Sunteți pe pagina 1din 24

AGA 5 Calculation Spreadsheet - Imperial Units of Measure

mole fraction (xi)


Methane
Nitrogen
Carbon Dioxide
Ethane
Propane
Water (gas)
Hydrogen Sulfide
Hydrogen
Carbon Monoxide
Oxygen
Isobutane
Normal Butane
Isopentane
Normal Pentane
Hexane
Heptane
Octane
Nonane
Decane
Helium
Argon
2,2-Dimethyl Propane
2-Methyl Pentane
3-Methyl Pentane
2,2-Dimethyl Butane
2,3-Dimethyl Butane
Ethylene
Propylene
Methyl Alcohol

0.906724
0.031284
0.004676
0.045279
0.008280
0.000000
0.000000
0.000000
0.000000
0.000000
0.001037
0.001563
0.000321
0.000443
0.000393
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000

molar mass
16.0425
28.0134
44.0095
30.0690
44.0956
18.0153
34.0809
2.0159
28.0101
31.9988
58.1222
58.1222
72.1488
72.1488
86.1754
100.2019
114.2285
128.2551
142.2817
4.0026
39.9480
72.1488
86.1764
86.1764
86.1764
86.1764
28.0532
42.0797
32.0419

1.000000
Pressure Base (Pb)
Temperature Base (Tb)

14.73
60

molar mass * xi
14.5461
0.8764
0.2058
1.3615
0.3651
0.0000
0.0000
0.0000
0.0000
0.0000
0.0603
0.0908
0.0232
0.0320
0.0339
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
17.5950

psia
F

Calculation Results
Compressibility Factor (Z) at Pb, Tb
Gross HV at Pb, Tb
Net HV at Pb, Tb
Wobbe Number
Ideal Gas Relative Density
Real Gas Relative Density
MON 1 (Linear Method)
MON 2 (CARB Method)
Methane Number (via MON 1 method)

0.997776
1034.8
933.6
1326.5
0.6075
0.6086
127.4
124.7
87.8

BTU(IT)/ft3
BTU(IT)/ft3
BTU(IT)/ft3

corrected for compressibility


corrected for compressibility
corrected for compressibility
corrected for compressibility

Methane Number (via MON 2 method)


Gas Constant
Standard T for Hf and Cp
Heat of Vaporization of Water
delta H for Liquid Water
Ideal Gas Molar Volume at Pb, Tb
Molar Mass of Air
Compressibility Factor (Z) of Air at Pb, Tb

83.5
8.314472
298.15
44.41
-711.1
23.6357
28.9625
0.999566

J mol-1 K-1
Kelvins
kJ/mole at
kJ/mole at
litres

60
60

Conversion Factors
Volume
Mass
Energy
Pressure
Volumetric Heating Value
Length

1
2

convert
ft3
lbm
BTU(IT)
psi
BTU(IT)/ft3
foot

to
m3
kg

multiply by
0.028316846592
0.45359237

joules
kPa

1055.05585262
6.894757293

MJ/m3
meter

0.037258945808
0.3048

Notes
Heating values calculated by this spreadsheet do not have uncertainties better than +/- 0.1%.
In some cases, extra digits have been added to calculated values to achieve internal
consistency or to permit recalculation of experimental values.

version 1.1
Gross Ideal HV (BTU(IT)/ft3)
1012.344
0.000
0.000
1773.777
2522.017
50.429
638.579
324.912
321.260
0.000
3259.500
3269.926
4010.166
4018.033
4767.048
5515.269
6263.365
7012.573
7760.953
0.000
0.000
3994.021
4758.674
4761.307
4745.848
4754.732
1603.421
2338.936
868.813

26-Feb-08
Gross HV * xi Net Ideal HV (BTU(IT)/ft3)
917.9162
0.0000
0.0000
80.3149
20.8823
0.0000
0.0000
0.0000
0.0000
0.0000
3.3801
5.1109
1.2873
1.7800
1.8734
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
1032.5451

101.5597749259
15.5555555556
288.7055555556

cted for compressibility


cted for compressibility
cted for compressibility

cted for compressibility

kPa
C
Kelvins

911.485
0.000
0.000
1622.489
2320.300
0.000
588.150
274.483
321.260
0.000
3007.354
3017.780
3707.591
3715.457
4414.043
5111.835
5809.501
6508.281
7206.231
0.000
0.000
3691.446
4405.669
4408.303
4392.843
4401.727
1502.562
2187.648
767.955

