I-N-O-R-G-A-N-I-C C-H-E-M-I-S-T-R-Y Single Choice Questions

I-N-O-R-G-A-N-I-C
C-H-E-M-I-S-T-R-Y
Single Choice Questions

Chemical Bonding
Q. 1. The bond order of individual carbon carbon bonds in benzene is :
(a) one
(b) two
(c) between one and two
(d)
one
alternately
Q. 2. The molecule that has linear structure is :
CO2
NO2
(b)
(c)
(a)
SO2
(d)
and
two,
SiO 2
Q. 3. Hydrogen bonding is maximum in :

(a) ethanol (b) diethyl ether (c) ethyl chloride (d) triethyl amine
Q. 4. Element A has 3 electrons in the outermost orbit and element B has 6 electrons
in the outermost orbit. The formula of the compound formed between A and B
would be
A2 B3
A2 B6
A3 B2
A2 B
(b)
(c)
(d)
(a)
Q. 5. The correct order of the O O bond length in

O3 H 2 O2 O2
(a)
(b)
O2 O3 H 2 O2
(d)
(c)
XeF2 , XeF4 ,
O3
O2 , H 2 O 2
and
O2 H 2 O2 O3
is :
H 2 O2 O3 O2
XeF6
Q. 6. In
and
the number of lone pairs on Xe is respectively :
(a) 2, 3, 1 (b) 1, 2, 3 (c) 4, 1, 2 (d) 3, 2, 1
Q. 7. The ONO angle is maximum in :
NO3
NO2
(b)
(a)
(c)
NO2
(d)
NO2
Q. 8. Which of the following hydrocarbons has the lowest dipole moment?

H3C
CH3
Kota Academy ,Bapat nagar Nagpur Road ,Chandrapur.Mob:
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(a)
(b)CH3-C = C-CH3
H
H
(c)CH3CH2C = CH
(D) CH2 = CH C =C--H
Q. 9. The correct order of hybridization of the central atom in the following species,
NH 3
BCl 3
[ Pt (Cl ) 4 ] 2 , PCl5
,
and
:
2
3
2
3
dsp , dsp , sp , sp
sp 3 , dsp 2 , sp 3 d , sp 2
(a)
(b)
(c)
2
2
3
3
2
3
2
3
dsp , sp , sp , dsp
dsp , sp , sp , dsp
(d)
Q. 10.
In which of the following pairs of molecule have bond order three and are
iso-electronics?
CN , CO
NO , CO
CN ,O2
(a)
(b)
(c)
(d)
CO, O2
s, p block Elements
B2 O3
Q. 11.
(a) Acidic
is
(b) Basic
(c) Ozonide
(d) Amphoteric
Q. 12.
The most powerful oxidant among the following is :

HClO 2
(a) HOCl (b)
(c) HCIO3
(d) HCIO4
Q. 13.
The element which forms a solid acidic oxide is :
(a) Na
(b) P
(c) S
(d) Si
Q. 14.
The solubility of
(a) CCl4
(b) CHCl3
I2
in water is increased in the presence of :

(c) KCl
(d) Kl
Q. 15.
Anion that reacts with HCl to yield pungent gas is:
(a) SO32(b) CO32(c) Cl(d) SO42-
HgCl 2
SnCl2
Q. 16.
and
cannot coexist in a solution due to :
(a) Common ion effect (b) solubility product
(c) Redox change
these
Q. 17.
(d) All of
Which has octahedral shape?
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(a) PF4
(b) SF6
(c) NH + 4
(d) CO 2 3
Q. 18.
The one which is widely used as aprotic solvent is :
(a) Liq. SO3 (b) Liq.SO2 (c) HlF
(d) H2SO4
Q. 19.
The following acids have been arranged in the order of decreasing acid
strength. Identify the correct order.
(I) ClOH
(II) BrOH
(III)IOH
(a) I>II>III (b) II>I>III (c) III>II>I (d)I>III>II
(ClO3 )
Q. 20.
The tetrahedral nature of the three bonds in a chloride ion
is
due to
(a) The presence of a lone pair of electrons
(b) sp3 hybridization
(c) sp2 hybridization
(d) Trigonal bipyramidal shape of ion
Transition Elements And Co-ordination Compounds
Q. 21.
Choose the correct options

[ Fe( NH 3 ) 4 O2 C 2 O4 ] Cl
In
(a) O2 is superoxo having charge -3
(b)Iron is +4
(c) O2 is peroxohaving charge -4
(d)O2 will behave as aneutral ligand
Q. 22.
In the dichromate dianion
(a) 4 Cr O bonds are equivalent
(c) All Cr- O bonds are equivalent
(b) 6 Cr- O bonds are equivalent

(d) All Cr-O bonds are non equivalent
TiF 62 , CoF63 , Cu 2 Cl 2
NiCl 42
Q. 23.
Amongst
and
(At. Nos. Ti = 22, CO =
27, Cu = 29, Ni = 28) the colourless species are
(a) TiF 2 6 and Cu2Cl2(b) Cu2Cl2 and NiCl 2 4 (c) TiF 2 6 and CoF
36 (d) CoF 36
and NiCl 2 4
Q. 24.
Except copper, all elements of 3d series have negative reduction potential
values but they are not good reducing agents. This is because of their
(a) high enthalpy of sublimation
(b) high enthalpy of ionization
(c) poor enthalpy of hydration
(d) all of these
Q. 25.
First four ionization energies of Ni and Pt are given below :
(IE1 + IE2)
(IE3 + IE4)
Ni 2.49 103 kJ mol-1
8.8103 kJ mol-1
Pt 2.66 103 kJ mol-1
6.7 103 kJ mol-1
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From the data it can be concluded that

(a) Ni(II) compounds are thermodynamically more stable than Pt(II) compounds
(b)Pt(IV) compounds thermodynamically more stable than Ni(II) compounds
(c) Both correct
(d)None of these is correct
Q. 26.
The hexa-aquairon (III) ion hydrolyses as shown below :
[Fe(H2O)6]3++H2O[Fe(H2O)5OH]2+(aq.)+H3O+
Which of the following statements is correct ?
(a) This hydrolysis is favoured by low pH values
(b) the iron under goes a change in oxidation state
(c) The corresponding iron (III) ion [Fe(H2O)5OH]2+ is less likely to undergo
hydrolysis
(d) the hydrolysis is highly favoured at high temperature
Mn3 (CO)12
Q. 27.
The correct IUPAC name of
(a)Dodecacarbonyl manganate(0)
(c) Dodecacarbonyl trimanganese (0)
is :
(b) Dodecacarbonyl magnatic (II)
(d) Maganic dodecacarbonyl(0)
Q. 28.
A complex of platinum, ammonia and chlorine produces four ions per
molecule in the solution. The structure consistent with the observation is :
(a) [Pt(NH3)4]Cl4 (b) [Pt(NH3)2Cl4] (c) [Pt(NH3)5]
(d) [Pt(NH3)4Cl2]Cl2
Q. 29.
The oxidation state of Ag in Tollens reagent is
(a) zero
(b) +1
(c) +2
(d) +1.5
Q. 30.
Which one does not belong to ligand?
(a) PH3
(b) NO+
(c) BF3
(d) ClOres And Metallurgy
Q. 31.
Which is an example of chlorodising roasting?

(a) Ag2S + 2NaCl 2AgCl+Na2S
(b) PbS + 2O2 PbSO4
(c) AgCl + 2Hg AgH + HgCl
(d) Both (A) and (C)
Q. 32.
Rolled gold is formed by alloying :
(a) Cu and Al
(b) Cu and Au
and Sb
(c) Au and Al
(d)
Au
Q. 33.
In the Hoopes process for refining of aluminium, the fused materials form
three different layers and they remain separated during electrolysis also. This is
because
(a) there is special arrangement in the cell to keep the layers separate
(b) the three layers have different densities
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(c) the three layers are maintained at different temperatures

