P=

a (T )
RT

v b v ( v b )

La cual contiene los siguientes parmetros, que hacen de esta ecuacin una
forma alternativa de la EDE SR, al reemplazar a en el trmino de atraccin por
una funcin dependiente de T y . Por lo tanto la ecuacin de Soave-RedlichKwong es idntica en su estructura a la ecuacin de Redlich-Kwong, ya que la
modificacin de Soave consiste en un clculo diferente de la constante

a(T ) .

Por lo tanto, el comportamiento que tienen los complementos asociados a la

ecuacin SRK son:

T
T ref
1+m

m=0.48+1.57 w0.176 w2

0.42748R2 T 2C
a=
PC

b=0.08664
a ( T )=a

RTC
PC

La ecuacin se satisface cuando se le agregan los datos termodinmicos de

especies puras.
Para fines de esta demostracin se llev a cabo con la sustancia pura Etano,
con las siguientes propiedades y valores termodinmicos.

M =30.07

w=0.1
Tc=305.3 K

Pc=48.72
Vc=145.5

cm3
mol

De tal manera que la ecuacin pueda manipularse, se simplifica agregando los

valores que se obtienen con los datos termodinmicos y las funciones
complementarias de la EDE de SRK.
En este punto se describe brevemente el algoritmo a seguir para la obtencin
del diagrama P-V.
1. A partir de la EDE SRK, se obtiene manipulando matemticamente una
forma explcita de la ecuacin cbica.

v 3v 2 C 2v C 1 +C0
Los coeficientes

C2 , C1 y C 0

son la simplificacin de los datos para

facilitar la manipulacin.
2. Se fijan condiciones de T y P tales que pueda satisfacer la siguiente
condicin.
v

P ( v v )= Pdv

3. Se integra la funcin

Pdv
v

para poder evaluar los trminos.

4. Se fija una temperatura y se resuelve la EDE en su forma de ecuacin

cbica explcita se toman las races mayor y menor de la solucin
vectorial de 3 componentes. Dichas races corresponden a los
volmenes de lquido (raz menor) y de vapor (raz mayor).
5. Fijada la temperatura, se busca satisfacer la ecuacin
v

P ( v v )= Pdv
v

Variando dentro de esta la presin de saturacin, la cual arrojara los

datos de volmenes que representan cada punto de la curva de
equilibrio de la sustancia pura.
6. Se repite el mismo procedimiento aumentado y disminuyendo la
temperatura.
7. Se procede a graficar P vs V

La ecuacin S-R-K es ms eficaz que la de R-K en los clculos de equilibrio

lquido-vapor. Su falla ms notable es en la estimacin de densidad de lquido
saturado, que da errores que varan desde el 7 al 19 %. La ecuacin de SoaveRedlich-Kwong es vlida para todos los gases en condiciones alejadas de las
ambientes. Es vlida para todas las presiones excepto la crtica. Ha sido
aplicada con xito a gases y lquidos. Es moderadamente eficaz en la
prediccin de propiedades de mezclas. La ecuacin de Soave-RedlichKwong no
es vlida para sustancias polares o asociadas. Esta es una ecuacin en funcin
de tres parmetros: Tc, Pc y . Es la primera ecuacin cbica que emplea el
enfoque de tres parmetros basado en .
La programacin no fue conclusa.

Curva de Entalpas de vaporizacin

Con ayuda de los datos de volmenes del problema anterior, se calcula la
Entalpa de vaporizacin para el compuesto puro Etano, mediante la integral
resuelta.
v

H =T Pdv
v

Se proponen distintas temperaturas para obtener el valor de la Entalpa en

cada temperatura evaluada. Posteriormente se grafica
obtener la curva de Entalpa de vaporizacin.

Temperat
ura K
300
310
320
340
370
410
460
500
530
550
560

H
Kjoules
104.3589
74
107.9512
2
110.9046
51
113.0694
39
114.2997
59
114.4370
81
113.2939
34
110.6370
75
106.1566
85
99.40675
94
89.66865
5

570 75.57103
71.05406
580
91
65.98112
590
79
60.20839
600
91
53.50619
650
86

31307.69
23
33464.87
8
35489.48
84
38443.60
93
42290.91
08
46919.20
32
52115.20
99
55318.53
75
56263.04
3
54673.71
76
50214.44
68
43075.48
71
41211.36
01
38928.86
54
36125.03
95
34779.02
91

