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EXCELLENCE
DPT-1:
3. If the ionic radii of K+ and F are nearly same i.e. 1.34 A0 , then the atomic radii of K and
F respectively are
a) 1.34 A0 , 1.34A0 b)0.72 A0 , 1.96A0 c) 1.96 A0 , 0.72 A0 d) 1.96 A0 , 1.34A0
4. The first ionisation potentials of four consecutive elements present in the third period of
the periodic table are 5.98 eV, 8.15 eV, 11.0 eV and 10.4 eV respectively. Which one of the
following is the first ionisation potential of phosphorus (in eV) ?
a) 5.98 b) 8.15 c) 10.4 d) 11.0
5. For four elements the IP2 curve is shown. In the graph the elements represented by A, B, C
and D are
D
IP2 B
A C
Atomic no
7. I.P. and E.A of Cl are 13.0ev and 4.0 ev respectively E.N of Cl will be
a) 4.03 b) 2.5 c) 3.5 d) 3.03
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12. The strongest oxiding agent and the strongest reducing agent (in aqueous solution) are
a) Cs, F b) F, Cs c) F, Li d) F, O
13. Covalency of P in P4 is
a) 1 b) 2 c) 3 d) 4
X Where X is
% ionic character
1 2 3
EN difference
a) 25 b) 35 c) 50 d)
75
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17. The total energy holding the ion pair in the crystal can be calculated by using the formula
(N = Avagadro Number)
AZ +Z - e2 Be2 AZ +Z - e 2 Be 2
-N +N n -N + n
r r r r
a) b)
+ - 2
AZ Z e B AZ +Z - e 2 NBe 2
- +n - + n
r r r r
c) d)
18. Set I (Position of ion in the unit cell) Set II (No. unit cells sharing the ion)
1) Body centre A) 8
2) Face centre B) 4
3) Edge of a face C) 2
4) Corner D) 1
Correct match is
1 2 3 4 1 2 3 4
a) D C B A b) D B C A
c) D A B C d) D C A B
19. Statement I : Glucose is a polar covalent substance hence soluble in water.
Statement II : Iodine is a non polar covalent substance hence soluble in C6H6.
Statement III : Camphor is soluble in CCl4.
Statement IV : Fructose is Insoluble in C2H5OH.
Correct statement is / are
a) Only I, II & III b) Only I, III & IV c) I, IV only d) All
20. According to VBT, the expected bond angles in NH3 and H2O respectively are
a) 1070, 900 b) 900, 1040.30| c) 1070, 1040.30| d) 900, 900
21. The formal charge of second nitrogen in the following resonance structure is
N(1) N(2) O
a) 2 b) 0 c) 1 d) +1
22. In the following pair of species the central atom undergoes dsp 2 hybridisation and the
shape of the species is square planar
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DPT- 2:
I 3-
1. The shape of ion is
a) linear b) planar tringle c) tetrahedral d) angular
2. The inter atomic distances of H2 and Cl2 molecule are 0.74A0 and 1.98A0 respectively . The
bond length of HCl is
a) 2.72A0 b) 2.48A0 c) 1.36A0 d) 1.24 A0
3. Average bond energy of C H bond is 416 kJ/mole which of the following is correct
CH 4 + 416 Kj C + 2 H 2 CH 4 C + 4 H + 416 KJ
a) b)
CH 4 +1664 KJ C + 4 H CH 4 C + 4 H +1664 KJ
c) d)
4. The bond angle that would result maximum dipolement for the triatomic molecule XY2, is
a) 900 b) 1200 c) 1500 d) 1800
5. The percentage of ionic character is 12.33 % Bond length is 1.25A0 , the dipole moment is
a) 1D b) 2.2D c) 0.74D d) 0.1D
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p* p s 2 Pz s * 2 Pz
a) b) c) d)
11. 0.5 gm of an organic compound on combustion produced some gaseous products, which
were passed into caustic potash solution. The increase in weight of potash solution was
found to be 1.5 gms. The percentage of carbon in the compound is nearly.
a) 82 % b) 40 % c) 60 % d) 75 %
14. In acidic medium, the number of moles of ferrous oxalate (FeC2O4) oxidised by one mole
of each KMnO4 and K2Cr2O7 are respectively x and y. The relation between x and y is
a) x = y b) x < y c) x > y d) x + y = 1
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17. 0.2 mole of KMnO4 in acid solution oxidises 0.5 mole of AO2 to An+. Here n is
a) 1 b) 3 c) 5 d) 7
18. Four grams of hydrocarbon (CxHy) on complete combustion gave 12 grams of CO2. What
is the empirical formula of the hydrocarbon ?