(d) the upper layer is kept attracted by the cathode and the lower layer is kept
attracted by the
Anode
Q. 34.
The slag obtained during the extraction of copper from copper pyrites is
composed mainly of
(a) FeSiO3 (b) SiO2
(c) CuSio3 (d) Cu2S
Q. 35.
Silver obtained from argentiferous lead is purified by
(a) cupellation
(b) Distillation
(c) froth flotation (d) reacting with KCN
Q. 36.
In the manufacture of Mg by Carbon reduction of MgO, why is the product
cooled in the stream of an inert gas
(a) to enhance Mg formation
(b) Mg reacts with CO to form Mg(CO3)2
(c) to prevent reversible reaction
(d) None of these
Q. 37.
Poling process is used :
(a) for the removal of Cu O from Cu (b) for the removal of Al O from Al
(c) for thr removal of Fe O from Fe (d) in all the above
2
Q. 38.
From gold amalgam, gold may be recovered by :
(a) addition of Zn metal
(b) Electrolytic refining
(c) Distillation
(d) dissolving Hg in HNO
3
Q. 39.
The incorrect statement is :
(a) Calamine and siderite and carbonates
(b) Argentite and cuprite are oxides
(c) Zinc blende and iron pyrites are sulphides
(d) Malachite and azurite are ores of copper
Q. 40.
The acidic refractory material is :
(a) CaO
(b) P2O5
(c) SiO2
(d) MgO
Qualitative Analysis
I2
Q. 41.
AgBr is yellow,
is deep violet. They become colourless on adding :
(a) Kl
(b) Na2S2O3
(c) NH3
(d) NaOH
H 2 SO4
Q. 42.
An inorganic salt is heated with ethyl alcohol and conc.
,
vapours evolved produces green-edged flame on ignition; it indicates the
presence of
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(b) C2O 2 4
(a) F(c) BO 33
(d) ClO 3
Q. 43.
KCN is used for separating :
(a) Co2+ and Ni2+ (b) Mn2+ and Zn2+ (c)Ba2+ and Ca2+ (d) none of these
Hg 2 , Hg 22 , Pb 2
Q. 44.
An aqueous solution contains
addition of HCl (6N) will precipitate :
(a) Hg2Cl2 only
(b) PbCl2 only
(c) PbCl2 and Hg2Cl2
Cd 2
and
The
(d) PbCl2 and HgCl2
Q. 45.
In order to refine blister copper, it is melted in a furnace and is stirred with
green logs of wood. The purpose is :
(a) to expel the dissolved gases in blister copper
(b) to bring the impurities to surface and oxidize them
(c) to increase carbon content of copper
(d) to reduce the metallic oxide impurities with hydrocarbon gases liberated
from the wood
FeCl3
Q. 46.
Addition of
to
(a) Prussian blue (b) fe4[Fe(CN)6]3
K 4 Fe(CN ) 6
gives :
(c) Ferriferrocyanide
(d) All of these
Q. 47.
Silver dissolves in the solution of an alkali cyanide in the presence of
oxygen to form :
(a) [Ag(CN)2]1(b)[Ag(CN)3]1(c) [Ag(CN)2]2(d) [Ag(CN)4]2-
Fe(SCN ) 3
Fe(SCN ) 4
Q. 48.
The deep red colour of
and
is destroyed by
addition of.
(a) F(b) CN(c) SCN(d)Fe+
Q. 49.
Hydrogen bonds of minimum length are formed by :
(a) HF
(b) H2O
(c) NH3
(d) CH3COOH
Q. 50.
Cu 2
Which one of the following is used to separate
?
(a) Dimethylglyoxime (b) EDTA
(c) Excess of KCN
Cd 2
in presence of
(d) NaCN
Multiple Choice Questions

Chemical Bonding
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Q. 51.
Which of the following is correct among the following?
(a) Increasing polarizing power : Na+<Ca+2<Mg+2<Al+3
(b) Increasing covalent character : LiF < LiCl < LiBr< Lil
(c) Ionic character : MCl < MCl2 < MCl3
(d) Increasing polarisibility : F- < Cl- < Br- < IQ. 52.
Which of the following carbides are methanides?
(a) CaC2
(b) Mg2C3 (c) Al4C3
(d)Be2C
Q. 53.
Which of the statement is correct?
(a) In PCl5 hybridisation is sp3 d and it has trigonal bipyramidal structure
(b) The angle between the P and Cl is 90 which is same for all the P and Cl
present in PCl5
(c) the bond length of P-Cl in axil position is higher than in equatorial position
(d) PCl5 is ionic in solid phase.
Q. 54.
(a) HgCl2
CO2
molecule is not iso structural with

(b) SnCl2
(c) C2H
(d)NO2
Q. 55.
Which type of chemical bonds are not present in
(a)covalent (b) ionic
(c) Coordinate
(d) H-bond
N 2 O4
Q. 56.
Which of the following pair (s) has (have) same shape but different
structure
(a) [co2], SO2
(b) [XeF2,KBr3]
(c)[ClF3, NF3]
(d)
[XeF4,Ni(CN)
2 4 ]
Q. 57.
(a)
The molecule (s) with some finite positive dipole moment is (are) :
(b)
(c) PF3Cl2 (d) PCl3F2
Q. 58.
(are) :
The pair of molecules/ions with same BO and same magnetic property is
(a) [O2,N2] (b) [N2,CO] [c] O + 2 ,N 2
(d) [O 2 2 , H2]
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Q. 59.
In which case the hybridization of central atom changes

(a) BCl3 to BCl 4 (b) NH3 to NH + 4 (c) BF3 to BF3.NH3 (d) SO2 Cl2 to H2SO4
s,p- block Elements

Q. 60.
Which of the following pairs of elements will give superoxides and
peroxides respectively when heated in excess of air
(a) K,Ba
(b) Na,Rb (c) K, Rb
(d) Na, Ba
Q. 61.
All the following substances react with water, in which of the cases same
gaseous product is obtained?
(a) Na
(b) Na2O2 (c) KO2
(d) NaH
Q. 62.
Sodium nitrate decomposes above ~800C to give
(a) N2
(b) O2
(c) NO2
(d) Na2O
Q. 63.
Aluminium becomes passive in
(a) conc. HNO3
(b) H2CrO4
(c) HClO4
C2 H 4
(d) conc. HCl
Q. 64.
Which carbide does not give
(a) CaC2
(b) Be2C
(c) Al4C3
on hydrolysis with water

(d) Mg2C3
Q. 65.
Which of the acid is reducing in nature
(a) H3PO4
(b) H3PO2
(c) H3PO3
(d) HPO3
p d
Q. 66.
back bonding occurs between oxygen and
(a) Phophorus in P4O10 (b) chlorine in HClO4
(c) Nitrogen in N2O5
carbon in CO2
(d)
( H 3 PO4 )
Q. 67.
Phosphoric acid
(a) HPO4-2
(b) PO4-3
can be neutralized to
(c) H2PO4(d) HPO3-2
Q. 68.
Which of the following are true about diborane?
(a) it has two bridging bridging hydrogens and four terminal hydrogens
(b) when methylated, the product is Me4B2H2
(c) The bridging hydrogen are in a plane perpendicular to the rest
(d) All the six B-H bond distances arre equal
NH 3
Q. 69.
and its salts are identified by
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(a) K2HgI4 and KOH

(C) HgCL2 + KI (excess) + NH4OH
(b) HgCl2+KI (excess) + KOH

(D) Hg2CL2 + excess of NH4OH
Q. 70.
Which is/are acidic salts (s)?
(a) NaH2PO3
(b)
OH
(c) NaHCO3
(d) Na2HPO3
COONa
Q. 71.
(a)
Hypervalent anion(s) is/are :

2
3
(b)
(c)
SO 3
PO 4
2
SO 4
(d)
CIO 4
Ores And Metallurgy

Q. 72.
Hoops process of purification of aluminium involves formation of layers
during electrolysis.
This is because :
(a) The three layers have same densities but different materials
(b)The three layers have different densities
(c) The upper layer is of pure aluminium which acts as a cathode
(d)The bottom layer is of impure aluminium which acts as an anode and middle
layer consists of NaF, BaF2 and ALF3
Q. 73.
Which of the following option is/are correct?
(a) On fast cooling of pig iron we will get white cast iron & carbon impurity is
present in from of
cementite Fe3C
(b) On slowly cooling of pig iron we will get grey cast iron C impurity is present
in from of
graphite.
(c) The M.Pt of gray cast iron is more than pure iron due to presence of impurity.
(d) Cast iron does not rust easily and neither be tempered. Due to high carbon
content it is hard
& brittle cannot be welded.
Q. 74.
The difference (s) between roasting and calcinations is (are)
(a) Roasting is highly enothermic while calcinations is not
(b) Partial fusion occurs in calcinations but not in roasting.
(c) Calcinations is performed in limited supply of air but roasting employs excess
air
(d) Combustion reactions occur in roasting but not in calcinations
Q. 75.
and
Which of the following statement (s) is are correct when a mixture of NaCl
K 2 Cr2 O7
H 2 SO4
is
gently warmed with concentrated
?
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(a) A deep red vapour is ivolved