Net HV * xi
826.4654
0.0000
0.0000
73.4647
19.2121
0.0000
0.0000
0.0000
0.0000
0.0000
3.1186
4.7168
1.1901
1.6459
1.7347
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
931.54840

F
F

Summation factor (s)


0.044427
0.016980
0.074855
0.091445
0.133071
0.249993
0.091778
0.024636
0.021610
0.027547
0.169195
0.180283
0.220899
0.232519
0.297637
0.365001
0.433067
0.501436
0.597379
0.022007
0.027250
0.199233
0.279832
0.290531
0.267123
0.280156
0.079612
0.125619
0.293299

Summation factor * xi
0.040282931
0.0005312148
0.0003500241
0.0041405509
0.0011018306
0
0
0
0
0
0.0001754547
0.000281783
7.09086486603424E-005
0.0001030058
0.0001169713
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.04715

Methane
Nitrogen
Carbon Dioxide
Ethane
Propane
Water (gas)
Hydrogen Sulfide
Hydrogen
Carbon Monoxide
Oxygen
Isobutane
Normal Butane
Isopentane
Normal Pentane
Hexane
Heptane
Octane
Nonane
Decane
Helium
Argon
2,2-Dimethyl Propane
2-Methyl Pentane
3-Methyl Pentane
2,2-Dimethyl Butane
2,3-Dimethyl Butane
Ethylene
Propylene
Methyl Alcohol

Ideal Gas Molar Heating Value (kJ/mole)


Gross HV at 298.15 K
Net HV at 298.15 K
890.63
802.60
0.00
0.00
0.00
0.00
1560.69
1428.64
2219.17
2043.11
44.016
0.00
562.01
517.99
285.83
241.81
282.98
282.98
0.00
0.00
2868.20
2648.12
2877.40
2657.32
3528.83
3264.73
3535.77
3271.67
4194.95
3886.84
4853.43
4501.30
5511.80
5115.66
6171.15
5730.99
6829.77
6345.59
0.00
0.00
0.00
0.00
3514.63
3250.53
4187.57
3879.46
4189.87
3881.76
4176.27
3868.16
4184.07
3875.96
1411.15
1323.12
2058.43
1926.38
764.17
676.14

Gross HV at Tb
891.51
0.00
0.00
1562.06
2220.99
44.41
562.36
286.13
282.91
0.00
2870.45
2879.63
3531.51
3538.44
4198.06
4856.97
5515.77
6175.56
6834.61
0.00
0.00
3517.30
4190.68
4193.00
4179.39
4187.21
1412.04
2059.76
765.11

Ideal Gas Mass Heating Value (BTU(IT)/lbm)


Net HV at Tb
802.69
0.00
0.00
1428.83
2043.35
0.00
517.95
241.72
282.91
0.00
2648.40
2657.58
3265.05
3271.98
3887.19
4501.69
5116.08
5731.46
6346.10
0.00
0.00
3250.84
3879.81
3882.13
3868.52
3876.34
1323.22
1926.53
676.29

Gross HV at Tb
23892
0
0
22334
21654
1060
7094
61022
4342
0
21232
21300
21044
21085
20944
20839
20760
20701
20652
0
0
20959
20907
20918
20850
20889
21640
21044
10266

Net HV at Tb
21511
0
0
20429
19922
0
6534
51551
4342
0
19590
19658
19456
19497
19393
19315
19255
19212
19176
0
0
19371
19356
19367
19300
19339
20279
19683
9074

Ideal Gas Volumetric Heating Value (BTU


Gross HV at Tb
1012.3
0.0
0.0
1773.8
2522.0
50.4
638.6
324.9
321.3
0.0
3259.5
3269.9
4010.2
4018.0
4767.0
5515.3
6263.4
7012.6
7761.0
0.0
0.0
3994.0
4758.7
4761.3
4745.8
4754.7
1603.4
2338.9
868.8

olumetric Heating Value (BTU(IT)/ft3)


Net HV at Tb
911.5
0.0
0.0
1622.5
2320.3
0.0
588.1
274.5
321.3
0.0
3007.4
3017.8
3707.6
3715.5
4414.0
5111.8
5809.5
6508.3
7206.2
0.0
0.0
3691.4
4405.7
4408.3
4392.8
4401.7
1502.6
2187.6
768.0

