Documente Academic
Documente Profesional
Documente Cultură
Summer 2016
Pearson Edexcel
International Advanced Level
in Chemistry (WCH02) Paper 01
Application of Core Principles of
Chemistry
Summer 2016
Publications Code 46659_MS*
All the material in this publication is copyright
Pearson Education Ltd 2016
All candidates must receive the same treatment. Examiners must mark
the first candidate in exactly the same way as they mark the last.
Mark schemes will indicate within the table where, and which strands
of QWC, are being assessed. The strands are as follows:
i) ensure that text is legible and that spelling, punctuation and
grammar are accurate so that meaning is clear
ii) select and use a form and style of writing appropriate to purpose
and to complex subject matter
iii) organise information clearly and coherently, using specialist
vocabulary when appropriate
Correct Answer
Question
Number
2(a)
Correct Answer
Question
Number
2(b)
Correct Answer
Question
Number
2(c)
Correct Answer
Question
Number
2(d)
Correct Answer
Question
Number
3
Correct Answer
Question
Number
4(a)
Correct Answer
Question
Number
4(b)
Correct Answer
Question
Number
4(c)
Correct Answer
Question
Number
4(d)
Correct Answer
Question
Number
5
Correct Answer
Question
Number
6(a)
Correct Answer
Reject
(1)
Reject
Mark
(1)
Reject
Mark
(1)
Reject
Mark
(1)
Reject
Mark
(1)
Reject
Mark
(1)
Reject
Mark
(1)
Reject
Mark
(1)
Reject
Mark
(1)
Reject
Mark
(1)
Reject
Mark
Mark
(1)
Reject
Mark
(1)
Question
Number
5(b)
Correct Answer
Question
Number
7
Correct Answer
Question
Number
8
Correct Answer
Reject
(1)
Reject
C
Reject
Question
Number
10(b)
Correct Answer
Question
Number
11
Correct Answer
Question
Number
12
Correct Answer
(1)
Reject
Mark
(1)
Reject
Mark
(1)
Reject
Mark
(1)
B
Correct Answer
Mark
(1)
Question
Number
10(a)
Mark
Mark
(1)
Reject
Mark
(1)
Section B
Question
Number
13(a)
Acceptable Answers
Reject
pyramidal
Just
planar
OR
Trigonal
OR
(1) Triangular
o
(1)
No TE on incorrect shape
Answers may be given the wrong way round
ie bond angle first, then shape
Mark
(2)
Question
Number
*13(b)
Acceptable Answers
Reject
(Shape)
Ignore references to tetrahedral/pyramidal
Cl
Cl
Cl
N
\
Cl Cl Cl
N
/ I
Cl Cl
(4)
No M1 if
incorrect
name for
shape eg
bipyramidal
Just dot
and cross
ALLOW
\
Cl
TWO lone
pairs
(1)
(Explanation)
Minimum repulsion
(between pairs/groups of electrons /centre
of
electron density)
between
atoms/
bonds
ALLOW
maximum separation
(1)
(between pairs/groups of electrons /centre
of
electron density)
between
atoms/
bonds
Mark
Question
Number
13(c)(i)
Correct Answer
Reject
7, -7
+7 / +VII
Mark
(1)
ALLOW
7+ / 7+
Question
Number
13(c)(ii)
Correct Answer
Reject
Mark
(1)
ALLOW
O
O
|
|
O Cl O Cl - O
|
|
O
O
OR
O
O
O Cl O Cl O
O
O
IGNORE
Any dot and cross diagram or added
dots and crosses
Question
Number
13(c)(iii)
Correct Answer
Cl2O7
H2 O
Reject
2HClO4
Mark
(1)
H2Cl2O8
ALLOW multiples
(Total for Question 13 = 9 marks)
Question
Number
14(a)(i)
Correct Answer
Reject
Question
Number
14(a)(ii)
(2)
...reduced
to iodine
(1)
Correct Answer
Reject
PI3 + 3C4H9OH
2PI3
P3
PI5
(1)
3C4H9I + H3PO3
ALLOW
P(OH)3
TE for second mark
PI5 + C4H9OH C4H9I + POI3 + HI
Mark
(2)
ALLOW
P2
+
Mark
(1)
Question
Number
14(b)(i)
Correct Answer
Reject
Mark
Just
solvent
(1)
OR
As a (co-)solvent for polar and non-polar