(b) The vepour when passed into NaOH solution gives a yellow solution of
Na2CrO4
(c) Chlorine gas is evolved
(d) Chromyl chloride is formed
Zn , Ni ,
Q. 76.
Among the ions
(a) Zn++
(b) Ni++
(c) Cr+++
Cr
and
, which are coloured
(d) None of these

H 2 SO4
Q. 77.
A
(Black)
B D HCl
E H 2 SO4
Colloidal Sulphur
HNO3
(W hiteturbid)
(gas
( ppt.)
;Identify A and E
(a) A = FeS (b) A = CuS (b) B = CuS (d) B = HgS
Comprehension Questions
Chemical Bonding
Comprehension 1
The shapes of molecules can be predicted by VSEPR theory, hybridization and
dipole moment. Total number of hybrid orbitals (H) on the central atom of a molecule
can be calculated by using
the following relation :
H = [Total no. of valence electron pairs (P) 3 x (no. of atoms surrounding the
central atom,
exclusing Hydrogen atoms)]
One can also calculate total no. of bond pairs (n) around central atom as n =
total number of atoms surrounding the central atom also, total no. of lone pairs (m)
=Hn
AX n E m
Thus, VSEPR notation of a molecule can be written as
.
Where, A denotes central atom of the molecule
X denotes bond pairs on central atom of the molecule
E denotes lone pairs on central atom of the molecule
In a polar molecule, the net dipole moment of the molecule m.
Q. 78.
VSEPR notation of chlorine trifluoride molecule is :
(a) AX5
(b) AX3
(c) AX2E3
(d)AX3E2
Q. 79.
Some molecules are given below :
CO2
SO2
H 2O
,
II.
III.
I.
The incorrect increasing order of dipole moment of given species is :
(a) I<II<III (b) II<I<III (c) III<II<I (d) III<I<II
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Q. 80.
Arrange the following compounds in the increasing order of dipole moment
I. o-nitrophenol
II. o-xylene
III. o-dichlorobenzene
(a) I<II<III (b) III<II<I (c) II<I<III (d) III<I<II
Comprehension 2
According to molecular orbital theory of chemical bonding, the atomic orbitals of
participating
atoms interact when the concerned nuclei approach each other. As a
result new orbitals, called
molecular orbitals are formed. These orbitals comprise
the nuclei of the combining atoms, i.e., they are polycentric.
The number of
molecular orbitals formed is equal to the number of atomic orbitals taking part in the
combination.
The formation of molecular orbitals can be explained on the basis of
principle of linear
combination of atomic orbitals (LCAO). The wave functions of
participating atomic orbitals combine either by addition when the electron waves are
in phase, or by subtraction (electron
waves in apposite phase).
( A) ( B )
Combination by addition :
( A) ( B )
Combination by subtraction :
( A)
(B)
Where
and
are the wave function of atomic orbitals taking
part in chemical combination and

is the molecular orbital wave function. The
probable electron density in t he two orbitals are given by
2 2 ( A) 2 ( B ) 2 ( A) ( B )
2 2 ( A) 2 ( B ) 2 ( A) ( B )
and
2 ( A)
2 (B)
Here,
and
represent the probable electron density in the
two atomic orbitals.
The molecular orbital resulting from the addition of the wave functions
corresponds to
the high electron density in the in between space of the two nuclei of
the participating orbitsla.
As a result, the nuclear-nuclear repulsion is weak and
energy of this molecular orbital, called
bonding molecular orbital, is lower than
those of participating atomic orbitals. On the other hand, the molecular orbital
resulting from the subtraction combination, there is low electron density
in
the
inbetween space and the nucleus-nucleus repulsions is high. As a result the energy of
this molecular orbital, called anti-bonding orbital, is more than those of combining
atomic orbitals.
,
The bonding molecular orbitals are designated as

and
while the
*
*
,
*
antibonding molecular orbitals as

and
.
molecular orbital is
formed by the axial overlapping of atomic
orbitals and is symmetrical about the
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internuclear axis.
colecular orbital is formed by
sidewise
atomic orbitals and is unsymmetrical about the internuclear axis.
overlapping
of
A molecular orbital can accommodate at the maximum 2 electrons with

spins paired.
These orbitals, like atomic orbitals, are filled following Aufbau
principle, and electron pairing in
degenerate orbitals starts only when all of them
are singly filled (Hund rule).
Stability of molecule depends on the electronic configuration of molecular
(Nb )
orbitals in that if bonding electrons
are greater than antibonding electrons
(Nb )
Nb Na
Nb N a
the molecule is
stable. For
and
, the molecule
is unstable. The bond order, half of the difference between the bonding and
antibonding electrons, conveys important information
about the stability of
molecule, dissociation energy of the bond, bond length and multiplicity of
bonds.
Molecular orbital theory predicts also the paramagnetic and diamagnetic nature of
substances.
If all the electrons in the molecule or ion are paired, it is
diamagnetic in nature. However, if it has one or more unpaired electrons, it is
paramagnetic.
Q. 81.
In the homoatomic molecule, which of the following set of orbitals are
degenerate?
(a) 1s and 2s
(b) 2px and 2py
(c) 2px and 2pz
(d)
and
2pz
Q. 82.
order :
2px
The bond lengths in the species
+
(a) 02
(d)
02
Q. 83.
O2 ,O2
> 02 >
> 02 >
02
(b)
+
02
>
02
> 02
and
O2
ions are in the
(c) 02 >
+
02
>
02
+
02
Which of the following is not correct?
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(a) During
orbital
(b) During
molecular orbital
(c) During
orbital
(d) During
+
N2
formation, one electron is removed from the bonding molecular
+
02
formation, one electron is removed from the antibonding
02
formation, one electron is added to the bonding molecular
CN
formation one electron is added to the bonding molecular
orbital
s, p-block Elements
Comprehension 3
sp 3
In all the oxyacids of phosphours, each phosphorus atom is in
hybrid state, i.e., it is tetrahedrally bonded to neighboring four atoms. All these
acids contain P OH bonds, the
hydrogen atom of which are ionisable imparting
acidic nature to the compound. The ous acids (oxidation state of P = +1 or +3) also
have P H bonds in which hydrogens are not ionisable (P and hydrogen have nearly
same electronegativity). The presence of P H group in these acids
imparts
reducing properties. The structure of the various acids are drawn below (note that the
tetrahedral shape of phosphorus is not shown only for
convenience of
representation).
Q. 84.
Which of the acid show reducing properties?
(a) A & C (b) A & B (c) A, B & E (d) A only
Q. 85.
Although metaphosphoric acid is written as a monomer, it exists as a

( HPO3 ) n
. the number of P O P bonds in cyclic tri-metaphosphoric
polymer,
acid is
(a) zero
Q. 86.
(b) two
(c) three
(d) four
Among the above acids, the acids having basicity 4 are:
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(a) A & E
(b) C & D
(c) C & F
(d) D & F
Comprehension 4
It is well known that there are two major forms of carbon, that is, carbon
has two main
allotropes; graphite and diamond. These differ greatly from each
other with respect to their
physical properties as shown in Table 1. The physical
properties of silicon are also shown in
Table 1 for comparison as carbon and
silicon belong to the same group in the periodic table.
Physical
Graphite
Diamond
Silicon
Properties
Density (g cm-3)
2.26
3.51
2.33
Entahlpy
of -393.3
-395.1
-910
combustion
to
yields
oxide
( H ) kJ mol 1
Melting point C
2820
3730
1410
Boiling point C
4830
Good
Conductivity
Fairly good
Non-conductor
Good
(electrical)
Conductivity
Fairly good
Non-conductivity Good
(thermal)
Graphite possesses what is commonly known as a layer structure : carbon
atoms form
three covalent bonds with each other to yield layers of carbon
assemblies parallel with each
other. These layers are held together via weak
Vander Walls Forces which permit some movement of the layers relative to one
another.
The most common compound of carbon is carbon dioxide which makes up
0.03% of the
atmosphere. The triple point of carbon dioxide occurs at 217 K and
515 kPa.
One of the unique properties of carbon is that it can form multiple bonds
between itself
and other atoms, including other carbon atoms.
Thus, large
polymers involving carbon atoms are possible.
Q. 87.
Using the information in the table, calculate the enthalpy change for the
following process :
C
C
graphite
dimond
(a) +1.8kJ mol-1
(b) 1.8 kJ mol
-1
(c) +1.0 kJ mol-1 (d) 1.0 kJ mol-1
Q. 88.
Diamond consists of tetrahedral arrangement of carbon atoms, with each
atom covalently bound to four others to yield a giant molecular structure. What is
the hybridization state of c
arbon in diamond?
(a) It is not hybridized (b) sp
(c) sp2
(d) sp3
Q. 89.
it is possible to convert graphite into diamond via various chemical
processes. Based on the
information in the passage, which of the following would
- 94022962099,9158665588
facilitate increased amounts of

equilibrium?
(a) High pressures
of the above
diamond
assuming
that
(b) High temperature
the
system
(c) A catalyst
is
in
(d) None