a) CH3 b) C4H9 c) CH d) C3H8
19. A mixture of Mg metal and Magnesia weighing 20 gm when treated with HCl produced
4.48 litre of H2 at S.T.P. then what is weight percent of Mg in the mixture?
a) 50% b) 64% c) 36% d) 24%
20. In the dichromate titrations the end point is recognised by the formation of ---------
colouration in the presence of indicator -------------.
a) Intense blue , starch solution b) Pale pink , self indicator
c) pale pink , methyl orange d) Intense blue, diphenyl amine
21. Assertion (A) : Boiling point of water is greater than that of hydrogen fluoride
Reason (R) : Molecular weight of water is 18 and that of hydrogen fluoride is 20
a) Both A and R are true, and R is correct explanation of A
b) Both A and R are true, and R is not the correct explanation of A
c) A is true but R is falsed) A is false but R is true
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24. Assertion (A) : Para hydroxy benzaldehyde has a lower boiling point than ortho hydroxy
benzaldehyde.
Reason (R): Ortho hydroxybenzaldehyde has intramolecular hydrogen bonding.
a) (A) and (R) are true and (R) is the correct explanation of (A).
b) (A) and (R) are true but (R) is not the correct explanation of (A).
c) (A) true, (R) false d) (A) false, (R) true
25. Assertion (A) : In a redox reaction, the oxidation number of oxidant decreases while that
of reductant in creases
Reason ( R) : Oxidant gains electron (s) and reductant loses electron (s)
a) Both A and R are correct. R is the correct explanation of A.
b) Both A and R are correct. R is the not correct explanation of A.
c) A is true, but R is false d) A is false, but R is true
26. Assertion (A) : The equivalent weights of nitric acid and crystalline oxalic acid are same
Reason (R) : The basicity of nitric acid and oxalic acid are same
The correct answer is
a) A and R are true and R is the correct explanation of A.
b) A and R are true and R is not the correct explanation of A.
c) A is true, R is false. d) A is false, R is true.
HNO
3
27. Assertion (A) : acts as an oxidising agent, but not as reducing agent.
Reason (R) : Compound of an element, where the element is in its maximum oxidation
state undergo reduction, but can not undergo oxidation.
a) A & R are correct. R is the correct explanation of A
b) A & R are correct. R is not the correct explanation of A
c) A is true, R is false d) A is false, R is true
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DPT-3:
1. 0.5 mole of HCl is allowed to react with 0.5 mole of Sodium Carbonate the number of mole
of Carbondioxide formed is
1) 0.25 2) 0.5 3) 1.0 4) 1.25
2. 10 litres of H2 and 20 litres of Cl2 are mixed and exploded. The volume of the mixture will
be
3) 10 litres of Cl2 & 20 litres of HCl 4)10 litres of Cl2 & 30 litres of HCl
4. If one litre of a gas at S.T.P weights 1.165gm. Then the gas may be
1) Acetylene 2) CO 3) Oxygen 4)Methane
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5. A gas mixture containing 7g of CO & 11 g of CO2 was passed over and hot coke. Then the
volume of gas mixture at STP is
1) 22.4 lit 2) 16.8 lit 3) 11.2 lit 4) 5.6 lit
Reason (R) : In Phosphorus acid molecule three hydrogen atoms are attached to
8. In the balanced equation H2SO4 + XHI H2S + YI2 + ZH2O. The values of X,Y,Z
respectively are
1) X = 3, Y = 5, Z = 2 2) X = 8, Y = 4, Z = 4
3) X = 4, Y = 8, Z = 5 4) X = 5, Y = 3, Z = 4
9. 4g of a sample containing Mg + MgO is treated with excess of dil HCl acid. Then the S.T.P.
volume of H2 gas liberated is 2.24 lit. Then the percentage of 'Mg' metal in the given
sample is
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12. When 2.7g. of Aluminium metal on heating with excess of oxygen, gives how many grams
of alumina ?