H v vs T para

Tablas de Entalpa, Energa interna, Entropa a condiciones de temperatura y presin dentro de los
rangos de:
T 274 a 873.15 K
P0.1 a 400 bar
Mediante la EDE Peng-Robinson, se estimaran las tablas de entalpa, energa interna y entropa a las condiciones
sujetas de T y P para la sustancia pura Etano.
Esta ecuacin, propuesta en 1977, constituye un intento de mejorar la calidad predictiva de la ecuacin de SoaveRedlich-Kwong, especialmente en la exactitud de los clculos de equilibrio lquido-vapor. El enfoque de Peng y
Robinson consiste en escribir el trmino atractivo de la ecuacin de Van der Waals.

P=

a (T )
RT
2
v b v +2 vbb2

T
T ref
1+m

m=0.37464 +1.54226 w0.26992 w

0.45724R T C
a=
PC

b=0.0778

RTC
PC

Con los parmetros de la EDE de Peng-Robinson y las condiciones crticas del componente puro, adems de
la bsqueda de valores de los coeficientes de Cp (Capacidades Calorficas en estado de gas ideal) y
condiciones de referencia establecidos, se determinaron los valores de la entalpa, energa interna y entropa
a diferentes rangos de temperatura y presin.

ref
T T

1
T ref
T 2
Z +1+ 2 B
H=( T CT ) ( Z 1 )
k
+1 ln
+Cpa
TC
b 22
Z +1 2 B

[[ ] ] [

1+ 2 B
P
T
Cpd
T C +Rln
+Cpaln
+Cpb( T T ref ) +
P ref
T ref
3 (T 3 T 3ref )

[ ]

T C + ( 1 2 B )

ak
b
S=Rln ( ZB )

U=H PV

( T T C )
2
2

1
2

ln

0.1 bar

1 bar

Temperatu
ra en K

H
(J/mol)

283.150 113.9688

303.150

S (J/mol
K)
-19.5284

30.5546

-19.0345

323.150 184.1079

-18.5434

343.150 346.7799

-18.0543

363.150 518.6595

-17.5669

383.150 699.8355

-17.0807

403.150 890.3969

-16.5954

423.150

1090.432
4

-16.1107

443.150

1300.031
0

-15.6262

463.150

1519.281
6

-15.1419

1748.273

483.150
1
503.150 1987.094
3

-14.6574
-14.1727

U
(J/mol)
2465.812
7
2487.409
3
2499.976
0
2503.423
9
2497.664
3
2482.608
3
2458.166
9
2424.251
4
2380.772
8
2327.642
2
2264.770
7
2192.069

V
Temperat
H (J/mol)
(M3/mol) ura en K

S (J/mol
K)

U (J/mol)

V
(M3/mol)

0.2352

283.150

-113.9688

-38.6721 -2465.8127

0.0235

0.2518

303.150

30.5546

-38.1782 -2487.4093

0.0252

0.2684

323.150

184.1079

-37.6870 -2499.9760

0.0268

0.2850

343.150

346.7799

-37.1980 -2503.4239

0.0285

0.3016

363.150

518.6595

-36.7106 -2497.6643

0.0302

0.3182

383.150

699.8355

-36.2244 -2482.6083

0.0318

0.3349

403.150

890.3969

-35.7391 -2458.1669

0.0335

0.3515

423.150

1090.4324

-35.2544 -2424.2514

0.0351

0.3681

443.150

1300.0310

-34.7699 -2380.7728

0.0368

0.3847

463.150

1519.2816

-34.2856 -2327.6422

0.0385

0.4013
0.4179

483.150
503.150

1748.2731
1987.0943

-33.8011 -2264.7707
-33.3164 -2192.0695

0.0401
0.0418

523.150

2235.834
3

-13.6875

543.150

2494.581
9

-13.2017

563.150

2763.426
1

-12.7153

583.150

3042.455
7

-12.2281

603.150

3331.759
8

-11.7400

623.150

3631.427
2

-11.2509

643.150

3941.546
8

-10.7607

663.150

4262.207
7

-10.2694

683.150
703.150
723.150
743.150
763.150
783.150

4593.498
8
4935.508
9
5288.327
1
5652.042
2
6026.743
3
6412.519

5
2109.449
5
2016.821
9
1914.097
7
1801.188
1
1678.004
0
1544.456
6
1400.456
9
1245.916
0
1080.745
0