Comprehension 5
Silver is still one of the most versatile metals known to man, being used in
almost
everything from electrical wires to jewellery. It is also quite unreactive,
and is resistant to
attack by common agents such as acid and oxygen. Needless
to say, the mining of this precious metal is the mainstary of the economy of many
countries. Unfortunately, silver does not occur in its elemental state in nature. It is
Ag 2 S
AgCl
mined as argentite (
containing ore) and horn silver (
containing
ore)
The main method used in industry for separating silver from its ores
CN
involves
complexation and the cyanide ligand (
). The cyanide ligand is
used to produce the soluble silver cyanide complex according to Reaction I and
Reaction II.
Ag 2 S 4CN 2[ Ag (CN ) 2 ] S 2
Reaction I :
AgCl 2CN [ Ag (CN ) 2 ] Cl
Reaction II :
The silver metal in its elemental form is then precipitated by adding zinc
dust to the solution as shown in Reaction III.
2[ Ag (CN ) 2 ] [ Zn(CN ) 2 ] 2 Ag ( s)
Reaction III :
Silver complexes provide one of the most fascinating demonstrations of
the relative
strength of different ligands for a particular cation. This is a common
occurrence with most complexes of this nature but what makes silver unique is that
many of its complexes differ in
colour.
Complex
[ Ag (CN ) 2 ]
Colour
Clear solution
AgI
[ Ag ( EDTA )]
Ag 2 S
Yellow precipitate
Clear solution
Black precipitate
- 94022962099,9158665588
One will notice that precipitates are listed in the table. These can regarded as
neutral
complexes and as is often the case with neutral complexes, they are quite
insoluble and hence
precipitate out of solution
K a1 ( H 2 S ) 9.1 10 8
K a2 ( H 2 S ) 1.2 10 15
Q. 90.
Give that
and
, what would
be the effect on Reaction
I if protons were added to the reaction mixture at
equilibrium?
(a) The equilibrium would shift to the left
(b) The equilibrium would shift to the right
(c) There would be no change in the equilibrium position of the reaction
(d) The change in the equilibrium position can not be determined from the
information given
Q. 91.
12 grams of silver was extracted from a sample of an ore from which the
Ag 2 S
Ag 2 S
only source of silver
was
. How many grams of
were in the
original sample?
(a) 27.6 g (b) 13.8 g (c) 8.6 g (d) 5.2 g
Q. 92.
Which of the following ligands will give a precipitate when added to the
Ag
clear solution of the
complexes detailed in Table 1? Order of affinity for
2
EDTA S CN I
ions :
S 2
CN
I
EDTA
(b)
(c)
(d)
(a)
Comprehension 6
Transition metals have the ability to form a wide variety of complex ions in
which other
atoms of groups of atoms (called ligands) surround them in welldefined geometric shapes.
When the central metal ions have partially filled dorbitals, colors are often seen in the
crystalline compounds or in their solutions.
(Figure 1 shows three common shapes of complex ions)
L
L
L
L
L
M
L
M
L M
L
L
L
L
L
L
L
Octahedral complex
tetrahedral complex
square planer complex
Crystal field theory, and its subsequent extension ligand field theory, show
that for a metal ion surrounded by six ligands in a square bipyramidal (or octahedral)
arrangement, the
highest occupied d-orbital of the metal have energies in the 3
and 2 arrangement, as shown in figure 2.
- 94022962099,9158665588
D orbitals after ligand field splitting

When determining the electronic configuration of a transition metal ion,
e
call that the

uppermost 4s-electrons, for example, are removed before the
3d electrons in first-row
transition metals, and that a similar relationship holds for
later rows of transition metals. Note
that some ligands (described as bidentate)
are large enough that they can bond to the central
tom at two sites. An important
H 2 NCH 2 CH 2 NH 2
example is ethylenediamine,
, abbreviated en,
which can bond
to a central metal ion at each of its two nitrogen atoms.
NH2
H2N
NH2
NH2
M(en)2 tetrahedral complex
max
The value of the splitting factor,
, can be determined by measuring
for absorption and converting to energy units. The magnitude of

depends not only upon the nature of the metal ion, but also upon the ligand, as the
following list shows :
Patial Spectroscopic Series
I Cl OH H 2 O NH 3 NO2 CO CN
weak-field ligands
strong-field ligands
3
FeCl3 (CN ) 3
0
In the case of mixed ligands (e.g. , the
ion),
is
determined by the
additive contributions of the ligand strengths.
0
The size of
is critically important in determining how the energy
levels are filled. An
ion with five d-electrons may exhibit the configuration shown
0
in figure 4(a) below (low spin)
characteristic of large values of
. But,
0
surprisingly, a low a value for
will lead to the high spin configuration shown
in Figure 4 (b). In the latter case, the extra energy needed to
promote
two
electrons to the upper level is exceeded by the gain in stability that results when
electrons move to separate obitals.
- 94022962099,9158665588
a.
Low spin (due to strong field ligands)
b. high spin (due to weak field ligands )
Although octahedral geometry is extremely common in transition metal

complexes, it is the
only possibility. Figure 5 shows the ordering of energy levels
in tetrahedral and square planar
complexes.
Tetrahedral levels
square planaer levels
Generally the ligand field splitting is low in tetrahedral complexes, which usually
display highspin configurations. The situation is reversed for square planar
complexes, which display lowspin configuration.
Q. 93.
Given the following data about the absorption maxima of several complex
0
ions, what is the order of
for these ions?
Compound
max
3-
[Crcl6]
758
[Cr(NH3)6]3+
465
3+
[Cr(H2O)6]
694
[Crcl ]3- < [Cr(NH ) ]3+ < [Cr(H O) ]3+
(a)
0
6
0
3 6
0
2
6
(b) 0 [Cr(NH3)6]3+ < 0 [Cr(H2O)6]3+ < 0 [Crcl6]3+
(c) [Crcl ]3- < [Cr(H O) ]3+ < [Cr(NH ) ]3+
0
(d)
[Cr(H2O)6]3+ <
[Cr(NH3)6]3+ <
3 6
[Crcl6]3-
0
Q. 94.
I.
(a)
(III)
Predict the order of

[ Fe( H 2 O ) 6 ] 2
II.
0
0
(I) <
(II) <
0
(c)
0
(III) <
for the following compounds :

[ Fe(CN ) 2 ( H 2 O) 4 ]
[ Fe(CN ) 4 ( H 2 O2 )] 2
III.
0
0
0
0
(III)(b)
(II) <
(I) <
0
(II) <
0
(I)(d)
0
(II) <
0
(III) <
(I)
- 94022962099,9158665588
Q. 95.
From the information given in the passage, what is the most likely
CoCl63
Co(NO2 ) 36
configuration of the cobalt d electrons for the species
and
?
CoCl63
Co(NO2 ) 36
CoCl63
(a)
; low spin ;
: low spin (b)
; high spin ;
3
Co(NO2 ) 6
: low spin
CoCl63
Co(NO2 ) 36
CoCl63
(c)
; low spin ;
: high spin (d)
; high spin;
3
Co(NO2 ) 6
: high spin
Ores And Metallurgy
Comprehension 7
Metals are extracted from their ores bya wide variety of techniques. The most
common ores
are oxides.
( MnO2 , Al 2 O3 , SnO2 )
,
sulfides
(PbS,
ZnS),
chlorides
(Ca3 ( PO4 ) 2 )
( NaCl, KCl, CaCl2 , MgCl 2 )
, and phosphates
.
Most metals are
obtained by direct treatment of their ores with chemical agents, but the extraction of
certain other requires electrolysis. An example of the former type of
process is the
extraction of iron fromits oxide, described by the following equation :
Fe2 O3 3C 2 Fe 3CO
The relative case of extraction of a metal from its oxide can be estimated
using the Ellingham diagram, which is shown in figure. This diagram plots the free
energies of formation of various oxides per mole of consumed oxygen as a function
of absolute temperature.
(kJ)
(f)
1000
fe
(f)
2000 1 (k)
Electrolytic extraction proceeds in three steps (see equation). In the first

step, the
crystalline lattice of the ore is thermally disintegrated to form a liquid
containing free metal cations. In the second step, the matal cations are stabilized by
solvating them with some
thermally stable non-aqueous solvent (NAS). In the final
step, an applied electric potential reduces the cations to neutral atoms.
Step 1Ore ( s) M n (l )
- 94022962099,9158665588
Step 2 M n (l ) M n ( solvated )
Step 3M n solvated ) ne M
Extraction of a metal is usually preceded by enrichment of the ore. Some
ores can be
concentrated after pulverization by the use of specific collectors
such as salts of organic acids and bases, which make the ores hydrophobic and thus
separable from hydrophilic admixtures. Other enrichment techniques include density
separation and magnetic separation.
Q. 96.
All of the following agents could be used to extract lead from its oxide
EXCEPT.
(a) molecular fluorine(b) Molecular boron(c) molecular nitrogen(d) elemental
carbon
Q. 97.
If for a certain ore the enthalpies of steps 1 and 2 were 248.50 and
250.25 kJ, respectively,
which of the following would determine the rate of
extraction
(a) The lattice energy of the ore
(b) The salvation energy of the metal cations
(c) The magnitude of the electric potential used
(d) The size of the metal cations
2 CaO ( s ) C ( s ) 2Ca ( s ) CO2 ( g )