1) 2.86 g 2) 5.1 g 3) 2.42 g 4) 10.3 g
13. The period having elements of all blocks and the longest group in periodic table respectively
are
1) 1st , zero 2) 6th , IIIB 3) 7th & IIB 4) 6th , IA
15. Eka silicon belongs to .... and .... in long form of periodic table
1) Group 14 and fourth period 2) Group 14 and third period
3) Group 4 and third period 4) Group 16 and fourth period
16. Assertion (A) : Fluorine atom has less electron affinity than Chlorine atom
Reason (R) : Additional electrons are repelled more strongly by 3p electrons in Chlorine
atom than by 2p electrons in Fluorine atom
1) Both A and R are correct and R is the correct explanation of A
2) Both A and R are correct and R is not the correct explanation of A
3) A is correct, R is false 4) A is false, R is correct
17. The electronic configuration of element (x) in its ground state is [Ar]3d 54s1 . The position of
element just below it in modern periodic table is
1) 4th period ; VI B group 2) 6th period ; VI B group
3) 5th period ; VI B group 4) 4th period ; IV B group
18. Which one of the following is correct
1) EN of Chlorine > EN of Fluorine 2) EA1 of oxygen > EA1 of sulphur
3) EA1 of silicon > EA1 of sulphur 4) EA1 of Chlorine > EA1 of Fluorine
19. The radii of F-1,F, O and O2- are in the order
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l
22. Assertion (1) : For n = 3, may be 0, 1, 2 and m may be 0; (+ 1and 0 ); (+2, + 1 and 0)
l l
Reason (R) : For each value of n, possible values of are 0 to (n-1).For each value of ,
l l
the possible values of m are - ..0.+
1) Both A and R are correct and R is the correct explanation of A
2) Both A and R are correct and R is not the correct explanation of A
3) A is correct, R is false 4) A is false, R is correct
23. In hydrogen atom, the kinetic energy of electron is 82KJ / mole. The distance of that
electron from the nucleus is
1) 2.116A 2) 2.116nm 3) 8.464nm 4) 8.464A
24. The wave number of the 4th line in the Lyman series of hydrogen spectum is
24 25 25R 24R
cm -1 cm -1 cm -1 cm -1
25R 24R 24 25
1) 2) 3) 4)
25 Velocity of electron in 3rd orbit of Li+2 ion is
1) 3 times the velocity of electron in first orbit H-atom
2) 1/3 times the velocity of electron in first orbit H-atom
3) Equal to velocity of electron in first orbit of He+ ion
4) Equal to velocity of electron in second orbit of He+ ion
26. In an atom, the kinetic energy of the electron is 4.55x10 - 25 J. Then its de Broglie wavelength
is
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28. In the radial probability distribution curve for the 2s orbital of the hydrogen atom, the first
maximum, the second maximum and the node respectively occur at the following distances
from the nucleus
1) 1.1A0, 0.53 A0 & 2.6 A0 2) 0.53 A0 ,1.1A0 & 2.6 A0
3) 2.6 A0 , 1.1A0 & 0.53 A0 4) 0.53 A0 , 2.6 A0 &1.1A0
29. The electron configuration of which of the following is not correct
1) 2, 8, 13, 1 2) 2, 8, 18, 1 3) 2, 8, 18, 2 4) 2, 8, 14, 1
30. The difference in angular momentum associated with the electron in two successive orbits
of hydrogen is
h h 3h 3h
2 2
1) 2) 3) 4)
31. Assertion (A) : CuCl is more covalent than KCl
1) 3 2) 5 3) 7 4) 1
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34. Lattice energy of NaCl is X. If the ionic size of A+2 is equal to that of Na+ and B-2 is equal
to that of Cl- , then lattice energy associated with the crystal AB is
1) X 2) 2X 3) 4X 4) 8X
35. If positive ion is present at the body center of the unit cell in FCC lattice, the negative ions
are present .
1) Only at face centers 2) Only at corners
3) Only at the center of edges 4) At corners and also at face centers
36. Identify incorrect statement among the following
1) Ionic nature is in the order of NaCl < KCl < RbCl < CsCl
2) Melting temperature are in the order of NaCl < KCl < RbCl < CsCl
3) Crystal lattice energy is in the order of NaCl > KCl > RbCl > CsCl
4) The co-ordination numbers of metal ions in NaCl = KCl = RbCl < CsCl
37. Assertion (A): BF3 molecule is planar and NF3 molecule is pyramidal in shape
Reason (R): Nitrogen atom is smaller than boron atom
1) Both A and R are correct and R is the correct explanation of A
2) Both A and R are correct and R is not the correct explanation of A
3) A is correct, R is false 4) A is false, R is correct
I-3 I-3
38. The geometrical arrangement of hybrid orbitals in and shape of are respectively
1) Trigonal bipyramidal and linear 2) Octahedral and linear
3) Planar triangular and Planar triangular 4) Tetrahedral, Pyramidal
39. Which of the following statements is not correct from the view point of molecular orbital
theory.
