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Contents
Page
Scope................................................................................................................................................1
Designation system..........................................................................................................................2
Examples of designations..............................................................................................................11
iii
ISO/WD xxxxx-1
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies
(ISO member bodies). The work of preparing International Standards is normally carried out through ISO
technical committees. Each member body interested in a subject for which a technical committee has been
established has the right to be represented on that committee. International organizations, governmental and
non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the
International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.
International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2.
The main task of technical committees is to prepare International Standards. Draft International Standards
adopted by the technical committees are circulated to the member bodies for voting. Publication as an
International Standard requires approval by at least 75 % of the member bodies casting a vote.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. ISO shall not be held responsible for identifying any or all such patent rights.
ISO xxxxx-1 was prepared by Technical Committee ISO/TC 61, Plastics, Subcommittee SC 9, Thermoplastic
materials.
This second/third/... edition cancels and replaces the first/second/... edition (), [clause(s) / subclause(s) /
table(s) / figure(s) / annex(es)] of which [has / have] been technically revised.
ISO xxxxx consists of the following parts, under the general title Plastics Polyamide (PA) moulding and
extrusion materials:
Part 1: Designation system and basis for specification
Part 2: Preparation of test specimens and determination of properties
Annex A forms an integral part of this part of ISO XXXXX.
iv
ISO/WD xxxxx-1
Introduction
The ISO 1874-1: 1992 - Polyamides Designation system and basis for specification is complex and does not
fit with daily practice anymore. In practice ISO 1043 and ISO 11469 are, in combination, 'improperly' being
used as a designation system for e.g. marking. The aim of this revision is to simplify the data block system
and to connect more to ISO 1043 and ISO 11469, where the first two blocks are used for generic identification
and marking of products.
The revised designation system needs a new ISO number, as many existing documents refer to ISO 1874-1.
If the existing ISO 1874-1 would be replaced by the new designation system, these documents would refer to
the incorrect designation system. Therefore, after publication of the new designation system ISO 1874-1 need
to be phased out in 5 to 10 years. During that period of time ISO 1874-2; Preparation of test specimens and
determination of properties, will serve as the part 2 for as well ISO 1874-1 as the new ISO PA-designation
standard.
WORKING DRAFT
ISO/WD xxxxx-1
Scope
This part of ISO xxxxx establishes a system of designation for polyamide (PA) thermoplastic materials which
is based on ISO 1043 and is intended to coordinate with the marking document ISO 11469.
The designation system may be used as the basis for specifications.
It covers Polyamide homopolymers, copolymers and blends of various compositions for moulding and
extrusion.
The types of polyamide plastic are differentiated from each other by a classification system based on
appropriate levels of the designatory properties
a) viscosity number,
b) tensile modulus of elasticity and
and on information about chemical structure, method of processing, important properties, additives, colour,
fillers and reinforcing materials
The designation system is applicable to all polyamide homopolymers, copolymers and blends. It applies to
materials ready for normal use, unmodified and modified by colorants, additives, fillers, reinforcing materials,
polymer modifiers, etc.
This part of ISO xxxxx does not apply to monomer casting-type polyamides of PA6 and PA12.
It is not intended to imply that materials having the same designation give necessarily the same performance.
This part of ISO xxxxx does not provide engineering data, performance data or data on processing conditions
which may be required to specify a material for a particular application and/or method of processing. If such
additional properties are required, they shall be determined in accordance with the test methods specified in
part 2 of ISO 1874, if suitable.
In order to specify a thermoplastic material for a particular application or reproducible processing, additional
requirements shall be given in Data Block 5 (3.1, 3.6).
ISO/WD xxxxx-1
Normative references
The following normative documents contain provisions, which through reference in this text, constitute
provisions of this part of ISO 1874. For dated references, subsequent amendments to, or revisions of, any of
these publications do not apply. However, parties to agreements based on this part of ISO 1874 are
encouraged to investigate the possibility of applying the most recent editions of the normative documents
indicated below. For undated references, the latest edition of the normative document referred to applies.
