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UNIT8
THE d- AND f-BLOCK ELEMENTS
4. Benedict Solution Alkaline Solution cupric ions complexed with citrate ions.
5. Blue Vitriol CuSO4 . 5 H2O
(Blue Stone)
6. Bayers Reagent Cold alkaline KMnO4 Solution
(Lemon Chrome)
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(Hara Kasis)
24. Ferro Chrome Fe + 2 Cr + 4 CO
25. Guigrets green Cr2O3 . 2 H2O
26. Haematite Fe2O3
(Red Haematite)
27. Horn Silver AgCl
(Chloragynite)
28. Lucas reagent Conc. HCl + anhydrous ZnCl2
29. Lunar Caustic AgNO3
30. Lithopone ZnS + BaSO4
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1 MARK QUESTIONS
Q. 1. What is the equivalent wt. of KMnO4 in :
in Ni in Pt
Ni2+ is stable than Pt+2.
IE1 + IE2 + IE3 + IE4 < IE1 + IE2 + IE3 + IE4
in Pt4+ in Ni4+
Pt4+ is stable, K2PtCl6 is well known compound.
Au + 4 H+ + 4 Cl + NO3 AuCl4 + NO + 2 H2O
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Pt + 6 Cl PtCl62 + 4 e 3 (oxidation)
4 e + 4 H+ + NO3 NO + 2 H2O 4 (reduction)
18 Cl + 3 Pt + 16 H+ + 4 NO3 3 PtCl62 + 4 NO + 8 H2O
Q. 6. (a) CrO is basic but Cr2O3 is amphoteric ?
CrO Cr2O3
O. N. +2 +3
Ans. (a) Higher the oxidation state higher the acidity. In lower oxidation state some of valence e
of the metal atom are not involved in bonding, can donate e and behave as base. In
higher oxidation state e are involved in bonding and are not available, rather it can
accept e and behave as an acid.
(b) Why the following is the order :
V2O3 V2O4 V2O5
O. N. +3 +4 +5
Basicity.
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Ans. Basicity
Oxidation No.
TiIV = 3 d
(b)
Q. 12. A wellknown orange crystalline compound (A) when burnt impart violet colour to flame.
(A) on treating (B) and conc. H2SO4 gives red gas (C) which gives red yellow solution (D)
with alkaline water. (D) on treating with acetic acid and lead acetate gives yellow p. pt.
(E). (B) sublimes on heating. Also on heating (B) with NaOH gas (F) is formed which
gives white fumes with HCl. What are (A) to (F) ?
Ans. (i) K2Cr2O7 + 4 NH4Cl + 3 H2SO4 K2SO4 +
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Cr2+ = 3 d4 4 s0 Mn3+ = 3 d4 4 s0
Cr3+ = 3 d3 4 s0
Cr3+ = 3 d3 4 s0 d5
Ans. (a) The ability of oxygen to form multiple bonds to metals, explain its superiority to show
higher oxidation state with metal.
(b) Positive E value (+ O 34 Volt) accounts for its inability to liberate H2 from acids. The
high energy to transform Cu (s) to Cu2+ (aq) is not balanced by its Hydration enthalpy.
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blue solution
COCl2 in solution is [CO (H2O)6]2+
blue pink
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