0.4345

523.150

2235.8343

-32.8312 -2109.4495

0.0435

0.4511

543.150

2494.5819

-32.3454 -2016.8219

0.0451

0.4678

563.150

2763.4261

-31.8590 -1914.0977

0.0468

0.4844

583.150

3042.4557

-31.3718 -1801.1881

0.0484

0.5010

603.150

3331.7598

-30.8837 -1678.0040

0.0501

0.5176

623.150

3631.4272

-30.3946 -1544.4566

0.0518

0.5342

643.150

3941.5468

-29.9044 -1400.4569

0.0534

0.5508

663.150

4262.2077

-29.4131 -1245.9160

0.0551

0.5674

683.150

4593.4988

-28.9207 -1080.7450

0.0567

-9.2832 -904.8548

0.5840

703.150

4935.5089

-28.4269

-904.8548

0.0584

-8.7882 -718.1567

0.6006

723.150

5288.3271

-27.9319

-718.1567

0.0601

-8.2918 -520.5615

0.6173

743.150

5652.0422

-27.4355

-520.5615

0.0617

-7.7940 -311.9804
-7.2948 -92.3245

0.6339
0.6505

763.150
783.150

6026.7433
6412.5193

-26.9377
-26.4385

-311.9804
-92.3245

0.0634
0.0650

-9.7770

803.150
823.150
843.150
863.150
883.150
903.150

3
6809.459
0
7217.651
5
7637.185
7
8068.150
6
8510.635
0
8964.728
1

-6.7940

138.4953

0.6671

803.150

6809.4590

-25.9377

138.4953

0.0667

-6.2918

380.5678

0.6837

823.150

7217.6515

-25.4355

380.5678

0.0684

-5.7880

633.9820

0.7003

843.150

7637.1857

-24.9317

633.9820

0.0700

-5.2826

898.8268
1175.191
3
1463.164
3

0.7169

863.150

8068.1506

-24.4263

898.8268

0.0717

0.7335

883.150

8510.6350

-23.9193

1175.1913

0.0734

0.7502

903.150

8964.7281

-23.4106

1463.1643

0.0750

-4.7756
-4.2669

Temperatu
ra en K

5 bar
S (J/mol
K)

H
(J/mol)

283.150 432.4452
-

303.150 298.3395

-52.7804
-52.2785

323.150 155.1273

-51.7800

343.150

-2.7269

-51.2844

363.150 158.9445

-50.7909

383.150 329.9707

-50.2991

403.150 510.4360

-49.8086

423.150 700.4253

-49.3191

443.150 900.0241

-48.8302

1109.318
1

-48.3416

463.150

U
(J/mol)
2670.143
9
2694.095
6
2708.940
9
2714.598
0
2710.984
1
2698.015
3
2675.607
5
2643.675
7
2602.134
4
2550.897
9

V
Temperat
H (J/mol)
(M3/mol) ura en K

10 bar
S (J/mol
K)

U (J/mol)

V
(M3/mol)

0.0045

283.150

-432.4452

-58.5432 -2670.1439

0.0022

0.0048

303.150

-298.3395

-58.0413 -2694.0956

0.0024

0.0051

323.150

-155.1273

-57.5429 -2708.9409

0.0026

0.0054

343.150

-2.7269

-57.0472 -2714.5980

0.0027

0.0057

363.150

158.9445

-56.5537 -2710.9841

0.0029

0.0061

383.150

329.9707

-56.0619 -2698.0153

0.0030

0.0064

403.150

510.4360

-55.5714 -2675.6075

0.0032

0.0067

423.150

700.4253

-55.0819 -2643.6757

0.0033

0.0070

443.150

900.0241

-54.5930 -2602.1344

0.0035

0.0073

463.150

1109.3181

-54.1044 -2550.8979

0.0037

1328.393
483.150
4

-47.8532

503.150

1557.336
5

-47.3648

523.150

1796.234
1

-46.8762

543.150

2045.173
0

-46.3871

563.150

2304.240
3

-45.8976

583.150

2573.523
3

-45.4074

603.150

2853.109
3

-44.9165

623.150

3143.086
0

-44.4248

643.150

3443.540
8

-43.9321

663.150

3754.561
5

-43.4384

683.150

4076.236
1

-42.9436

4408.652

703.150
3
723.150 4751.898

-42.4477
-41.9505

2489.880
0
2418.994
4
2338.154
3
2247.272
8
2146.263
0
2035.037
4
1913.508
9
1781.589
7
1639.192
4
1486.229
1
1322.612
0
1148.253
3
-963.0649

