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# Institution of Chemical Engineers
Trans IChemE, Vol 81, Part A, January 2003
www.ingentaselect.com=titles=02638762.htm
xisting re nery distillation systems are highly energy-intensive, and have complex
column con gurations that interact strongly with the associated heat exchanger
network. An optimization approach is developed for existing re nery distillation
processes. The optimization framework includes shortcut models developed for the simulation
of the existing distillation column, and a retro t shortcut model for the heat exchanger network.
The existing distillation process is optimized by changing key operating parameters, while
simultaneously accounting for hydraulic limitations and the design and the performance of the
existing heat exchanger network. A case study shows that a reduction in energy consumption
and operating costs of over 25% can be achieved.
Keywords: heat integration; crude oil; retro t; heat exchanger network; shortcut models.
INTRODUCTION
Crude oil distillation systems are among the largest
energy consumers in the chemical industries. Crude oil
distillation systems are complex con gurations that interact
strongly with the associated heat recovery systems. In crude
oil distillation, the crude oil is preheated in two stages
before entering the distillation column. The rst stage is a
heat exchanger network (HEN), where the oil is heated to an
intermediate temperature by cooling distillation process
streams and recovering the heat from condensers. Afterwards, the crude oil enters a furnace to reach the required
processing temperature. The more fuel consumed in the
furnace, the larger the operating cost. Any heat
recovered from the distillation process reduces the utility
consumption in the furnace. The energy ef ciency of the
distillation process can be improved by designing the
distillation column to create opportunities for heat recovery
and designing the HEN to exploit these opportunities.
Any change in the operating conditions of the distillation
column changes the amount of heat that may be recovered,
and therefore affects the energy ef ciency of the distillation
system (i.e. the distillation column and the associated HEN).
These operating conditions include the feed preheating
temperature, re ux ratios, pump-around temperature drops
and liquid ows, and stripping steam ows. For example,
when the temperature drop across the pump-around is
reduced, the pump-around will operate at a higher temperature, which creates opportunities for heat recovery. Therefore, the energy ef ciency of the distillation system can be
improved by optimizing all these variables simultaneously.
Objectives of retro t projects in re neries include reducing
energy consumption and increasing production capacity, in
order to increase pro t. The retro t targets are preferably
achieved by re-using the existing equipment more ef ciently
rather than installing new units and incurring greater capital
investment. While ful lling these retro t objectives, existing
LITERATURE REVIEW
Retro t of re nery distillation systems has been studied
by a number of researchers. Early research concentrated on
proposing modi cations to the distillation column and
the heat exchanger network in order to reduce energy
consumption. Sittig (1978) suggested that, in order to
improve the ef ciency of the distillation system, new internals with higher ef ciency should be installed and recommended the use of intermediate reboilers. Bannon and
Marple (1978) proposed other column modi cations, such
147
GADALLA et al.
148
149
ow rates exceeding these hydraulic limitations, the distillation column becomes bottlenecked and ooding occurs. To
avoid ooding, signi cant capital investment will be
required. In this work, the hydraulic limitations of the
distillation columns are taken into account in the optimization framework. During the optimization, the diameter
required for separation in each section is calculated from
ooding correlations and vapour ows inside the column.
Then, the hydraulic limitations (e.g. the existing diameters)
of the existing distillation column are applied as constraints
to the optimization to keep the required diameter of each
section less than the existing diameter. This consideration
ensures that process modi cations resulting from the retro t
design procedure are feasible with respect to the column
hydraulics.
Simultaneous Optimization Framework
An overall model for optimization of an existing heatintegrated distillation process is formulated by combining
the column retro t model and the area retro t model for the
heat exchanger network. Since the models for the distillation
column and the existing heat exchanger network are nonlinear, the optimization problem is a non-linear programming (NLP) problem. The optimization uses a successive
quadratic programming (SQP) solver. In particular, the
subroutine E04UCF of the NAG Fortran Library (NAG,
1990) is used to implement the Quasi-Newton method
(Dennis and Schnabel, 1983) in the solution.