Q. 98.
For the extraction :
The standard free energy change of the forward reaction is 814.1 kJ. According
to this data,
standard conditions are likely to favour.
(a) the forward reaction
(b) the reverse reaction
(c) both forward and reverse reaction
(d) neither the forward not the reverse
reaction
Comprehension 8
Standard Electrode Potentials and Metallurgy : The method employed for
extracting a
metal from its ore depends on the nature of the metal, that of the
ore and may be related to the
position of the metal in the electrochemical series.
In general; metals with reduction potential
less than -0.5 volt yield compounds
which are very difficult to reduce. Such metals are isolated
by electrolysis.
On
the other hand noble metals with reduction potential +0.5 volt form easily
reducible
compounds.
The standard electrode potential of a metal is a measure of its tendency to
go into
solution as hydrated ion. ON the other hand, in metallurgical extractions
we generally come
across ores which are to be reduced to the metallic state.
Thus, it may be said that a metal higher up in the electrochemical series should be
more difficult to reduce to metallic form. As
we moe down, the reduction becomes
more and more easy. However, it must be borne in mind that this is a very general
- 94022962099,9158665588
statement and cannot be strictly applied because metals ae seldom

extracted from
aqueous solution.
Energy Factors and Electrode Potentials The heat of sublimation (S) of
solid metal, the ionization energy (I) of gaseous metal atom and the heat of
hydration (H) of gaseous ion are the
contributory
factors
towards
electrode
potential (E). These factors may be consolidated in a
Born-Haber type of cycle.
E
M(solid)
M+(aq)+eS
l
H
M(gaseuse)
M +(gaseuse)+eThus , E = +S + 1 H
S and I are positive because energy is supplied while H is negative as the
process of hydration is an exothermic one liberating heat. As expected, ionization
energies of alkali metals
follow the trend : Li > Na > K > Rb > Cs
It means Li has the least tendency to lose electron among a alkali metals.
However, from
electrochemical series we find that lithium is the most reducing in
Li
30.5
Li
character (E for
volt).
The anomalous behavior of Li is
understandable from the fact that heat of
hydration of its ion is highest because
of small size. The contribution of this hydration of its ion is highest because of small
size. The contribution of this hydration factor towards electrode potential makes Li
even more reducing than Na or K.
Q. 99.
Arrange the metals A, B, C, D, E in order of electrochemical series if :

A H 2 SO4 ASO4 H 2 ; ACl2 C CCl2 A
ECl2 C
2 BCl D DCl 2 2 B
No reaction;
H 2 SO4 D
No reaction
(a) ABCDE (b) ECADB (c) BDAEC (d) ADBEC
Q. 100.
The standard reduction potentials at 298 K for the following half reactions
are given against
each.
2+
Zn (aq) + 2e
Zn(s)
-0.762
Cr3+ (aq) + 2e Cr(s)
-0.740
2H+ (Aq) + 2e
H2(g)
0.000
FE3+ (aq) + 2e
Fe2+ (aq)
0.770
Which is the strongest reducing agent?

Zn(s )
Cr (s )
(b)
(c)
(a)
H 2 (g)
Fe 2 (aq)
(d)
- 94022962099,9158665588
Q. 101.
(a)
Mg
(b)
potential
(c)
Mg
(d)
The incorrect statement among the following is

the first ionization potential of Al is less than the first ionization potential of
the second ionization potential of Mg is greater than the second ionization
of Na
The first ionization potential of Na is less than the first ionization potential of
The third ionization of Mg is greater than third ionization of Al.
Comprehension 9
Due to the fact that many cations form sparingly soluble salts, a method
known as selective precipitation can be used to separate a mixture of cations. The
process involves the
addition of a soluble salt containing an anion which forms a
sparingly soluble salt with one or more of the cations. If it forms a sparingly soluble
salt with only one of the cations in solution,
then
that
cation
is
effectively
separated out of solution. However, this is not usually the case. More often than not a
number of cations in solution will form sparingly soluble salts with the anion.
K sp
Separation then depends on the magnitude of the
value of the sparingly
K sp
soluble
salts that could be formed. The smaller the
value for a salt, the
earlier it will precipitate out of solution relative to the other salts. Thus the process is
similar to a titration : the anion is added gradually in increasing amounts and
precipitating each of these salts separately, then the precipitate is removed when all
of that particular cation species has been extracted from solution.
This is used
extensively in the mining of ions from various bodily fluids. A mixture of
bismuth
3
2
2
( Bi )
( Ag )
( Zn )
(Cu )
, Silver
, zinc
, and copper
cations is to be
K sp ( Bi 2 S 3 ) 1.0 10 97
( Na2 S )
separated using sodium
sulphide
.
;
49
21
36
K sp ( Ag 2 S ) 2.0 10 ;
K sp ( ZnS ) 1.0 10
K sp (CuS ) 9.0 10
;
.
Q. 102.
Which cation will precipitate out of solution first on the addition of sodium
sulphide?
Ag
Bi 3
Zn 2
Cu 2
(b)
(c)
(d)
(a)
K sp
Q. 103.
The
Bi 2 S 3
expression for
is :
- 94022962099,9158665588
(a)
[ Bi 3 ]3 [ S 2 ]2
[ Bi 3 ] 2 [ S 2 ]3
[ Bi 2 ][ S 3 ]
(b)
[ Bi 2 ][ S 2 ]
(c)
(d)
(CN )
Q. 104.
Cyanide ions
could also have been used to precipitate the
cations. If after all the cations
have been precipitated, the concentration of
CN
is 0.02 M, calculate the pH of the solution given that :
CN H 2 O HCN OH
K b 1.39 10 5 ; log 5 0.5
(a) 4.9
(b) 5.4
(c) 7.7
(d) 10.7
Comprehension 10
An unknown solid mixture contains one or two of the following :
CaCO3 , BaCl 2 , AgNO3 , Na 2 SO4 , ZnSO4
and NaOH. The mixture is completely soluble in
water
and the solution gives pink colour with phenolphthalein. When dilute
hydrochloric acid is
gradually added to the above solution, a precipitate is
produced which dissolves with further
addition of the acid. What is/are present in
the solid? Give equation to explain the appearance of the precipitate and its
dissolution.
Q. 105.
What is/are present in the solid?