0.0076

483.150

1328.3934

-53.6161 -2489.8800

0.0038

0.0080

503.150

1557.3365

-53.1276 -2418.9944

0.0040

0.0083

523.150

1796.2341

-52.6390 -2338.1543

0.0041

0.0086

543.150

2045.1730

-52.1500 -2247.2728

0.0043

0.0089

563.150

2304.2403

-51.6604 -2146.2630

0.0045

0.0092

583.150

2573.5233

-51.1703 -2035.0374

0.0046

0.0095

603.150

2853.1093

-50.6794 -1913.5089

0.0048

0.0098

623.150

3143.0860

-50.1876 -1781.5897

0.0049

0.0102

643.150

3443.5408

-49.6949 -1639.1924

0.0051

0.0105

663.150

3754.5615

-49.2012 -1486.2291

0.0052

0.0108

683.150

4076.2361

-48.7064 -1322.6120

0.0054

0.0111
0.0114

703.150
723.150

4408.6523
4751.8981

-48.2105 -1148.2533
-47.7134 -963.0649

0.0056
0.0057

743.150
763.150
783.150
803.150
823.150
843.150
863.150
883.150
903.150

1
5106.061
7
5471.231
1
5847.494
6
6234.940
2
6633.656
3
7043.731
1
7465.253
1
7898.310
6
8342.992
0

-41.4521 -766.9588

0.0117

743.150

5106.0617

-47.2149

-766.9588

0.0059

-40.9524 -559.8469

0.0121

763.150

5471.2311

-46.7152

-559.8469

0.0060

-40.4512 -341.6409

0.0124

783.150

5847.4946

-46.2141

-341.6409

0.0062

-39.9487 -112.2528

0.0127

803.150

6234.9402

-45.7115

-112.2528

0.0063

-39.4447

128.4058

0.0130

823.150

6633.6563

-45.2075

128.4058

0.0065

-38.9392

380.4232

0.0133

843.150

7043.7311

-44.7021

380.4232

0.0067

-38.4322

643.8878

0.0136

863.150

7465.2531

-44.1950

643.8878

0.0068

-37.9236

918.8878
1205.511
7

0.0140

883.150

7898.3106

-43.6865

918.8878

0.0070

0.0143

903.150

8342.9920

-43.1763

1205.5117

0.0071

-37.4135

20 bar
Temperat
ura en K

283.150

303.150
323.150
343.150
363.150
383.150

H
(J/mol)
1615.086
2
1518.614
4
1412.745
5
1297.424
3
1172.590
8
1038.180
9

403.150 -894.1273
423.150 -740.3604

S (J/mol
K)

-67.1822
-66.6498
-66.1237
-65.6028
-65.0862
-64.5732
-64.0630
-63.5552

50 bar
U
(J/mol)
3446.699
0
3479.601
3
3503.106
4
3517.159
3
3521.699
7
3516.663
8
3501.984
4
3477.591

V
Temperat
(M3/mol
H (J/mol)
ura en K
)

S (J/mol
K)

U (J/mol)

V
(M3/mol)

0.0009

283.150 -1615.0862

-74.8003 -3446.6990

0.0004

0.0010

303.150 -1518.6144

-74.2678 -3479.6013

0.0004

0.0010

323.150 -1412.7455

-73.7417 -3503.1064

0.0004

0.0011

343.150 -1297.4243

-73.2208 -3517.1593

0.0004

0.0012

363.150 -1172.5908

-72.7042 -3521.6997

0.0005

0.0012

383.150 -1038.1809

-72.1912 -3516.6638

0.0005

0.0013
0.0014

403.150
423.150

-71.6810 -3501.9844
-71.1732 -3477.5914

0.0005
0.0005

-894.1273
-740.3604

443.150 -576.8078

-63.0493

463.150 -403.3957

-62.5449

483.150 -220.0483

-62.0416

503.150

-26.6889

-61.5392

523.150

176.7608

-61.0373

543.150

390.3800

-60.5359

563.150

614.2487

-60.0346

583.150

848.4478

-59.5332

603.150

1093.058
8

-59.0317

623.150

1348.163
8

-58.5299

643.150

1613.845
5

-58.0276

663.150

1890.187
2

-57.5247

4
3443.412
9
3399.374
8
3345.401
5
3281.416
1
3207.340
4
3123.095
2
3028.600
5
2923.775
5
2808.538
6
2682.807
6
2546.499
8
2399.532
2