The optimization framework proposed for re nery distillation columns is shown in Figure 2. As shown in the gure,
the column retro t model and the HEN model are solved
simultaneously within the optimization framework. The cost
model calculates the annual cost of the energy consumption
and the capital costs for additional exchanger area and HEN
retro t modi cations. The lower and upper boundaries of
each optimization design parameter need to be provided.
The hydraulic limitations of the existing distillation column
are applied to the optimization as a constraint. Any practical
constraints of the existing HEN, such as maximum duty of
pump-arounds, may be applied in the optimization.
The objective of the optimization is the minimization of
the objective function, i.e. the total annualized cost of the
energy consumption and additional HEN area required for
retro t.
GADALLA et al.
150
spheric crude oil distillation tower, where the crude oil assay
is that of Tia Juana Light (Watkins, 1979); the HEN is based
on an industrial example.
The unit processes 100,000 barrels per day of crude oil to
produce light naphtha (LN), heavy naphtha (HN), light
distillate (LD), heavy distillate (HD) and residue. The
column uses three side strippers and three pump-arounds.
The diameter of each column section is given in Figure 4.
The existing operating conditions of the distillation column
are listed in Table 1. These operating conditions include
feed preheating temperature, ow rate of liquid through each
pump-around, temperature drop along each pump-around,
steam ow rate to each section, and re ux ratio. The existing
heat exchanger network is illustrated in Figure 5; the HEN
contains 27 exchangers, with a total area of 4000 m2. The
energy consumption of the existing distillation column is
99 MW; the utility cost is 17 million per year.
RESULTS
Prior to the optimization of the existing crude oil distillation unit, an extensive retro t study is carried out on the
existing HEN, using network pinch (Asante, 1996), to
obtain the area retro t model. This study xes the existing
exchanger matches, and introduces network modi cations to
reduce the energy consumption. The retro t data obtained is
then regressed to calculate the retro t parameters of the area
retro t model.
area 1:0738 106 Denergy consumption1:2298
1
where the units of area are m2 and those of energy consumption are MW.
For the existing re nery distillation unit, the operating
variables of the distillation column are then optimized
simultaneously to minimize the total annualized cost.
During this simultaneous optimization, the column con guration (including locations of condenser, pump-arounds
and reboilers) is xed. The product speci cations in terms
of component recoveries are kept unchanged, while the
product ows are allowed to change within a speci ed
Unit
Existing
Optimum
Parameter
C
kmol h1
kmol h1
kmol h1
C
kmol h1
kmol h1
365
2187
2306
5791
30.0
50.0
20.0
1200
250
4.78
370
2027
3508
6992
33.5
30.5
18.6
1085
213
3.61
Energy consumption
Energy saving
Energy cost
Stripping steam cost
Saving in operating cost
Additional HEN area
HEN modi cation
HEN capital investment
Payback
DTmin
CONCLUSIONS
An optimization approach for retro t of re nery distillation columns has been developed. This approach can
optimize an existing heat-integrated re nery distillation
Unit
Existing
Optimum
MW
MW
106 =year
106 =year
106 =year
m2
99
17.50
2.90
35
72
27
12.66
2.59
5.15
1411
Resequence
0.95
0.2
25
106 =year
year
151
GADALLA et al.
152
Unit
1
kmol h
kmol h1
kmol h1
kmol h1
kmol h1
Existing
Optimum
680.7
493.5
652.8
149.8
633.9
681.9
495.3
651.2
150.2
632.1
REFERENCES
Asante, N.D.K., 1996, Automated and interactive retro t design of practical
heat exchanger networks, Ph.D. Thesis, UMIST, Manchester.
Asante, N.D.K. and Zhu, X.X., 1997, An automated and interactive
approach for heat exchanger network retro t, Chem Engng Res Des,
75(3): 349360.
