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K V KHANAPARA
INSERVICE COURSE CHEMISTRY 2014
CLASS: XII
SUBJECT: CHEMISTRY
BLUE PRINT
S.
No
Chapter
VSA
SA I
SA II
VBQ
LA
1
Mark
1
2
Marks
3
Marks
1
4
Marks
5
Marks
M (Q)
Solid State
Solution
5(2)
Electrochemistry
5(2)
Chemical Kinetics
5(2)
Surface Chemistry
P block elements
Coordination Compounds
10
11
12
13
Organic compounds
containing Nitrogen.
4(2)
14
Biomolecules
4(2)
15
Polymers
3(1)
16
3(1)
M(Q)
4(2)
4(2)
3(1)
8(2)
5(1)
3(1)
5(5)
4(1)
4(2)
10(5)
36(12)
4(1)
15(3)
6(2)
70(26)
CLASS:XII
SUBJECT: CHEMISTRY
TIME: 3 HRS
MAX.MARKS: 70
----------------------------------------------------------------------------------------------1. All questions are compulsory.
2. Questions number 1 to 5 are very short answer questions and carry 1 mark each.
3. Questions number 6 to 10 are short answer questions and carry 2 mark each.
4. Questions number11 to 22 are also short answer questions and carry 3 marks each.
5. Questions number 23 is values based and carry 4 marks.
6. Question number 24 to 26 are of long answer questions and carry 5 marks each.
7. Use Log tables, if necessary. Use of calculator is not allowed.
8. There is no overall choice in the paper; however there is an internal choice in one question of 2 marks weightage, one question
(4) Arrange the following in the decreasing order of their basic strength in aqueous solutions:
(5) Glucose or sucrose are soluble in water but cyclohexane or benzene (simple six membered ring compounds) are
insoluble in water. Explain.
(6) A 1.00 molal aqueous solution of trichloroacetic acid (CClCOOH) is heated to its boiling point.
The solution has the boiling point of 100.18 C. Determine the van't Hoff factor for trichloroacetic acid.
(Kb for water = 0.512 K kg mol)
(7) Explain the following
(i) Henry's law about dissolution of a gas in a liquid (ii) Boiling point elevation constant for a solvent
2
2
(8) What do you understand by the 'order of a reaction' ? Identify the reaction order from each of the
following units of reaction rate constant: (i) L1 Mol S-1 (ii) L Mol-1 S1
2
(9)(i) What is meant by coagulation of a colloidal solution? Describe briefly any three methods by which
coagulation of lyophobic sols can be carried out.
2
(10) Name the two groups into which phenomenon of catalysis can be divided. Give an example of each
group with the chemical equation involved.
3
(11) Tungsten crystallizes in body centred cubic unit cell. If the edge of the unit cell is 316.5 pm, what is the
radius of tungsten atom?
3
OR
Iron has a body centred cubic unit cell with a cell dimension of 286.65 pm. The density of iron is
7.874 g cm. Use this information to calculate Avogadro's number. (At. mass of Fe = 55.845 u)
(12) Calculate the amount of KCl which must be added to 1 kg of water so that the freezing point is depressed
by 2K. (Kf for water 1.86 K kg mol-1 )
3
(13)(a) The resistance of a conductivity cell containing 0.001 M KCl solution at 298 K is 1500 . What is the
cell constant if the conductivity of 0.001 M KCl solution at 298 K is 0.146 x 103 S cm-1
3
Q14. For the reaction
2NO(g) + Cl2(g) 2 NOCl(g) the following data were collected. All the measurements were taken at 263 K :
3
3
1x3=3
(i) Co3+ ion is bound to one Cl , one NH3 molecule and two bi dentate ethylene diamine (en) molecules.
(ii) Ni2+ ion is bound to two water molecules and two oxalate ions.
Write the name and magnetic behaviour of each of the above coordination entities.
(At. nos. Co = 27, Ni = 28)
Q18. Answer the following questions:
(i) What is meant by chirality of a compound? Give an example.
(ii) Which one of the following compounds is more easily hydrolyzed by KOH and why?
CH3CHClCH2CH3 or CH3CH2Cl
Q19. Describe the following giving the relevant chemical equation in each case:
(i) Carbylamine reaction (ii) Hofmann's bromamide reaction (iii)Gabrel Phthalamide
Q20. Write any three properties of glucose which cannot be explained by the open chain structure of
glucose molecule.
Q21.(a) Define the term, 'homopolymerisation' giving an example.
(b) Draw the structure of the monomer for each of the following polymers: (i) Nylon 6 (ii) Polypropene
3
3
Q22 What are the following substances? Give one example of each one of them.