Methane
Nitrogen
Carbon Dioxide
Ethane
Propane
Water (gas)
Hydrogen Sulfide
Hydrogen
Carbon Monoxide
Oxygen
Isobutane
Normal Butane
Isopentane
Normal Pentane
Hexane
Heptane
Octane
Nonane
Decane
Helium
Argon
2,2-Dimethyl Propane
2-Methyl Pentane
3-Methyl Pentane
2,2-Dimethyl Butane
2,3-Dimethyl Butane
Ethylene
Propylene
Methyl Alcohol
Sulfur Dioxide

Enthalpy Change
Cp at 298.15 K
35.7086
29.1253
37.1409
52.4746
73.3368
33.5873
34.1086
28.8339
29.1388
29.3759
96.6394
98.4809
118.8894
120.0358
142.5899
165.1814
187.7820
210.4144
233.0274
20.7862
20.7862
120.9160
142.2604
140.2468
141.7290
139.3867
42.8526
64.3181
44.0214
39.8686

Cp at Tb
35.3376
29.1203
36.7131
51.3143
71.4681
33.5423
33.9956
28.7758
29.1299
29.3265
94.0494
96.0555
115.6580
117.0855
139.0632
161.0296
183.0120
204.9974
227.0026
20.7862
20.7862
117.4484
138.3102
136.3416
137.8415
135.2344
41.9354
62.8273
43.3992
39.5271

term 1
-329.3462
-274.9876
-339.6859
-467.9204
-647.2926
-316.3010
-319.6602
-270.2418
-275.0435
-276.4437
-849.4108
-871.5422
-1041.7129
-1063.1037
-1262.2604
-1460.5135
-1658.9727
-1856.0551
-2054.9807
-196.3139
-196.3139
-1052.1440
-1244.2157
-1225.9059
-1240.9257
-1210.0531
-383.0710
-571.1120
-401.8774
-368.0291

term 3
-5.7052
-0.0480
-9.1969
-21.7610
-36.0599
-0.6308
-1.8300
-2.0072
-0.0928
-0.6845
-50.5918
-46.4283
-65.9839
-55.6022
-66.5536
-78.5461
-90.4677
-104.2400
-115.8326
0.0000
0.0000
-74.4867
-80.8957
-80.5360
-79.4101
-87.6019
-16.9015
-28.9944
-10.3989
-6.8852

term 3
-0.5813
-0.0168
0.1672
-0.5655
-0.5862
-0.0901
-0.1473
0.2655
-0.0280
-0.1016
-0.6169
-0.8804
0.1462
-1.3512
-1.5869
-1.8056
-2.0017
-1.7928
-2.0273
0.0000
0.0000
1.3344
0.2540
0.4312
0.1854
1.0888
-0.5426
-0.3952
-0.7097
-0.0130

dHi
-335.6327
-275.0525
-348.7156
-490.2468
-683.9388
-317.0220
-321.6376
-271.9836
-275.1643
-277.2298
-900.6196
-918.8509
-1107.5506
-1120.0570
-1330.4009
-1540.8652
-1751.4421
-1962.0878
-2172.8405
-196.3139
-196.3139
-1125.2963
-1324.8573
-1306.0108
-1320.1504
-1296.5662
-400.5151
-600.5016
-412.9860
-374.9273

O2 Term
554.4597
0.0000
0.0000
970.3044
1386.1491
0.0000
415.8447
138.6149
138.6149
0.0000
1801.9939
1801.9939
2217.8386
2217.8386
2633.6834
3049.5281
3465.3728
3881.2176
4297.0623
0.0000
0.0000
2217.8386
2633.6834
2633.6834
2633.6834
2633.6834
831.6895
1247.5342
415.8447
0.0000

H2O Term (GHV)


-1422.1444444445
0
0
-2133.2166666667
-2844.2888888889
0
-711.0722222222
-711.0722222222
0
0
-3555.3611111111
-3555.3611111111
-4266.4333333333
-4266.4333333333
-4977.5055555556
-5688.5777777778
-6399.65
-7110.7222222222
-7821.7944444445
0
0
-4266.4333333333
-4977.5055555556
-4977.5055555556
-4977.5055555556
-4977.5055555556
-1422.1444444445
-2133.2166666667
-1422.1444444445
0