Members of ISO and IEC maintain registers of currently valid International Standards.
ISO 307; Plastics - Polyamides Determination of viscosity number
ISO 472; Plastics - Vocabulary
ISO 527-1; Plastics Determination of tensile properties Part 1:General principles
ISO 527-2; Plastics Determination of tensile properties
plastics
ISO 1043-1; Plastics Symbols and abbreviated terms Part 1: Basic polymers and their special
characteristics
ISO 1043-2; Plastics -- Symbols and abbreviated terms - Part 2: Fillers and reinforcing materials
ISO 1874-2; Plastics Polyamide (PA) moulding and extrusion materials Part 2: Preparation of test
specimens and determination of properties
ISO 3451-4; Plastics Determination of ash Part 4: Polyamides
ISO 11469; Plastics Generic identification and marking of plastics products Determination of ash
Part 4: Polyamides
3
3.1
Designation system
General
The designation system for polyamides is based on the following standardized pattern (fig 1).
Designation
Identity Block
Description
block
(optional)
International
Standard
Block
Data Block 2
Data Block 3
Data Block 4
Data Block 5
ISO/WD xxxxx-1
See page 5
DESIGNATION
Identity Block
Individual Item Block
Description
block
(optional)
Thermoplastics
ISO
Standard
XXXXX
Data
Block 1
Data
Block 2
Data
Block 3
Data
Block 4
Data
Block 5
Polymer
Application &
Processing
Properties
Additional
information
Type
Additive
Filler
Flame
retardant
Recyclate
Moulding
Chracteristics
-PA6
-P
GF+MD
25
FR(30)
(R50)
60-14
>Part marking<
No
No
Yes
Yes
No
Designation:
Part marking:
>PA6-P(GF+MD)25FR(30)(R50)<
No
No
ISO/WD xxxxx-1
3.2
Data Block 1
In this Data Block, after the hyphen, the polyamide (PA) is identified by using the symbols and designations
listed in tables 1 and 2.
Polyamides containing a plasticizer may be designated by adding the letter P after the symbol, separated from
it by a hyphen (example: PA610-P).
Polyamides containing an impact modifier may be designated by adding the letter I after the symbol,
separated from it by a hyphen (example: (PA6-I).
Table 1 Symbols indicating the chemical structure of polyamide materials in Data Block 1
Symbol
PA6
PA11
PA12
PA410
PA66
PA69
PA610
PA612
PA1212
PA6T
PA9T
PAMXD6
PA6I
1,10-Decanedicarboxylic acid
ISO/WD xxxxx-1
Table 2 Examples of symbols indicating the chemical structure of copolyamide materials in Data
Block1
Symbola
Chemical structure
PA66/610
PA6/12
PA6/66/PACM6
PA12/IPDI
PA46/6
PA4T/6T
PA6T/XT
Polyamide copolymers based on hexamethylene diamine, terephthalic acid and an unspecified diamine
PA6T/66
Polyamide copolymers based on hexamethylene diamine, terephthalic acid and adipic acid
PA6T/6I
Polyamide copolymers based on hexamethylene diamine, terephthalic acid and isophthalic acid
PA6T/6I/66
Polyamide copolymers based on hexamethylene diamine, terephthalic acid, isophthalic acid and adipic
acid
PA66/6I
Polyamide copolymers based on hexamethylene diamine, adipic acid, and isophthalic acid
PANDT/INDT
Polyamide copolymers based on 1,6 diamino-2,2,4-trimethylenehexane, 1,6 diamino-2,4,4trimethylenehexane and terephthalic acid
PA12/IPDI
The following two designations include an indication of the mass content ratio (Annex A).