3
3
3
(i) P4 + SO2Cl2
(ii) XeF6 + H2O
(b) Predict the shape and the asked angle (900 or more or less) in each of the following cases:
(i) SO32- and angle O-S-O
(ii) ClF3and the angle F Cl F
(iii) XeF2 and the angle F Xe F
OR
(a) An organic compound A with molecular formula C5H8O2 is reduced to n-pentane on
treatment with Zn-Hg/HCl.
A forms a dioxime with hydroxylamine and gives a positive iodoform test and Tollens
test. Identify
the compound A and deduce its structure.
(b) Write the chemical equations for the following conversion:
(i) Ethyl benzene to benzoic acid
(ii) Acetaldehyde to 3-hydroxy butanal
(iii)
Acetone
to
propan-2-ol
2+3=5
Q25. (a) Complete the following chemical equations:
Q26. (a) Illustrate the following name reactions giving suitable example in each case:
(a) Illustrate the following reactions giving a suitable example for each.
(i) Cross aldol condensation (ii) Decarboxylation
(b) Give simple tests to distinguish between the following pairs of compounds
(i) Pentan-2-one and Pentan-3-one (ii) Benzaldehyde and Acetophenone (iii) Phenol and Benzoic acid
CLASS:XII
SUBJECT: CHEMISTRY
Marking Scheme
CLASS:XII
SUBJECT: CHEMISTRY
Marking Scheme
SNo.
1
Marks
1
2
3
4
Prop-1-ene-2,3 diol
5
6
Due to H- bonding
1
2
(a) (i) The Partial pressure of the gas above the liquid is directly proportional
to the mole fraction of the gas dissolved in the liquid.
(ii) Boiling Point Elevation Constant. It is equal to elevation in boiling
point of 1molal solution, i.e., 1 mole of solute is dissolved in 1 kg of
solvent. (or mathematical expression)
The sum of powers of the concentration of the reactants in the rate law expression
is called the order of that chemical reaction / r= k[A] x[B]y
Order =x+y
(i) zero order
(ii) second order
The process of settling of colloidal particles is called coagulation or precipitation
of the sol.
(i) By Electrophoresis / The collidal particles move towards oppositely charged
electrodes.
(ii) By mixing two oppositely charged sols
(iii) By addition of electrolytes / When excess of an electrolyte is added the coll- , ,
oidal particles are precipitated.
10
11
1
1
1
+1/2
2
r=137 pm
OR
12
13
14
15
16
17
(a) By hydrometallurgy
(i) Ability of Nickel to form volatile compound which can decompose on further
heating.
(ii) Different components of a mixture are differently adsorbed on an adsorbent
(or described in any other appropriate manner)
(i) Mole fraction is the ratio of number of moles of one component to the total
number of moles in a mixture (or mathematical expression)
(ii) Two solutions having same osmotic pressure at a given temperature are called
Isotonic Solutions.
Ideal Solution:-The solution which obeys Raoults law under all conditions is known as an
ideal solution.
(i) [Co(en)2(NH3)Cl
: amminechloridobis-(ethane-1,2-diamine) cobalt(III) ++
diamagnetic
(ii) [Ni(C2O4)2(H2O)]2: diaquadioxalatonickelate(II), ++
18
paramagnetic
The objects which are non superimposable on their mirror image are said to
be chiral and this property is known as chirality
eg. Butan-2-ol
CH3CHClCH2CH3 because it will form secondary carbocation which is more stable (SN 1mechanism)
19
(1)
20
21
3
3
22
(i) Tranquilizers are chemical compounds used for the treatment of stress and
mild or even severe mental diseases. +
eg. equanil/meprobamate/veronal (or any one correct example)
(ii) Food preservatives: are the compounds which prevent spoilage of food
due to microbial growth. eg: sodium benzoate, vinegar +
(or any one correct example)
(iii) Synthetic Detergents are cleansing agents which have all the properties of
soap but which actually do not contain any soap +
eg: Sodium Lauryl sulphate. (or any one correct example)
23
Pyramidal or
o
24
OR
(a) A is a straight chain organic compound with carbonyl functional group.
CH3CO-
group
1/2
1/2
(b)
(i)
1
n-propyl
benzene
to
benzoic
acid
2523. (i)2,2-Bis(4-chlorophenyl)-1,1,1-trichloroethane
mark
(ii)Plants growth improved because it is a very effective insecticide but aquatic
life got destroyed as it is toxic to fish.
1 mark
(iii)We should not used insecticide excessively by keeping environmental
concern in mind.
1 mark
OR
Five reactions of one mark each,
26
OR