1) Be2 is not a stable molecule 2) He2 is not stable but He+ is expected to exist
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*
2PZ
40. Following molecules of atoms of A and X have SP 3 hybridisation of the central atom A. If
E is the lone pair, bond angle is minimum for
1) AX2E2 2) AX3E 3) AX4 4) Equal in all
41 List-I (Molecules) List-II (overlappings)
The correct match is
1) C2H4 A) p p and sp-p
2) C6H6 B) sp2 sp2, sp2 s and p p
3) PCl5 C) sp2 sp2, sp2 s and sp p
4) CO2 D) sp3d p
1) 1 B 2 C 3D 4A 2) 1B 2C 3A 4D
3) 1 B 2 B 3D 4A 4) 1 B 2A 3C 4D
42. Some statements are given below. Among them, the correct statements are
A) O - hydroxybenzaldehyde is steam volatile
B) P - hydroxybenzaldehyde is more soluble than O-hydroxybenzaldehyde in water
C) The B.P. of O-hydroxybenzaldehyde is greater than that of P-hydroxybenzaldehyde
1) All are correct 2) Only A and B are correct
3) Only B and C are correct 4) Only A and C are correct
43. In a polar molecule, the Ionic charge is 4.8 x 10 10 esu. The Inter Ionic distance is 1A 0. The
Dipolemoment is _____ Debyes
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1 1 2 3 3 3 4 1 5 2 6 3 7 3 8 2 9 4 10 4
11 1 12 2 13 2 14 4 15 1 16 3 17 3 18 4 19 1 20 3
21 4 22 1 23 4 24 4 25 4 26 3 27 3 28 4 29 4 30 2
31 1 32 1 33 3 34 3 35 4 36 2 37 2 38 1 39 4 40 1
41 3 42 2 43 1 44 4 45 3
DPT- 4:
Ph Ph
N N N N
OH OH OH OH
a) b) c) d)
2. A group which deactivates the benzene ring towards electrophilic substitution but directs
the incoming group towards o - and p - positions is
Zn + Alcohol Na 2CH3I
excess A excess B C + 2Nal
3. Westron
c) 1 butyne d) 2 butyne
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Reason (R) : At a temperature of 200 - 400C in presence of silver and air ethylene forms
epoxide
a) Both (A) and (R) are correct. (R) is the correct explanation of (A).
b) Both (A) and (R) are correct. (R) is not the correct explanation of (A).
c) (A) is true, but (R) is false d) (A) is false, but (R) is true
a) b)
CH3
CH3
c) d)
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anhyd. AlCl
3
dark,cold
8. + Excess of chlorine X
10. Assertion (A) : Peroxide effect is observed in the addition of HBr to unsymmetrical
Reason (R) :HBr bond is cleaved by free radical whereas HCl bond is not cleaved
a) (A) is true, but (R) is false b) (A) is false, but (R) is true
c) Both (A) and (R) are correct. (R) is the correct explanation of (A). d)
Both (A) and (R) are correct. (R) is not the correct explanation of (A)
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O
a) b) c) d)
D) Benzene sulphonic acid 4) Zinc dust,
5) Soda lime,
a) A-3, B-4, C-1, D-5 b) A-2, B-5, C-1, D-3 c) A-5, B-4, C-1, D-2 d) A-2, B-4, C-1, D-3
14. Ethylene is reacted with Br2 in CCl4 to form 'x'. When 'x' is reacted with alcoholic KOH
'y' is formed 'x' and 'y' are respectively
15. The formation of product in the following reactions follows Markovnikov's rule
a) CH3CH=CH2 + HBr CH3CHBrCH3 + CH3CH2CH2Br
Major Minor
b) CH3CH=CH2 + HBr CH3CHBrCH3 + CH3CH2CH2Br
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Major Minor
(C H CO) O
6 2
5 2
d) CH3CH=CH2 + HBr CH3CHBrCH3 + CH3CH2CH2Br
Minor Major
16. Which of the following gas decolourises alkaline KMnO 4 but does not give white
precipitate with ammonical silver nitrate ?
17. Polyethene can be produced from calcium carbide by the following reactions
CaC2 + 2H2O Ca(OH)2 + C2H2
C2H2 + H2 C2H4
n(C2H4) (C2H4)n
i)Iodoform + Ag
X redhot iron
ii) X Y
(powder) tube
19.