PA66/6 (90/10)
Polyamide copolymers based on 90% (m/m) hexamethylenediamine and adipic acid and 10% (m/m)
-caprolactam
PA6/66 (80/20)
Polyamide copolymers based on 80% (m/m) -caprolactam and 20% (m/m) hexamethylenediamine and
adipic acid
PA66/6 (80/20)
Polyamide copolymers based on 80% (m/m) hexamethylenediamine and adipic acid and 20% (m/m)
-caprolactam
Semi-crystalline Polyamides, designated as PA6T/xx/yy may also be called Polyphthalamides (PPA) if the residues of terephthalic acid
or isophthalic acid or a combination of the two comprise at least 55 mole percentage of the dicarboxylic acid portion of the repeating
structural units of the polymer chain (ASTM D 5336)
ISO/WD xxxxx-1
Blends.
Blends can be made from materials mentioned in both tables and/or other polymers (ISO 1043).
For polymer blends or alloys use the abbreviated terms for the basic polymers, with the main component in
first place followed by the other components in descending order according to their mass fractions, separated
by a plus sign and no space before or after the plus sign.
EXAMPLE
3.3
Data Block 2
In this data block, the type of filler or reinforcing material is represented by one code-letter and its physical
form by a second code-letter (Table 3, ISO 1043-2). Subsequently (without a space), the mass content may
be given by a two-figure code-number.
Mixtures of filler materials or forms may be indicated by combining the relevant codes using the sign "+" within
parenthesis followed by the total filler content outside the parenthesis. For example, a mixture of 25 % (m/m)
glass fibre (GF) and 10 % (m/m) mineral powder (MD) would be indicated by (GF+MD)35.
Separated from the reinforcement code by a space, the addition of a flame retardant or flame retardant
behaviour is represented by the code FR, where the type of flame retardant according ISO 1043-4 is given by
a two letter code between parenthesis.
Separated by a space from the flame retardant or the reinforcement code if no flame retardant code is used,
the declaration of recyclate is represented by the code RC between parenthesis (RC). Following the code RC
the mass content may be given between the parenthesis without a space. For example, a PA66 containing
20% glass fibres resulting from an overall minimum 70% of weight recyclate and 30% of virgin material would
be indicated PA66 GF20 (RC70).
Table 3 Coding system for fillers and reinforcing materials in Data Block 2
Code-letter
Material
(Position 1)
Boron
Carbona
Fiber
Glass
Granules; ground
Whiskers
Form
(Position 2)
Balls; beads; spheres
Minerala; metal b
Organic; synthetica
Talcum
Not specified
Not specified
Othersa
Others
These materials may be identified after the code-letter, e.g. by chemical symbol or additional codes to be agreed upon.
Metal filler shall be identified by the chemical symbol (in capital letters) after the mass content. For example, steel whickers may be
designated MH05FE.
EXAMPLE
ISO 1874-PA6-I,(GF+MD)25
ISO/WD xxxxx-1
3.4
Data Block 3
In this data block, information about the method of processing is represented by a code letter, followed by
code letters about additives, supplementary information, and other characteristics. The code-letters are
specified in table 4.
If no specific information is given on the method of processing the letter X shall be used as the first
code-letter.
First letter
Processing stabilized
A
B
Letters 2 to 8
Blow moulding
Antiblocking
C1
Coloured, transparent
C2
Coloured, non-transparent
Powder; dry blend
D
E
Expandable
Pellets; granules
G
H
Coating
Monofilament extrusion
Injection moulding
Heat-ageing stabilized
Light and/or weather stabilized
Natural (not coloured)
N
P
Rotational moulding
Lubricated
Tape manufacture
Improved transparency
Stabilized against hydrolysis
W
X
No indication
Antistatic
3.5
Data block 4
In this data block, the viscosity number is represented by a two-figure code-number (3.5.1) and the tensile
modulus of elasticity by a three-figure code-number (3.5.2). The two codes are separated from each other by
a hyphen.
If no specific information is given in one of the two positions, the letter X shall be used.
If a property value falls on or near a range limit, the manufacturer shall state which range will designate the
material. If subsequent individual test values lie on, or either side of, the range limit because of manufacturing
tolerances, the designation is not affected.
