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P R O P E R T I E S O F NEON
CONTENTS
A. V a p o r Pressure
B. D e n s i t y of S a t u r a t e d V a p o r and L i q u i d
C. C o m p r e s s i b i l i t y Factor
D. Specific H e a t
1. S a t u r a t e d l i q u i d
2. Gas
E. H e a t of V a p o r i z a t i o n
F. E n t h a 1py
G. Thermal Conductivity
1. L i q u i d
2. Gas
H. D i e l e c t r ic C o n s t a n t
1. L i q u i d
2. Gas
I. S u r f a c e Tension of L i q u i d
J. Viscosity
1. L i q u i d
2. Gas
K. V e l o c i t y of Sound
1. G a s
v-INDEX
VAPOR PRESSURE LIQUID NEON
Temperature Pressure
0
K ( atm)
25 0.50366
26 0.70902
27 0.97255
28 1 J037'
29 1.7124
30 2.2088
31 2.8031
32 3 SO61
33 4.3286
34 5 .28ia
3s 6.3773
36 7.6271
37 9.0439
38 10.641
39 12.432
40 14.434
41 ' 16.661
42 19.133
43 21.867
44 24.887
44.4 26.19
V-A-1
30.0
20.0
10.0
h
9.0
i
u)
8.0
n 7.0
u)
E
t
6 .O
0
Y 5.0
w 4.0
az
3
cn
v) 3.0
w
a
a
2.0
az
0
a
a
>
- I - t H W W - H I V A P O R PRESSURE I
M i
ID
0.9
0.8
0.7
0.6
0,s
0.4 I 1 I I I I I I I I
I
I I I I I I I I I I
I
I I 1 1 1 1 1 1 1 1
I
1 1 1 1 1 1 1 1 1
25 30 35 40 45
TEMPERATURE ,OK
V-A- 2
8 DENSITY OF SATURATED VAPOR AND LIQUID NEON
Saturated Saturated
Vapor Liquid
~-
T e m p e r at u r e P
3 4
0
K (g/cm 1 x LO
25 c. 51.019 1.24020
26 69.708 L.. 22370
27 93.109 1.20640
28 121.95 1.18850
29 157.02 , 1.17000
30 199.23 1.15080
31 249.58 1.13100
32 309.26 1.1103~1
33 379.65 1.08880
34 462.43 1.06640
35 559.61 1.04280
36 673.68 1.01800
37 807.73 0.99156
38 965.67 0 -96319
39 1152.6 0.93235
40 1375.5 0.89822
41 1645.1 0.85944
42 1981.6 0.81338
43 2434.5 0.75363
44 3224 .O 0.65096
44.4 4830 .O 0.48300
V-B-1
TEMPERATURE, OK
V-B-2
Z tlOl3Wd ALlllt3ISS3tldW03
SPECIFIC E~EAT( os
~ 0 ) SATURATED -LIQUID NEON
Source of D a t a : G l a d u n , C. "The S p e c i f i c H e , a t a t C o n s t a n t
V o l u m e of L i q u i d N e o n " , C r y o g e n i c s , V o l .g,
27-30 (1966)
Temperature C
(5
0
K
0
joules/g K
25 1.80
26 1.82
I 27 1.85
28 1.88
29 1.92
30 1.96
31 2.01
32 .2.06 '
33 2.12
34 2.19
35 2.27
36 2.36
37 2.47
38 2.58
39 2.77
40 2.97
41 3.27
42 3.77
43 4.96
V-D-1.1
r l l l l l l l l l l l l l l l l l l I l l l l l l r r l l r l l l l l r l 1 1 1 1 1 1 1 1 1 1 1 1 ~
I I 1 I I
25 30 35 40 45 50
TEMPERATURE, O K
V-D-1.2
SPECIFIC HEAT o f CASEOUS WEOES
Pressure
cal
C
-
tal tal
-.-
tal
Atm. .
+3z% @;-mole'K 3
26.25 0.6 5.36 0.266 3 -07 0.152 1.744
26.25 0.4 5.22 0 259 30 0 4 0.151 1.717
26.25 0.2 5.08 0.252 30 0 0 0.149 1.692
26.25
q.80
0.0
1.0
, 4.95
5.55
0.248
0.m5
97
2'-
3 .I4
.
