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CatalogNo.401105
Zirconium1,4dicarboxybenzeneMOF(UiO66)
StructureofUiO66
TheSpecialNatureofUiO66
ThestabilityofMOFsislargelydeterminedbythestructureoftheinorganic
brickandthenatureofthechemicalbondsitformswiththelinker.Todate,
most MOFs have exhibited weak thermal, chemical, and mechanical
stability,whichhaslimitedtheiruseinlargescaleindustrialapplications.
DevelopedbyProf.KarlPetterLillerudoftheDepartmentofChemistryat
theUniversityofOslo,UiO66iscomprisedofZr6O4(OH)4octahedrathatare
12fold connected to adjacent octahedra through a 1,4benzene
dicarboxylate (BDC) linker, resulting in a highlyp a c k e d f c c
structure.
TheZrObondsformedbetweentheclusterandcarboxylateligandsisbelievedtobethesourceofincreasedstabilityofZrbased
MOFs. Specifically, the combination of strong ZrObonds andtheability ofthe inner Zr6cluster to rearrange reversibly upon
removaloradditionof3OHgroupswithoutanychangesintheconnectingcarboxylatesarethoughttocontributetothegreater
stabilityofUiO66.
KeyPropertiesofUiO66
TheparticlesizeofUiO66is0.250.35mm,andtheparticleshave
SEMimageofUiO66
clearlyvisiblefacets.
UiO66N2adsorptionat77K
ThespecificsurfaceareaofUiO66afterheatingto300Cis1147m2/g.
TheporesizeoftheUiO66is6.ThatmeansthatamoleculethesizeoffullymethylatedbenzenecanentertheUiO66structure.
ThetoughnessofUiO66isdemonstratedinitsphysicalproperties:
Stableuponwashinginboilingwaterandafterheatinginairto300Cfor6h,
Decompositionabove500C,
Resistancetomostchemicals,and
Retentionofcrystallinityevenafterexposureto10tons/cm2ofexternalpressure.
PXRDofUiO66afterheatinginairat300Cfor6hours
ThermogravimetricresponseofUiO66duringheatinginair
SoldunderlicensefromInven2AS
forresearchpurposesonly.
EP09738396andUS12/989,641.
References:
1.J.Am.Chem.Soc.,2008,139,13850.
2.J.Phys.Chem.Lett.,2013,4(6),925.
3.ChemistryAnAsianJournal2011,6(12),3270.
4. Chem.Mater.,2011,23(7),1700.