molecules
OR
To allow the reagents/reactants to
mix/dissolve/become miscible
ALLOW
To dissolve the halogenoalkane (as it is not
water soluble)
OR
Just (As a) co-solvent
Question
Number
14(b)(ii)
Correct Answer
Reject
Mark
(1)
Butan-1-ol
Butanol
ALLOW
But-1-ol
1-butanol
OR
Butane-1-ol
Question
Correct Answer
Number
14(b)(iii) Yellow
Ag+(aq)
I(aq)
Reject
(1)
AgI(s)
(1)
Pale yellow/
cream
Mark
(2)
Question
Correct Answer
Number
14(b)(iv)
Reject
Mark
(2)
Observation
with dilute
aqueous
ammonia
Observation
with
concentrated
aqueous
ammonia
Precipitate
from Tube A
Dissolves/
soluble
Dissolves/
soluble
Precipitate
from Tube C
No change/
insoluble/ppt
and remains
No change/
insoluble/ppt
and remains
Question
Number
14(b)(v)
Correct Answer
Reject
Mark
(1)
CBA
OR
AgI, AgBr, AgCl
OR
Silver iodide, silver bromide, silver chloride
Question
Correct Answer
Number
*14(b)(vi) The carbon-halogen bond polarity
decreases from chlorine to iodine
Reject
Mark
(2)
(1)
Question
Number
14(c)(i)
Correct Answer
Reject
Mark
(1)
CH3CH2CHCH2
ALLOW
CH3CH2CH=CH2
OR
Displayed/ skeletal formula
Ignore C4H8
Reject
Mark
(1)
ALLOW dehydrohalogenation
Question
Number
14(c)(iii)
Correct Answer
Reject
M2 depends on M1
Bromine/Br2 (water)
(Yellow to) colourless
(20
(1)
.to clear
(1)
ALLOW
Other colours brown/red/orange for
bromine water
Any other
colour
OR
Acidified potassium manganate(VII)
(1)
OR H+ and MnO4Purple/pink to colourless
Mark
(1)
.to clear
Question
Number
14(d)(i)
Correct Answer
Reject
2NH3 + CH3CH2CH2CH2I
CH3CH2CH2CH2NH2 + NH4I (NH4+I-)
Mark
(1)
ALLOW
NH3 + CH3CH2CH2CH2I
CH3CH2CH2CH2NH2 + HI
C4H9 for carbon chain
Displayed formulae
Question
Number
14(d)(ii)
Correct Answer
(CH3CH2CH2CH2)2NH
C4H11N
Reject
Mark
(1)
OR
(CH3CH2CH2CH2)3N
OR
(CH3CH2CH2CH2)4N(+)I()
ALLOW
C4H9 for carbon chain
Displayed formulae
(Total for Question 14 = 19 marks)
Question
Number
15(a)(i)
Question
Number
15(a)(ii)
Correct Answer
Reject
Mark
Ba(NO3)2 ((s))
(1)
Correct Answer
Reject
Question
Correct Answer
Number
15(a)(iii) Oxygen relights/rekindles a glowing
splint
Mark
Reject
(1)
Mark
(1)
Question
Correct Answer
Number
15(a)(iv) 2Ba(NO3)2.4H2O 2BaO + 4NO2 + O2 + 8H2O
OR
Ba(NO3)2.4H2O BaO + 2NO2 + O2 + 4H2O
Ignore state symbols even if incorrect
ALLOW
multiples
Reject
Mark
(2)
Question
Number
15(b)
Correct Answer
Reject
Mark
(3)
Heating in
a water
bath
Test tubes
with
bungs
Reflux
apparatus
Heat
OR
Two test tubes being heated
(1)
(1)
OR
Time taken for fixed volume of gas
to be collected
OR
Measure rate of gas given off
ALLOW
Gives out oxygen/nitrogen dioxide/gas faster
(1)
IGNORE
Decomposes faster
Heat the sample up for the same time and
masure volume of gas evolved would score
two bullet points
Heat to
constant
mass
Question
Number
*15(c)
Correct Answer
Reject
M1
Calcium (ions) are smaller than barium (ions)
/have a higher charge density
Mark
(3)
Allow
Atoms for ions
Reverse argument
(1)
M2
The calcium ion polarizes/distorts
(1)
M3
The nitrate/anion (ion)/N-O bond is
polarised/distorted/broken (this weakens the N-O
bond)
(1)
Question
Number
15(d)
Correct Answer
Reject
Calcium red
Crimson
Mark
(2)
(1)
(1)
(Total for Question 15 = 13 marks)
(Total for Section B = 41 marks)
Section C
Question
Number
16(a)(i)
Correct Answer
Reject
Mark
(2)
ALLOW
Any bond lengths and any angles.