H2O Term (LHV)


-634.0440
0.0000
0.0000
-951.0660
-1268.0880
0.0000
-317.0220
-317.0220
0.0000
0.0000
-1585.1100
-1585.1100
-1902.1319
-1902.1319
-2219.1539
-2536.1759
-2853.1979
-3170.2199
-3487.2419
0.0000
0.0000
-1902.1319
-2219.1539
-2219.1539
-2219.1539
-2219.1539
-634.0440
-951.0660
-634.0440
0.0000

CO2 Term
-348.7156
0.0000
0.0000
-697.4313
-1046.1469
0.0000
0.0000
0.0000
-348.7156
0.0000
-1394.8625
-1394.8625
-1743.5781
-1743.5781
-2092.2938
-2441.0094
-2789.7250
-3138.4407
-3487.1563
0.0000
0.0000
-1743.5781
-2092.2938
-2092.2938
-2092.2938
-2092.2938
-697.4313
-1046.1469
-348.7156
0.0000

SO2 Term
0
0
0
0
0
0
-374.927
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

dH (GHV)
-880.768
275.052
348.716
-1370.097
-1820.348
317.022
-348.517
-300.474
65.064
277.230
-2247.610
-2229.379
-2684.622
-2672.116
-3105.715
-3539.194
-3972.560
-4405.857
-4839.048
196.314
196.314
-2666.877
-3111.259
-3130.105
-3115.966
-3139.550
-887.371
-1331.328
-942.029
374.927

dH (LHV)
-92.667
275.052
348.716
-187.946
-244.147
317.022
45.533
93.577
65.064
277.230
-277.359
-259.128
-320.321
-307.814
-347.363
-386.792
-426.108
-465.355
-504.495
196.314
196.314
-302.575
-352.907
-371.754
-357.614
-381.198
-99.271
-149.177
-153.929
374.927

Methane
Nitrogen
Carbon Dioxide
Ethane
Propane
Water (gas)
Hydrogen Sulfide
Hydrogen
Carbon Monoxide
Oxygen
Isobutane
Normal Butane
Isopentane
Normal Pentane
Hexane
Heptane
Octane
Nonane
Decane
Helium
Argon
2,2-Dimethyl Propane
2-Methyl Pentane
3-Methyl Pentane
2,2-Dimethyl Butane
2,3-Dimethyl Butane
Ethylene
Propylene
Methyl Alcohol

Summation Factor Calculation


term 1
term 2
-4.9007801E-01
9.4776133E-01
-2.2413260E-01
4.5930282E-01
-1.7276675E+00
3.6961136E+00
-1.9340481E+00
3.8460043E+00
-5.0978896E+00
1.0785430E+01
-2.0149330E+02
5.4961910E+02
-2.5434289E+00
5.4605925E+00
-1.1171849E-02
5.5234431E-02
-2.5021661E-01
5.0094736E-01
-2.5663170E-01
5.0546615E-01
-8.9921356E+00
1.9409973E+01
-1.1403540E+01
2.5090221E+01
-2.0234239E+01
4.5869946E+01
-2.3425658E+01
5.3425385E+01
-4.4762737E+01
1.0361251E+02
-7.1893811E+01
1.6747850E+02
-1.0583461E+02
2.4743415E+02
-1.4573558E+02
3.4165768E+02
-2.1770439E+02
5.1232288E+02
1.3159012E-02
-1.6835244E-03
-2.4623380E-01
4.8395022E-01
-1.4910420E+01
3.3401053E+01
-3.7543050E+01
8.6511642E+01
-8.3256687E+01
2.1204838E+02
-5.9875080E+01
1.5072477E+02
-7.2550109E+01
1.8399733E+02
-1.5539888E+00
3.1640994E+00
-4.5381793E+00
9.6405645E+00
-3.3786365E+02
9.2262789E+02

term 3
-6.8415994E-01
-3.2713645E-01
-2.9096953E+00
-2.8874491E+00
-8.4322094E+00
-5.0734994E+02
-4.3187956E+00
-4.0194954E-02
-3.5295409E-01
-3.6087331E-01
-1.5373242E+01
-2.0079644E+01
-3.7370614E+01
-4.3672735E+01
-8.5171273E+01
-1.3806255E+02
-2.0425681E+02
-2.8244917E+02
-4.2412778E+02
-2.5435854E-04
-3.4525878E-01
-2.7081894E+01
-7.1002797E+01
-1.8682616E+02
-1.3196374E+02
-1.6175762E+02
-2.4269326E+00
-7.5779722E+00
-8.5049998E+02

