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Bioleaching is leaching where the extraction of metal from solid minerals into a solution is
facilitated by the metabolism of certain microbes - bioleaching microbes. Bioleaching is a
process described as "the use of microorganisms to transform elements so that the elements can
be extracted from a material when water is filtered trough it".
Applications
Bioleaching is a preparatory step to metal recovery. In subsequent processes, different from
bioleaching, the metal is recovered from the leachate.
Bacterial oxidation such as bioleaching or biooxidation on a commercial scale has been done on
sulfide metal bearing materials such as arsenopyrite, pyrite, pyrrhotite, covellite and chalcocite
ores and concentrates, the one exception to this processing being the oxidation of chalcopyrite
ores and concentrates.
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Gold and copper are the dominating valuable metals that are commercially extracted:
Direct bioleaching. The microbes are kept together with the valuable metal-bearing
material
Indirect bioleaching. The microbes are kept in a pond external to the valuable metalbearing material and provide the leaching chemicals at a distance.
Bioleaching involves abiotic and biotic reactions, often with different physicochemical
requirements. Indirect bioleaching is a way of satisfying the requirements independently by
separating the biotic and abiotic reactions. In direct bioleaching the challenge is to select
microbes whose living conditions are as close to the optimal conditions of the abiotic leaching
reactions as possible.
Advantages
Despite the advantages with bioleaching it is not always easy to choose among the different
methods of metal extraction in order to explore a potential mine. The Techno-Economic factors
of a resource need to be evaluated from case to case.
Tools and materials
Sulfide ore or concentrate binding or hosting the valuable metal; energy for
bioleaching microbes
Air (supplied actively or passively)
o O2 bioleaching microbes are aerobes and crave oxygen to extract energy from
sulfide minerals.
o CO2 bioleaching microbes need the macro-nutrient carbon to build cell mass
N, P, K, Mg nutrients for bioleaching microbes
pH-regulators (to keep pH 1-2)
o H2SO4
o CaCO3, CaO
Bioleaching microbes like T. ferrooxidans, T. thiooxidans & L. ferrooxidans
1. Cultivate (amenability testing, selection) or buy mixtures of bioleaching
microbes for inoculation.
2. Inoculate add to leaching reagents or spray ore before building heap (10^5
microbes/g ore for rapid Fe(II) oxidation)
Control of temperature (affected by climate)
o Air regulation
o Cover
o Cooling tower
Do a bleed in order to neutralize and precipitate metals (mostly iron)
Distribution system, stirring (in tanks), sprinklers, airflow, tubes - "blood-circulation" of
the heap.
Reaction catalysts