0 147
0.156
1.669
1.n1
27.m 0.8 5 -43 0.269 30 I - l 0.154 1.748
n.80 0.6 5.31 0.263 3 007 0.152 1.726
2a.M 0.4
0.2
5.19
5 -07
0 257
0.251
3 .Oh
3.01 .
0.151
0 149
1.706
1.687
q.@J 0.0
62.54
74.11
0.9784
0.8152
4-95
5.01
4*99
0.245
-
0.248
0 247
2.97
2.99
2.98
.
0.147
0 148
0.148
1.W
1.677
1.673
90.24 0.9581 4.97 0.246 2.97 .
0 147 .
'1 674
170.0
2'73.1
0-9822
0 87!n
4.96
4.96 .
0.246
0 246
-
2.97
2.98
0.147
0.148
1.670
1.668
8 V-D-2.1
S P E C I F I C HEAT , cal / gm-OK
8
HEAT OF VAPORIZATION O F NEON
,.
Temperature
0
K joules/ g
25 88.67
26 87.52
27 86.23
28 84.80
29 83.23
30 81.51
31 ' 79.62
32 77.55
33 75.31
34 72.86
1) 35
36
70.20
67.31
37 64.15
38 ' 60.69
39 56.90
40 52.69
41 47.91
42 42.23
43 34.81
44 22.12
44.4 0
8 V-E-1
* From published data, Advances i n Thennophysical P r o p e r t i e s a t Extrene Temperatures and Pressures, American Society of Mechmical Engineers,
New York (1965) pp 84-97.
Triple point.
N o m 1 boiling point.
Critical point.
FTO
+
( s a t vapo 104.7 91.1 3.369 55.09 91.5 11 09 9.3
25 1011 90.1 4.255 .Eo61
3% -3d.F l. n .BO42 1 1.1 I ,010 .a019 1.4 .oc5
30 1216 95.2 4.447 117.3 93.0 7%;- A 1 112.1 a311
40 1624 105.6 4.744 159.6 104.9 3.784 78.27 104.0 3.486 12.n 95.7 2.m
50 2031 115.9 4.974 201.3 115.4 4.019 99.61 114.8 3.725 18.26 109.7 2.934
60 2439 126.2 5.162 242.6 125.8 4.209 120.6 125.3 3.918 23.01 121.7 3.213 (.
no 3153 146.8 5.455 324.7 146.6 4.508 162.0 146.3 4.?19 64.39 145.4 3.834 31.88 144.0 3.535
90 36 I 3 157.1 5.580 365.6 156.9 4.630 182.5 156.7 4.342 72.75 156.0 3.958 36.17 154.9 3.663
100 4067 167.4 5.683 406.4 167.3 4.739 203.1 167.1 4.451 81.06 166.5 4.069 40.41 165.6 3.776
110 4473 177.7 5.787 447.2 177.6 4.837 223.5 177.4 4.550 89.33 177.0 4.169 44.61 176.2 3.877
120 4883 188.0 5.876 488.0 187.9 4.927 244.0 187.8 4.640 97.58 187.4 4.260 48.79 186.8 3.969
140 5694 208.6 6.035 563.5 208.6 5.086 284.8 208.5 4.800 114.0 208.2 4.420 55.09 207. F, 4.131
160 6507 229.2 6.173 651.0 229.2 5.224 325.6 229.1 4.938 130.4 229.0 4.558 65.35 FP8.7 0.273
180 7321 249.9 $294 732.4 249.8 5.345 366.4 249.8 5.059 146.8 249.7 4.680 73.58 249.5 4.393
200 8134 270.5 0.402 813.8 270.4 5.454 $07.1 270.4 5.168 163.1 270.3 4.789 81.79 270.2 'I ,502
220 894 9 291.1 6.501 855.3 291.0 5.552 447.8 291.0 5.265 179.5 291.0 4.888 89.98 291.0 4.601
240 9761 311.7 6.590 976.7 311.7 5.642 488.6 311.7 5.356 195.8 311.7 4.978 98.15 311.7 I( .691
260 10575 332.3 6.673 058 33R.3 5.724 529.3 332.3 5.438 212.1 332.3 5.060 106.3 537.4 i,.TI4
280 11388 35P.9 6.749 139 352.9 5 .e00 570.0 352.9 5.515 228.4 353.0 5.137 114.5 153.0 11 ,850
300 12201 373.5 6.820 221 373.5 5.871 610.7 373.5 5.586 ,-44.7 373.6 5.208 122.7 373.7 11 ,922