term 4
1.7982573E-01
8.5151262E-02
8.0881050E-01
7.7784569E-01
2.3261288E+00
1.5774699E+02
1.2025420E+00
1.0477347E-02
9.1185287E-02
9.4102855E-02
4.2787909E+00
5.6247533E+00
1.0581570E+01
1.2395147E+01
2.4227665E+01
3.9328979E+01
5.8224459E+01
8.0584164E+01
1.2107464E+02
2.2566868E-04
8.9991199E-02
7.6530726E+00
2.0183395E+01
5.6039431E+01
3.9427532E+01
4.8455294E+01
6.6701801E-01
2.1026119E+00
2.6370249E+02

B
-4.6650896E-02
-6.8149683E-03
-1.3243872E-01
-1.9764721E-01
-4.1854010E-01
-1.4771511E+00
-1.9909007E-01
1.4344975E-02
-1.1038051E-02
-1.7936010E-02
-6.7661344E-01
-7.6820980E-01
-1.1533376E+00
-1.2778611E+00
-2.0938301E+00
-3.1488845E+00
-4.4328110E+00
-5.9429094E+00
-8.4346593E+00
1.1446798E-02
-1.7551159E-02
-9.3818878E-01
-1.8508109E+00
-1.9950417E+00
-1.6865175E+00
-1.8551041E+00
-1.4980395E-01
-3.7297519E-01
-2.0332395E+00

s
4.4426894E-02
1.6980398E-02
7.4855452E-02
9.1445281E-02
1.3307133E-01
2.4999333E-01
9.1778459E-02
2.4635754E-02
2.1610368E-02
2.7547289E-02
1.6919451E-01
1.8028346E-01
2.2089922E-01
2.3251864E-01
2.9763683E-01
3.6500123E-01
4.3306747E-01
5.0143600E-01
5.9737869E-01
2.2006854E-02
2.7250148E-02
1.9923291E-01
2.7983175E-01
2.9053064E-01
2.6712306E-01
2.8015611E-01
7.9611828E-02
1.2561917E-01
2.9329876E-01

MON 1 (Linear Correlation Method)


mole fraction (xi)
Methane
Ethane
Propane
Butane(s)
Carbon Dioxide
Nitrogen
MON 1 (Linear Correlation
Methane Number

Methane
Nitrogen
Carbon Dioxide
Ethane
Propane
Water (gas)
Hydrogen Sulfide
Hydrogen
Carbon Monoxide
Oxygen
Isobutane
Normal Butane
Isopentane
Normal Pentane
Hexane
Heptane
Octane
Nonane
Decane
Helium
Argon
2,2-Dimethyl Propane
2-Methyl Pentane
3-Methyl Pentane
2,2-Dimethyl Butane
2,3-Dimethyl Butane
Ethylene
Propylene
Methyl Alcohol
Sulfur Dioxide
MON 2 (CARB Method)
Methane Number

0.906724
0.045279
0.00828
0.0026
0.004676
0.031284
127.4
87.8

MON 2 (CARB Method)


HC Ratio
4
0
0
3
2.6667
0
4.0708
0
0
0
2.5
2.5
2.4
2.4
2.3333
2.2857
2.25
2.2222
2.2
0
0
2.4
2.3333
2.3333
2.3333
2.3333
2
2
4
0
sum
124.7
83.5

coefficient
137.78
29.948
-18.193
-167.062
181.233
26.994

HC Ratio * xi
3.62689600
0.00000000
0.00000000
0.13583700
0.02208000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00259250
0.00390750
0.00077040
0.00106320
0.00091700
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
0.00000000
3.79406360

coeff * xi
124.92843272
1.356015492
-0.15063804
-0.4343612
0.847445508
0.844480296

