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CHEMICAL KINETICS
2) 3, 2 & 3
d [ A]
d [ B]
d [C ]
=
= 1.5
. Then x, y and z are
dt
dt
dt
3) 3, 3 & 2
4) 2, 2 & 3
d [ NH 3 ]
d[ N2 ]
= K1[NH3],
= K2[NH3] and
dt
dt
d[H 2 ]
= K3[NH3]. The relation between K1, K2 and K3 is
dt
1) 1.5 K1=3K2=K3
2) 2K1=K2=3K3 3) K1=K2=K3 4) K1 = 3K2 =
2K3
3. Rate constant of a reaction is K. If the concentration of reactant is increased by x times
the rate constant of the reaction will be
1) Ck/x
2) K/x
3) K
4) x/K
4. The rate law for a reaction between the substances A and B is given by r = K[A]n[B]m.
When the conc. of A is doubled and that of B is halved, the rate of reaction changes by
times.
1) 1/2m+n
2) m+n
3) nm
4) 2nm
5. The rate of a reaction is expressed in different ways as follows : +
+
1 d A
d B
=
. The reaction is
4 dt
dt
1) 4A+B 2C+3D
6.
7.
8.
9.
1 d C
1 d D
=
=
2 dt
3 dt
B+ D 4A + 2C
2
The value of activation energy of a reaction can be found from the graph of
1) InK Vs T
2) InK Vs 1/T
3) K Vs T
4) 1/K Vs T
For a first order reaction t0.75 is 138.6 sec. Its specific rate constant (in sec1) is
1) 102
2) 104
3) 105
4) 106
For a certain reaction the activation energy is zero. If the value of its rate constant at
300 K is 1.6 x 106 sec1, the value of its rate constant at 280 K is
1) 1.6 x 106 sec1
2) Zero
3) 4) 3.2 x 1012 sec1
In the following first order reactions, X + Reagent Product and Y + Reagent
Product, if only 50% of Y reacts in the time taken for 94% consumption of X, the ratio
of K1 / K2 is
1) 2. 06
2) 3.06
3) 4.06
4) 0.06
d [ A]