AgNO3 & NaOH
BaCl 2 & Na2 SO4
(a)
(b)
CaCO3 & AgNO3
ZnSO4 & NaOH
(c)
(d)
Q. 106.
In a separate analysis, if the mixture (as mentioned in the passage) gives a
K 2 SO4
white precipitate with
, then what is present in the mixture.
CaCO3
AgNO3
BaCl 2
(a)
(b)
(c)
(d) None of these
Q. 107.
The aqueous solution of the mixture gives a precipitate (A) with brine. (A)
is soluble in
ammonium hydroxide. What is present in the mixture.
AgNO3
CaCO3
BaCl 2
ZnSO4
(b)
(c)
(d)
(a)
Match Type Questions

- 94022962099,9158665588
Chemical Bonding
Q. 108.
Match the following column
Column I
(a) Zero dipole moment
(b) Violation of octact rule
(c) Overlapping concept
(d) Paramagnetic molecule
Column II
C2 H 4
(p)
O2
(q)
(r) Polar bond
(s) Ice
Q. 109.
Column I
SnCl 2
(a)
TeCl 4
(b)
ICl 5
(c)
XeF6
(d)
s, p-block Elements
Matching the following

Column II
Q. 110.
Column I

Column II
NH 4 NO3 CaCO3
(p)
(q) Ammonium chloride
(r) Nangal fertilizer
(s) Mixed fertilizer
(a)
(b)
(c)
(d)
CAN
NPk
Nitrachalk
Salammoniac
Q. 111.
Column I
(a) 2e-3c bond
(b) 4e-3c bond
sp 3
(c)
hybrid orbitals
(d) Inorganic graphite
Q. 112.
Column I (Name)
(p) Irregular tetrahedron

(q) Square pyramidal
(r) Distorted octahedral
(s) V shaped

Column II
B2 H 6
(p)
( BN ) x
(q)
AlCl 3
(r)
B4 H 10
(s)
Column II (Acid)
- 94022962099,9158665588
H 3 PO2
(a) meta phosphoric acid
(b) ortho phosphoric acid
(p)
HPO 2
(q)
H 3 PO4
(c) hypo phosphoric acid
(r)
HPO3
(d) meta phosphoric acid
(s)
Q. 113.
Match List I (molecules) with List (II)
(bond order) and select the correct answer using the codes given in the lists :
Column I
Column II
Li2
(a)
(p) 3
N2
(b)
(q) 0
Be 2
(c)
(r) 1.0
O2
(d)
(s) 2
Q. 114.
Column I
Bi 3 ( BiO )
(a)
[ AlO 2 ] Al (OH ) 3
(b)
4
6
SiO 4 Si 2 O7
(c)
2
( B4 O7 ) [ B (OH ) 3 ]
(d)
Match the Column I with Column II

Column II
(p) Heat
(q) Hydrolysis
(r) Acidification
(s) Dilution of water

Q. 115.
Column I
FeO.Fe2 O3
(a)
FeC2 O4
(b)

Column II
Na2 S 2 O3
(p) Iodometrically with
(q) NaCl
- 94022962099,9158665588
(c)
CuSO4
(r)
AgNO3
(d)
(s)
Q. 116.
Column I
(a) Potash alum
(b) Ferric alum
(c) Ammonium Alum
(d) Chrome alum
Q. 117.
Column I
Cu 2
(a)
Zn 2
(b)
compounds
(c)
(d)
Cr 3
Sc
KMnO4
in acidic medium
K 2 Cr2 O7
in acidic medium

Column II
K 2 SO4 Cr2 ( SO4 ) 3 24 H 2 O
(p)
K 2 SO4 . Al 2 ( SO4 ) 3 .24 H 2 O
(q)
( NH 4 ) 2 SO4 . Al2 ( SO4 ) 3 24 H 2 O
(r)
( NH 3 ) 2 SO4 .Fe2 ( SO4 ) 3 .24 H 2 O
(s)
Match list I with Column II
column II
(p) form amphoteric oxide
(q)
diamagnetic
and
colourless
NH 3
(r) form complex with
Q. 118.
Column I
[CoCl3 ( NH 3 ) 3 ]
(a)
[Cr (OX ) 3 ] 3
(b)
[CrCl 2 (OX ) 2 ]
(c)
[ RhCl 3 ( Py) 3 ]
(d)
(s) form complex with KCN
Match list I with Collumn II

Column II
(p) show facial form
(q) Cis form is optically active
(r) Trans form is optically
(s) Show meridian form
Q. 119.
Match Column I with Column Ii and
select the correct answer using the codes given below t
he lists
- 94022962099,9158665588
Column I
[ NiCl 4 ]
(a)
[ Ni(CO) 4 ]
(b)
[ PtCl4 ]
(c)
[ Ni(CN ) 4 ]
(d)
Column II
(p) Tetrahedral
(q) square planar
(r) Paramagnetic
(s) diamagnetic
Ores And Metallurgy
Q. 120.
Column I
(a) Chalcopyrites (or) copper pyrites
(b) Chalcocite (or) copper glance
(c) Bronite
(d) Cuprite (red)

Column II
CuFeS 2
(p)
Cu3 FeS 3
(q)
Cu 2 S
(r)
Cu 2 O
(s)
Q. 121.
Column I(Element)
(a) Lithium
(b) Sodium
(c) Potassium
(d) Rubidium

Column II (Compound)
(p) Chile salt petre
(q) Spodumene
(r) Rubidium oxide
(s) Carnalite
Q. 122.
Column I
(a) Castners process
Match the following

Column II
(p) KCl
Na 2 CO3
(q)
(r) Sodium
(s) NaOH
(b) Solvays Process

(c) Nelsons Cell
(d) Oxone
Q. 123.
Match the following
- 94022962099,9158665588
Column I
(a) Magnelium
(b) Colemanite
(c) Bauxite
(d) Borax
Column II
Na3 AlF6
(p)
(q) Alloy
Ca2 B6 O11.5 H 2 O
(r)
Na 2 B4 O7 10 H 2 O
(s)
Q. 124.
Column I
( NH 4 ) 2 CO3
(a)
in presence of
(b) NaOH
(c) Nesslers reagent
(d) ppt of carbonates
Q. 125.
(a) Chromylchloride test
(b) Ring Test
(c) Smell of vinegar
(d) Smell of rotten egg
Q. 126.
Column I
(a)
Fe 2

Column II
NH 4 OH
(p) Group V
NH 4
(q)
(r) Iodide of millions base
(s) Salts of Ca, Sr, Ba
Cl
(p)
S
(q)
NO3
(r)
CH 3COO
(s)
Column II
K 4 [ Fe(CN ) 6 ],
(p) with
blue color
ppt.
(b)
Fe 3
K 4 [ Fe(CN ) 6 ],
(q) with
bluish white
ppt
(c)
(d)
Zn 2
Cu
K 4 [ Fe(CN ) 6 ],
(r) with
brown ppt
K 3 [ Fe(CN ) 6 ],
(s) with
blue ppt
- 94022962099,9158665588
Q. 127.
Column I
(a) Canary yellow precipitate with
ammonium molybdate
(b) Ring test (Brown)
(c) Acid radical decomposed by dil.
Match Column I with Column II

Column II
PO43
(p)
(q)
H 2 SO4
(r)
H 2 SO4
(d) Acid radical decomposed by conc.
As 3
NO3
(s)
NO2
Assertion Reasoning Questions

Code :(a) STATEMENT 1 IS True, STATEMENT 2 is True; STATEMENT 2 is a correct
explanation
for STATEMENT 1.
(b) STATEMENT 1 is True, STATEMENT 2 is True; STATEMENT 2 is NOT a correct
explanation for STATEMENT 1.
(c) STATEMENT 1 is True, True, STATEMENT 2 is False.
(d) STATEMENT 1 is False , STATEMENT 2 is True.
Chemical Bonding
Q. 128.
STATEMENT 1
The order of thermal stability of
Li2 CO3 Na2 CO3 K 2 CO3 Rb 2 CO3 Cs 2 CO3
Because
STATEMENT 2
Li 2 CO3 Na2 CO3 K 2 CO3 Rb 2 CO3 Cs 2 CO3
As we go along
character of
, ionic
carbonates increases.
Q. 129.
STATEMENT 1
SF4 has lone pair of electrons at equatorial position in preference to axial position
in overall
trigonal bipyramidal geometry.
Because
STATEMENT 2
- 94022962099,9158665588
If lone pair is at equatiorial position thenonly repulsion is minimum.

Q. 130.
STATEMENT 1
Antibonding MO always have node in between the nuclei of the atoms
participating in bonding.
Because
STATEMENT - 2
px, py have two anti bondings node
Q. 131.
STATEMENT 1
PF5 molecule is little less stable as compared to SF6 molecule.
because
STATEMENT 2
In PF5 , all bonds do not have same bond length while it is the same in SF 6
molecule
Q. 132.
STATEMENT 1
In PF3Cl2, fluorine occupy axial position and chlorine occupy equatorial position.
because
STATEMENT 2
F is smaller in size than Cl
s, p block Elements
Q. 133.
STATEMENT 1
Black phosphorus is thermodynamically the most stable allotrope of phosphorus.
because
STATEMENT 2
White phosphorus is monomer (P4 ) while yellow phosphorus is its polymer [(P4)m]
Q. 134.
STATEMENT 1
2
6
2
6
SiF
exists but SiCl
does not.
STATEMENT 2
Si atom has vacant d-orbital in its valence shell
Q. 135.
STATEMENT 1
Na2 SO4
is soluble while
BaSO 4
is insoluble.
because
STATEMENT 2
Lattice energy of
Q. 136.
BaSO 4
exceeds its hydration energy.