Molar Masses
Methane
Nitrogen
Carbon Dioxide
Ethane
Propane
Water (gas)
Hydrogen Sulfide
Hydrogen
Carbon Monoxide
Oxygen
Isobutane
Normal Butane
Isopentane
Normal Pentane
Hexane
Heptane
Octane
Nonane
Decane
Helium
Argon
2,2-Dimethyl Propane
2-Methyl Pentane
3-Methyl Pentane
2,2-Dimethyl Butane
2,3-Dimethyl Butane
Ethylene
Propylene
Methyl Alcohol
Sulfur Dioxide
Atomic Weights
Hydrogen
Helium
Carbon
Nitrogen
Oxygen
Sulfur
Argon

kg/kg-mol
16.0425
28.0134
44.0095
30.0690
44.0956
18.0153
34.0809
2.0159
28.0101
31.9988
58.1222
58.1222
72.1488
72.1488
86.1754
100.2019
114.2285
128.2551
142.2817
4.0026
39.9480
72.1488
86.1764
86.1764
86.1764
86.1764
28.0532
42.0797
32.0419
64.0638

1.00794
4.0026
12.0107
14.0067
15.9994
32.065
39.948

Enthalpies of Formation at 298.15 kelvins


kJ/mole
Methane
-74.54
Nitrogen
0
Carbon Dioxide
-393.51
Ethane
-83.82
Propane
-104.68
Water (gas)
-241.814
Hydrogen Sulfide
-20.63
Hydrogen
0
Carbon Monoxide
-110.53
Oxygen
0
Isobutane
-134.99
Normal Butane
-125.79
Isopentane
-153.7
Normal Pentane
-146.76
Hexane
-166.92
Heptane
-187.78
Octane
-208.75
Nonane
-228.74
Decane
-249.46
Helium
0
Argon
0
2,2-Dimethyl Propane
-167.9
2-Methyl Pentane
-174.3
3-Methyl Pentane
-172
2,2-Dimethyl Butane
-185.6
2,3-Dimethyl Butane
-177.8
Ethylene
52.47
Propylene
20.41
Methyl Alcohol
-201
Sulfur Dioxide
-296.81

Methane
Nitrogen
Carbon Dioxide
Ethane
Propane
Water (gas)
Hydrogen Sulfide
Hydrogen
Carbon Monoxide
Oxygen
Isobutane
Normal Butane
Isopentane
Normal Pentane
Hexane
Heptane
Octane
Nonane
Decane
Helium
Argon
2,2-Dimethyl Propane
2-Methyl Pentane
3-Methyl Pentane
2,2-Dimethyl Butane
2,3-Dimethyl Butane
Ethylene
Propylene
Methyl Alcohol
Sulfur Dioxide

Stoichiometric Coefficients
Oxygen
Water
-2
2

Carbon Dioxide
1

-3.5
-5

3
4

2
3

-1.5
-0.5
-0.5

1
1
0

0
0
1

-6.5
-6.5
-8
-8
-9.5
-11
-12.5
-14
-15.5

5
5
6
6
7
8
9
10
11

4
4
5
5
6
7
8
9
10

-8
-9.5
-9.5
-9.5
-9.5
-3
-4.5
-1.5

6
7
7
7
7
2
3
2

5
6
6
6
6
2
3
1

Sulfur Dioxide
0

0
0
1
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0
0
0

Equation Constants for the Ideal Gas Heat Capacity Correlation


a
b x 100
Methane
4.1941264
0.35829459
Nitrogen
3.5018867
0.00301590
Carbon Dioxide
4.3257999
0.57757890
Ethane
5.9588285
1.36661730
Propane
8.2430809
2.26461070
Water (gas)
4.0280005
0.03961628
Hydrogen Sulfide
4.0707790
0.11492711
Hydrogen
3.4414503
0.12605524
Carbon Monoxide
3.5025979
0.00582673
Oxygen
3.5204293
0.04298729
Isobutane
10.8169970
3.17722960
Normal Butane
11.0988330
2.91575680
Isopentane
13.2659070
4.14387400
Normal Pentane
13.5383120
3.49188670
Hexane
16.0745150
4.17965310
Heptane
18.5992090
4.93279710
Octane
21.1265290
5.68148970
Nonane
23.6363150
6.54640460
Decane
26.1695740
7.27443580
Helium
2.5000000
0.00000000
Argon
2.5000000
0.00000000
2,2-Dimethyl Propane
13.3987440
4.67786080
2-Methyl Pentane
15.8447200
5.08035470
3-Methyl Pentane
15.6115510
5.05776590
2,2-Dimethyl Butane
15.8028240
4.98705580
2,3-Dimethyl Butane
15.4096700
5.50151490
Ethylene
4.8782970
1.06143470
Propylene
7.2729431
1.82088540
Methyl Alcohol
5.1177910
0.65306439
Sulfur Dioxide
4.6867423
0.43239642

