GeneralChemistry(CHEM101)1058101

PRACTICE First Exam

Student Name:

ID No.:

Instructor:

Group

Constant: NA = 6.02 X1023

Thisexamconsistsoftwoparts:
PartI:multiplechoicequestions:circleyouranswerontheanswersheetprovided.30questions,1point
each,30pointstotal.
PartII:showyourworkquestions:4questions,2.5pointseach,10pointstotal.
PartI:

Answermultiplechoicequestions130andenteryouranswersontheattachedtable
30points
1.Whichofthesequantitiesrepresentsthelargestmass?
A.2.0102mg
B.0.0010kg
C.1.0105g
D.2.0102cg
E.10.0dg
2.Dotheindicatedarithmeticandgivetheanswertothecorrectnumberofsignificantfigures.

(1.510461.3)+2.01=
A.2.0192
B.2.0
C.2.019
D.2.02
E.2.019195

3.Thediameterofanatomisapproximately1108cm.Whatisthisdiameterwhenexpressedinnanometers?
A.11019nm
B.11015nm
C.1101nm
D.11010nm
E.1101nm
4.Thenumber1.05010

A.2
B.3
C.4
D.9
E.13

hashowmanysignificantfigures?

5.Howmanysignificantfiguresdoesthesum8.5201+1.93contain?
A.1
B.2
C.3
D.4
E.5
6.Apieceofmetalwithamassof125gisplacedintoagraduatedcylinderthatcontains25.00mLofwater,
raisingthewaterlevelto56.00mL.Whatisthedensityofthemetal?
A.5.00g/cm3
B.4.03g/cm3
C.2.23g/cm3
D.1.51g/cm3
E.0.25g/cm3
7.Theelementsinacolumnoftheperiodictableareknownas
A.metalloids.
B.aperiod.
C.noblegases.
D.agroup.
E.nonmetals.

8.Ananionisdefinedas
A.achargedatomorgroupofatomswithanetnegativecharge.
B.astableatom.
C.agroupofstableatoms.
D.anatomorgroupofatomswithanetpositivecharge
E. a particle with one negative charge
9.Atomsofthesameelementwithdifferentmassnumbersarecalled
A.ions.
B.neutrons.
C.allotropes.
D.chemicalfamilies.
E.isotopes.
10.Analuminumion,Al3+,has:
A.13protonsand13electrons
B.27protonsand24electrons
C.16protonsand13electrons
D.13protonsand10electrons
E.10protonsand13electrons

11.Whichisthecorrectformulaforcopper(II)phosphate?
A.Cu2PO4
B.Cu3(PO4)2
C.Cu2PO3
D.Cu(PO4)2
E.Cu(PO3)2

12.ThecorrectnameforBa(OH)2is
A.bariumhydrogenoxide.
B.boronhydroxide.
C.bariumhydrate.
D.berylliumhydroxide.
E.bariumhydroxide.
13.Whichoftheseelementsischemicallysimilartomagnesium?

A.sulfur
B.calcium
C.iron
D.nickel
E.potassium
14.Whichofthesechoicesistheformulaforhydrobromicacid?
A.KBr
B.HBr
C.HBrO
D.HBrO2
E.HBrO3
15.ThecorrectnameforS4Cl2is
A.Tetrasulfurdichloride
B.Sulfurdichloride
C.Tetrasulfurchloride
D.Tetrasulfurdichlorine
E.Sulfurdichlorine
16.Inacompoundofmanganese55andoxygen16.63%ofthemassisduetomanganese,whatisthe
empiricalformulaofthecompound?
A.MnO
B.Mn2O
C.Mn2O2
D.MnO2
E.noneofthese

17.Whatisthemassof7.801018carbonatoms?
A.1.30105g
B.6.43103g
C.7.801018g
D.1.56104g
E.12.01g
18.If0.274molesofasubstanceweighs62.5g,whatisthemolarmassofthesubstance,inunitsofg/mol?