STATEMENT 1
- 94022962099,9158665588
Alkali metals impart colour to the Bunsen flame.

because
STATEMENT 2
Their ionization energies are low.
Q. 137.
STATEMENT 1
Boric acid behaves as a weak monobasic acid.
because
STATEMENT 2
Boric acid contains hydrogen bonds in its structure
Q. 138.
STATEMENT 1
In crystalline AgO, half of the silver atoms are linearly coordinates to two
nearest
neighbor oxygen atoms and half are
coordinated to four nearest neighbor oxygen atoms in
square
planar
configuration.
Because
STATEMENT 2
The 2-coordinate silver atom is Ag (I) and 4-coordinate silver atom are Ag (III)
Q. 139.
[Cu(CN ) 4 ]
because
STATEMENT 2
[Cu(CN ) 4 ]2
greater basic nature of
central metal.
is more stable than
is least stable than
STATEMENT 1
[CdH 2 O ) 4 ] 2
[Cu (CN ) 4 ] 2
and the stability is due to

ligand or greater charge density on
Q. 140.
STATEMENT 1
Fe(CN )
[ Fe(CN ) 6 ] 4
is weakly paramagnetic while
is diamagnetic.
because
STATEMENT 2
[ Fe(CN ) 6 ]3
[ Fe(CN ) 6 ] 4
has +3 oxidation state while
has +2 oxidation
3
6
state.
Q. 141.
STATEMENT 1
The ligands nitro and nitrito are called ambidentate ligands.
because
- 94022962099,9158665588
STATEMENT 2
These lignds give linkage isomers.
Q. 142.
STATEMENT 1
Complex formation can be seen as a lewis acid-base reaction.
because
STATEMENT 2
There occurs formation of co-ordinated covalent bond between empty orbitals of
metals and
filled orbital of ligands.
Ores And Metallurgy
Q. 143.
Gold occurs in native state
because
STATEMENT 2
Gold dissolve in aqua-regia
STATEMENT 1
Q. 144.
STATEMENT 1
Zinc is used and copper is not used in the recovery of Ag from the complex
[ Ag (CN ) 2 ]
because
STATEMENT 2
Zinc is a powerful reducing agent than copper.
Q. 145.
STATEMENT 1
H 2 O2
The O O bond length is
is shorter than that of
STATEMENT 2
because
H 2 O2
is on ionic compound.
Q. 146.
O2 F2
STATEMENT 1
SnO2
by magnetic separation.
Wolframite impurity is separated from

Because
STATEMENT 2
Tin stone is ferromagnetic, therefore attracted by magnet.
Q. 147.
CuO can be reduced by C,
because
STATEMENT 1
H2
as well as CO.
- 94022962099,9158665588
STATEMENT 2
CuO is basic oxide.
Q. 148.
STATEMENT 1
NH 4 OH
.
White ppt. of AgCl is soluble in

because
STATEMENT 2
It is due to the formation of soluble complex.
Q. 149.
STATEMENT 1
BaCl 2
All soluble sulphides gives white ppt. with
solution.
because
STATEMENT 2
BaS is soluble in water.
Q. 150.
STATEMENT 1
Borax bead test is applicable only to coloured salts.
because
STATEMENT 2
In borax bead test coloured slats are decomposed to give metal meta borates
which are
coloured.
Q. 151.
STATEMENT 1
A solution of BiCl3 in conc. HCl when diluted with water gives white ppt.
because
STATEMENT 2
BiCl3 is insoluble in dil. HCl
Q. 152.
STATEMENT 1
Sulphate is estimated as BaSO4 and not as MgSO4.
STATEMENT 2
because
Ionic radii of Mg2+ is smaller than that of Ba2+.
Subjective Type Questions
1.
find the quantum number n corresponding to the excited state of He + ion if on
transition
to
the ground state that ion emits
two photons in succession with wavelength 108.5 and 30.4 nm.
2.
A solid mixture (5.0 g) consisting of lead nitrate and sodium nitrate was heated
below
600C until the mass of the residue
was constant. If the loss in mass is 28% , find the mass of lead nitrate and sodium
nitrate in the mixture.
- 94022962099,9158665588
3.
Two flasks of equal volume connected by a narrow tube (of negligible volume)
are at 27C
and contain 0.70 mole of H2 at 0.5
atm. One of the flask is then immersed into a both kept at 127C, while the other
remains at 27C. Calculate the final pressure and the no. of moles of H2
in
each
flask.
4.
The isotopes 238U and 235U occur in nature in the ratio of 140:1. Assuming that
of the time
of
earth formation, they were
present in equal ration, make an estimation of the age of earth. The half life period
of 235U are 4.5 109 and 7.13 108 years respectively.
5.
A 2000C water is 2% dissociated into oxygen and hydrogen at a total pressure
of 1 atm
(a) calculate Kp (b) will the degree of
dissociation increase or decrease if argon gas is added,
holding the total pressure
equal to 1 atm (d) will the degree of dissociation change if the pressure is raised hy
addition of argon at constant volume to the closed system containing partially
dissociated water vapour (e) will the degree of dissociation increase or decrease if
oxygen gas is added while holding the total pressure constant at 1 atm.
6.
Though AgI having lower lattice energy compared to AgF it is less soluble in
water
explain.
7.
Solid BaF2 is added to a solution containing 0.1 mole of sodium oxalate solution
(IL) until
equilibrium is reached. If the K sp of
-6
3 3
-7
2 -2
BaF2 and BaC2O4 is 10 mol L and 10 mol L
respectively, find the equilibrium
concentration of Ba2+, F- and C2O42- in the solution. Assume
addition of BaF2 does
not cause any change in volume.
8.
A solution containing 28g phosphorus in 315g CS 2 (boiling point 43.3C) boils at
47.98C,
Kb
for CS2 = 2.34 K kg mol-1. The
formula of phosphorus can be given as
9.
Determine the enthalpy of the reaction,

C 3 H 8( g ) H 2 ( g ) C 2 H 6 ( g ) CH 4 ( g )
at 25C, using the gien enthalpy of combustion values under standard condition.
Compound
H 2( g )
G 0 / kJ
mol-1
- 289.0
CH 4 ( g )
- 890.0
C 2 H 6( g )
- 1560.0
C ( graphite)
- 393.5
- 94022962099,9158665588
C 3 H 8( g )
The standard enthalpy of formation of
is 103.8 kJ/mol
10.
An element with atomic number 60 crystallizes in one of cubic unit cell. The
density of the
defected unit cell (where one corner
atom is missing) is found to be 13.786 g/cc. Find out in
which
cubic
form
it
crystallizes. The edge length of the unit cell is 28
11.
Calculate the quantity of electricity delivered by a Daniel cell initially
containing 1 L each
of 1 M Cu2+ ion and 1 M Zn2+ C which
is operated until its potential drops to 1V.
E Zn 2 / Zn 0.76 V ; ECu 2 / Cu 0.34 V
Given :
12.
An organic compound (A) gives positive Libermann reaction and on treatment
with CHCl3/KOH
followed by hydrolysis gives (B) and
(C). Compound (C) gives colour with Schiffs
reagent
but not (B) which is steam
volatile. (B) on Treatment with LIAIH4 gives (D) C7H8O2
which on
oxidation gives
(E). Compound (E) reacts with (CH3CO)2O/CH3COOH to give a pain
reliever
(F).
Give structures of (A) to F with proper reasoning.
13. The alkyl halide C4HgBr(A) reacts with alcoholic KOH and gives an alkene (B),
which reacts
with bromine to give dibromide (C).
(C) is transformed with sodamide to a gas (D) which forms a precipitate when passed
through an ammonical silver nitrate solution. Give the structure formulae
of
the
compounds (A), (B), (C) and (D) and explain reactions involved.
14.
Which unshared pair of following molecule is more basic and why?