NOTE
Not all combinations of the values of the designatory properties are provided by currently available m aterials.
ISO/WD xxxxx-1
3.5.1
Viscosity number
The viscosity number shall be determined in accordance with ISO 307, using the solvent specified in table 5.
The average value of the viscosity number is represented by a two-figure code-number as specified in table 5.
For copolyamides, 96% (m/m) sulfuric acid should preferably be used as solvent, but some copolyamides
dissolve better in m-cresol or phenol/1,1,2,2-tetrachloroethane (60/40%). Information concerning the most
suitable solvent can be obtained from the supplier of copolyamides and homopolyamides which are not
covered in the last column of table 5.
Table 5 Code-numbers used for viscosity number in Data Block 4
Code-number
09
Solvent
m-cresol
Applicable to
Solvent
phenol/1,1,2,2tetrachloroethane
(60/40%)
PA6,
90
PA66,
10
>90 to 110
12
>110 to 130
PA69,
14
>130 to 160
PA610,
18
>160 to 200
PA612,
22
>200 to 240
MXD6 and
27
>240 to 290
Copolyamides
32
>290 to 340
34
>340
11
110
PA1212,
12
>110 to 130
PA11,
14
>130 to 150
PA12 and
16
>150 to 170
Copolyamides
18
>170 to 200
22
>200 to 240
24
>240
12
120
PA6T/66,
13
>120 to 140
PA6I/66, PA6I/6T,
15
>140 to 160
PA6T/6I/66,
17
>160 to 180
PA6T/6I,
19
>180 to 200
PA6I/6T/66, PPA
20
>200
and
Copolyamides
ISO/WD xxxxx-1
NOTE
Viscosity numbers determined with 90 % (m/m) formic acid as solvent can be converted into viscosity
numbers determined in 96 % (m/m) sulfuric acid using the following equations (ISO 307: 2007).
For PA6:
For PA66:
In y = 0,416 1 + 0,927 6 In x
In y = 0,454 1 + 0,926 1 In X
For PA69:
In y = 0,463 4 + 0,909 5 In x
For PA610:
In y = 0,982 3 + 0,793 2 In x
Where
x is the viscosity number in 90 % (m/m) formic acid;
y is the viscosity number in 96 % (m/m) sulfuric acid.
For the viscosity number of PA612, which may be determined in accordance with ISO 307: 2007 in either m-cresol or 96
% (m/m) sulfuric acid, the following conversion formula applies:
ln y = 0,285 7 + 0,985 9 ln x
where
x is the viscosity number in 96 % (m/m) sulfuric acid;
y is the viscosity number in m-cresol.
The above conversion formulae have been calculated from the results of an interlaboratory investigation carried out in
1982 ( ISO 307:2007). The accuracy of the conversions depends on both the size of the viscosity number and the type of
PA, the latter resulting from the fact that different numbers of the different PA-types were included in the investigation. The
95 % confidence intervals for the values of the nominal viscosity number in 96 % (m/m) sulfuric acid, converted from
different values of the nominal viscosity number in the other solvent, are given in table 5.
100
140
180
220
260
300
340
a
PA6
PA66
PA69
PA610
PA612
0.8
0,8
0,7
0,7
0,8
1,0
1.3
1,6
1,4
1,2
1.3
1,7
2,4
3,3
2,0
1.9
2.9
4.7
6.9
9.3
11,9
4,7
4,1
5,8
9,0
12,9
17,2
21,8
4.4
4,9
10,2
17,6
26.0
35,3
45.3
Solvents: 90 % (m/m) formic acid for PA6, PA66, PA69 and PA610; m-cresol for PA612
ISO/WD xxxxx-1
3.5.2
The tensile modulus of elasticity shall be determined in the dry state in accordance with ISO 527 under the
test conditions specified in ISO 1874-2. The average value of the tensile modulus of elasticity is represented
by a three-figure code-number as specified in table 7.