- - -
-- -
- -
- -
Temp
"K
P = 20 atm
( S a t t e r n = 42. K)
-
P = 40 atm P = 60 atm
I =
P = 100 atm
25 .014
I
30
40 .37" ,8450 12.9 .350 .E348 13.8 .312 .a77 15.8 .&
60
50 5% 1.032
2.602
4.856
34.4
79.8
107.4
.970
1.959
2.47~0
.9%6
1.501
34.4
63.0
.E73
1.39b
,9499
1.194
35.2
56.5
,839
1.311
2.873 2.872 96.6 1.W 1.697 82.8 1.731
80 15.66 141.4 3.224 7.623 136.4 2.01 2.679 3.693 iu.6 2.518 2.945 123.7 2.336
148.8 2.6.19 139.2 2.568
I
90 17.91 152.7 3.358 8.833 3.037 2.837 0.315 142.1 3.509
I
100 20.u 163.8 3.475 9.991 la.7 3.162 2.970 5.010 155.3 2.828 4.033 153.1 2.715
110 22.27 174.8 3.57s 11.13 172.2 3.271 7.444 163.9 3.084 5.616 167.8 2.917 4.530 16.1 2.838
120 24.41 185.6 3.673 12.24 183.4 3 * 369 8.208 181.5 3.136 6.204 179.9 3.052 5.01C
140 28.64 206.9 3.838 14.42 :05.5 3.539 9.696 204.2 3.360 7.342 203.1 3.231 5.936
160 32.82 228.1 3.975 16.56 r27.1 3.684 11.15 226.3 3.508 N.45n Z25.6 3.381 G.8p
180 36.98 243.1 4.103 18.68 ~48.5 3.830 12.58 248.0 3.65 3.537 '47.6 3.511 7.7l.l
200 41.12 270.0 4.213 20.7E 269.7 3.922 14.m '69.5 3.749 10.61 'J9.3 3.625 "577
220 45.24 290.9 4.313 4.022 15.40 290.8 3.850 11.6- :'go. 6 3.727 7.131
240 49. 35 311.7 4.403 4.114 16.80 311.9 3.943 1.2.7? 312.1 3.820 10.2E
260 53.46 332.5 4.4% 4.191 18.19 333.0 h.027 u.7e 333.3 3.905 11.1:
280 57.56 353.2 4.563 4.275 19.58 354.0 4.105 14.82 354.5 3.983 11.97
300 61.65 374.0 4.635 4.347 20.96 375.0 375.5 4.056 12.91
-
* 'From published d e b , Advvanc-s i n Thermnphysical Properties e t Extreme Temperatures and Pressures, American Society of Mechanic el Enginoers ,
New York (1'365) pp.84-97.
Bald h o r i z o n t e l line i n d i c a t e s phose change (liquid above, vapor below t h e line).
Conversion0 for Units, t o Equivalent i n B r i t i s h System of Units:
To convert temperature i n degreec Kelvin ("9) t o degresc Rankine ('R) , multiply (OK) by 1.8
To convert pressure i n atmospheres (atm) t o ( p s i = ) , multiply (atm) by 14.6%
To Convert volume (v) i n cubic centimeters per gram (cm"/g) t o (cu f t / l b ) multiply (cm"/g) by .016018
W convert enthalpy (h) in joules per gram (j/g) t o (Eitullb) multiply ( J I B ) by .42993
To convert entropy (s) in loulec. per gram 'K ( j/g'K) t o (Btu)lb'R), multiply ( j/gK) by .23885
V-F-1
v-P- 3
Vnn.UBS.BL
THERMAL CONDUCTIVITY OF LIQUID NEON
Temperature
K
0
25
26
1.17
1.15
1
27 1.13
27 5 1.125
28 1.13
28 5 1.11
29 1.07
30 0.91
V-G-1.1
TEMPERATURE, OK
V-G-1.2
Sources of Data:
Mu, I., 3. mem. ~ y a 1., 19-4 (1948)
.6
Kannuluik, W. 0. E. H., Ppoe. mys. Soc. ( U d o n ) -'
65B
701-9 (1952)
Srivastava, B. 1. aria S 8. C,, phye.
