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Mole Balance
Rate Laws
Stoichiometry
Heat Effects
Isothermal Design
Stoichiometry
Rate Laws
Mole Balance
Rate Law
Stoichiometry
DERIVE THE LAST
TWO
October 16, 2016
V=1701 dm3
Rate Law
Stoichiometry
Gas phase, isothermal (T = T0), no
pressure drop (P = P0), CAo= CBo ,
v=vo(1+eX)
October 16, 2016
V=227 dm3
10
Rate Law
Stoichiometry
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t = 41 sec
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13
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Reaction
Additional Information
CA0 = 0.2
mol/dm3
KC = 100
dm3/mol
k = 2 dm3/molmin
FA0 = 5 mol/min
15
FTo
CAo = 2 mol/dm3
V= 500 dm3
and
k=0.1/min
October 16, 2016
16
V= ?
and
k=?
October 16, 2016
X=0.75
BITS, PILANI K. K. BIRLA GOA
CAMPUS
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18
Stoichiometry
PFR: DIY
Zero order
reaction in CSTR
/ PFR
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Final Problem
The following reaction follows an
elementary rate law
Initially 77% N2, 15% O2, 8% inerts are fed to a
batch reactor where 80% of the equilibrium
conversion (Xe = 0.02) is reached in 151 s. What
is the specific reaction rate constant k1?
Additional Information
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For
1st
Reaction time
tr
First order k
(sec-1)
Second order
kCAo (sec-1)
Hours
10-4
10-3
Minutes
10-2
10-1
Seconds
10
Milliseconds
1000
10,000
Order
t = (1/k) ln (X / 1- X )
October 16, 2016
t = t f + t e + tr + t c
(1.5 3), (0.2 2.0),
varies, (0.5 1.0)
BITS, PILANI K. K. BIRLA GOA
CAMPUS
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GETTING TOUGH
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Include P
Neglect P
October 16, 2016
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25
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Ergun Equation
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dP / dz = o (Po/P) (T/To)(FT/Fto)
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CATALYST WEIGHT
Bulk density is
mass of catalyst
per unit volume of
reactor bed
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WHEW!!!!
FINALLY WE HAVE
SOMETHING
TWO COUPLED FIRST
ORDER DIFFERENTIAL
EQUATIONS SOLVED
ANALYTICALLY OR BY
COMPUTER
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ANALYTICAL SOLUTION
P = f(z)
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X = 0.54
NOTE
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Practice (DIY)
What is the conversion of the PFR?
X=?
W = 500kg
k = 0.1111 dm3 s-1 kg
FA0 = 10 mol/s
CA0 = 1 mol/dm3
0.96
41
Practice (DIY)
FA0 = 10 mol/s
CA0 = 0.1 mol/dm3
X1 = 0.8
W2 = W1
T = 350 K
W1 = ?
T = 325 K ; E = 2500 cal
X = 0.66
X2 =?
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Solution
X = 0.66
October 16, 2016
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DESIGN ON REACTORS
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Damkohlers number
It is important to know what values of
Damkohler number, Da give high and low
conversion in continuous flow reactors.
Equation for the 1st order liquid phase reaction in
a CSTR can also be written in the Terms of
Damkohler number
CSTR in series
A first order reaction with no change
in the volumetric flow rate is to be
carried out in two CSTRs placed in
series:
CSTRs in parallel
We now consider the
case in which equal
sized reactors are
placed in parallel rather
then in
series, and the feed is
distributed equally
among each of the
reactors
October 16, 2016
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53
54
Solution:
77