Table 7 Codes used for tensile modulus of elasticity in Data Block 4
Tensile modulus of elasticity
Code-number
001
3.6
Range MPa
150
002
003
004
005
007
010
020
030
040
050
060
070
080
090
100
110
120
140
160
190
220
250
> 23 000
Data Block 5
Indication of additional requirements in optional data block 5 is a way of transforming the designation of a
material into a specification for a particular application. This may be done for example by reference to a
suitable national standard or to a standard-like, generally established specification (4.2).
10
ISO/WD xxxxx-1
Examples of designations
4.1
An unfilled polyamide material PA6 for injection moulding (M), with moulding release agent (R), having a
viscosity of 150 ml/g (14) and a tensile modulus of elasticity of 2 700 MPa (030), and with a nucleating
additive (N), would be designated:
DESIGNATION
Identity Block
Individual Item Block
Description
block
(optional)
ISO
Standard
Data
Block 1
Data
Block 2
Data
Block 3
Data
Block 4
Data
Block 5
Polymer
Application &
Processing
Properties
Additional
information
Type
Thermoplastics
XXXXX
Modification
Filled
Flame
retardant
Recyclate
Moulding
Chracteristics
-PA6
14-030N
>Part marking<
No
No
Yes
Yes
No
No
No
ISO
Standard
Type
Thermoplastics
XXXXX
Data
Block 1
Data
Block 2
Data
Block 3
Data
Block 4
Data
Block 5
Polymer
Application &
Processing
Properties
Additional
information
Modification
-PA66
Filled
Flame
retardant
Recyclate
GF37
Moulding
Chracteristics
14-100
>Part marking<
No
No
Yes
Yes
No
No
No
11
ISO/WD xxxxx-1
An unfilled polyamide material containing plasticizer (PA12-P) for extrusion (E), with a heat-ageing stabilizer
(H) and a light and weather stabilizer (L), and having a viscosity number of 210 ml/g (22) and a tensile
modulus of elasticity of 280 MPa (003), would be designated:
DESIGNATION
Identity Block
Individual Item Block
Description
block
(optional)
Thermoplastics
ISO
Standard
XXXXX
Data
Block 1
Data
Block 2
Data
Block 3
Data
Block 4
Data
Block 5
Polymer
Application &
Processing
Properties
Additional
information
Type
Modification
-PA12
-P
Filled
Flame
retardant
Recyclate
Moulding
Chracteristics
HL
22-003
>Part marking<
No
No
Yes
Yes
No
No
No
This section provides examples of how to use this designation system and how to turn the designations into
specifications. When used only as designations, the pattern employs information from Data Blocks 1-4. When
converting the designation into a Specification, the pattern also includes information from Data Block 5
An unfilled polyamide material (PA6) for injection moulding (M), containing heat aging stabilizer (H), having a
viscosity of 150 ml/g (14), and a tensile modulus of 2 200 MPa (020), and meeting the requirements of ASTM
D6779 PA0213 would have the specification:
DESIGNATION
Identity Block
Individual Item Block
Description
block
(optional)
ISO
Standard
Type
Thermoplastics
XXXXX
Data
Block 1
Data
Block 2
Data
Block 3
Data
Block 4
Data
Block 5
Polymer
Application &
Processing
Properties
Additional
information
14-020
ASTM
D6779
PA0213
No
No
Modification
Filled
Flame
retardant
Recyclate
-PA6
Moulding
Chracteristics
>Part marking<
No
No
Yes
Yes
No
Specification:
12
ISO/WD xxxxx-1
A polyamide material (PA6T/6I) reinforced with 33% of glass fiber (GF) with special burning characteristics
(FR) for injection moulding (M), having a tensile modulus of elasticity of 8 000 MPa (080) and meeting the
requirements of ASTM D5336 PPA0121FL34 would have the specification:
DESIGNATION
Identity Block
Individual Item Block
Descriptio
n block
(optional)
ISO
Standard
Data
Block 1
Data
Block 2
Data
Block 3
Data
Block 4
Data
Block 5
Polymer
Application &
Processing
Properties
Additional
information
X-080
ASTM
D5336
PPA
012FL34
No
No
Type
Thermoplastics
XXXXX
Modification
-PA6T/6I
Filled
GF33
Flame
retardant
Recyclate
FR
Moulding
Chracteristics
>Part marking<
No
No
Yes
Yes
No
Specification:
13
ISO/WD xxxxx-1
Annex A
(normative)
Definition and designation of polyamides
Polyamide materials are thermoplastic materials that contain carboxylic amide groups, -CONH-, at regular
intervals in the linear polymer chain.