ROC. smr (London) 7 0 ~ -
369-78 (1957)
Thorns, L. B. and C b X i h , R. J. Chm. Phye, 22, 300-5 (1954)
C.,
Weber, S., A m . Physik. 2, 3259 437, 481 (1917)
. .
Weber, S o , Proc Roy. Ac&. S c l Amsterdam 2l, 342 (1919(
Weber, S c 9 Verslag Wetemchappen Amsterdam 26, 1338-53 (1918)
Comments :
Conversiom from 0% t o "K i n the table below are based on a value of
the ice point of 273 .W% used by the Leiden laboratory i n 1917 and 1918.
The disagreement wLth the currently accepted value, 83.15% i s of no
consequence because of the Q ratme dcpndence of thermal
conductivityandtb relative uncertainty of -the conductivity measurements.
-
e 'I
-183 .Og
-183 .Og
90 *4 * 86
4.93
It -- 78.5 1.94 59
198.72
* 8.85
8 979
II
90
- 74937
I1
'I.
4-
Calculat .' Values +
Interpolated values
Presented as Q/K, where KO 11.04 cal/cm-sec-'% a t OC
#-If
f, .20&
-
V-G-2.1
250 300
TEMPERATURE, OK
V-G-2.2
8
Sources of % t a t
Kannuluik, W. 0 . and Ctulaan, E. H., Proc. Phys. SOC. (Mndon) -'65~
701-9 (1952)
Kanuuluik, W. G. and Martin, L. IWOC.., Roy. Soc. (London) A-'l a
496-513 (1934)
-
Weber, S., Ann, mysik. 82, 479-503 (19g)
Conrmcnts :
Values of the! thermal conductivity at 273.09% aad 1 atmosphere are
10.91 x 10-58g-cal/cmsec "K [Bannawitz, E., Ann. Physik. 48, 577-92
(1915)1, 10.92 x 10-5 g-cal/cm 8ec % [Curie M. and L e papy M.,
Compt. rend. 193, 842-3 (1931)], 11.10 x 10-5 g-cal/cm sec 9c
[Kannuluik, W 3 . and C 7,
E. G . , Proc. phys. Bloc. alandon) 65B,
701-9 (1952)1, 11.12 x 10 g-cal/cm 8cc % [Kanpuluik, W. C. r n T
Mwtia, L.
F*
Proc. Roy. Soc. (Mndon),%A
10.87 x 10' g-cal/cm sec IC [Weber, s., ~ert31a.g
496-513 (1934)1, and
~ k a d .~etenschappen
w b r d e m &, 1338-53 (1918)1.
A value of 11.04 x loo5 g-cel/cm sec % given by Weber is consi&red
to be the best value at zT3.Og"K and 1 atmosphere.
I T = 274.79"K 1 T = 373.0gK*
Press . Thermal Cond. Press. Thermal Cond.
cm/@ cell/cm-sec-K cm/Hg cd/cm-sec-OK
67.0 ll.28 x 10-5 75 *07 13.58 x 10-5
67.0 u.28 It 66.43 13 59
55.6 u.29 57 42 13 59 "
42.4 u.29
.
50.I5 13 57
.
tt
I'
30.6 U-30 I1
41 89 13 47 "
19.4 11.30 l1 33.82 13.56
25 56 13.58
17.40 13.60 It
V-G-2.3
DIELECTRIC CONSTANT LIQUID NEQN
T risins T fa1
. T(>K) 8 T (OK) E
26.11
8 V-H-1.1
DIEZECTRIC CONSTANT OF LIQUID NEON
I I
o Run 1
Run 2
Run 3
Run 5
0 Run 6
26 27
T
Dlelectrlc conrtant of llquld neon (24.5-29.8" K)
1.1 80
1.170
- .
1.1 60
1150
' 1140
1.130
1420
1.1 10
T (OK)
V-H-1.2
Sources of Deta:
(1929), The Melectric Constants of Argon and Neon., 2,615-17;
Bryan, A. B.