c x 105
1.76836150
0.05114154
-0.50862361
1.72015700
1.78330360
0.27421031
0.44823055
-0.80754203
0.08532127
0.30912462
1.87669950
2.67822360
-0.44459765
4.11040320
4.82740980
5.49265150
6.08923990
5.45373580
6.16707070
0.00000000
0.00000000
-4.05937300
-0.77281151
-1.31167140
-0.56395253
-3.31221940
1.65054910
1.20217140
2.15880560
0.03957661

Methane
Nitrogen
Carbon Dioxide
Ethane
Propane
Water (gas)
Hydrogen Sulfide
Hydrogen
Carbon Monoxide
Oxygen
Isobutane
Normal Butane
Isopentane
Normal Pentane
Hexane
Heptane
Octane
Nonane
Decane
Helium
Argon
2,2-Dimethyl Propane
2-Methyl Pentane
3-Methyl Pentane
2,2-Dimethyl Butane
2,3-Dimethyl Butane
Ethylene
Propylene
Methyl Alcohol

Equation Constants for the 2nd Virial Coefficient


a
b
c
-4.9007801E-01
3.2827956E-03
-8.2081892E-06
-2.2413260E-01
1.5909040E-03
-3.9248102E-06
-1.7276675E+00
1.2802364E-02
-3.4908986E-05
-1.9340481E+00
1.3321546E-02
-3.4642088E-05
-5.0978896E+00
3.7357889E-02
-1.0116519E-04
-2.0149330E+02
1.9037358E+00
-6.0869163E-03
-2.5434289E+00
1.8914054E-02
-5.1814626E-05
-1.1171849E-02
1.9131752E-04
-4.8223780E-07
-2.5021661E-01
1.7351497E-03
-4.2345565E-06
-2.5663170E-01
1.7508016E-03
-4.3295672E-06
-8.9921356E+00
6.7231035E-02
-1.8444003E-04
-1.1403540E+01
8.6905916E-02
-2.4090495E-04
-2.0234239E+01
1.5888141E-01
-4.4835287E-04
-2.3425658E+01
1.8505146E-01
-5.2396238E-04
-4.4762737E+01
3.5888646E-01
-1.0218399E-03
-7.1893811E+01
5.8010141E-01
-1.6564015E-03
-1.0583461E+02
8.5704672E-01
-2.4505652E-03
-1.4573558E+02
1.1834122E+00
-3.3886758E-03
-2.1770439E+02
1.7745515E+00
-5.0884609E-03
1.3159012E-02
-5.8312851E-06
-3.0516593E-09
-2.4623380E-01
1.6762761E-03
-4.1422323E-06
-1.4910420E+01
1.1569245E-01
-3.2491425E-04
-3.7543050E+01
2.9965354E-01
-8.5185402E-04
-8.3256687E+01
7.3447972E-01
-2.2414415E-03
-5.9875080E+01
5.2207091E-01
-1.5832312E-03
-7.2550109E+01
6.3731829E-01
-1.9406824E-03
-1.5539888E+00
1.0959607E-02
-2.9117054E-05
-4.5381793E+00
3.3392376E-02
-9.0916504E-05
-3.3786365E+02
3.1957400E+00
-1.0203849E-02

d
7.4728523E-09
3.5385527E-09
3.3610994E-08
3.2324218E-08
9.6664796E-08
6.5553464E-06
4.9972930E-08
4.3539747E-10
3.7893031E-09
3.9105458E-09
1.7780978E-07
2.3374270E-07
4.3972857E-07
5.1509373E-07
1.0068068E-06
1.6343582E-06
2.4195803E-06
3.3487620E-06
5.0313874E-06
9.3779059E-12
3.7396815E-09
3.1803170E-07
8.3874277E-07
2.3287791E-06
1.6384537E-06
2.0136121E-06
2.7718654E-08
8.7376308E-08
1.0958442E-05

Compressibility of Air at Pb, Tb


B
Z

-0.010253311
0.9995661935

Correlation from AGA Report #8, 2nd Edition

S-ar putea să vă placă și