0.0014

443.150

-576.8078

-70.6673 -3443.4129

0.0006

0.0015

463.150

-403.3957

-70.1629 -3399.3748

0.0006

0.0016

483.150

-220.0483

-69.6596 -3345.4015

0.0006

0.0016

503.150

-26.6889

-69.1572 -3281.4161

0.0007

0.0017

523.150

176.7608

-68.6554 -3207.3404

0.0007

0.0018

543.150

390.3800

-68.1539 -3123.0952

0.0007

0.0018

563.150

614.2487

-67.6526 -3028.6005

0.0007

0.0019

583.150

848.4478

-67.1513 -2923.7755

0.0008

0.0020

603.150

1093.0588

-66.6497 -2808.5386

0.0008

0.0020

623.150

1348.1638

-66.1479 -2682.8076

0.0008

0.0021

643.150

1613.8455

-65.6456 -2546.4998

0.0008

0.0021

663.150

1890.1872

-65.1427 -2399.5322

0.0009

683.150

2177.272
4

-57.0211

703.150

2475.185
1

-56.5168

723.150

2784.009
6

-56.0116

743.150

3103.830
7

-55.5054

763.150

3434.733
3

-54.9983

783.150

3776.802
5

-54.4900

803.150
823.150
843.150
863.150
883.150
903.150

4130.123
9
4494.783
1
4870.866
0
5258.458
6
5657.647
1
6068.518
0

2241.821
1
2073.282
4
1893.831
9
1703.384
8
1501.856
3
1289.161
0
1065.213
7

0.0022

683.150

2177.2724

-64.6392 -2241.8211

0.0009

0.0023

703.150

2475.1851

-64.1348 -2073.2824

0.0009

0.0023

723.150

2784.0096

-63.6296 -1893.8319

0.0009

0.0024

743.150

3103.8307

-63.1235 -1703.3848

0.0010

0.0025

763.150

3434.7333

-62.6163 -1501.8563

0.0010

0.0025

783.150

3776.8025

-62.1081 -1289.1610

0.0010

0.0026

803.150

4130.1239

-61.5987 -1065.2137

0.0010

-53.4700 -829.9285

0.0027

823.150

4494.7831

-61.0881

-829.9285

0.0011

-52.9582 -583.2197

0.0027

843.150

4870.8660

-60.5762

-583.2197

0.0011

-52.4450 -325.0011

0.0028

863.150

5258.4586

-60.0631

-325.0011

0.0011

-51.9305

-55.1866

0.0029

883.150

5657.6471

-59.5485

-55.1866

0.0011

-51.4146

226.3102

0.0029

903.150

6068.5180

-59.0326

226.3102

0.0012

-53.9806

100 bar

150 bar

V
Temperat
S (J/mol
Temperat
H (J/mol)
U (J/mol) (M3/mol
H (J/mol)
ura en K
K)
ura en K
)
283.150

303.150
323.150
343.150

11243.342
5
11325.009
6
11394.100
7
11450.851
7

-105.4681
-104.6016
-103.7729
-102.9763

11938.658
9
12069.438
9
12187.643
0
12293.506
9

0.000070

283.150

0.000074

303.150

0.000079

323.150

0.000084

343.150

11243.342
5
11325.009
6
11394.100
7
11450.851
7

S (J/mol
K)

-108.8391
-107.9726
-107.1439
-106.3473

U (J/mol)
11938.658
9
12069.438
9
12187.643
0
12293.506
9

V
(M3/mol)

0.000046
0.000050
0.000053
0.000056

363.150
383.150
403.150
423.150
443.150
463.150
483.150
503.150
523.150
543.150
563.150
583.150
603.150

11495.451
5
11528.051
4
11548.771
7
11557.706
9
11554.930
3
11540.496
7
11514.446
0
11476.804
5
11427.587
3
11366.799
8
11294.438
5
11210.492
5
-

-102.2071
-101.4615
-100.7363
-100.0289
-99.3371
-98.6589
-97.9928
-97.3373
-96.6913
-96.0537
-95.4235
-94.8001
-94.1825

12387.219
7
12468.932
6
12538.765
8
12596.813
9
12643.150
2
12677.829
6
12700.891
8
12712.363
3
12712.259
1
12700.584
5
12677.336
1
12642.503
0
-