The correct statement about 'X' and 'Y' are
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b) Both 'X' and 'Y' form white precipitate with Tollen's reagent
a) The straight chain alkenes have higher boiling point than branched chain alkenes
c) Dehydrohalogination of alkyl halides is an example of elimination reaction
45. The type of overlappings involved in the formation of ethyne molecule are
sp 2 s sp 2 sp 2 p p
a) Four , one and one
sp s sp sp p p
b) Two , one and two
sp s sp sp p p
c) Two , two and two
sp 2 s sp 2 sp 2 p p
d) Four , two and one
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11) 12) 13) 14) 15) 16) 17) 18) 19) 20)
21) 22) 23) D 24) B 25) B 26) D 27) B 28) B 29) A 30) D
31) C 32) C 33) B 34) C 35) C 36) A 37) A 38) B 39) B 40) B
41) D 42) C 43) D 44) C 45) B
DPT-5:
46. The ratio of the sp, sp2 and sp3 hybrid orbitals in the compound CH3-CH=CH-CC-CH3
s p
47. The ratio of & bonds in benzene is
C2 H 5
CH 3 CH CH 2 CH CH 3
C2 H 5
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a) Alkyl group on Benzene ring is ortho and para directing because of hyperconjugation
List I List II
B. Violet 2. AgCl
5. AgBr
A B C D A B C D
a) 3 4 1 5 b) 4 1 3 2
c) 3 1 5 2 d) 4 5 1 3
51. In kJehldahls estimation of nitrogen, the ammonia evolved from 0.5gm of an organic compound
neutralized 10ml of 1M H2SO4.The percentage of nitrogen in the compound is
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CH3 CH 2 CH3 2 CH 3 3 C
CH 3 CH
b)
55. Both methane and ethane may be obtained separately in one step from
a) b)
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c) d)
d)
HCl S2Cl2
Zn
C2 H 5Cl A B C.
5000 C
58. Here C is
59. In the chlorination of ethane in the presence of sunlight, which one of the following is also formed
in minute quantity?
60. n- Hexane and n- Heptane, when passed through Cr 2O3 supported over alumina at 6000C
respectively give
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O3 H 2O / Zn
CH3CH=CHCH3 A B
62. Acetylene and Ethylene react with cold and dilute alk.KMnO 4 to respectively give
a)Acetic acid and Ethylene oxide b) Oxalic acid and epoxy ethane
HBr
X (Major)
CH3CH=CH2
HBr/Peroxide
Y (Major)
63.
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Cl
a)NaOH b)Na c)Tollens reagent d)H
66. Which of the following reacts with an aqueous solution of [Ag(NH 3)2]+OH-
a) CH3 CH= CH2 b) CH3 C CH
c) CH3 CH = CH CH3 d) CH3 C C CH3
67. Two organic compounds A and B both containing C and H yield on analysis, the same percentage
composition by weight. A decolourises bromine water but B does not. Which among the following
will be the correct formulae of A and B
A B C D A B C D
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c) IV III I II C) IV I II III
X
Zn
71. The heat of hydrogenation of Benzene is 51K.cal/mole, while its resonance energy is 36K.cal/mole.
Then the heat of hydrogenation of cyclohexene is
C2 H 2
Re
d not
Fe tube
A Fu min g
H 2 SO4
B
72. . In this sequence B is
Cl2 / h
A
C6H6
Cl2 / FeCl3
B
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75. The correct order of reactivity of the following compounds towards electrophilic substitution is
76. When an aqueous solution of sodium acetate is electrolysed, the possible products are/is
a) C2H6 b) CO2 c) NaOH d) All the above
77. The correct order of acidic nature of
A) C2H2 B) CH3 C CH and C) CH3C C CH3 is
a) C>A>B b) B>A>C c) C>B>A d) A>B>C
( H2 )
a) The isotopic abundance of normal hydrogen is 99.98%
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H 2O 40 C
a)The density of is maximum at
H 2O D2O
b)The dielectric constant of is higher than that of
D2O H 2O
c)Ionic product of is higher than that of
NaCl H 2O D2O
d) is more soluble in than in
83. In Clarks method, the substance which is used to remove temporary hardness of water is
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c) Water with 1mg MgSO4 per litre d) all have equal value
I) Al4C3+12D2O 3CD4+4 Al(OD)3 II) SO3+D2O D2SO4
III) SiCl4+2H2O SiO2+4 HCl IV) NaOH+D2O NaOD+ HOD
87. The product obtained at anode, when 50% H2SO4 aq. solution is electrolysed
MnO4
a) FeSO4 / H+ b) KI / H2O c) / H+ d) All the above
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