Q1. At which of the following pressure, water will boil at 101.5C?

(A) 76 cm of Hg (B) 76 mm of Hg (C*) > 76 cm of Hg (D) < 76 cm of Hg

Q2. Which of the following aqueous solution will show maximum vapour pressure at 300
K?
(A) 1 M NaCl (B) 1 M CaCl2 (C) 1 M AlCl3 (D*)1 M C12H22O11
Q3. The vant Hoff factor for a dilute aqueous solution of glucose is:
(A) Zero (B*) 1.0 (C) 1.5 (D) 2.0
Q4. Which of the following colligative properties is not associated with molality?
(A) Lowering of vapour pressure (B*) Osmotic pressure
(C) Depression in freeaing point (D) Elevation in boiling point
Q5. The correct relationship between the boiling points of very dilute solution of AlCl 3
(T1K) and CaCl2(T2K) having the same molar concentration is:
(A) T1 = T2 (B*) T1 > T2 (C) T2 > T1 (D) T2 T1
Q6. Elevation in boiling point of a molar glucose solution (d = 1.2 g/ml) is:
(A*) 0.98 Kb (B) Kb (C) 1.20 Kb (D) 1.02 Kb
Q7. What will be the molecular weight of NaCl determined exprimentally from elevation
of boiling point or depression in freezing point method?
(A*) < 58.5 (B) > 58.5 (C) = 58.5 (D) None of these
Q8. The value of K1 for water is 1.86C mole1 kg, calculated for glucose solution. The
value of K1 for water, calcuated for NaCl solution will be:
(A*) = 1.86 (B) < 1.86 (C) > 1.86 (D) Zero
Q9. Acetic acid in benzene solution forms dimmer due to intermolecular H-bonding. Vant
Hoff factor for acetic acid in benzene is:
(A) i = 1 (B) i > 1 (C*) i < 1 (D) data
insufficient
Q10. Which of the following solution will have least vapour pressure?
(A) 0.1 M BaCl2 (B) 0.1 M urea (C) 0.1 M Na2SO4 (D*) 0.1 M
Na3PO4
Q11. The values of observed and calculated molecular weights of silver nitrate are 92.64
and 170 respectively. The degree of dissociation of silver nitrate would be:
(A) 60% (B*) 83.5% (C) 46.7% (D) 60.23%
Q12. The density of 1 M solution of a non-electrolyte C6H12O6 is 1.18 g/ml. If K1 of H2O is
1.86C mol1 kg, then solution freezes at:
(A) 1.58C (B*) 1.86C (C) 3.16C (D) 1.86C
Q13. An aqueous solution of urea has freezing point of 0.52C. If molarity and molality
are same and K1 for H2O is 1.86 K molality1, the elevation in boiling point of solution
would be (Given: Kb for H2O is 0.52 K molality1.)
(A*) 0.1456 K (B) 0.52 K (C) 1.86 K (D) 0.2912 K
Q14. A substance (A) is completely trimerised on dissolution in solvent B. The vant Hoff
factor for such a change is:
(A) 1 (B) 2 (C) 3 (D*) 1/3