:N
N
H
15.
Describe at leat two reactions of each functional group of -amino acid
16. Treatment of compound A (C8H10O) with chromic acid/pyridine given B(C8H8O)

which
reacts with bromine yielding C(C8H6O).
C generates D (C8H8O3) upon treatment with alkali and
subsequent
acidification
oxidation of D with alkaline KMnO4 and subsequent acidification gives benzoic
acid
treatment of (B) with SiO2gives E(C8H6O2) which also affords D when treated with
alkali follow by acidification identify A, B, C, D & E with proper reasoning.
17.
An aromatic compound (A) gave a
mixture of two isomeric compounds (B) and (C) on reaction
with NH2OH.
(C)
rearranged to (D) (C8H9NO) on heating with H2SO4. (D) only hydrolysis produced
(E)
- 94022962099,9158665588
and (F) . (A) was oxidized with perbenzoic acid to (G). Hydrolysis of
(G) gave
(H)
and (E). An hydride of (E) and its sodium salt on condensation with PhCHO if produced
cinnamic acid;.
(H) on reaction with phthalic anhydride in H 2SO4 gave
phenolphthalein.
Suggest structures for the compounds
(A) to (H).
18.
Predict the relatie acidic strength among the following

CH 4 , NH 3 , H 2 O, HF
H 2 O, H 2 S , H 2 Se, H 2 , Te
(a)
(b)
CF3
19.
NO2F
?
0
BF
100
C
3
20.
An organic compound (A) of m.f. C 2H4 on treatment with aq. Cl2 gave a
compound (B)
with m.f. C2H5CIO. (B) on treatment
with an acid in presence of benzene formed a compound
(C). (C) on treatment with
alc. KOH gave a compound (D) which decolorized Br2/CCl4 solution.
(D) gave two
isomeric compounds (E) and (F) when treated with HBr in presence and in
absence
of peroxide. Identify the structures of compounds (A) to (F).
2CuFeS 2 O2
14001450C
Cu 2 S Fe2 O3 SO2
21.
Equation
How we
Cu 2 S
. Explain with the help equations.
22.
get the
. Showing what change.

blister
copper
from
What happens when?

(a) Silver oxide is treated with hydrogen peroxide.
(b) Ferric chloride is treated with hydroxylamine.
(c) Phosphene is reacted with acidified cupric sulphate solution.
(d) Silver nitrate solution is treated with phosphene.
(e) Mercuric chloride solution is treated with phosphorous acid.
23.
An inorganic mixture X dissolves in dil. HNO 3. The solution of X is filtered to get
a black
precipitate A which dissolves, in a
mixture of 1M NaOCl and dil. HCl. This solution on boiling and adding SnCl2 gives
white precipitate which turns to grey or black. The filtrate of the solution X is divided
into two parts. The first part on adding H2SO4 and alcohol gives white ppt.
B. Then
to the second part of the filtrate H 2SO4 is added which is heated in a fume cupboard
until white fumes appear and then cooled and on adding water to it gives white
precipitate C.
The filtrate of this precipitate is added
to conc. NH3 until the solution is distinctly alkaline, which gives white precipitate C,
which dissolves in dil. HCl and on addition of cold sodium tetrahydroxo stannate (II) a
black precipitate is noted. The filtrate of D was blue in color, which
was
divided
into two parts. To the first part dilute acetic acid and K 4[Fe(CN)6] was added to give
reddish-brown precipitate E and to the second part of the filtrate KCN was added
- 94022962099,9158665588
until the color

is discharged, through which H 2S is
passed resulting in yellow precipitate F. Identify all the
compounds from A to
F and the mixture X.
24. (a)
Why chlorine cannot form effective hydrogen bonding though its
electronegativity is
the same as that of nitrogen?
(b) AlCl3 is covalent but AlCl3.6H2O is ionic. Why?
(c) Explain why BaSO4 is insoluble in water through it is basic.
25.
of a
(i) A black coloured compound (B) is formed on passing H 2S through the solution
compound (A) in NH4OH.
(ii) (B) on treatement with HCl and KClO3 gives (A)
(iii) (A) on treatment with KCN gives a buff coloured ppt. which dissolves in
excess of this
reagent forming a compound (C).
(iv) The compound (C) is changed into a compound (D) when its aqueous
solution is boiled.
(v) The solution of (A) was treated with excess of NaHCO 3 and then with Br2
water. On colling
and shaking for some time, a green
colour of compound (E) is formed. No change is observed on heating.
Identfy (A) to (E) and give chemical equations for the reaction at steps (i) to (v)
26.
Gives the IUPAC names of the following Co-ordination compounds :
[Co.Cl.CN .NO2 ( NH 3 ) 3 ]
(i)
[CoSO4 ( NH 3 ) 4 ]NO3
(ii)
Na3 [ Ag ( S 2 O3 ) 2 ]
(iii)
(v)
(vii)
[Co( NH 3 ) 6 ]Cl3
(iv)
K 2 [OsCl 5 N ]
Li[ AlH 4 ]
[ Zn( NCS ) 4 ]
(vi)
2
(viii)
[Cr (en) 3 ]Cl3

(ix)
(xi)
[Cd ( SCN ) 4 ] 2
K 4 [ Fe(CN ) 6 ]
(x)
Na 2 [ ZnCl 4 ]
[Co ( NH 3 ) 5 ONO ] Cl 2
(xii)
K 3 [Cr (CN ) 6 ]
(xiii)
[Co ( NH 3 ) 5 NO2 ] ( NO3 ) 2

(xiv)
[Co ( NH 3 ) 5 ONO ] Cl 2
(xv)
Na2 [ Fe(CN ) 5 NO]

(xvi)
[ Ir ( Ph3 P ) 2 (CO)Cl ]
(xvii)
( NH 4 ) 3 [Co(C 2 O4 ) 2
(xviii)
[ Al (OH )( H 2 O) 5 SO4 ]
(xix)
[V ( H 2 O) 6 ]Cl3
(xx)
- 94022962099,9158665588
[Co( NH 3 ) 4 Cl 2 ][Cr (CN ) 6 ]

(xxi)
(xxiii)
[ Pt ( NH 3 ) 4 Cl 2 ][ PtCl4 ]
(xxii)
[ Pt ( py ) 4 ][ PtCl4 ]
[Co( NH 3 ) 5 CO3 ] 2 [CuCl 4 ]

(xxiv)
[ Ni( NH 3 ) 6 ][Co( NO2 ) 6 ] 2

(xxv)
- 94022962099,9158665588

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Single Choice Questions

Q. 3. Hydrogen bonding is maximum in :

Q. 5. The correct order of the O O bond length in

Q. 8. Which of the following hydrocarbons has the lowest dipole moment?

The most powerful oxidant among the following is :

in water is increased in the presence of :

Which has octahedral shape?

Kota Academy ,Bapat nagar Nagpur Road ,Chandrapur.Mob:

Choose the correct options

(b) 6 Cr- O bonds are equivalent

From the data it can be concluded that

Which is an example of chlorodising roasting?

(c) the three layers are maintained at different temperatures

(d) PbCl2 and HgCl2

(d) All of these

Which one of the following is used to separate

(c) Excess of KCN

Multiple Choice Questions

molecule is not iso structural with

The pair of molecules/ions with same BO and same magnetic property is

(a) [O2,N2] (b) [N2,CO] [c] O + 2 ,N 2

Kota Academy ,Bapat nagar Nagpur Road ,Chandrapur.Mob:

In which case the hybridization of central atom changes

s,p- block Elements

(d) conc. HCl

on hydrolysis with water

and its salts are identified by

Kota Academy ,Bapat nagar Nagpur Road ,Chandrapur.Mob:

(a) K2HgI4 and KOH

(b) HgCl2+KI (excess) + KOH

Hypervalent anion(s) is/are :

Ores And Metallurgy

Kota Academy ,Bapat nagar Nagpur Road ,Chandrapur.Mob:

(a) A deep red vapour is ivolved

part in chemical combination and

The bonding molecular orbitals are designated as

antibonding molecular orbitals as

Kota Academy ,Bapat nagar Nagpur Road ,Chandrapur.Mob:

A molecular orbital can accommodate at the maximum 2 electrons with

The bond lengths in the species

ions are in the

Which of the following is not correct?

Kota Academy ,Bapat nagar Nagpur Road ,Chandrapur.Mob:

formation, one electron is removed from the bonding molecular

formation, one electron is removed from the antibonding

formation, one electron is added to the bonding molecular

formation one electron is added to the bonding molecular

Although metaphosphoric acid is written as a monomer, it exists as a

Among the above acids, the acids having basicity 4 are:

Kota Academy ,Bapat nagar Nagpur Road ,Chandrapur.Mob:

(a) +1.8kJ mol-1

(b) 1.8 kJ mol

(c) +1.0 kJ mol-1 (d) 1.0 kJ mol-1

Kota Academy ,Bapat nagar Nagpur Road ,Chandrapur.Mob:

facilitate increased amounts of

(b) High temperature

Transition Elements And Co-ordination Compounds

Kota Academy ,Bapat nagar Nagpur Road ,Chandrapur.Mob:

square planer complex

Kota Academy ,Bapat nagar Nagpur Road ,Chandrapur.Mob:

D orbitals after ligand field splitting