Bagajewicz, M., 1997, Energy savings horizons for the retro t of chemical
processes: application to crude fractionation units, Comput Chem Engng,
23(1): 19.
Bannon, R.P. and Marple, S., 1978, Chem Engng Prog, 7: 4145.
Carlberg, N.A. and Westerberg, A.W., 1989, Ind Engng Chem Res, 28:
13791386.
Carlsson, A., Franck, P. and Berntsson, T., 1993, Chem Engng Prog, 89(3):
8796.
Cerda, J. and Westerberg, A.W., 1981, Ind Engng Chem Proc Des Devl,
20(3): 546557.
Ciric, A. and Floudas, C.A., 1989, Comput Chem Engng, 13(6): 703715.
Dennis, J.E. and Schnabel, R.B., 1983, Numerical Methods for Unconstrained Optimization and Nonlinear Equations (Prentice-Hall, New
Jersey, USA).
Dhole, V. and Buckingham, P., 1994, Re nery column integration for debottlenecking and energy saving, paper presented at ESCAPE IV Conference, Dublin.
Dhole, V.R. and Linnhoff, B., 1993, Comput Chem Engng, 17(56): 549
560.
Fraser, A.C.S. and Sloley, A. W., 2000, Hydrocarbon Process, 79(6): 5763.
Gadalla, M., Jobson, M. and Smith, R., 2003, Shortcut models for retro t
design of distillation columns, Chem Engng Res Des (submitted).
Glinos, K. and Malone, M.F., 1985, Ind Engng Chem Proc Des Devl, 24(4):
10871090.
Harbert, W.D., 1978, Hydrocarbon Process, 57(7): 123125.
Liebmann, K., 1996, Integrated crude oil distillation design, Ph.D. Thesis,
UMIST, Manchester, UK
Linnhoff, B., Dunford, H. and Smith, R., 1983, Chem Engng Sci, 38(8):
11751188.
NAG, 1990, NAG Fortran Library, Vol. 4, 1st edn (NAG, Illinois, USA).
Petlyuk, F.G., Platonov, V.M. and Slavinskii, D.M., 1965, Int Chem Engng,
5(3): 555561.
Shokoya, C.G., 1992, Retro t of heat exchanger networks for debottlenecking and energy savings, Ph.D. Thesis, UMIST, Manchester.
Sittig, M., 1978, Petroleum Re ning Industry Energy Saving and Environmental Control (Noyes Data Corporation, New Jersey).
Stupin, W.J. and Lockhart, F.J., 1972, Thermally coupled distillation: a case
history, Chem Engng Prog, 68(10): 7072.
Suphanit, B., 1999, Design of complex distillation system, Ph.D. Thesis,
UMIST, Manchester.
Tjoe, N. and Linnhoff, B., 1986, Using pinch technology for process retro t,
Chem Engng, 28 April: 4760.
Triantafyllou, C. and Smith, R., 1992, The design and optimization of fully
thermally coupled distillation columns, Chem Engng Res Des, 70(2):
118132.
Underwood, V., 1948, Fractional distillation of multi-component mixtures,
Chem Engng Prog, 44: 603.
Watkins, R.N., 1979, Petroleum Re nery Distillation, 2nd edn (Gulf Publishing Company, Texas).
Yee, T.F. and Grossmann, I. E., 1991, Ind Engng Chem Res, 30(1): 146162.
ADDRESS
Correspondence concerning this paper should be addressed to
Dr M. Jobson, Department of Process Integration, UMIST, PO Box 88,
Manchester, M60 1QD, UK.
E-mail: megan.jobson@umist.ac.uk
The paper was presented at the International Conference on Distillation
and Absorption held in Baden-Baden, Germany, 30 September2 October
2002. The manuscript was received 8 July 2002 and accepted for publication after revision 1 November 2002.