Polyamide homopolymers may be built up from a single starting material (an aminocarboxylic acid or its
lactam); in this case, they are designated by a number corresponding to the number of carbon atoms in the
starting material (table A.1).
Table A.1 Designation of linear aliphatic polyamides of general formula [NH-(CH2)x -CO]n
Symbol
Value of x
PA6
PA11
10
11
PA12
11
12
However, polyamide homopolymers may also be built up from on starting material with amino groups plus one
starting material with carboxylic acid groups. These polyamides, based on diamines and dicaboxylic acids, are
designated by a two-digit, three-digit or four-digit number, respectively. In the case of the four digit number,
the first digit (or the first and second digits) corresponds to the number of C atoms in the linear aliphatic
diamine and the second digit (or with some materials the second and third or the third and fourth digits)
corresponds to the number f C atoms in the linear aliphatic dicarboxylic acid (table A.2).
Table A.2 Designation of linear aliphatic polyamides of general formula
[NH-(CH2)x-NH-CO-(CH2)y-CO]n/2
Value of
Symbol
X
PA46
PA66
PA610
PA612
10
PA1212
12
10
Copolymer polyamides, also called copolyamides, may be built up from various starting materials (lactams,
aminocarboxylic acids, equimolar amounts of diamines and dicarboxylilc acids). These copolyamides are
designated PA plus numbers representing the components of the copolyamide, the numbers being separated
by an oblique stroke (ISO 1043-1:2001 annex A, clause A.6). But copolyamides with the same numbers or
symbols can give quiet different properties, depending on the ratio of the starting materials. Therefore, if there
is a need for a more exact designation, the mass content ratio shall be included. If it is necessary to indicate
this ratio, the two figures, separated by an oblique stroke, may be placed in parentheses at the end of the
designation (table 2).
14
ISO/WD xxxxx-1
Starting materials (monomers) for copolyamides, as well as for homopolyamides, include not only linear
aliphatic compounds, but also branched aliphatic-aromatic, cyclo-aliphatic and aromatic compounds. The
monomer units of these non-linear aliphatic compounds may be derived from the substances listed, together
with their designations, in table A.3. Because of the large number of possible combinations of copolyamides,
only a few examples have been listed in table 2.
Table A.3 Symbols of aromatic and non-linear aliphatic monomer units
Symbol of
monomer unita
Terephthalic acid
Isophthalic acid
2,6-Naphthalenedicarboxylic acid
PACP
2,2-Bis(p-aminocyclohexyl)propane
MACM
3,3-Dimethyl-4,4-diaminodicyclohexylmethane
PACM
Bis(p-aminocyclohexyl)methane
IPD
Isophorone diamine
ND
1,6-Diamino-2,2,4-trimethylhexane)
IND
1,6-Diamino-2,4,4-trimethylhexane
PPGD
Polypropylene glycoldiamine
PBGD
Polybutylene glycoldiamine
MXD
m-Xylylene diamine
PXD
m-Xylylene diamine
PTD
p-Toluylene diamine
MTD
m-Toluylene diamine
PABM
Diphenylmethane-4,4-diamine
MC
1,3-Bis(aminomethyl)cyclohexane
MPMD
2-Methylpentamethylenediamine
XX
YY
15