0.000089

363.150

0.000094

383.150

0.000099

403.150

0.000104

423.150

0.000109

443.150

0.000114

463.150

0.000119

483.150

0.000124

503.150

0.000128

523.150

0.000133

543.150

0.000138

563.150

0.000143
0.000148

583.150
603.150

11495.451
5
11528.051
4
11548.771
7
11557.706
9
11554.930
3
11540.496
7
11514.446
0
11476.804
5
11427.587
3
11366.799
8
11294.438
5
11210.492
5
-

-105.5782
-104.8325
-104.1074
-103.4000
-102.7081
-102.0299
-101.3638
-100.7083
-100.0623
-99.4247
-98.7946
-98.1711
-97.5536

12387.219
7
12468.932
6
12538.765
8
12596.813
9
12643.150
2
12677.829
6
12700.891
8
12712.363
3
12712.259
1
12700.584
5
12677.336
1
12642.503
0
-

0.000059
0.000063
0.000066
0.000069
0.000073
0.000076
0.000079
0.000082
0.000086
0.000089
0.000092
0.000095
0.000099

623.150
643.150
663.150
683.150
703.150
723.150
743.150

11114.944
3
11007.770
5
10888.942
5
10758.427
0
10616.186
4
10462.179
7
10296.362
3
10118.686
5
-

763.150 9929.1019

-93.5703
-92.9628
-92.3596
-91.7600
-91.1639
-90.5707
-89.9801
-89.3919

783.150 9727.5557

803.150 9513.9926

-88.8057
-88.2213

823.150 9288.3555
843.150
9050.5850

-87.6384
-87.0569

12596.067
8
12538.006
9
12468.291
9
12386.889
2
12293.761
7
12188.867
9
12072.163
4
11943.600
5
11803.128
9
11650.695
6
11486.245
5
11309.721
3
11121.063

11114.944
3
11007.770
5
10888.942
5
10758.427
0
10616.186
4
10462.179
7
10296.362
3
10118.686
5

0.000153

623.150

0.000158

643.150

0.000163

663.150

0.000168

683.150

0.000173

703.150

0.000178

723.150

0.000182

743.150

0.000187

763.150 -9929.1019

-92.7629

0.000192

783.150 -9727.5557

-92.1767

0.000197

803.150 -9513.9926

-91.5923

0.000202
0.000207

823.150 -9288.3555
843.150 -9050.5850

-91.0094
-90.4279

-96.9414
-96.3339
-95.7306
-95.1311
-94.5349
-93.9417
-93.3512

12596.067
8
12538.006
9
12468.291
9
12386.889
2
12293.761
7
12188.867
9
12072.163
4
11943.600
5
11803.128
9
11650.695
6
11486.245
5
11309.721
3
11121.063

0.000102
0.000105
0.000109
0.000112
0.000115
0.000118
0.000122
0.000125
0.000128
0.000131
0.000135
0.000138

863.150 8800.6203

883.150 8538.3989

903.150 8263.8565

8
10920.212
-86.4765
0
10707.103
-85.8970
5
10481.674
-85.3183
1

0.000212

863.150 -8800.6203

-89.8475

0.000217

883.150 -8538.3989

-89.2680

0.000222

903.150 -8263.8565

-88.6894

200 bar

283.150

303.150
323.150
343.150
363.150

-108.4246
-107.5287
-106.6735
-105.8527
-105.0614

0.000141
0.000145
0.000148

300 bar

V
Temperat
S (J/mol
Temperat
H (J/mol)
U (J/mol) (M3/mol
H (J/mol)
ura en K
K)
ura en K
)
11421.524
6
11471.743
8
11509.108
2
11533.879
1
11546.267
3

8
10920.212
0
10707.103
5
10481.674
1

12683.627
4
12822.993
9
12949.505
6
13063.423
8
13164.959
3

0.000063

283.150

0.000068

303.150

0.000072

323.150

0.000076

343.150

0.000081

363.150

11421.524
6
11471.743
8
11509.108
2
11533.879
1
11546.267
3

S (J/mol
K)

-111.7956
-110.8998
-110.0446
-109.2238
-108.4324

U (J/mol)
12683.627
4
12822.993
9
12949.505
6
13063.423
8
13164.959
3

V
(M3/mol)

0.000042
0.000045
0.000048
0.000051
0.000054

383.150
403.150
423.150
443.150
463.150
483.150
503.150
523.150
543.150
563.150
583.150
603.150
623.150

