11¢ Kanyakumari District Examination
Second Mid Term Test, November - 2013
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Standard 11
Time: 1.30 Hrs. CHEMISTRY Marks: 75
Part-I
Answer all the questions. Choose and write the correct answer.
1) The most electronegative element of the periodic table is
a) iodine b) fluorine —c) chlorine d) oxygen
2) The law of octaves was stated by
a) Doberiner b) Mendeleev c) Moseley d) Newland
3) Electron affinity of noble gases are
a) zero b) maximum c) minimum d) positive
4) The compound which contains both ionic and covalent
nature is
a) CH, b) H, c) KCN d) KCé
5). The crystal lattic of electrovalent compound is composed
of .
a) atom b) molecules c) oppositely charged ions
d) both molecules and ions
6) The bond: angle in water molecule is
a) 104.5° —b) 109°28' cc) 107° d) 90°
7) Which solution would possess the lowest boiling point
a) 1% NaCé solution b) 1% urea solution
c) 1% glucose solution d) 1% sucrose solution
8) The Van't Hoff factor of 0.005 M aqueous solution of KCé
is 1.95. The degree of ionisation of KCé is
a) 0,94 b) 0.95 c) 0.96 d) 0.59
9) Isotonic solutions are the solutions having the same
a) Surface tension b) Vapour pressure
c) Osmotic pressure d) Viscosity
10) The relative lowering of vapour pressure is equal to
a) mole fraction of solvent
b) number of moles of solute
c) number of moles of solvent
d) mole fraction of solute1ic
11)
12)
13)
14)
15)
.16)
Note:
17)
_ 18)
19)
20)
21)
22)
23)
24)
25)
26)
27)
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2
In which process work is maximum
a) Reversible b) Irreversible c) Exothermic d) Cyclie
Enthalpy H cah be defined as
a) H = V-PV b) H = P+U4+V
c) H = U+PV d) H = U-TS
Which of the following is not a state function
ayq b) qt+w c) AH d) V+PV
Diels-Alder reaction is the reaction between
a) Diene and dienophile b) Electrophile and nucleophile
c) Oxidant and reductant d) none
Alcohols can be dehydrated to olefins using
a) H,SO, b) PCe ¢) Soce, — d) Zn/Hg
Which isomerism is present in but-1-ene and 2-methyl
prop-1-ene?
a) positioin isomerism b) meta merism
c) Cheun isomerism d) tauto merism
Part-II
Answer any eight: 8x3=24
State Hund's rule of maximum multiplicity.
Write the electronic configurationi element with Mn and Cu.
What is Octet rule.
What is meant by hybridisation?
Define relative lowering af vopour pressure.
What are the advantages of Berkley-Hartley method?
State Charle's - Vant Hoff law.
Write the difference between an exothermic and an
endothermic process.
Define Zeroth law of thermodynamics.
Write - Sabatier Senderens reduction.
What are the uses of ethylene?11C
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4
Part - III
Answer any three questions. Choose at least one question
from each section: 3x5=15
28)
29)
30)
31)
32)
33)
Section-A
Explain the various quntem. numbers.
Explain the important properties of Ionic compound.
Section -B
Describe about Beckmann thermo meter.
Derives the equivation AH = AV+RT An(g)
Section -C
Explain the following reaction:
(i) Hydroboaration (ii) Arorhatization
(iii) Nitration in alkane
Describe geometrical isomerism present in alkene.
Part-IVv
Question number 36 is compulsory and answer any one from
the remaining questions: 3x5=15
34)
35)
36)
a] Describe the limitation of Bohr theory.
b] Calculate the latitue energy of NaCé using Born-Haber
cycle,
a] Explain the determination of relative lowering of vapour
pressure of Ostwlad Walker method.
b] Compare the enthalpy changes that occur between the
neutralisation of a strong acid and a weak acid by
sodium hydroxide. Explain the difference seen.
a] A solution containing 2.5 g of a non-volatile solute in
100 gm of benzen boiled at a temperature 0.42 K higher
than at the pure solvent boiled. What is the molecular
weight of the solute? The molal elevation constant of
benzene is 2.67 K.Kg mol‘.11¢c
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b] An organic compound A(C,H,O) reacted with H,SO, at
c
d
160°-170°C to give compound B with molecular formula
C,H,. Compound B react with Baeyer's reagent to give
compound C(C,H,O,). Identify A, B and C. Explain the
reaction.
(OR)
Calculate the enthalpy of combustion of ethylene at 300
K at constant pressure if its enthalpy of combustion at
constant volume is -1406 K) mol".
An organic compound A(C,H.,)-is passed into dilute
sulphuric acid in the. presence of mercury sulphate give
an aldehyde B(C,H,O). Further (A) is passed through
red hot iron tube under pressure get polymerised to
aromatic compound C(C,H,). Identify A, B and C explain
the reaction.