A.2.28102g/mol
B.1.71101g/mol
C.4.38103g/mol
D.2.17102g/mol
E.noneofthese

19.Howmanyatomsarein4.39gofCO2?
A.1.801023atoms
B.6.011022atoms
C.1.161026atoms
D.6.041024atoms
E.1.811025atoms
20.HowmanymolesofHClarerepresentedby1.01019HClmolecules?
A.1.7105mol
B.1.5103mol
C.1.01019mol
D.36.5mol
E.6.02104mol
21.Howmanysodiumatomsaretherein6.0gofNa3N?
A.3.61024atoms
B.4.61022atoms
C.1.31023atoms
D.0.217atoms
E.0.072atoms
22.Calculate the percent composition by mass of each element in Na2CO3.
A.43.4% Na,
11.3% C,
45.3% O
B.53.4% Na,
12.3% C,
45.3% O
C.66.4% Na,
3.3% C,
55.3% O
D.43.4% Na,
24. 3% C,
45.3% O
E.67.4% Na,
11.3% C,
43.3% O
23.Whatisthemassof0.20moleofC2H6O(ethanol)?
A.230g
B.46g
C.23g
D.4.6g
E.noneofthese
4

24.MesityleneisacompoundconsistingonlyofCandH.Ifyouburn0.115gofthecompound,andfindthat

itproduces0.379gofCO2and0.1035gofH2O,determinetheempiricalformulaofthecompound.
A.CH
B.C2H3
C.C3H4
D.C9H10
E.C2H2
25Aluminumreactswithoxygentogivealuminum(III)oxide.

4Al(s)+3O2(g) 2Al2O3(s)Ifyouhave6.0molesofAl,
A.youneed3.0molesofO2forcompletereactionandproduce2.0molesofAl2O3.
B.youneed18.0molesofO2forcompletereactionandproduce12.0molesofAl2O3.
C.youneed3.0molesofO2forcompletereactionandproduce4.0molesofAl2O3.
D.youneed4.5molesofO2forcompletereactionandproduce3.0molesofAl2O3.
E.youneed4molesofO2forcompletereactionandproduce3.0molesofAl2O3.
26.HowmanymolesofCF4aretherein171gofCF4?
A.0.51mol
B.1.94mol
C.4.07mol
D.88.0mol
E.171mol
27.Ammoniareactswithdiatomicoxygentoformnitricoxideandwatervapor:
4NH3+5O24NO+6H2O
When40.0gNH3and50.0gO2areallowedtoreact,whichisthelimitingreagent?
A.NH3
B.O2
C.Neitherreagentislimiting
D.NO
E.H2O
28.Whichofthesecompoundsisanonelectrolyte?
A.NaF
B.HNO3
C.CH3COOH(aceticacid)
D.NaOH
E.C6H12O6(glucose)

29.Basedonthesolubilityrules,whichoneofthesecompoundsshouldbesolubleinwater?
A.AgBr
B.AgCl
C.Ag2CO3
D.AgNO3
E.Ag2S

30.Basedonthesolubilityrules,whichoftheseprocesseswilloccurifsolutionsofCuSO4(aq)andBaCl2(aq)
aremixed?
A.CuCl2willprecipitate;Ba2+andSO42arespectatorions.
B.CuSO4willprecipitate;Ba2+andClarespectatorions.
C.BaSO4willprecipitate;Cu2+andClarespectatorions.
D.BaCl2willprecipitate;Cu2+andSO42arespectatorions.
E.Noprecipitatewillform.
.

PartII,SolveProblems3134andshowyourwork

10marks

31.Thepercentcompositionbymassofacompoundis76.0%C,12.8%H,and11.2%O.Themolarmassof
thiscompoundis284.5g/mol.Whatisthemolecularformulaofthecompound?

32.HowmanygramsofCl2canbepreparedfromthereactionof16.0gofMnO2and30.0gofHClaccording
tothefollowingchemicalequation?

MnO2+4HClMnCl2+Cl2+2H2O

33.Whatisthetheoreticalyieldofchromiumthatcanbeproducedbythereactionof40.0gofCr2O3with8.00
gofaluminumaccordingtothischemicalequation?
2Al+Cr2O3Al2O3+2Cr

34.ThefirststepintheOstwaldprocessforproducingnitricacidis:4NH3(g)+5O2(g)4NO(g)+6H2O(g).
Ifthereactionof150.gofammoniawith150.gofoxygengasyields87.gofnitricoxide(NO),whatisthe
percentyieldofthisreaction?