11546.443
0
11534.543
0
11510.676
1
11474.928
3
11427.366
1
11368.039
0
11296.982
7
11214.220
5
11119.764
9
11013.619
4
10895.779
2
10766.232
4
-

-104.2954
-103.5513
-102.8264
-102.1183
-101.4248
-100.7444
-100.0755
-99.4169
-98.7673
-98.1259
-97.4917
-96.8640
-96.2421

13254.282
3
13331.529
5
13396.809
9
13450.209
5
13491.794
5
13521.614
7
13539.705
7
13546.090
7
13540.782
5
13523.784
3
13495.091
4
13454.691
8
-

0.000085

383.150

0.000090

403.150

0.000094

423.150

0.000099

443.150

0.000103

463.150

0.000108

483.150

0.000112

503.150

0.000117

523.150

0.000121

543.150

0.000126

563.150

0.000130

583.150

0.000134
0.000139

603.150
623.150

11546.443
0
11534.543
0
11510.676
1
11474.928
3
11427.366
1
11368.039
0
11296.982
7
11214.220
5
11119.764
9
11013.619
4
10895.779
2
10766.232
4
-

-107.6664
-106.9224
-106.1975
-105.4893
-104.7959
-104.1155
-103.4466
-102.7879
-102.1384
-101.4969
-100.8628
-100.2350
-99.6131

13254.282
3
13331.529
5
13396.809
9
13450.209
5
13491.794
5
13521.614
7
13539.705
7
13546.090
7
13540.782
5
13523.784
3
13495.091
4
13454.691
8
-

0.000057
0.000060
0.000063
0.000066
0.000069
0.000072
0.000075
0.000078
0.000081
0.000084
0.000087
0.000090
0.000093

10624.960
7
10471.940
643.150
3
10307.142
663.150
1
10130.532
683.150
9
-

703.150 9942.0752

-95.6254
-95.0133
-94.4054
-93.8011

723.150 9741.7279

743.150 9529.4466

-93.2002
-92.6023

763.150 9305.1840

783.150 9068.8900

-92.0069
-91.4139

803.150 8820.5121

823.150 8559.9954

-90.8229
-90.2337

843.150 8287.2833
863.150
8002.3168

-89.6460
-89.0597

13402.567
5
13338.694
3
13263.043
5
13175.581
6
13076.271
1
12965.071
1
12841.937
1
12706.821
8
12559.675
1
12400.444
4
12229.075
1
12045.510
2
11849.691

10624.960
7
10471.940
3
10307.142
1
10130.532
9

0.000143

643.150

0.000148

663.150

0.000152

683.150

0.000157

703.150 -9942.0752

-97.1722

0.000161

723.150 -9741.7279

-96.5713

0.000166

743.150 -9529.4466

-95.9733

0.000170

763.150 -9305.1840

-95.3780

0.000175

783.150 -9068.8900

-94.7849

0.000179

803.150 -8820.5121

-94.1939

0.000183

823.150 -8559.9954

-93.6047

0.000188
0.000192

843.150 -8287.2833
863.150 -8002.3168

-93.0171
-92.4308

-98.9964
-98.3843
-97.7764

13402.567
5
13338.694
3
13263.043
5
13175.581
6
13076.271
1
12965.071
1
12841.937
1
12706.821
8
12559.675
1
12400.444
4
12229.075
1
12045.510
2
11849.691

0.000096
0.000099
0.000102
0.000104
0.000107
0.000110
0.000113
0.000116
0.000119
0.000122
0.000125
0.000128

883.150 7705.0356

903.150 7395.3775

1
11641.557
-88.4746
1
11421.046
-87.8904
3

0.000197

883.150 -7705.0356

-91.8456

0.000201

903.150 -7395.3775

-91.2614

400 bar

283.150

303.150
323.150
343.150
363.150
383.150

-111.7772
-110.8504
-109.9672
-109.1210
-108.3063
-107.5187

0.000131

U (J/mol)

V
(M3/mol)

0.000134

500 bar

V
Temperat
S (J/mol
Temperat
H (J/mol)
U (J/mol) (M3/mol
H (J/mol)
ura en K
K)
ura en K
)
11173.753
1
11160.049
6
11133.197
3
11093.484
4
11041.144
8
10976.368
5