C.A. e, 1259 (1930).
Phys. Rev.
Watson, E. E., Rao, G. G., end Ramewemy, K. L. (1931), The Dielectric Coefficients of
Gases. Part I. The Rare Gases and Hydrogen., Proc. Roy. SOC. (London) E,
569-85;
C-A. 25, 5320 (1931)-
,
Cuthbertson, C., and Cuthbertson, M. (1932) The Refraction and Dispersion of Neon and
,
Helium. Proc, Roy. SOC, (London) z,
40 j C.A. 26, 2093 (1932).
Using the heterodyne-beat method, Bryan found the value of the dielectric constant for
neon at one atmosphere and OC to be 1.000148 after calibrating his instrument with air
assMling its dielectric constant to be l.000589. Using the same general method, Watson
et al. reported values of 1.000134 and 1.0001346 for OC and 1 atmosphere, determined
from measurements at 25 and -191C respectively. They also report values for 25"C of
1.0001229 determined from measurements at 25OC and 1.0001233 determi,ned from measurement8
at -191C.
Cuthbertson and Cuthbertson report an index of refraction which through the Cauchy
relation is equivalent to a dielectric constant of 1.000133 at OC and 1 atmosphere.
Hector and WoerriLey made a study of dielectric constants primarily to determine whether
there was a marked difference between values obtained by static techniques and by high
frequency techniques. They observed no such difference. Measurements of the dielectric
constant of neon yielded the value of 1.0001274 0.000005 at 0C and 1 atmosphere.
Jeletis concludedthat the wide discrepancies in the data of previous observers are due
i n part, at least, to the neglect of certain stray components in the circuits involved.
He gives values of 1.0001337 and 1.0001341 resulting f r m s i x and five determinations
respectively at S I T (Probably 0 OC and 1 atmosphere).
Reprinted from NBS Report 8252
v-H- 2
SURFACE TENSION of SATURATED LIQUID NEON
Sources of Ddta:
-
Guggenheim, E. A . , J. Chem. Phys. 13, 253-61 (1945)
Van Urk, A. T., Keesom, W. H. and Nijhoff, G. P., Proc.
Acad. S e i . Amsterdam 35, 482-4 (1926)
I Temperature
"K
24
24.8
25
25 07
26 5*15*
26.6 4.99"
27 4.80*
27.4 4.69"
28 4.45
28.3 4.44.n
* Experimental values
* Smqothed values
Taken from WADD TECH.REPQRT 60-56
v-1-1
8
0
v-1-2 8
VISCBSITY OF LIQUID NEON
Tempe r,ature Vi s c o si t y
0
K T (10-3poise
25.09 1.60
27.10 1.24
27.70 1.21
28.10 1.15
28.83 1.08
31.40 0.86
34.50 0.67
38.90 0S O
44.13 0.27
V-J-1.1
TEMPERATURE, OK
V-J-1.2
m c e of Data: EdwaPde, R. s.) P ~ C .ROY. SOC. (London), All9
-'
578-90 (1928); van ItterbeekA. and van Paemel, O . ,
-
Teq Viscosity
Table of Values
Temp e v%S CQ8 ity vi8 COS ity
64.25 10 43
68.52 m.go
.
