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UiO-66 Zirconium Building Bricks for Stable

Metal Organic Frameworks


metals inorganics organometallics catalysts ligands custom synthesis cGMP facilities nanomaterials

CatalogNo.401105
Zirconium1,4dicarboxybenzeneMOF(UiO66)
StructureofUiO66
TheSpecialNatureofUiO66
ThestabilityofMOFsislargelydeterminedbythestructureoftheinorganic
brickandthenatureofthechemicalbondsitformswiththelinker.Todate,
most MOFs have exhibited weak thermal, chemical, and mechanical
stability,whichhaslimitedtheiruseinlargescaleindustrialapplications.

UiO66 (and isoreticular UiO67 and UiO68), however, is a


zirconiumbased MOF with very high surface area (1147m2/g) and
unprecedentedstability.

DevelopedbyProf.KarlPetterLillerudoftheDepartmentofChemistryat
theUniversityofOslo,UiO66iscomprisedofZr6O4(OH)4octahedrathatare
12fold connected to adjacent octahedra through a 1,4benzene
dicarboxylate (BDC) linker, resulting in a highlyp a c k e d f c c
structure.

TheZrObondsformedbetweentheclusterandcarboxylateligandsisbelievedtobethesourceofincreasedstabilityofZrbased
MOFs. Specifically, the combination of strong ZrObonds andtheability ofthe inner Zr6cluster to rearrange reversibly upon
removaloradditionof3OHgroupswithoutanychangesintheconnectingcarboxylatesarethoughttocontributetothegreater
stabilityofUiO66.

KeyPropertiesofUiO66
TheparticlesizeofUiO66is0.250.35mm,andtheparticleshave
SEMimageofUiO66
clearlyvisiblefacets.

UiO66N2adsorptionat77K

Visit www.strem.com for new product information and searchable catalog.


Strem Chemicals, Inc. Strem Chemicals, Inc. Strem Chemicals, Inc. Strem Chemicals UK Ltd.
7 Mulliken Way 15, rue de lAtome Postfach 1215 Newton Hall, Town Street
Newburyport, MA 01950-4098 Zone Industrielle 77672 KEHL Newton, Cambridge
U.S.A. 67800 BISCHHEIM France Germany England CB22 7ZE
Tel.: (978) 499-1600 Tel.: (33) 03 88 62 52 60 Telefon: 0 78 51/ 7 58 79 Tel.: 0845 643 7263
Fax: (978) 465-3104 Fax: (33) 03 88 62 26 81 Email: info.europe@strem.com Fax: 0845 643 7362
Email: info@.com strem Email: info.europe@strem.com Email: enquirires@strem.co.uk
UiO66_0714
-2-
KeyPropertiesofUiO66

ThespecificsurfaceareaofUiO66afterheatingto300Cis1147m2/g.

TheporesizeoftheUiO66is6.ThatmeansthatamoleculethesizeoffullymethylatedbenzenecanentertheUiO66structure.

ThetoughnessofUiO66isdemonstratedinitsphysicalproperties:
Stableuponwashinginboilingwaterandafterheatinginairto300Cfor6h,
Decompositionabove500C,
Resistancetomostchemicals,and
Retentionofcrystallinityevenafterexposureto10tons/cm2ofexternalpressure.

PXRDofUiO66afterheatinginairat300Cfor6hours



















ThermogravimetricresponseofUiO66duringheatinginair

SoldunderlicensefromInven2AS
forresearchpurposesonly.
EP09738396andUS12/989,641.

References:
1.J.Am.Chem.Soc.,2008,139,13850.
2.J.Phys.Chem.Lett.,2013,4(6),925.
3.ChemistryAnAsianJournal2011,6(12),3270.
4. Chem.Mater.,2011,23(7),1700.

Visit www.strem.com for new product information and searchable catalog.


Strem Chemicals, Inc. Strem Chemicals, Inc. Strem Chemicals, Inc. Strem Chemicals UK, Ltd.
7 Mulliken Way 15, rue de lAtome Postfach 1215 Newton Hall, Town Street
Newburyport, MA 01950-4098 Zone Industrielle 77672 KEHL Newton, Cambridge
U.S.A. 67800 BISCHHEIM France Germany England CB22 7ZE
Tel.: (978) 499-1600 Tel.: (33) 03 88 62 52 60 Telefon: 0 78 51/ 7 58 79 Tel.: 0845 643 7263
Fax: (978) 465-3104 Fax: (33) 03 88 62 26 81 Email: info.europe@strem.com Fax: 0845 643 7362
Email: info@.com strem Email: info.europe@strem.com Email: enquirires@strem.co.uk
UiO66_0613

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