CHEM101Key

1.Whichofthesequantitiesrepresentsthelargestmass?

a.2.0102mgb.0.0010kgc.1.0105gD.
2.0102cge.10.0dg
2.Dotheindicatedarithmeticandgivetheanswertothecorrectnumberofsignificantfigures.
(1.510461.3)+2.01=
a.2.0192b.2.0c.2.019D.
2.02
3.Thediameterofanatomisapproximately1108cm.Whatisthisdiameterwhenexpressedinnanometers?
a.11019nmb.11015nmc.1101nmd.11010nmE.
1101nm
4.Thenumber1.050109hashowmanysignificantfigures?
a.2b.3C.
4d.9e.13
5.Howmanysignificantfiguresdoesthesum8.5201+1.93contain?
a.1b.2c.3D.
4e.5

6.Apieceofmetalwithamassof125gisplacedintoagraduatedcylinderthatcontains25.00mLofwater,
raisingthewaterlevelto56.00mL.Whatisthedensityofthemetal?
a.5.00g/cm3B.
4.03g/cm3c.2.23g/cm3d.1.51g/cm3e.0.25g/cm3

7.Theelementsinacolumnoftheperiodictableareknownas
a.metalloids.b.aperiod.c.noblegases.D.
agroup.e.nonmetals.
8.Ananionisdefinedas
A.
achargedatomorgroupofatomswithanetnegativecharge.
b.astableatom.
c.agroupofstableatoms.
d.anatomorgroupofatomswithanetpositivecharge.

9.Atomsofthesameelementwithdifferentmassnumbersarecalled
a.ions.b.neutrons.c.allotropes.d.chemicalfamilies.E.
isotopes.
10.Analuminumion,Al3+,has:
a.13protonsand13electrons
b.27protonsand24electrons
c.16protonsand13electrons
D.13protonsand10electrons
e.10protonsand13electrons

11.Whichisthecorrectformulaforcopper(II)phosphate?
a.Cu2PO4B.Cu3(PO4)2c.Cu2PO3d.Cu(PO4)2e.Cu(PO3)2
12.ThecorrectnameforBa(OH)2is
a.bariumhydrogenoxide.b.boronhydroxide.c.bariumhydrate.d.berylliumhydroxide.
E.bariumhydroxide.

13.Whichoftheseelementsischemicallysimilartomagnesium?
a.sulfurB.calciumc.irond.nickele.potassium

14.Whichofthesechoicesistheformulaforhydrobromicacid?
a.KBrB.
HBrc.HBrOd.HBrO2e.HBrO3

15..18.ThecorrectnameforS4Cl2is
ATetrasulfurdichlorideB.SulfurdichlorideC.TetraSulfurchlorideD.TetraSulfurdichlorine
E.Sulfurdichlorine
16.Themineralpyrolusiteisacompoundofmanganese55andoxygen16.If63%ofthemassofpyrolusiteis
duetomanganese,whatistheempiricalformulaofpyrolusite?
a.MnOb.Mn2Oc.Mn2O2D.MnO2e.noneofthese
17.Whatisthemassof7.801018carbonatoms?
a.1.30105gb.6.43103gc.7.801018gD.
1.56104ge.12.01g
18.If0.274molesofasubstanceweighs62.5g,whatisthemolarmassofthesubstance,inunitsofg/mol?
A.
2.28102g/molb.1.71101g/molc.4.38103g/mold.2.17102g/mole.noneofthese

19.Howmanyatomsarein4.39gofCO2?
A
.1.801023atomsb.6.011022atomsc.1.161026atomsd.6.041024atomse.1.811025atoms

20.HowmanymolesofHClarerepresentedby1.01019HClmolecules?
A.1.7105molb.1.5103molc.1.01019mold.36.5mole.6.02104mol

21.Howmanysodiumatomsaretherein6.0gofNa3N?
a.3.61024atomsb.4.61022atomsC.
1.31023atomsd.0.217atomse.0.072atoms

22.Calculate the percent composition by mass of all the elements in Na2CO3.