Q15. The boiling point of an aqueous solution of a non-volatile solute is 100.15C . What is
the freezing point of an aqueous solution obtained by diluting the above solution with
an equal volume of water? The values of Kb and K1 for water are 0.512C and 1.86C
molalilty1.
(A) 0.544C (B) 0.512C (C*) 0.272C (D) 1.86C
Q16. The vapour pressure of a solution of a non-volatile electrolyte B in a solvent A is 95%
of the vapour pressure of the solvent at the same temperature. If the molecular weight
of the solvent is 0.3 times the molecular weight of solute, the weight of solute, the
weight ratio of the solvent and solute are :
(A) 0.15 (B*) 5.7 (C) 0.2 (D) 4.0
Q17. For CrCl3.xNH3, elevation in boiling point of one molal soltuion is double than that of
one molala urea solution, hence x would be (complex is 100% ionized).
(A*) 4 (B) 5 (C) 6 (D) None of thes
Q18. For an ideal binary liquid solution with > , which of the following relation between
XA (mole fraction of A in liquid phase) and YA (mole fraction of A in vapour phase) is
correct?
(A) XA = YA (B) XA > YA (C) XA < YA (D*) <
Q19. A complex contains Pt (IV) and has vant Hoff factor 3 in aqueous solution. The
complex is :
(A) K2[PtCl4] (B*) K2[PtCl3] (C) K3[PtCl5] (D) k[PtCl3]
Q20. In cold countries, ethylene glycol is added to water in the radiators of cars during
winters.It result in:
(A) lowering of boiling point (B) reduced viscosity
(C) reduced specific heat (D*) lowering of freezing point
Q21. A liquid is kept in a closed vessel. If a glass plate (of negligible mass) with a small
hole is kept on top of the liquid surface, then the vapour of the liquid in the vessel.
(A) is more than what would be if the glass plate was removed
(B*) is same as what would be if the glass plate was removed
(C) is less than what would be if the glass plate was removed.
(D) cannot be predicted
Q22. At a given tempreture, total vapour pressure in Torr of a mixture of volatile
components A and B is given by
PTotal = 120 75XB
hence, vapour pressure of pure A an dB respectively (in Torr) are
(A) 120,75 (B) 120,195 (C*) 120,45 (D) 75,45
Q23. Maximum freezing point will be for the complex salt solution of (assume equal
ionization of all complex salts)
(A) 1 M [Fe(H2O)6]Cl3 (B) 1 M [Fe(H2O)5Cl]Cl2H2O
(C) 1 M [Fe(H2O)4Cl2]Cl.2H2O (D*) 1 M [Fe(H2O)3.3H2O
Q24. Glucose is added to 1 litre water to such an extent that becomes equal to 1/1000, the
weight of glucose added will be:
(A) 0.32 g (B) 0.42 g (C) 0.22 g (D*) 0.18 g
Q25. The vapour pressure of a dilute aqueous solution of glucose is 750 mm of Hg at 373
K. The mole fraction of solute will be :
(A) (B) (C) (D*)
Q26. Assuming each salt to be 90% dissociated, which of the following will have highest
boiling point?
(A*) Decimolar Al2(SO4)3 (B) Decimolar BaCl2
(C) Decimolar Na2SO4 (D) A solution obtained by mixing equal
volumes of (b) and (c).
Q27. On mixing 10 ml of carbon tetrachloride witg 10 ml of benzene, the total volume of
the solution would be:
 (A) > 20 ml (B) < 20 ml (C*) = 20 ml (D) cannot be
predicted
Q28. At 25C, the vapour pressure of pure methyl alcohol is 92 Torr. Mole fraction of
CH3OH in a solution in which vapour pressure of CH3OH is 23 Torr at 25C is:
(A*) 0.25 (B) 0.75 (C) 0.50 (D) 0.66
Q29. The vapour pressure of pure liquid solvent A is 0.80 atm. When a non-volatile
substance B is added to the solvent, its vapour pressure reduces to 0.60 atm. Mole
fraction of the component B in the solution is:
(A) 0.50 (B*) 0.25 (C) 0.75 (D) 0.40
Q30. At 40C, the vapour pressure (in Torr) of methyl and ethyl alcohol solutions is
represented by
PTotal = 119XA + 135 where XA is the mole fraction of methyl alochol. The value of at
limxA 0 and at limXB 0 are
(A*) 135 Torr & 254 Torr (B) 135 Torr & 230 Torr
(C) 119 Torr & 135 Torr (D) 140 Torr & 135 Torr
Q31. A solution of one mole of benzoic acid in 15 moles of benzene produces a relative
lowering of vapour pressure equal to 1/31. The molar mass of benzoic acid in benzene
is:
(A) 122 (B*) 244 (C) 61 (D) 189
Q32. 15 g of solute in 100 g water makes a solution freeze at 1C. 30 g of a solute in 100
g of water will give a depression in freezing point equal to:
(A) 2C (B) 0.5C (C*) 2C (D) 1C
Q33. The exact mathematical expression of Raoults law is:
P Ps n P Ps N P Ps n P Ps
(A) P = N (B) P = n (C*)
Ps = N (D) P = n N
Q34. For the given electrolyte AxBy, the degree of dissociation can be given as
1 i
(A) = x y 1 (B*) i = (1 ) + x + y
i 1
(C) = 1 x y (D) All of these
Q35. A complex of iron and cyanide ions is 100% ionized at 1 molal. If its elevation in
boiling point is 2.08, then the complex is (Given : Kb = 0.52C mol1 kg).
(A) [Fe|| (CN)6]3 (B*) K3[Fe|||(CN)6]
(C) K4[Fe||(CN)6] (D) [Fe|||(CN)6]2
Q36. A mixture contains 1 mole of volatile liquid A [ = 100 mm Hg] and 3 moles of volatile
liquid B(= 80 mm Hg).If solution behaves ideally, the total vapour pressure of the
distillate is:
(A) 85 mm Hg (B*) 85.88 mm Hg (C) 90 mm Hg (D) 92 mm Hg
Q37. Depression in freezing point of 0.01 molal aqueous CH 3COOH solution is 0.02046. 1
molal urea solution freezes at 1.86C. Assuming molality of solution equal to its
molarity, pH of CH3COOH solution would be:
(A) 2 (B*) 3 (C) 3.2 (D) 4.2
Q38. Mole fraction of A vapours above the solution in mixture of A and B(X A = 0.4) will be
[Given: = 100 mm Hg and = 200 mm Hg]
(A) 0.4 (B) 0.8 (C*) 0.25 (D) none of these
Q39. 12.2 g of benzoic acid (M = 122) in 100 g benzene has depression in freezing point
2.6C. If there is 100% association, number of molecules of benzoic acid in
associated state would be (Given : Kf = 5.2C kg/mol).
(A) 1 (B*) 2 (C) 3 (D) 4
Q40. Surface tension of water is 73 dyn cm at 20C. If the surface area is increaed by 0.1
1

m2, work done would be:

(A) 73 joule (B) 730 joule (C*) 73 104 joule (D) 0.073 joule
Q41. A liquid is in equilibrium with its vapours at its boiling point. On average, the
molecules in the two phases have equal :
(A) intermolecular forces (B) potential energy
(C) total energy (D*) kinetic energy
Q42. According to Raoults law the relative decrease in the solvent vapour pressure over
the solution is equal to:
(A) the mole fraction of the solvent (B*) the mole fraction of the solute
(C) the number of moles of the solute (D) none of the above
Q43. Choose incorrect statement for a binary solution which show negative deviation from
Raoults law:
(A) The negative deviation from linearity diminishes and tends to zero as the
concentration of the solution component approaches unity.
(B) When solutions form, their volumes are smaller than the sum of the volumes of
their components.
(C) Heat is released during the formation of the solution.
(D*) Heat is evolved during the formation of the solution.
Q44. The degree of dissociation () of a weak electrolyte AxBy is related to vant Hoff
factor (i) by the expression
i 1 i 1

(A*)
( x y 1) (B)
( x y 1)
x y 1 x y 1

(C) i 1 (D) i 1
Q45. When mercuric iodide is added to an aqueous solution of KI, the :
(A*) freezing point is raised (B) freezing point is lowered
(C) boiling point does not change (D) freezing point does not change
Q46. The normality of orthophosphoric acid having purity of 70% by wt. (sp. gr. 1.54)
would be :
(A) 11 N (B) 22 N (C*) 33 N (D) 44 N
Q47. If in solvent, n simple molecules of solute combine to form an associated molecule, u
is degree of association, the vant Hoffs factor i is equal to :
1 1 x nx
(A) 1 nx (B) 1
x x
1 x 1 x
n n
(C*) 1 (D) 1
Q48. Which of the following solutions has maximum freezing point, water being the
solvent in each case:
(A) 0.9 M NaCl (B*) 0.3 M CaCl2
(C) 1.2 M sugar solution (D) 0.3 M Al2(SO4)3
Q49. Vant Hoff factor of nitration of benzene in presence of H2SO4 and HNO3 is almost :
(A) 1 (B) 2 (C) 3 (D*) 4
Q50. 0.01 m aqueous solution of K3[Fe(CN)6] freezes at 0.062C. What is the apparent %
of dissociations:
(A) 72% (B) 88% (C*) 78% (D) 56%
Q51. Two liquids A and B have vapour pressure in the ratio : = 1 : 2 at a certain
temperature. Suppose that we have an ideal solution of A and B in the mole fraction
ratio A : B = 1 : 2, the mole % of A in the vapour in equilibrium with the solution at
the given temperature is :
(A*) 20 (B) 25 (C) 35 (D) 75
Q52. The elements X and Y form two different binary compounds XY 2 and XY4. When
dissolved in 20 g of CS2 solvent, 1 g of XY 2 lowers the freezing point by 2.5C,
whereas 1 g of XY4 lowers the freezing point by 1.5C. The molal depression constant
for CS2 is 5. The atomic mass of element Y will be :
(A) 42.64 (B) 64.42 (C*) 33.34 (D) 12.8
Q53. Mol fraction of the component A in vapour phase is x1 and mol fraction of component
A in liquid mixture is x2 then (pA0 = vapour pressure of pure A; pB0 = vapour pressure
of pure B), then total vapour pressure of the liquid mixture is :
(A) (B) (C) (D)
Q54. Which of the following solution pairs can be separated by fractional distillation?
(A) Water HNO3 (B) Water HCl (C) Benzenetoluene (D) C2H5OH
water
Q55. Pressure cooker reduces cooking time because :
(A) the heat is more evenly distributed inside the cooker
(B) a large flame is used
(C) boiling point of water is elevated
(D) whole matter is converted into steam
Q56. An electrolyte A gives 3 ions and B is nonelectrolyte. If 0.1 M solution of B
produces an osmotic pressure P, then 0.05 M solution of A will produce an osmotic
pressure, assuming that the electrolyte is completely ionised :
(A) 1.5 P (B) P (C) 0.5 P (D) 0.75 P
Q57. The freezing point of equimolal aqueous solution will be heighest for :
(A) C6H5NH3+Cl (B) Ca(NO3)2 (C) La(NO3)3 (D) C6H12O6
(glucose)
Q58. The molal elevation constant of water is 0.51. The boiling point of 0.1 molal aqueous NaCl solution is
nearly :
(A) 100.05C (B) 100.1C (C) 100.2C (D) 101.0C
Q59. The van't Hoff factor of a 0.005 M aquesous solution of KCl is 1.95. The degree of
ionisation of KCl is:
(A) 0.95 (B) 0.97 (C) 0.94 (D) 0.96
Q60. The molecular weight of benzoic acid in benzene as determined by depression in
freezing point method corresponds to :
(A) Ionisation of benzoic acid (B) Dimerization of benzoic acid
(C) Trimerization of benzoic acid (D) Solvation of benzoic acid