58.60 9.48 x w"3
n
11
140.0 270.0
273.1
72.11 11.40 81
170.o 21.155. 'I 283.2
72.3
77.37
80 .O 23 $2
8
81
291.1
83 45 23.67 It
291.1
292.6
90.08 210.8 293 -1
90.20 228.0 25.43% '? 296.1
90.3 229.8 26.7 11
298.1
V-3-2 e II
0
In
N
V-3-2.2
v-J-2 s 3
20 40 60
TEMPERATURE, OK
V-J-2.4 8
YISCOSITY of GASEOUS NEON
(Below 1 atmosphere at 20.42OK and go.08'~~)
Source of Data:
Van Itterbeek, A. and Van Paemel, C., Physica, 1,273-83
(1940)
!Fable of Selected V a l u e s
T 20842% T - gO.O8?c
Corrected Observed
viscosity viscosity
Preroure Rrtrrure
Centipoise Centipoise
-@3 -a
300 00
378
9.51
2,186
18149
08 6 0 0
0 -312
0 81528
o .on2
0 80352
080222
o .om83
o 40521
Reprinted from WADD TECH. REPORT 60-56
V-J-2.5
V I S C O S I T Y of
G A S E O U S NEON
Source of Data:
Keesom, W. H. and Van Lammeren, J. A.; Physica I,1161 (1934)
Other References:
Grennspan, M. J.; Acoust. SOC. Am. 28, 644 (1956)
Keesom, W. H. and Van Itterbeek, A.; Proc. Acad. Sci. Amsterdam 33,
440 (1930); Comrmlns. Phys. Lab. Univ. Leiden No. 2Oga (1930)
Shdrzyk, E.; Acta Phys. Austriaca g, 148 (1949)
Van Itterbeek, A. and Mariens, P.; Physica 1,125 (1940)
Van Itterbeek, A. and Thys, L.; Physica 2, 889 (1938)
Comments:
The values of the velocity of sound in gaseous neon are given here as
functions of pressure and temperature for temperatures from 26.25OK
to 273.1K at various pressures between 0 and 0.9825 atmospheres. The
26.25'~isotherm on the plot of the velocity of sound versus pressure
has been terminated at the point of saturation. All the data tabulated
below are from Keesom and Van Lameren listed above under "Sources of
Data".
!he values of velocity of sound by Keesom and Van Lammeren are th.e
average values from measurements at several frequencies in the audible
sound range. The error caused by the resonator (heat conduction and
viscosity) in the experimental apparatus was corrected by means of the
Kircbhoff-Helmholtz formula as reported by Keesom and Van Itterbeek.
No estimate is made of the accuracy of the measurements or the purity
of the neon gas used.
The values of the velocity of sound at 0 pressure were calculated for
the ideal gas , i.e., c = where c is the velocity of sound, R is
the gas constant, T is the temperature and y is the specific heat ratio.
The 26.25'~ isotherm has been terminated at the saturated vapor pressure.
The units of the velocity of sound in neon gas used in the tabulations
below and on the graphs are: temperature in degrees Kelvin (0C =
273.16"~),pressure in atmospheres (g = 8% .665) and the velocity of
sound in meters per second.
(Continued on f o ~ o w i n gpage)
V-K-1.1
VELOCITY of SOUND in GASEOUS NEON (Cont.)
Comments: (cont )
27.80"K 26.25"K
0.9825 134.9 0.6760 131.9
0.8053 135 6 0.5063 132.6
0.6024 136.3 0.4113 133-0
0.4514 136.8 0.2763 133 5
0.2859 137.3
0.1376 138.1
Van Itterbeek and Thys made measurements of the velocity of sound in
neon gas using a sound wave with a frequency of 304.4 kilocycles per
second; whereas Keesom and Van Lammeren had used audible sound. From
these measurements they calculated the value of the velocity of sound
at 0C and l atmosphere pressure in neon gas as 434.9 m/sec, differing
slightly from the value of 4.33.4.
m/sec reported by Keesom and Van
Lammeren. Van Itterbeek and Thys conclude that their own neon contained
a small amount of hydrogen.
Van Itterbeek and Mariens made measurements on carbon dioxide to which
small amounts (0.2%) of neon had been added to study the effect of
this impurity.
Skudrzyk derived relations of absomtion and velocity of sound and com-
pared them with the classical hypothesis of Stokes. The specific be-
havior of helium and neon was also explained.
Greenspan measured the speed and attenuation of sound at 11 megacycles
in helium, neon, argon, krypton, and xenon at various pressures between
atmospheric and a few mm Hg, and compared the results with existing
theories.
Taken from WADD TECH. REPORT 60-56
V-K-1.2
PRESSURE, p s i a
0 2 4 6 8 10 12 14
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452
450
I37
448
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0
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0
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0
0
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w
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438
I33
436
434
I32
0 0.I 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
PRESSURE, atmospheres
V-K-1.3
500
440
400
420
400
300
380
200
360
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c
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V 340 c
aJ 100
0
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280
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u
0
0
-I 100 W
s
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220
'00
200
'00
I80
160
00
I40
V-K-1.4