Ignore displayed/structural formulae
(1)
(1)
Question
Number
16(a)(ii)
Correct Answer
Reject
Just stronger
intermolecular
forces
London/dispersion forces
OR
instantaneous dipole-induced dipole forces
ALLOW
Stronger Van der Waals forces/ VdW
IGNORE minor spelling errors
(1)
Mark
(2)
Question
Number
16(a)(iii)
Correct Answer
Reject
Any
statement
that this
compound
is a CFC
OR
(Halothane products like)
1,1,1-trichloroethane are narcotic inhalants /
poisonous / toxic
ALLOW
Carcinogens/ greenhouse gases
Mark
(1)
OR
forms Cl2
(on
breaking
down)
IGNORE
References to just:
Question
Number
16(b)(i)
formation of Cl
Correct Answer
Reject
Mark
(1)
I
Cl
I
Cl
|
|
|
|
CH3(CH2)4C CCH2C C(CH2)7COOH
|
|
|
|
H
H
H
H
I and Cl on either side of each bond, either
up or down
Look out for only I or Cl added with extra
hydrogen, also 2I and 2Cl added
I and Cl on
the same
carbon
Question
Number
16(b)(ii)
Correct Answer
Reject
Mark
(1)
Question
Correct Answer
Number
16(b)(iii) To prevent formation of free radicals
Reject
Causes
oxidation
OR
C-Cl breaks
To prevent (I-Cl) bonds breaking
(homolytically)
ALLOW
To prevent UV/sunlight entering
UV/sunlight causes it to react /
decompose
heterolytically
Mark
(1)
Question
Correct Answer
Number
16(b)(iv)
ICl +
I
+1 (-1)
Reject
(1)
I2 + Cl
-1
Mark
Just 0
for ICl
(1)
Just
Iodine
Question
Number
16(c)(i)
Correct Answer
(1)
Reject
From red/brown/yellow to
pale yellow/ straw coloured
Mark
(1)
to colourless
ALLOW
Red/brown/yellow colour fades/pales
Question
Number
16(c)(ii)
Correct Answer
An insoluble compound forms (if starch is
added too soon)
OR
Starch iodine complex forms
ALLOW
Any indication of solid formation
Reject
Mark
(1)
Correct Answer
Question
Number
16(d)(ii)
Correct Answer
Reject
Mark
(1)
Mark
(1)
Question
Correct Answer
Number
16(d)(iii) 2.00 x 103/0.00200 (mol)
Allow TE from (ii)
Reject
Question
Correct Answer
Number
16(d)(iv) 0.00200 - 0.00110 =
9.00 x 104/0.00090 (mol)
Allow TE from (iii) unless value is negative
(or if calculation reversed for this reason)
Reject
Mark
(1)
Mark
(1)
Correct Answer
Reject
Question
Correct Answer
Number
16(d)(vi) 0.45 x 2 x 126.9 = 114(.2) (g)
If I=127 then final answer is 114(.3)
(g)
Ignore SF except 1.
Mark
(1)
Reject
Mark
(1)
Question
Number
16(e)
Correct Answer
Sample titre - higher
AND
Iodine value lower
Reject
Mark
(1)