A.43.4% Na, 11.3% C,
45.3% O
B.53.4% Na, 12.3% C,
45.3% O
C.66.4% Na, 13.3% C,
55.3% O
D.43.4% Na, 24. 3% C,
45.3% O
E.67.4% Na, 11.3% C,
43.3% O
23.Whatisthemassof0.20moleofC2H6O(ethanol)?
a.230gb.46gc.23gd.4.6gE.
noneofthese

10

24.Mesityleneisaliquidhydrocarbon,acompoundconsistingonlyofCandH.Ifyouburn
0.115gofthecompound,andfindthatitproduces0.379gofCO2and0.1035gofH2O,
determinetheempiricalformulaofthecompound.
A.CH(b)C2H3(c)C3H4(d)C9H10

25.Aluminumreactswithoxygentogivealuminum(III)oxide.
4Al(s)+3O2(g) 2Al2O3(s)
Ifyouhave6.0molesofAl,
(a)youneed3.0molesofO2forcompletereactionandproduce2.0molesofAl2O3.
(b)youneed18.0molesofO2forcompletereactionandproduce12.0molesofAl2O3.
(c)youneed3.0molesofO2forcompletereactionandproduce4.0molesofAl2O3.
D.youneed4.5molesofO2forcompletereactionandproduce3.0molesofAl2O3.
e.youneed4molesofO2forcompletereactionandproduce3.0molesofAl2O3.

26.HowmanymolesofCF4aretherein171gofCF4?
a.0.51molB.
1.94molc.4.07mold.88.0mole.171mol

27.Ammoniareactswithdiatomicoxygentoformnitricoxideandwatervapor:
4NH3+5O24NO+6H2O
When40.0gNH3and50.0gO2areallowedtoreact,whichisthelimitingreagent?
a.NH3B.O2c.Neitherreagentislimiting.d.NOe.H2O

28.Whichofthesecompoundsisanonelectrolyte?
A.NaFB.HNO3C.CH3COOH(aceticacid)D.NaOHE.C6H12O6(glucose)

29.Basedonthesolubilityrules,whichoneofthesecompoundsshouldbesolubleinwater?
A.AgBrB.AgClC.Ag2CO3D.AgNO3E.Ag2S

30.Basedonthesolubilityrules,whichoftheseprocesseswilloccurifsolutionsofCuSO4(aq)andBaCl2(aq)
aremixed?
A.CuCl2willprecipitate;Ba2+andSO42arespectatorions.
B.CuSO4willprecipitate;Ba2+andClarespectatorions.
C.BaSO4willprecipitate;Cu2+andClarespectatorions.
D.BaCl2willprecipitate;Cu2+andSO42arespectatorions.
E.Noprecipitatewillform.
.

11

Showyourworkquestions
31.Thepercentcompositionbymassofacompoundis76.0%C,12.8%H,and11.2%O.Themolarmassof
this compound is 284.5 g/mol. What is the molecular formula of the compound?
Answer:C18H36O2.
32.HowmanygramsofCl2canbepreparedfromthereactionof16.0gofMnO 2and30.0gofHClaccording
tothefollowingchemicalequation?
MnO2
+ 4HCl
MnCl2
+ Cl2
+ 2H2O
Answer:

13.0

g
33.Whatisthetheoreticalyieldofchromiumthatcanbeproducedbythereactionof40.0gofCr 2O3with8.00
g of aluminum according to the chemical equation below?

2Al

Cr2O3

Al2O3
+

2Cr
Answer:15.4g
34.The first step in the Ostwald process for producing nitric acid is

4NH3(g)

5O2(g)

4NO(g)

6H2O(g).
Ifthereactionof150.gofammoniawith150.gofoxygengasyields87.gofnitricoxide(NO),whatisthe
percent

yield

of

this

reaction?
Answer:

33%

12

General Chemistry 1 CHEM 1058101

PRACTICE 1st EXAM 2008

Time: 2 hrs.

Student Name:

ID No.:

Group:

Instructor

Circle the correct answers to questions 1-30 in this table

1

16

17

18

19

20

21

22

23

24

10

25

11

26

12

27

13

28

14

29

15

30

13