1
11641.557
1
11421.046
3

13468.996
9
13617.415
5
13752.685
3
13875.094
5
13984.877
0
14082.222
9

0.000057

283.150

0.000061

303.150

0.000065

323.150

0.000070

343.150

0.000074

363.150

0.000078

383.150

11173.753
1
11160.049
6
11133.197
3
11093.484
4
11041.144
8
10976.368
5

S (J/mol
K)

-113.6324
-112.7057
-111.8225
-110.9762
-110.1615
-109.3740

13468.996
9
13617.415
5
13752.685
3
13875.094
5
13984.877
0
14082.222
9

0.000046
0.000049
0.000052
0.000056
0.000059
0.000062

403.150
423.150
443.150
463.150
483.150
503.150
523.150
543.150

10899.309
7
10810.092
5
10708.816
2
10595.559
2
10470.381
9
10333.329
3
10184.433
4
10023.714
7

-106.7548
-106.0114
-105.2861
-104.5766
-103.8811
-103.1981
-102.5261
-101.8639

563.150 9851.1835 -101.2106

-

583.150 9666.8416 -100.5651

-

603.150 9470.6830

623.150 9262.6949
643.150

-99.9267
-99.2945
-98.6681

14167.286
2
14240.191
1
14301.037
0
14349.902
1
14386.846
8
14411.916
4
14425.142
6
14426.545
9
14416.136
9
14393.917
1
14359.880
6
14314.014
6
-

10899.309
7
10810.092
5
10708.816
2
10595.559
2
10470.381
9
10333.329
3
10184.433
4
10023.714
7

0.000082

403.150

0.000086

423.150

0.000090

443.150

0.000094

463.150

0.000098

483.150

0.000102

503.150

0.000106

523.150

0.000110

543.150

0.000114

563.150 -9851.1835

-103.0658

0.000118

583.150 -9666.8416

-102.4203

0.000122

603.150 -9470.6830

-101.7819

0.000126
0.000130

623.150 -9262.6949
643.150 -9042.8584

-101.1498
-100.5233

-108.6100
-107.8666
-107.1413
-106.4318
-105.7363
-105.0533
-104.3813
-103.7191

14167.286
2
14240.191
1
14301.037
0
14349.902
1
14386.846
8
14411.916
4
14425.142
6
14426.545
9
14416.136
9
14393.917
1
14359.880
6
14314.014
6
-

0.000065
0.000069
0.000072
0.000075
0.000078
0.000082
0.000085
0.000088
0.000091
0.000095
0.000098
0.000101
0.000104

9042.8584
-

663.150 8811.1492

683.150 8567.5381

-98.0467
-97.4299

703.150 8311.9917

723.150 8044.4725

-96.8172
-96.2082

743.150 7764.9397

763.150 7473.3490

-95.6024
-94.9995

783.150 7169.6535

803.150 6853.8033

-94.3993
-93.8014

823.150 6525.7463

843.150 6185.4281

-93.2055
-92.6114

863.150 5832.7923
883.150
5467.7806

-92.0189
-91.4277

14256.300
2
14186.713
1
14105.224
1
14011.799
8
13906.402
8
13788.992
1
13659.523
5
13517.950
1
13364.222
0
13198.287
1
13020.091
0
12829.577
4
12626.687

0.000134

663.150 -8811.1492

-99.9020

0.000138

683.150 -8567.5381

-99.2851

0.000142

703.150 -8311.9917

-98.6724

0.000147

723.150 -8044.4725

-98.0634

0.000151

743.150 -7764.9397

-97.4576

0.000155

763.150 -7473.3490

-96.8548

0.000159

783.150 -7169.6535

-96.2545

0.000163

803.150 -6853.8033

-95.6566

0.000167

823.150 -6525.7463

-95.0607

0.000171

843.150 -6185.4281

-94.4666

0.000175
0.000179

863.150 -5832.7923
883.150 -5467.7806

-93.8741
-93.2829

14256.300
2
14186.713
1
14105.224
1
14011.799
8
13906.402
8
13788.992
1
13659.523
5
13517.950
1
13364.222
0
13198.287
1
13020.091
0
12829.577
4
12626.687

0.000108
0.000111
0.000114
0.000117
0.000120
0.000124
0.000127
0.000130
0.000133
0.000137
0.000140
0.000143

903.150 5090.3331

8
12411.362
-90.8377
4

0.000183

903.150 -5090.3331

-92.6929

8
12411.362
4

0.000146